https://cikguadura.wordpress.

com

https://cikguadura.wordpress.com

https://cikguadura.wordpress.com

https://cikguadura.wordpress.com

https://cikguadura.wordpress.com

JAWAPAN ULANGKAJI SPM 2015

Chemistry

https://cikguadura.wordpress.com

TIMES ANSWER PAPER 1 CHEMISTRY SPM

1C
6A
11 C
16 B
21 B
26 D
31 C
36 D
41 B
46 C

2A
7A
12 B
17 A
22 D
27 A
32 D
37 C
42 D
47 C

3B
8A
13 D
18 B
23 C
28 B
33 A
38 C
43 B
48 C

4D
9A
14 A
19 A
24 B
29 A
34 C
39 A
44 A
49 D

5D
10 D
15 D
20 A
25 D
30 A
35 A
40 B
45 B
50 B

SOALAN boleh didapati di laman web www.afterschool.my

[4541/1]
[4541/2]

93

94

JAWAPAN ULANGKAJI SPM 2015

TIMES ANSWER PAPER 2 CHEMISTRY SPM
https://cikguadura.wordpress.com

Question
1

(a)

Compound A and Compound E.

They have the elements carbon and hydrogen only and
with single bonds between all carbon atoms.
Compound B and Compound C.
They have the same molecular formula but different
structural formulae.
Butan-1-ol
Compound F
Compound D
CH3Cl
Compound B and Compound C.
Hydrogenation
Platinum as a catalyst.

(b)

SOALAN boleh didapati di laman web www.afterschool.my

(c)
(d)
(e)
(f)
(g)
(h)

(a)

Mark scheme

(i)

To make plastic bottles /container

To make plastic bags

(ii)

(b)

(iii)
(i)

Polyamides
Hard/ brittle/ electrical insulator/ resistant to chemical
corrosion

(ii)

Glass: silicon dioxide / silica / SiO 2

Ceramic: kaolinite/ aluminosilicate/ Al2Si2O5
Borosilicate glass
Does not melt at high temperatures

(iii)
(iv)
3

Sub
mark
1
1

Total
mark
2

1
1

1
1
1
1
1
1

1
1
1
1
1
1

Total
1
1

10

1+
1
1
1
1
1
Total

2
2
1
1
10

1+1

1+1

(a)

(b)

An alkali is a molecules which dissociates partially in

water to produce OH ions of a low concentration.

(c)

Sodium hydroxide has a higher pH value than ammonia

solution.
The concentration of OH ions in sodium hydroxide is
higher that that of ammonia solution.
Sodium hydroxide dissociates completely when
dissolved in water, whereas ammonia dissociates
partially when dissolved in water.

1
1
1

95

JAWAPAN ULANGKAJI SPM 2015

Dip a glass rod into concentrated hydrochloric acid.

Bring the glass rod close to the ammonia gas. Thick
white fumes are produced.

(e)

Ethanoic acid

(a)

A: Liquid
B: Solid

(b)

(c)

Particles of Y held together by weak intermolecular

forces
A small amount of heat energy is required to overcome
the forces

(d)

(e)

(a)

(e)

To relieve pain
To destroy the growth of bacteria
To change the emotions and behaviour of the patients
May cause bleeding in the stomach
Paracetamol
Codeine
Test the patient if he is allergic to penicillin
Streptomycin
Must complete all the dosage given by doctor
May cause addiction

(a)
(b)
(c)
(d)
(e)

Saponification
Sodium hydroxide
To precipitate soap
Glycerol
RCOONa

(b)
(c)
(d)

"

(i)
(ii)
(iii)
(i)
(ii)
(i)
(ii)
(iii)

#"

1
1

1
Total
1
1

1
10

1
1

1+2

1+1

Total
1
1
1
1
1
1
1
1
1
1
Total
1
1
1
1
1

10
1
1
1
1
1
1
1
1
1
1
10
1
1
1
1
1

SOALAN boleh didapati di laman web www.afterschool.my

(d)

96

JAWAPAN ULANGKAJI SPM 2015

(f)
(g)

(i)
(ii)

(a)

It has a hydrophilic part that dissolves in water.

It has a hydrophobic part that dissolves in grease.
It forms scum.
Detergent
It does not form scum.
*Brass is harder than pure copper.
*Pure copper has same size of atom.
*Arrange in orderly manner
*Easily to slide over one another when force is applied
Pure copper

1
1
1
1
1
Total
1
1
1
1

2
1
2
10

SOALAN boleh didapati di laman web www.afterschool.my

*Brass has two types of atoms with different size of

atoms ( zinc and copper )
*The presence of zinc atoms of different size disrupts
the orderly arrangement of the copper atoms
*The layers of atoms do not slide over one another
easily when a force is applied

1
1
1

Brass

9
(b)

(i)

(ii)

(c)
"

Composite materials are materials made from two or

more different constituent materials,
When combined, produce a material with characteristics
different and superior from the individual components.

#Concrete is consists of loose stones held with cement.

# Concrete is a very strong material and will not
compress or shatter even under quite a large
compressive force.
# Concrete cannot stand tensile loading (If stretched it
will break apart easily).
# Reinforced concrete consists of concrete
strengthened using steel bars.
# Reinforced concrete has the ability to resist being
stretched as well as being compressed.

1
1

Similarities:

Hard/ brittle
$"

1
1
1

97

JAWAPAN ULANGKAJI SPM 2015

Differences:
Glass
Transparent
Can be melted
and remoulded
Does not have a
melting point
8

(a)

Ceramic
opaque
Can be melted and
remoulded
Have very high melting
point

#Between Y and Z
#Type of compound is covalent compound
#Electron arrangement of Y is 2.7
#Electron arrangement of Z is 2.8.4
#Z needs 4 electrons to achieve stable octet electron
arrangement 2.8
#Y needs 1 electron to achieve stable octet electron
arrangement 2.8.8
#One atom Z share its 4 electron with 4 atom Y to form
a compound with the formula ZY4
#Between X and Y
#Type of compound is ionic compound
#Electron arrangement of X is 2.8.1
#Electron arrangement of Y is 2.7
#X needs to release 1 electron to achieve stable octet
electron arrangement 2.8
#Y needs 1 electron to achieve stable octet electron
arrangement 2.8

1+1

1+1

4
TOTAL
1
1
1
1
1

20

1
1

1
1
1
1
1

12
(b)

"

Melting point:
#Melting point of compound (b)(i) is lower than (b)(ii)
#Compound (b)(i) is a covalent compound while (b)(ii)
is an ionic compound.
#Molecules in covalent compound are held by weak
force of attraction - van der Waals forces.
#Less energy is required to overcome the forces of
attraction between the molecules. Hence the melting
point is low.
#Ions in ionic compound are attracted to one another
by strong electrostatic forces between the ions. More
heat energy is required to overcome the forces,
hence the melting point is high.
Electrical conductivity
#Covalent bond in (b)(i) consist of molecules which is
neutral. It is also not an electrolyte and cannot conduct
electricity in both molten and solid state.
%"

1
1
1
1
1

SOALAN boleh didapati di laman web www.afterschool.my

Electrical insulator
Resistant to chemical corrosion

98

JAWAPAN ULANGKAJI SPM 2015

#Ionic compound is electrolyte which conduct electricity
in molten state and aqueous solution.
#This is because ionic compound contains free moving
ions which carry electrical charge.

(a)

Electron arrangement of atom S is 2.8.4

Atom S has 4 valence electron. Hence it is located in
Group 14
Atom S has 3 shells occupied with electrons. Hence it is
located in Period 3
Electron arrangement of lithium is 2.1
Atomic radius of lithium is smaller than sodium
The distance between the nucleus of lithium and the
valence electron is nearer/ closer
The force of attraction between the nucleus of lithium
and the valence electron is stronger
Hence the valence electron is more difficult to be
released
Procedure:
1. A small piece of lithium is cut using a knife
2. The oil on the surface of lithium is removed using
filter paper
3. Lithium is then placed slowly on the surface of water
in a basin
4. The experiment is repeated using sodium.
Observation:
Lithium moves slowly on the surface of water
Name of products: lithium hydroxide and hydrogen
Sodium moves rapidly/ faster/ vigorously on the surface
of water
Name of the products: sodium hydroxide and hydrogen
Equations:
2Li + 2H2O ' 2LiOH + H2/ 2Na + 2H2O ' 2NaOH + H2

(b)

SOALAN boleh didapati di laman web www.afterschool.my

(c)

1
1
TOTAL
1
1+1

20

1+1

1
1
1
1
1

(a)

(i)
(ii)

"

Sodium chloride
Potassium nitrate
Ammonium sulphate
Salt

1
1
1
1
1
1
1
1
1+1

TOTAL
10

10
20

3
Reactants

Sodium chloride

Hydrochloric acid and sodium

hyd oxide

Potassium
nitrate

Nitric acid and potassium hydroxide

&"

99

JAWAPAN ULANGKAJI SPM 2015

(b)

Sulphuric acid and ammonia

solution

(i)

Method II and method IV

1+1

(ii)

2HNO3 + CuO ' Cu(NO3)2 + H2O

2HNO3 + CuCO3 ' Cu(NO3)2 + H2O + CO2

1+1
1+1

(iii)

1.
2.
3.
4.
5.
6.
7.

Pour 50 cm dilute nitric acid into a beaker.

Heat to warm the acid.
Add copper(II) oxide to the nitric acid slowly and stir.
Add until in excess.
Filter to separate the excess copper(II) oxide.
Heat the filtrate until saturated.
Cool the saturated filtrate. Copper(II) nitrate crystals
are formed.
8. Filter to separate the crystals.
9. Dry the crystals between two pieces of filter paper
(or in the oven).

"

("

1
1
1
1
1
1
1
1
1

https://cikguadura.wordpress.com TOTAL

END OF MARKING SCHEME

9
20

SOALAN boleh didapati di laman web www.afterschool.my

Ammonium
sulphate