Although alum and iron salts are the most widely used chemical coagulants for community drinking water
treatment, other coagulants have been and are being used to coagulate household water at point of use,
including alum potash, crushed almonds or beans and the contents of Moringa and Strychnos seeds. Table
12 lists some the coagulants that have been and are being used for water treatment at the community and
household level, their advantages and disadvantages and their costs.
Table 12. Chemical coagulants for water treatment and their advantages, isadv
Community/Household
Coagulant Advantages Disadvantages Cost* Comments
Use
Same as Alum;
Lime (Ca(OH2)),
pH control and Softeners;
lime+soda ash
neutralization a Moderate to not
(Na2CO3), Yes/rare-moderate Same as Alum
problem; high? applicable to
caustic soda
hazardous many waters
(NaOH)
chemicals
Same as Alum;
Use with
Improve hard to dose;
other
Soluble synthetic coagulation need training &
Yes/no-rare High coagulants;
organic polymers with alum and equipment;
limited
iron salts hazardous
availability
chemicals
Natural polymers
(carbohydrates)
Rare/Yes
from seeds, nuts,
beans, etc.
Source plant
required; Traditional
(in some Effective, available and training and use based
developing culturally accepted in skill required; Low on
countries) some places cultural historical
acceptability; practices
may be toxic
*Estimated Annual Cost: low is 0.01 per liter (corresponds to about $100, respectively, assuming household
use of about 25 liter per day)
Chemical coagulation-flocculation enhances the removal of colloidal particles by destabilizing them,
chemically precipitating them and accumulating the precipitated material into larger "floc" particles that can
be removed by gravity settling or filtering. Flocculation causes aggregation into even larger floc particles
that enhances removal by gravity settling or filtration. Coagulation with aluminum or iron salts results in the
formation of insoluble, positively charged aluminum or iron hydroxide (or polymeric aluminum- or iron-
hydroxo complexes) that efficiently attracts negatively charged colloidal particles, including microbes.
Coagulation-flocculation or precipitation using lime, lime soda ash and caustic soda is used to "soften"
water, usually ground water, by removing (precipitating) calcium, magnesium, iron, manganese and other
polyvalent, metallic cations that contribute to hardness. However, reductions in microbial contaminants as
well as turbidity, and dissolved and colloidal organic matter are also achieved in this process.
Duan and Gregory investigated on coagulation by hydrolyzing aluminum and iron salts and their
dependence on pH and coagulant dosage Duan, J. and Gregory, J., (2003)., Coagulation by hydrolyzing
metal salts, Advances in Colloid and Interface Science, 100, 475-502
Hydroxylated Ferric Sulfate [Fe5(SO4)7(OH)] - The newest of the iron salts. Billed as a
replacement for alum. Sold in solution form. Very acidic and corrosive.
Ferrous Sulfate [FeSO4] - Applications include phosphate removal, trace metals removal,
and odor control. Available in solid and solution (5-12% iron) form. Very acidic and
corrosive.
Aluminum Chloride [AlCl3] - Applications include metals removal, oil & grease separation
and water clarification. Available as a solid and in solution form. Acidic and corrosive.
Aluminum Sulfate [alum, Al2(SO4)3] - Perhaps the most widely used inorganic coagulant.
Uses similar to aluminum chloride. Available as a solid and in solution form. Acid and
corrosive.
Calcium Chloride [CaCl2] - Infrequently used for metals removal, organics reduction and
water clarification. CaCl2 also has great utility for. phosphate removal. Available as a solid
and in solution form. Nonhazardous.
Polyaluminum Chloride [PAC] - This describes a wide variety of materials containing more
than one aluminum atom in the molecule up to about 13. These materials are typically
described by their Al2O3 content and basicity. Al2O3 ranges from about 8% to 25% and
basicity is usually between 50 and 70% for most commercial products. Aluminum
chlorohydrate is an example of a PAC. Some manufacturers replace part of the chloride
content with silicate or sulfate. Some materials are corrosive. Available in solution form
only.
FLOCCULANT APPLICATIONS
FOR PRECIPITATION AND DEWATERING
Last updated October, 2009
Copyright ©1997-20
09 TRAMFLOC, INC. All Rights Reserved.
http://www.tramfloc.com/tf27.html
[Rationale for maximum allowable exposure level of aluminum sulfate and its
coagulants in the air of the workplace]
[Article in Russian]
Grekhova TD, Neizvestnova EM, Konstantinova LI, Dobroliubova LP, Babakova OM, Petelina EV, Fomina AS.
Aluminum sulfate, ammonium alum, purified and unpurified nephelinic coagulant are assigned to the 3rd jeopardy
class (moderately dangerous chemicals), sodium alum, , potash alum --to the 4th jeopardy class (slightly dangerous
chemicals) at the single exposure. Local irritation of rabbit's skin was not revealed, but instillation into the eye results
in conjunctivitis and purulent ophthalmitis. Aluminum sulfate and coagulants afflict the nervous system, liver and
heart. The recommended MAC in the air of workplace for aluminum sulfate, potash alum, sodium alum and
v
Table 4. Chemical or Physical-Chemical Methods for Water Treatment at the Household Level
Availability
Technical Microbial
Method and Cost (a)
Difficulty Efficacy (b)
Practicality
Coagulation-Flocculation or
Moderate Moderate Varies Varies (c)
Precipitation
Adsorption (charcoal, carbon, High to Low to Varies with
Varies
clay, etc.) moderate moderate adsorbent (d)
High to Low to
Chlorination Moderate High
Moderate Moderate
Ferrate is an excellent water treatment agent for its multi-functions in oxidation, disinfection, coagulation
and adsorption, but its coagulation ability depends on its dosage and is after its oxidation
Pages 49-53
Authors