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SolvaySpecialitiesIndiaPvt.Ltd.,
[SSIPL]

MATERIALSAFETYDATASHEET

Product:DHDPS
DATEISSUED:May20,2006DATEREVISED :01/01/2015
LANGUAGE :EnglishREVNO.

:000
1.CHEMICALPRODUCT&COMPANYIDENTIFICATION
MANUFACTURER/SUPPLIER
SolvaySpecialitiesIndiaPvt.Ltd.,
PlotNo.352627,GIDC,
Panoli,394116,
Dist.Bharuch,
India.
EMERGENCYTELEPHONE
Tel:(O)00912646/272575/272576(Medical)
:(O)00912646/329668/329667(Other)
NONEMERGENCYTELEPHONE
Tel:(O)00912646272578

PRODUCTINFORMATION

PRODUCTDISCRIPTION:4,4DIHYDROXYDIPHENYLSULFONE
CatalogueNumbers

: 146910000,146910050,146915000

Synonyms

: SDP,4,4'Sulfonyldiphenol

CAS#

: 80091

ProductUse

: Monomer,leather,dyestuff,fireretardant

2. COMPOSITION/INFORMATIONONINGREDIENTS
DHDPS(>99%)

DHDPS, MSDS, 20th May 2006, Rev., 003

3. HAZARDSIDENTIFICATION
POTENTIALHEALTHEFFECTS

EYES
: Productmaycauseirritationorinjuryduetomechanicalaction.
SKIN
: Pelletsnotlikelytocauseskinirritation.Maybeharmfulifabsorbedthrough
theskin
INGESTION :Maycauseirritationofthedigestivetract.Maybeharmfulifswallowed.
INHALATION :Maycauserespiratorytractirritation.Maybeharmfulifinhaled

4. FIRSTAIDMEASURES
EYES

: Removecontact lenses. Flush eyes well with copious quantities

ofwaterornormalsalineforatleast15minutes.Seekmedical
attentionifirritationpersists.

SKIN

: Flushskinthoroughlywithwaterandsoap.Removeandwashall
clothing before reuse. Seek medical attention if rash Or burns
occur.

INGESTION

: Seekmedicalattentionifingested.Washmouthoutwithwater.

INHALATION

: Movetowellventilatedarea.Ifnecessary,seekmedicalhelp.

5.FIREFIGHTINGMEASURES
GeneralInformation:
Asinanyfire,wearaselfcontainedbreathingapparatusinpressuredemand,MSHA/NIOSH
(approved or equivalent), and full protective gear. During a fire, thermal decomposition or
combustionmaygenerateirritatingandhighlytoxicgases.

ExtinguishingMedia:
Incaseoffire,usewater,drychemical,chemicalfoam,oralcoholresistantfoam.
6.ACCIDENTALRELEASEMEASURES
GeneralInformation:
UseproperpersonalprotectiveequipmentasindicatedinSection8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section.
Sweepup,thenplaceintoasuitablecontainerfordisposal.
7.HANDLING&STORAGE
Handling:
DHDPS, MSDS, 20th May 2006, Rev., 003

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Washthoroughlyafterhandling.Removecontaminatedclothingandwashbeforereuse.Avoid
contactwitheyes,skin,andclothing.Avoidingestionandinhalation.
Storage:
Storeinacool&dryplace.Keepcontainerclosedwhennotinuse.
8.EXPOSURECONTROLS/PERSONALPROTECTION

EngineeringControls:
Useadequateventilationtokeepairborneconcentrationslow.PersonalProtectiveEquipment
Eyes:Wearsafetyglassesandchemicalgogglesifsplashingispossible.
Skin:Wearappropriateprotectiveglovesandclothingtopreventskinexposure.
Clothing:Wearappropriateprotectiveclothingtominimisecontactwithskin.
Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full facepiece
airlinerespiratorinthepositivepressuremodewithEmergencyescapeprovisions.
9.PHYSICAL&CHEMICALPROPERTIES
PhysicalState

Powder

Appearance

whitelightpink

Odor

Notavailable.

pH

Notavailable.

VaporPressure

Notavailable.

Viscosity

Notavailable.

BoilingPoint

Notavailable.

2481OC

Freezing/MeltingPoint

AutoignitionTemperature :

Notavailable.

FlashPoint

Notavailable.

ExplosionLimits,lower

Notavailable.

ExplosionLimits,upper

Notavailable.

DecompositionTemperature :

Notavailable

Solubilityinwater

Insoluble.

SpecificGravity/Density

Notavailable

MolecularFormula

C12H10O4S

MolecularWeight

: 250.27

10.STABILITY&REACTIVITY

DHDPS, MSDS, 20th May 2006, Rev., 003

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ChemicalStability:
Stableundernormaltemperaturesandpressures.
ConditionstoAvoid:
Incompatiblematerials.
IncompatibilitieswithOtherMaterials:Strongoxidisingagents,strongbases,acidchlorides
andacidanhydrides.
HazardousDecompositionProducts:Irritatingandtoxicfumesandgases.
HazardousPolymerization:Hasnotbeenreported.

11.TOXICOLOGICALINFORMATION
RTECS#:
CAS#80091:SM8925000
LD50/LC50:
CAS#80091:Dermal,guineapig:LD50=>1mg/kg;Draizetest,
rabbit,eye:100mgModerate;Draizetest,rabbit,skin:500mg/24H
Mild;Oral,mouse:LD50=1600mg/kg;Oral,rat:LD50=4556mg/kg;
Skin,rabbit:LD50=>10250mg/kg.

Carcinogenicity:
NotlistedbyACGIH,IARC,NIOSH,NTP,orOSHA.
SeeactualentryinRTECSforcompleteinformation.

12.ECOLOGICALINFORMATION
GENERAL

: Notexpectedtopresentanysignificantecologicalproblems.

13.DISPOSALINFORMATION
Disposeofinamannerconsistentwithfederal,state,andlocalregulations
14.TRANSPORTATIONINFORMATION
IATA
:NotregulatedasahazardousmaterialIMO :Not
regulatedasahazardousmaterial
RID/ADR
:Notregulatedasahazardousmaterial
15.REGULATORYINFORMATION
DHDPS, MSDS, 20th May 2006, Rev., 003

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European/InternationalRegulations
EuropeanLabellinginAccordancewithECDirectives
HazardSymbols:Notavailable.
RiskPhrases:
SafetyPhrases:S24/25Avoidcontactwithskinandeyes.
WGK(WaterDanger/Protection)
CAS#80091:UnitedKingdomOccupationalExposureLimits
Canada
CAS#80091islistedonCanada'sDSLList.
CAS#80091islistedonCanada'sIngredientDisclosureList.
ExposureLimits
USFEDERAL
TSCA:CAS#80091islistedontheTSCAinventory.

16.OTHER
The information above is believed to be accurate and represents the best information
currentlyavailabletous.However,wemakenowarrantyofmerchantabilityoranyother
warranty, express or implied, with respect to such information, and we assume no
liabilityresultingfromitsuse.Usersshouldmaketheirowninvestigationstodetermine
the suitability of the information for their particular purposes. In no way shall the
companybeliableforanyclaims,losses,ordamagesofanythirdpartyorforlostprofits
or any special, indirect, incidental, consequential or exemplary damages, howsoever
arising,evenifthecompanyhasbeenadvisedofthepossibilityofsuchdamages.

DHDPS, MSDS, 20th May 2006, Rev., 003