Revista
de Ciencias Geolgicas, v. 23, nm. 3, 2006, p. 262-276
Weber Mexicana
et al.
Divisin Ciencias de la Tierra, Centro de Investigacin Cientfica y de Educacin Superior de Ensenada (CICESE),
Km. 107 carretera Tijuana-Ensenada, 22860 Ensenada BC, Mexico.
2
Instituto de Geofsica, Instituto de Geologa, Universidad Nacional Autnoma de Mxico,
Ciudad Universitaria, Delegacin Coyoacn, 04510 Mxico D.F., Mexico.
3
Department of Geosciences, University of Arizona, 1040 East Fourth St., Tucson AZ, 85721-0077 U.S.A.
4
Centro de Geociencias, Universidad Nacional Autnoma de Mxico, Campus Juriquilla, 76230 Quertaro, Mexico.
and Department of Geological Sciences, University of Colorado at Boulder, Boulder CO, 80309 U.S.A.
* bweber@cicese.mx
ABSTRACT
The Santa Rosa Formation in the State of Chiapas is a sequence of flysch-type sediments of
Mississippian to Pennsylvanian age. These sedimentary rocks correlate with the Santa Rosa Group of
Guatemala and Belize and crop out along the southern limit of the Maya block north of the Motagua fault,
which is currently considered the border between the North American and the Caribbean plates. Ages of
individual zircon grains from sandstones of the Upper Santa Rosa Formation in southern Mexico were
analyzed by Laser Ablation Multicollector ICPMS and by SHRIMP. The youngest zircon population is of
Silurian age (~420 Ma), but most grains have ages that correspond to the Pan-African-Brasiliano orogenic
cycle (500700 Ma). Other minor populations have ~820 Ma, Grenville (1.01.3 Ga), Mesoproterozoic
(1.41.6 Ga), Paleoproterozoic (1.82.2 Ga), and Archean (2.73.1 Ga) ages. Most of the sediments came
from either present-day West Africa or NE South America, where both Pan-African-Brasiliano orogens
and cratonic landmasses are present. In our model, southwestward progressive collision of Gondwana
with Laurentia during the Alleghanian orogeny resulted in erosion and deposition of flysch-type sediments
to the west, followed by westward movement of the Maya block and adjacent lithosphere.
Key words: provenance ages, zircon, sediments, SE Mexico, Gondwana, Pan-African-Brasiliano.
RESUMEN
La formacin Santa Rosa en el estado de Chiapas es una secuencia de sedimentos tipo flysch de
edad Misispica a Pensilvnica. Estas rocas sedimentarias correlacionan con el Grupo Santa Rosa de
Guatemala y de Belice y afloran a lo largo del lmite sur del bloque Maya al norte de la falla Motagua, la
cual se considera actualmente como el lmite entre las placas de Norteamrica y del Caribe. Se analizaron
edades de zircones individuales de areniscas de la Formacin Santa Rosa Superior en el Sur de Mxico
por ICPMS multicolector con ablacin con lser y con SHRIMP. La poblacin ms joven de zircones es
de edad silrica (~420 Ma), pero la mayora de los zircones tiene edades que corresponden con el ciclo
orognico Pan-Africano-Brasiliano (500700 Ma). Otras poblaciones menores tienen edades de ~820
Ma, del Grenvilleano (1.01.3 Ga), del Mesoproterozoico (1.41.6 Ga), del Paleoproterozoico (1.82.2
263
Ga) y del Arqueano (2.73.1 Ga). La mayora de los sedimentos proviene del oeste de Africa o del este
de Sudamrica, donde se encuentran tanto orgenos con edades del ciclo Pan-Africano-Brasiliano como
cratones precmbricos. En nuestro modelo, la colisin progresiva entre Gondwana y Laurentia durante
la orogenia Alleghaniana result en erosin y deposicin de los sedimentos flyschoides hacia el oeste,
seguido por un movimiento del bloque Maya y la litsfera adyacente en direccin poniente.
Palabras clave: edades de proveniencia, zircn, sedimentos, SE Mxico, Gondwana, Pan-AfricanoBrasiliano.
INTRODUCTION
Since the first reconstruction of Pangea by Bullard et
al. (1965) with overlapping areas between South America
and parts of southern Mexico, the paleogeographic position
of pre-Mesozoic crustal blocks in Mexico, Central America,
and the Caribbean region have been of special interest in
solving the spatial problems posed by the Pangea reconstruction (Ross and Scotese, 1988; Pindell and Barrett, 1990;
Pindell et al., 2000). Southern Mexico and Central America
consist of several blocks with different crustal evolution that
are separated by major fault zones, and hence these crustal
blocks were defined as tectono-stratigraphic terranes whose
origin and relation to each other is uncertain (Campa and
Coney, 1983; Sedlock et al., 1993; Ortega-Gutirrez et al.,
1994). Large scale sinistral strike-slip movements along the
hypothetical Mojave-Sonora Megashear (e.g., Anderson
and Schmidt, 1983), the Trans-Mexican Volcanic Belt (e.g.,
Shurbet and Cebull, 1984), and along the Motagua-Polochic
fault system (e.g., Anderson and Schmidt, 1983; Burkart
and Self, 1985) have been assumed to accommodate the
Mexican terranes and the Chorts block of Central America
prior to the opening of the Gulf of Mexico in Triassic to
Jurassic times. Plate reconstructions on the basis of geological and geophysical constraints have shown that most of the
Mexican terranes reached their present position with respect
to Laurentia after Carboniferous times (Dickinson and
Lawton, 2001). On the other hand, Precambrian (Grenville)
granulite basement, the Oaxaquia micro-continent, which
is thought to underlie most of central and southern Mexico
(Ortega-Gutirrez et al., 1995) and a Permian magmatic arc
which occur along the entire length of Mexico (Torres et
al., 1999), indicate that these crustal blocks were in contact
at least since Permian times. The pre-Mesozoic positions
of all these land masses either as peri-Gondwanan blocks
between Gondwana and Laurentia or as outboard terranes
in the Pacific margin, are important for the understanding
of the late Paleozoic assembly of western Pangea.
Provenance studies of zircons from late Paleozoic
sedimentary rocks in southeastern Mexico provide important arguments (1) to define the paleo-positions of
the crustal blocks prior to the assemblage of Pangea and
(2) to test geologic relations proposed between adjacent
geologic units and crustal blocks. In this paper, we present
264
Weber et al.
NORTH
AMERICA
L
n
ate
chit Fro
Paleozoic Oua a
SA
a)
b)
21
X
I
C
Mrida
PACIFIC
PLATE
CARIBBEAN
PLATE
Map area
Figure 1b
COCOS
PLATE
20
SOUTH
AMERICA
NAZCA
PLATE
19
YUCATN
Gulf of Mexico
BE
L
IZ
E
M A Y A
BLOCK
GUATEMAL
Villahermosa
Tuxtla
Area of Figure 3
Gutirrez
CM
Gulf of
Tehuantepec
t
a Faul
Motagu
16
CHORTS
BLOCK
Guatemala
City
14
EL S
ALVA
DOR
Paleozoic sediments
-93
17
HONDURAS
-94
Caribbean
Sea
MM
MM
CHU
-95
Belmopan
15
Polochic
Polochic
ult zone
Fa
Fault
18
-92
-91
-90
-89
-88
Figure 1. a: Plate-tectonic overview of Central America. b: Simplified geologic map showing pre-Mesozoic rocks exposed in southeastern Mxico and
Central America (modified after Ortega-Gutirrez et al., 1992, and French and Schenk, 1997). Abbreviations: CM: Chiapas Massif, CHU: Sierra de
Chuacs, MM: Maya Mountains.
265
248 Ma
Chiapas
Guatemala
Belize
Hernndez-Garca,
1973
Russel and
Burkart, 1971
Paso Hondo
Chochal
U
Permian
M
L
Grupera
290 Ma
Pennsylvanian
Upper
* Santa Rosa
Esperanza
Tactic
Chicol
323 Ma
Mississippian
Macal
Series
Maya
series
problematic (Donelly et al., 1990). The metamorphic basement of the Chorts block is overlain by a thick sequence of
Mesozoic sedimentary rocks, somewhat different from the
Mesozoic sequence in the Maya block (e.g., Dengo, 1985,
and references therein).
???
Lower
Santa Rosa
???
???
Limestone, dolomite
Shale, siltstone, sandstone, flysch
Volcanic
Conglomerate
Discordance
/ gap
266
Weber et al.
1600
Chicomuselo
CB55
SR01
Custepec
HIC
OC
POL ULT
FA
Mapastepec
1530
Mex
200
Motozintla
N
G
U
10km
A
T
A
A
an
ce
O
IC
fic
ci
Pa
Huixtla
1500
9300
9230
Triassic-Jurassic sandstones
(Todos Santos Formation)
Permian limestones and siltstones
(Paso Hondo Formation)
9200
Thrust
Figure 3. Simplified geologic map of eastern Chiapas (modified after the geologic map 1:250,000 Huixtla D-15-2, Jimnez-Hernndez et al., 2005),
showing sample locations. Note: Outline of the Lower Santa Rosa Formation was inferred from a sketch map of Hernndez-Garca (1973) and confirmed
by own reconnaissance at the locality marked by grey arrow.
267
268
Weber et al.
Table 1. LA-MC-ICPMS U-Th-Pb data of detrital zircons from Santa Rosa sandstone sample CB55, Chicomuselo, Chiapas. Longitude: -92.2845W,
latitude: 15.7554N.
Grain spot
(1)
CB55-1
CB55-3
CB55-4
CB55-5
CB55-7
CB55-8
CB55-9
CB55-10
CB55-11
CB55-12
CB55-13
CB55-14
CB55-15
CB55-16
CB55-17
CB55-18
CB55-19
CB55-20
CB55-21
CB55-22
CB55-23
CB55-24
CB55-26
CB55-27
CB55-28
CB55-29
CB55-30
CB55-31
CB55-32
CB55-33
CB55-34
CB55-35
CB55-36
CB55-37
CB55-38
CB55-39
CB55-40
CB55-41
CB55-42
CB55-43
CB55-44
CB55-45
CB55-46
CB55-47
CB55-49
CB55-50
CB55-51
CB55-54
CB55-55
CB55-56
CB55-57
CB55-58
CB55-60
CB55-61
CB55-62
CB55-63
CB55-64
CB55-65
CB55-66
CB55-67
CB55-68
206
Pb/204Pbc
U
ppm
Th
ppm
27
103
116
101
182
183
117
159
407
201
131
61
571
110
179
92
68
31
635
182
26
77
211
160
232
275
113
431
136
314
228
44
300
102
141
301
284
254
146
150
61
100
58
249
93
281
30
124
240
222
394
107
127
94
417
402
628
126
100
126
271
34
63
106
75
81
176
100
91
123
117
96
40
306
36
160
81
12
29
97
157
18
65
37
107
186
140
91
160
54
282
129
34
174
75
101
189
75
68
53
81
73
103
37
30
37
184
14
103
148
239
370
131
85
45
319
289
53
80
46
146
309
232
Th/238U
Pb*/235U 1
%
207
206
Pb*/238U 1
%
(2)
909
3508
1025
948
11464
12372
1677
7568
23268
4124
3897
5758
12770
821
5305
1326
2126
5419
6991
6096
1085
1991
1984
2074
3223
6708
2662
22353
7621
3250
2926
1546
2575
698
1708
4092
2143
5435
1944
1698
712
1075
3113
8311
2795
14950
830
3887
2796
2216
3187
2167
1482
10304
3626
3235
2930
5085
2145
1497
3068
%
disc
Err
corr
(3)
1.25
0.61
0.91
0.74
0.44
0.96
0.85
0.57
0.30
0.58
0.73
0.65
0.54
0.33
0.90
0.89
0.17
0.91
0.15
0.87
0.71
0.85
0.18
0.67
0.80
0.51
0.81
0.37
0.40
0.90
0.56
0.77
0.58
0.73
0.72
0.63
0.27
0.27
0.37
0.54
1.19
1.03
0.64
0.12
0.40
0.65
0.45
0.83
0.61
1.08
0.94
1.22
0.67
0.48
0.77
0.72
0.09
0.63
0.45
1.16
1.14
4.2184
1.2906
0.6690
0.3110
2.2600
0.8306
0.8770
0.8436
1.8792
0.7385
0.8922
7.0066
0.5308
0.8533
0.6662
0.6166
5.4783
3.2506
0.5776
0.7180
0.7936
0.7183
0.9403
0.7909
0.6677
0.8047
0.7500
13.5601
3.0221
0.8626
0.4769
0.6576
0.6418
0.7092
0.7252
0.8776
0.6692
0.6938
1.5506
1.1464
0.7350
0.3014
1.9838
0.8791
1.2748
0.8167
0.8330
0.7867
0.7680
0.6677
0.6561
7.0791
0.5892
5.5264
0.5086
0.7177
0.6762
2.8429
1.1950
0.4867
0.8581
5.4
4.9
7.7
10.9
0.7
3.0
4.4
3.0
2.4
2.7
4.1
1.5
2.9
13.5
4.6
6.3
4.0
4.8
1.8
4.8
12.4
6.6
2.9
4.5
2.1
2.5
4.6
2.8
1.4
2.5
4.4
15.0
2.4
8.8
4.6
2.1
3.3
3.6
1.7
2.2
12.6
11.9
4.4
2.3
2.9
2.7
12.9
3.3
7.5
3.4
2.6
2.0
3.7
1.8
2.1
2.6
2.1
2.2
3.5
7.3
2.3
0.27780
0.13796
0.07927
0.04623
0.20342
0.10279
0.09843
0.09606
0.17539
0.08701
0.10550
0.37768
0.06682
0.09330
0.08290
0.07466
0.31657
0.25564
0.07045
0.08837
0.08543
0.08682
0.11618
0.09703
0.08398
0.10138
0.08886
0.41523
0.24695
0.10686
0.06620
0.09713
0.08250
0.09574
0.08885
0.10752
0.08196
0.08515
0.16034
0.12929
0.08846
0.04964
0.18658
0.10395
0.13275
0.09639
0.10140
0.09721
0.08983
0.08547
0.08608
0.39167
0.07792
0.31354
0.06871
0.08905
0.08333
0.24022
0.14167
0.06660
0.10189
3.5
3.1
0.4
2.0
0.4
0.6
2.3
0.5
2.3
0.9
3.2
0.8
0.9
1.5
1.1
1.5
0.9
1.3
1.1
1.0
2.1
2.8
0.4
1.2
0.5
1.2
1.1
2.4
0.4
1.4
1.0
2.3
1.5
0.8
1.1
0.4
1.2
0.6
0.6
0.5
1.3
0.7
1.4
0.6
1.2
1.4
1.7
1.5
1.8
0.6
0.9
0.4
1.1
1.1
0.4
1.8
1.4
1.8
1.8
1.4
0.7
12
13
0
28
-2
-3
-1
15
-4
0.65
0.62
0.06
0.18
0.54
0.19
0.51
0.17
0.96
0.34
0.77
0.51
0.31
0.11
0.24
0.23
0.23
0.27
0.59
0.20
0.17
0.42
0.14
0.26
0.23
0.48
0.24
0.89
0.29
0.57
0.23
0.15
0.64
0.09
0.24
0.19
0.35
0.17
0.36
0.21
0.10
0.06
0.33
0.27
0.43
0.53
0.13
0.44
0.24
0.18
0.37
0.19
0.30
0.62
0.17
0.68
0.70
0.79
0.50
0.19
0.32
Apparent ages
Pb/ U
(Ma) 1
(4)
206
1580
833
492
291
1194
631
605
591
1042
538
647
2065
417
575
513
464
1773
1467
439
546
528
537
709
597
520
623
549
2239
1423
654
413
598
511
589
549
658
508
527
959
784
546
312
1103
638
804
593
623
598
555
529
532
2131
484
1758
428
550
516
1388
854
416
625
238
49
24
2
6
4
3
13
3
22
5
20
14
4
8
6
7
14
17
4
5
10
14
3
7
2
7
6
46
5
9
4
13
7
4
6
2
6
3
6
3
7
2
14
4
9
8
10
8
10
3
5
7
5
17
1
9
7
22
14
6
4
207
Pb/235U
(Ma) 1
1678
842
520
275
1200
614
639
621
1074
562
648
2112
432
626
518
488
1897
1469
463
549
593
550
673
592
519
599
568
2719
1413
632
396
513
503
544
554
640
520
535
951
776
559
267
1110
640
835
606
615
589
579
519
512
2121
470
1905
417
549
524
1367
798
403
629
44
28
31
26
5
14
21
14
16
12
20
13
10
64
19
24
34
37
7
20
56
28
14
20
9
12
20
26
11
12
14
61
9
37
20
10
13
15
11
12
54
28
29
11
16
12
60
15
33
14
10
17
14
16
7
11
8
17
19
24
11
Pb/206Pb
(Ma) 1
(4)
207
1802
864
647
138
1211
553
762
732
1139
659
651
2158
515
817
540
600
2036
1472
584
565
849
604
556
571
517
513
647
3099
1399
550
296
153
469
359
574
574
575
571
932
752
613
-109
1124
651
918
655
588
556
674
478
423
2113
406
2068
358
547
562
1334
646
329
642
74
80
166
255
12
63
80
63
13
54
57
23
60
285
98
133
69
88
31
103
257
130
62
95
46
49
97
20
26
44
97
355
40
200
98
45
67
78
34
46
275
295
82
48
53
49
282
65
156
74
53
34
78
26
47
42
32
27
66
163
48
269
206
(1)
CB55-70
CB55-71
CB55-72
CB55-74
CB55-75
CB55-76
CB55-77
CB55-78
CB55-79
CB55-80
CB55-82
CB55-84
CB55-85
CB55-86
CB55-87
CB55-88
CB55-89
CB55-90
CB55-91
CB55-92
CB55-93
CB55-95
CB55-96
CB55-97
CB55-98
CB55-99
Pb/204Pbc
U
ppm
Th
ppm
105
139
108
528
395
98
159
544
290
60
299
201
262
172
353
216
98
143
58
133
13
50
111
76
79
311
113
124
169
184
509
69
47
275
256
24
131
105
75
76
118
311
64
170
36
103
47
37
118
54
60
220
232
Th/238U
207
Pb*/235U 1
%
206
Pb*/238U1
%
(2)
3085
1533
3154
7567
7769
4085
7254
4246
20779
3895
4413
1379
8403
2644
20149
3477
3418
3405
4855
13411
690
1072
2022
3587
5112
10159
%
disc
Err
corr
(3)
1.07
0.89
1.57
0.35
1.29
0.70
0.29
0.51
0.88
0.39
0.44
0.52
0.29
0.44
0.33
1.44
0.66
1.19
0.63
0.78
3.59
0.75
1.06
0.71
0.75
0.71
0.6726 3.1
0.7139 6.1
0.7535 3.9
0.8436 1.5
0.8568 1.5
0.7116 5.1
1.7523 1.6
0.5364 2.3
13.8604 2.3
2.4700 3.3
0.6732 2.5
0.4737 5.7
2.2838 2.1
0.4693 5.6
1.3171 1.0
0.8278 5.3
0.6547 9.6
0.7086 3.4
2.0737 4.7
5.3820 0.8
1.5215 21.8
0.9536 10.9
0.7409 4.3
1.1931 6.5
2.7385 2.4
0.8304
2.6
0.09343
0.08734
0.10312
0.10161
0.10352
0.08813
0.17385
0.07420
0.52280
0.22352
0.08459
0.06641
0.19717
0.06331
0.14002
0.09726
0.08280
0.09425
0.20371
0.33886
0.12165
0.09783
0.09746
0.11929
0.21812
0.10113
1.0
2.0
1.5
0.6
0.9
0.6
0.6
1.5
2.2
0.6
1.0
1.4
1.4
1.0
0.4
1.8
0.9
0.7
0.8
0.4
2.6
2.4
0.8
4.4
0.4
1.1
-2
2
-8
10
-15
0
12
0.32
0.32
0.39
0.39
0.63
0.11
0.38
0.67
0.98
0.19
0.42
0.24
0.68
0.17
0.43
0.34
0.10
0.22
0.17
0.48
0.12
0.22
0.20
0.67
0.15
0.41
Apparent ages
Pb/ U
(Ma) 1
(4)
206
576
540
633
624
635
544
1033
461
2711
1300
523
414
1160
396
845
598
513
581
1195
1881
740
602
600
727
1272
621
238
5
10
9
3
6
3
6
7
50
7
5
6
15
4
3
10
5
4
9
6
18
14
5
30
4
6
207
Pb/235U
(Ma) 1
522
547
570
621
628
546
1028
436
2740
1263
523
394
1207
391
853
612
511
544
1140
1882
939
680
563
797
1339
614
13
26
17
7
7
22
10
8
22
24
10
18
15
18
6
24
39
14
32
7
137
54
19
36
18
12
Pb/206Pb
(Ma) 1
(4)
207
294
578
329
611
604
551
1017
304
2762
1201
519
274
1293
361
875
665
505
393
1037
1883
1441
949
418
1001
1448
587
68
126
82
30
25
112
30
39
7
64
50
126
30
125
18
107
212
75
94
13
434
221
94
98
45
51
(1): Sample identifier, spot number [missing numbers: spots were omitted due to high analytical errors]; (2): Isotope ratios corrected for common Pb using
measured 204Pb for correction. Individual errors are given as 1 sigma standard deviation; (3): Deviation of 206Pb/238U age relative to 207Pb/206Pb age is given
only if 207Pb/206Pb age is considered as the most reliable apparent age. Positive values are for normal discordance, negative values for inverse discordance;
(4): Most reliable apparent ages are in bold letters. Note: If the average of apparent ages is mid-Proterozoic and older (>900 Ma) then 207Pb/206Pb ages
are considered as most reliable apparent ages; for younger values 206Pb/238U ages are used.
270
Weber et al.
Table 2. SHRIMP-RG U-Th-Pb data of detrital zircons from Santa Rosa sandstone sample SR1, Motozintla-Chicomuselo highway, Chiapas: long. 93.2306, lat. 15.7172.
Grain
spot
Th 232Th
Pbc U
% ppm ppm /238U
206
Pb*
ppm
206
207
Pb*/206Pb*
1 %
Pb*/235U
1 %
207
Pb*/238U
1 %
206
% Err
disc corr
Apparent ages
Pb/ U
(Ma) 1
(6)
206
(1)
SR1-01
SR1-02
SR1-03
SR1-04
SR1-05
SR1-06
SR1-07
SR1-08
SR1-09
SR1-10
SR1-11
SR1-12
SR1-13
SR1-14
SR1-15
SR1-16
SR1-17
SR1-18
SR1-19
SR1-20
SR1-21
SR1-22
SR1-23
SR1-24
SR1-25
SR1-26
SR1-27
SR1-28
SR1-29
SR1-30
SR1-31
SR1-32
SR1-33
SR1-34
SR1-35
SR1-36
SR1-37
SR1-38
SR1-39
SR1-40
SR1-41
SR1-42
SR1-43
SR1-44
SR1-45
SR1-46
SR1-47
SR1-48
SR1-49
(2)
(3)
(4)
0.0539
0.0542
0.056
0.0531
0.0712
0.0817
0.0545
0.0606
0.0603
0.0559
0.0603
0.0607
0.0572
0.0448
0.0665
0.1318
0.0487
0.0578
0.084
0.088
0.0594
0.0528
0.0712
0.0578
0.0555
0.1155
0.0569
0.06375
0.0506
0.16275
0.0569
0.0705
0.0537
0.0634
0.1202
0.18611
0.0884
0.0623
0.0967
0.0648
0.1791
0.06016
0.05615
0.0563
0.10763
0.0899
0.13031
0.0873
0.1211
(4)
2.6
4.9
3.4
5.6
1.6
1.3
8.1
2.2
2.2
2.3
2.8
1.7
2
17
7.3
1.2
11
4.6
2.4
2
2.2
5.5
3.7
1.9
5.2
1.1
2.5
1.5
9
0.6
3.8
6.7
2.2
5.7
1.4
0.4
1.9
2.7
1.7
3.6
1
1.6
1.5
4.5
0.8
1.6
0.5
1.2
1.8
0.452
0.499
0.685
0.492
1.592
2.401
0.661
0.798
0.833
0.496
0.725
0.81
0.514
0.534
1.37
6.09
0.601
0.792
2.357
2.839
0.717
0.458
1.606
0.743
0.673
5.45
0.696
0.91
0.606
7.61
0.713
0.832
0.421
0.889
5.95
12.35
3.022
0.943
1.885
0.845
12.49
0.793
0.55
0.796
4.362
3.086
6.81
2.08
5.68
(4)
3.3
5.4
4
6
2.6
2.5
8.5
3
3.1
3.1
3.6
2.7
2.9
17
7.7
2.4
12
5.2
3.2
3
3
5.8
4.5
2.8
5.7
2.4
3.3
2.6
9.3
2.1
4.4
7.1
2.9
6.2
2.7
2
3
3.5
2.6
4.2
2.5
2.6
2.5
5.1
2.2
2.8
2
2.3
2.7
0.0608
0.0667
0.0888
0.0673
0.1623
0.2133
0.088
0.0955
0.1001
0.0643
0.0873
0.0967
0.0652
0.0864
0.1491
0.3351
0.0894
0.0994
0.2035
0.2339
0.0876
0.0629
0.1635
0.0933
0.088
0.3424
0.0888
0.1035
0.0869
0.3393
0.0908
0.0857
0.057
0.1016
0.3587
0.4814
0.2478
0.1096
0.1413
0.0945
0.506
0.0956
0.0711
0.1026
0.2939
0.2489
0.3788
0.1728
0.3404
(5)
2
2.2
2.1
2.3
2.1
2.1
2.5
2
2.1
2.1
2.2
2
2.1
2.7
2.6
2.1
2.5
2.3
2.2
2.3
2.1
2
2.5
2
2.3
2.1
2.1
2.1
2.4
2
2.3
2.4
2
2.4
2.3
2
2.3
2.1
2
2.2
2.3
2
2
2.4
2
2.2
2
2
2.1
-1
-1
14
8
2
-1
-1
32
-1
7
-2
83
0
6
-1
2
33
4
.622
.403
.521
.373
.795
.840
.292
.685
.685
.668
.616
.764
.719
.160
.334
.869
.213
.443
.682
.762
.698
.347
.563
.726
.408
.890
.644
.800
.254
.956
.519
.339
.673
.380
.853
.984
.760
.614
.763
.514
.913
.779
.800
.471
.936
.806
.972
.855
.758
381
416
548
420
969
1246
543
588
615
402
539
595
407
534
896
1883
552
611
1194
1355
541
393
976
575
544
1898
548
635
537
1863
560
530
357
624
1976
2533
1427
671
852
582
2638
588
443
629
1661
1433
2071
1028
1889
238
8
9
11
9
19
23
13
11
12
8
12
12
8
14
22
33
13
13
24
28
11
7.7
23
11
12
35
11
12
12
34
12
12
7
14
39
41
29
14
16
12
49
11
8.6
14
30
29
35
19
34
Pb/206Pb
(Ma) 1
(6)
207
366
381
451
331
962
1237
390
625
615
450
613
629
498
-66
821
2122
135
523
1292
1383
582
322
964
522
433
1887
486
733
221
2484
489
942
357
722
1960
2708
1392
686
1562
769
2645
609
458
463
1760
1424
2102
1367
1972
58
110
76
130
33
26
180
47
48
51
61
37
44
410
150
21
270
100
46
37
47
120
75
42
120
20
55
33
210
10
83
140
49
120
25
6
37
58
32
76
17
35
34
100
14
31
9
23
32
Pb/232Th
(Ma) 1
(6)
208
388
416
547
408
1063
1239
496
604
630
406
598
611
413
419
876
1968
496
564
1302
1437
543
385
965
600
536
1918
568
585
532
1795
557
567
335
670
1946
2538
1490
729
828
616
2580
603
456
635
1777
1404
2087
1052
1820
11
22
16
15
66
35
33
15
24
22
34
15
11
60
39
59
36
37
51
48
14
11
44
14
24
48
14
35
29
73
19
21
12
32
53
67
45
25
23
23
74
14
15
25
41
51
43
27
51
(1): Sample identifier, spot number; (2): Contribution of common 206Pb to total 206Pb in %; (3): Concentration of radiogenic (*) lead 206Pb; (4): Isotope ratios
corrected for common Pb using measured 204Pb for correction. Individual errors are given as 1 sigma standard deviation; (5): Deviation of 206Pb/238U age
relative to 207Pb/206Pb age is given only if 207Pb/206Pb age is considered as most reliable apparent age. Positive values are for normal discordance, negative
values for inverse discordance; (6); Apparent ages and all other corrections calculated with SQUID1.11 (Ludwig 2001). Most reliable apparent ages are
in bold letters. Note: If the average of apparent ages is mid-Proterozoic and older (>900 Ma) then 207Pb/206Pb ages are considered as most reliable apparent
ages, for younger values 206Pb/238U ages are used.
271
a)
2800
LA-MC-ICPMS
CB55
2400
2000
b)
c)
25
Figure 5
best age
588
659 624
10
5
200
600
2200
3000 Ma
3111
1400
2759
600
2159
1876
800
15
782
844
959
1144
1214
1435
1200
412
Relative probability
0.25
number
20
1600
0.15
30
544
0.35
206
P b /238 U
0.45
0.05
0
6
207
Pb/
235
10
12
14
Figure 4. (a) Concordia diagram for U-Pb isotope ratios of zircons from sample CB55 measured by LA-MC-ICPMS. Error ellipses of individual spots
are 2. (b) relative probability and (c) histogram plots of best ages for zircons analyzed. As best ages we defined 206Pb/238U apparent ages for average
apparent ages <900 Ma and 207Pb/206Pb apparent ages for average apparent ages >900 Ma.
are of late Archean age. A group of five grains have apparent 207Pb/206Pb ages between 1.9 and 2.1 Ga, and another
measurement yielded a 207Pb/206Pb age of 1.76 Ga. Three
concordant grains are about 1.4 Ga old, and another discordant zircon has a similar 207Pb/206Pb age. Each of the
1.2 to 1.3 Ga and the 0.95 to 1.0 Ga Grenville-type ages
are represented by two concordant grains. About half of the
analyzed spots yielded Pan-African-Brasiliano ages between
500 and 700 Ma. Two groups of concordant zircons yielded
mean 206Pb/238U ages of 629 21 Ma (2, group 3, Figure 6)
and 558 7 Ma (2, group 2, Figure 7). Another group of
seven zircons (group 1, Figure 7) yielded a mean 206Pb/238U
age of 416 19 Ma (2).
DISCUSSION
The U-Pb zircon data presented here clearly show
that the main source area of detrital components for the
sandstone samples from the Upper Santa Rosa Formation
at Chicomuselo is dominated by the Pan-African-Brasiliano
orogenic cycle. This source includes rocks with ages of
~630 Ma, 540560 Ma, ~520 Ma and, in a broader sense,
also a less pronounced population of ~820 Ma. There are
no outcrops of igneous and metamorphic rocks of any of
those ages known from Mexico and Central America that
may be considered as the local source of sediments for
272
Weber et al.
206
LA-MC-ICPMS
CB55
900
880
650
840
860
820
630
800
610
780
590
760
Mean =
816 41 Ma
MSWD = 43 (2)
0.15
data-point error ellipses are 2 sigma
850
Group 4
0.13
Group 5
750
629.0 9.6 Ma
0.11
650
206
Pb /
238
816 47 Ma
550
0.09
Group 3
544.7 6.0 Ma
450
0.07
Group 2
521.0 7.0 Ma
Group 1
350
422.0 12.4 Ma
0.05
0.4
0.6
0.8
207
206
440
Group 1: Silurian
540
1.0
Pb /
235
Group 2: Pan-african I
Group 3: Pan-african II
530
420
560
520
410
540
510
400
380
1.4
580
430
390
1.2
520
500
Mean = 422 12 Ma
MSWD = 16 (2)
490
500
Figure 5. Lower part of concordia diagram for U-Pb isotope ratios of zircons from sample CB55 measured by LA-MC-ICPMS. Error ellipses of individual
spots are 2. Mean 206Pb/238U ages calculated from the respective group of spots marked by filled dots in the Concordia diagram include a systematic error
of 0.9% and are given at 2 level. 2 error bars of 206Pb/238U apparent ages of individual spots and weighted means calculated from zircon populations
Group 1 to Group 5 without systematic error.
273
a)
2800
SHRIMP-RG
SR01
2400
2000
Fig. 7
1400
2200
3000
2708
600
1768
1974
2104
800
8
4
1255
1393
0.15
12
988
1200
421
636 605
Relative probability
0.25
c)
16
number
b)
1600
559
0.35
206
P b /238 U
0.45
0.05
0
6
207
10
12
14
Pb/ 235 U
Figure 6. (a) Concordia diagram for U-Pb isotope ratios of zircons from sample SR01 measured by SHRIMP-RG. Error ellipses of individual spots are
2. (b) relative probability and (c) histogram plots of best ages for zircons analyzed. As best ages we defined 206Pb/238U apparent ages for average apparent
ages <900 Ma and 207Pb/206Pb apparent ages for average apparent ages >900 Ma.
500 Ma (e.g., Veevers, 2003). Circum-cratonic convergence and collision of the West African craton started in
the Bassarides-Mauritanides (BA, Figure 8) of present-day
West Africa at 665655 Ma, progressing clockwise around
the craton, arriving at the Brasiliano belt (BR, Figure 8) at
600550 Ma, and finally at the Rokelides (R, Figure 8) with
ages from 547500 Ma in West Africa (e.g., Doblas et al.,
2002) and Florida (e.g., Hatcher, 2002). The Brazilide Ocean
was closed at 650600 Ma, followed by intracontinental
convergence that culminanted at ~550 Ma during the final
assemblage of Western Gondwanaland (e.g., Alkmin et al.,
2001). Taking into consideration these models, the most
probable source regions for the Pan-African-Brasiliano zircons of the Upper Santa Rosa Formation are West Africa and
northeastern South America. Archean (2.63.1 Ga) zircons
and more abundant Paleoproterozoic (1.82.2 Ga) populations probably came either from the northern Amazonian or
West African cratons, indicating similar source regions as
for the Pan-African-Brasiliano zircons. In Florida, detrital
zircons from a subsurface sandstone sample have main
age populations of (1) 515 to 637 Ma and (2) 1.9 to 2.3 Ga
(Mueller et al., 1994), indistinguishable from our present
zircon age data and indicating a similar provenance for the
Florida sedimentary basement and the Upper Santa Rosa
Formation.
Zircons of Mesoproterozoic (1.41.6) and Grenville
274
Weber et al.
data-point error ellipses are 2 sigma
0.12
SHRIMP-RG
SR01
750
750
Group 3
629 21 Ma
650
650
238
0.10
206
Pb /
550
550
Group 2
0.08
558 7 Ma
450
450
Group 1
0.06
416 19 Ma
350
350
0.04
0.2
0.4
0.6
207
206
Group 1: Silurian
460
440
420
Mean = 416 19 Ma
MSWD = 8.5, (2s)
Pb /
1.0
600
Mean = 558 7 Ma
MSWD = 0.5, (2s)
580
560
540
520
1.2
Group 2: Pan-african I
400
380
0.8
235
Group 3: Pan-african II
720
700
680
660
640
620
600
580
560
Mean = 629 21 Ma
MSWD = 6.0, (2s)
Figure 7. Lower part of concordia diagram for U-Pb isotope ratios of zircons from sample SR01 measured by SHRIMP. Error ellipses of individual spots
are 2. Mean 206Pb/238U ages calculated from the respective group of spots marked by filled dots. 2 error bars of 206Pb/238U apparent ages of individual
spots and weighted mean age calculated from zircon populations Group 1 to Group 3.
LAURENTIA
(Mexico)
(USA)
D
?
Proto Pacific
ocean
Oax
Ac
Cho
Amazonia
Amazonia
CA
CA
Late
Carboniferous
West
Africa
SM
A
D
W
BR
Craton
Plate
movement
ACKNOWLEDGEMENTS
This work was supported by CONACYT project
D41083-F and DFG/BMZ collaboration project HE2893/41. Many thanks to Susana Rosas-Montoya, Victor PrezArroyoz, and Gabriel Rendn-Mrquez (CICESE) for their
help with preparing the zircon separates. Many thanks go to
Teodoro Hernndez-Trevio (UNAM) for sample preparation. We are grateful to Joe Wooden and Wayne Premo (both
USGS) for assistance with running the SHRIMP-RG at
Stanford University and to George Gehlers and Joaquin Ruiz
for their assistance with running the LA-MC-ICPMS and
data reduction at University of Arizona, Tucson (NSF EAR0443387). We thank Alfred Krner (University of Mainz)
and Luigi Solari (UNAM) for their helpful reviews.
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Manuscript received: March 14, 2006
Corrected manuscript received: July 3, 2006
Manuscript accepted: July 7, 2006