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AIITS-PT-III-PCM(S)-JEE(Main)/15
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JEE(Main)-2015
ANSWERS, HINTS & SOLUTIONS
PART TESTIII
(Main)
Q. No.
1.
PHYSICS
D
CHEMISTRY
C
MATHEMATICS
C
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Physics
PART I
SECTION A
1.
2.
3.
0I
0I
1 0I 1
1
. sin 450 sin 450
4
2R
2R
R 2R
10
4 volts = 5 volt
44
100 4
10
100 4
V2
100 4
4
100 4
= 4.9 volts V1 V2 0.1 volt
V1
In steady state :-
E
E
R
2R
2
E
E
VQ VS
R
2R
2
VS VR
VP VR E
Q A CE
CE
QB
2
VP VQ
4.
VP V0 10 10 10 10
= - 200 volts.
5.
R
6.
C1+ C2
R
E
10V 2
10
I1 +2I 10 = 0 5 + I I1 + 2I 10 = 0
3
After solving we get, I1 = 0, Q = 0
1F
I
I1
10/3
I I1
5V
7.
V=
1
q q q
q
q ... =
40 1
2 4 8
40
1
q
1 1 2 20
8.
Field at any internal point of the cavity.
4
E G C2 C1
3
Since C1 and C 2 are fixed (cavity being concentric with C 2 all the time), field remains constant
both in magnitude and direction.

9.
If the fifth point P has identical charges the field at the centre of symmetry O would be zero.
Hence the field due to one single such charge at P would produce a field E , such that ( E + E ) =
0
E = E = ( 3i 4 j 2k )
due to this rearrangement, hence the required field at O is

this field
will
be
four
times
E
4 E = ( 12i 16j 8k ) units
10.
If IG 0 then it becomes a balanced whetstone bridge
12.
13.
2
2
200
1m 100
cm
3
3
3
Q/2
d
+
Apply gaus theorem
E 4r 2
14.
0 2A 0
Qd
V E1d
2A 0
E1
qin
q
1
E
E 2 field depends only on r.
2
0
4 0 r
r
R V I
R
V
I
R
V
I
100
100 100
R
V
I
3%
17.
Magnetic field is zero at the centre due to symmetrical current distribution.
18.
2
2
19.
B at O
2 0 I/ 4
2 0 I / 4 2
2
4 a / 2
4
a
5
5
5
20I
0I
30I
4 5a 4a 5 4 5a
a
a
20.
Due to electrostatic shielding, the ratio will be 1.
21.
When key is open

q1 = CE
when key is closed
q2 C
R2
R1 R2
CE
R2 R1 5
q
1
R1 R2
q2 CER2
R2
3
22.
If I1 is current in ACDB then
0 i1 0 i2
.
.
4 r
4 4r
i1 1
i2 4
i1
23.
1
i
i
5
5
From symmetry the currents in segment gh is zero. Thus, the equivalent resistance R is given by
1 1 1 1 1 3
2
R
R 4 4 2 2 2
3
10
Current in eh =
2.5A
4
Potential difference across eh = 5V
24.
It is a balanced Wheatstone bridge for capacitor. Consequently the potentials of points a and b
are equal. Thus energy stored in the capacitor is zero.
25.
Let after steady state the charges on the capacitor be q1 and q2

q1 = CV, q2 = CV where v is the potential difference between the plates.
Also from charge conservation
q1 + q2 = 0
V=0
Thus, final energy stored in the capacitors =
Initial energy stored =
1
1
CV2 + CV2 = 0
2
2
q2
q2 q2
2C 2C C
Thus, heat developed in the resistor = q2/C

26.
Initial capacitor is charged to Q/2

2
1Q
1
1 Q2

2 2 C
8 C
1
Finally energy stored in the capacitor, Uf = CE2
2
Energy stored in capacitor =
1
CE2 = Ui
8
3
3
CE E CE 2
2
2
Work done by the battery =
3
3
1
1
CE2 (Uf Ui) = CE2 CE2 CE2

2
8
2
2
3 1 1 9
= CE 2 CE 2
2 2 8 8
Heat energy lost =
27.
28.
The equivalent circuit is

Current flowing through 3 resistance
= 3/3 = 1 Amp
Current flowing through P to Q is also
1 amp.
From the figure current flowing through
AB is 1 + 0.5 = 1.5 Amp
2
3
A
I2
1A
B
I1
0.5 A
0.5 A
3
1A
3V
3V
By using the relation
0 i
where is in radian
4 r
Here = 180 i.e.

So, Bp =
0I
4r
29.
Let x = a potential is zero (region II)

q
2q
k k
a
a a
a = a
So, in the region II,
Potential is zero and can be proved.
A solution can also found in region I (x = a/3).
30.
In the steady state

E2 iR1 iR1 E1 iR1iR1 = 0
E2 E1 = 4iR1
I=
i
a
R1
E 2 E2
2.1
= (6.3 2.1)/(41.7) =
4R1
3.4
E1
R1
Solving, we get, Va Vb = iR1 + E2 iR1
2.1
= 6.3 21.7
= 6.3 2.1 = 4.2 V
3.4
R1
E2
R2
E2
R1
C
b
Chemistry
PART II
SECTION A
17
1.
OH
CH3C
18
OH
16.. H
:O
CH2CH3
17
17 ..
OH
CH3C
:OH
18
OH
..
CH3C
H OC2H5
18
OH
..
OC2H5 H
16
(i) H2O18 (ii) H

17
O
16
CH3C
3.
O
CH3CHCCH2CH3
Br
O
COH
CH3CHCHCH3
OH
H2O
O
CH3CHCCHCH3
Br
COOH
CH3CHCHCH3
H2O
O
C
CH3CHCHCH3
OH
COOH
CH3CHCH2CH3
4.
This is Baltz Schiemann reaction.
C2H5
+
4C2H5Cl + NH3 C2H5NC

2H5 Cl
C2H5
6.
CH3CH3
CH3 C C CH3
OH NH2
HNO2
OC2H5
CH3CH3
CH3 C C CH3
OH
CH3
CH3 C C CH3
OH CH3
H+
O CH3
CH3 C C CH3
CH3
7.
Carbyl amine test is responded by only 1 aliphatic/aromatic amines.
8.
This is Hundsdicker reaction.
O
Ph C O Ag
O
Ph C O + AgBr
Ph + CO2
PhBr
Br
9.
(C6H5)3CCl is hydrolysed most rapidly by SN1 because (C6H5)3C+ is most stable.
10.
SN1 reaction is accompanied by racemisation while SN2 reaction is accompanied by inversion of

configuration.
CH3 CH3
CH3 CH3
11.
CH3
CH2
CH CH3
CH3 CH3
(major)
CH CH3
H2/Ni
CH3 CH3
Cl
CH3
CH3CHCHCH3
2, 3 Dimethyl Butane
CH CH3
(minor)
12. Nucleophilic addition.

13.
Chloroform is formed when acetone is mixed with bleaching powder (CaOCl2).
14. Due to intramolecular Hbonding.

15.
Because CH2 hydrogen is more acidic than CH3 hydrogen.
DO
HOD
16.
O
D
D2O
OD
These steps are continued unless all the four -Hs are replaced by D.
17.
O
O
CH3CH2CCH3 contain C and keto methyl group both.
18.
In polystyrene the monomeric unit is styrene which is having the formula of H2C=CHC6H5.
19.
Step growth polymers (or condensation polymers) are prepared by reaction between two
functional groups and thereby eliminating small molecules during polymerization. Nylon-66 is an
example of step growth polymer.
20.
Test of terminal alkynes.
21.
Compound 'A' give positive test with Na metal. That means it contains polar Hydrogen i.e.,
alcoholic group. It gives negative test with neutral FeCl3 implies it does not contain of a phenolic
group. It gives positive Lucas test means it is an alcohol.
22
LiAlH4
N
|
H
COOH
PCl5
N
H
CH2OH
KCN
N
H
CH2Cl
N
H
H3O+
N
H
23.
CH2 CN
CH2COOH
RCOOH + CH2N2 RCOOCH3 + N2 ; methyl esters are formed.
24.
2 position is attached with two electron withdrawing groups.
25.
LiAlH4 can reduce both ketone and ester.
27.
n CH2=CHCH=CH2 + n C6H5CH=CH2 (styrene)

(1,3-butadiene)
[CH2CH=CHCH2CH(C6H5)CH2]n
(BunaS)
28.
CH3I (excess)
AgOH
CH3NH2
(CH3 )3 NI
(CH3 )4 N OH
(CH3 )3 N CH3 OH
30.
R
HIO4
(1)
O
R
O
R
OH
HO
O
HIO4
(2)
OH
R
O
OH
O
HIO4
(4) R CHOH CHOH R
R CH O R CH O
Mathematics
PART III
SECTION A
1 7 cos2 x
sec 2 x
tan x
1.
sin7 x cos2 x dx sin7 x dx sin7 x sin7 x c S
2.
tan x tan1 d tan x tan1

d = tan x tan1 n 1 2 c
2
2
1
3.
4.
In e x sin x dx e x sin x
1
et
et
dt = e t n 1 t dt = n 1 t e t
dt = e n2 k
0
1 t
1 t
0
0
0
In
n n 1 In 2
1 n2
n sin x
n 1
cos x ex dx
n n 1
In
In 2
1 n2
2k
5.
2k
sin x sin x dx
2k
sin x sin x sin x dx
= 2k sin x dx 2k cos x 0 4k
0
Ik = 4k
100
Ik
20200
k 1
6.
f(n) nf(n 1) = (1)[f(n 1) (n 1) f(n 2)] = (1)n 1 [f(1) f(0)] = (1)n
f n
n!
f n 1
n 1!
1
n!
and this gives
1
1 1
f n n! 1
.....
n!
1! 2 !
8.
9.
1
n N 0 as n by the definition of continuity f(xn) f(0) as n . But f(xn) = 0 for
n
all x N, so f(0) = 0
f x f 0
f xn f 0
Also lim
lim
f is derivable at x = 0
x 0
x 0
x0
xn 0
xn
Equation of tangent
y 2a sin
1
2
x a sin sin
x
y
1
2
a sin a sin
Sum of intercepts = a sin2 sin = 2a when sin = 1

10.
f 'x
sin x x cos x
sin2 x
10
12.
13.
14.
17.
18.
20.
Let h(x) = sin x x cos x

h(x) = x sin x > 0 0 < x 1
h(x) is increasing
h(0) < h(x) sin x x cos x > 0 for 0 < x 1
f (x) > 0
Similarly g(x) is decreasing
1
1
2x
1
x
1
dx e x tan1 x
c
e tan x 1 x2 1 x 2
2
1 x2
1 x2
1/10
1/10
11/10
5 2
2
8
9
dx = x 1 x 2 2x
dx =
x 2x
c
x x x 2x
11
Value of definite integral can be zero when either the lines coincide or f becomes identically zero
for given interval or f(x) = 0 has some root in the given interval.
Here sin(x + k) = 0 in n [0, 1]
Let for particular x0
g(x0) = a + k then g(x) = a k
h(x0) = 2a
h(x) = 2a x R
h(x) is many one and into
x 1
1
; put y = t t , 1
x 1
3
1
Hence, we get ,
4
As n
lim f n lim f n 2 lim f n 1 k (say)
y
1
9
lim f n 2 lim f n 1
n
n 2
f n
1
9
k k k = 3
2
k
21.
f(x) = x2 sin x tan x

f (x) = 2x sin x (sec2 x + 1)
f(x) < 0 f(x) is decreasing
f(x) < f(0) as x > 0
x2 sin x cos x < 0
24.
Put separately x
28.
f(x) = 3x2 2x + 100 > 0
30.
f(1) = f(3)
f = 3ax2 + 3bx + 11 = 0
Solving we get a = 1 and b = 6
1
, x = 1 and x = 2 we get
2
1
1
(A) f 2 f 1 (C) f(2) + f(1) = f (D) f(2) + f(1) = 0
2
2
.. (1)
.. (2)

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AIITS-PT-III-PCM(S)-JEE(Main)/15

Field at any internal point of the cavity.

both in magnitude and direction.

due to this rearrangement, hence the required field at O is

4 E = ( 12i 16j 8k ) units

If IG 0 then it becomes a balanced whetstone bridge

Apply gaus theorem

Magnetic field is zero at the centre due to symmetrical current distribution.

Due to electrostatic shielding, the ratio will be 1.

When key is open

If I1 is current in ACDB then

Let after steady state the charges on the capacitor be q1 and q2

Thus, heat developed in the resistor = q2/C

Initial capacitor is charged to Q/2

Work done by the battery =

CE2 (Uf Ui) = CE2 CE2 CE2

Heat energy lost =

The equivalent circuit is

By using the relation

Here = 180 i.e.

Let x = a potential is zero (region II)

In the steady state

Solving, we get, Va Vb = iR1 + E2 iR1

(i) H2O18 (ii) H

This is Baltz Schiemann reaction.

4C2H5Cl + NH3 C2H5NC

Carbyl amine test is responded by only 1 aliphatic/aromatic amines.

This is Hundsdicker reaction.

(C6H5)3CCl is hydrolysed most rapidly by SN1 because (C6H5)3C+ is most stable.

SN1 reaction is accompanied by racemisation while SN2 reaction is accompanied by inversion of

12. Nucleophilic addition.

Chloroform is formed when acetone is mixed with bleaching powder (CaOCl2).

14. Due to intramolecular Hbonding.

Because CH2 hydrogen is more acidic than CH3 hydrogen.

Test of terminal alkynes.

RCOOH + CH2N2 RCOOCH3 + N2 ; methyl esters are formed.

2 position is attached with two electron withdrawing groups.

LiAlH4 can reduce both ketone and ester.

n CH2=CHCH=CH2 + n C6H5CH=CH2 (styrene)

sin7 x cos2 x dx sin7 x dx sin7 x sin7 x c S

tan x tan1 d tan x tan1

sin x sin x sin x dx

f(n) nf(n 1) = (1)[f(n 1) (n 1) f(n 2)] = (1)n 1 [f(1) f(0)] = (1)n

and this gives

Sum of intercepts = a sin2 sin = 2a when sin = 1

Let h(x) = sin x x cos x

f(x) = x2 sin x tan x

f(x) = 3x2 2x + 100 > 0

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