5. 1995 Q17
Compound X is a white solid. When X is warmed with sodium hydroxide solution, a gas is evolved which turns
moist red litmus paper blue. When chlorine water is added to an aqueous solution of X, a brown solution is
formed. X is probably
A. ammonium bromide.
B. ammonium chloride.
C. sodium bromide.
D. sodium chloride.
Ans: A
6. 1995 Q18
Metal X reacts with dilute hydrochloric acid to liberate hydrogen, but metal Y and metal Z have no reaction
with the dilute acid. The oxide of metal Y decomposes on heating but the oxide of metal Z does not. Which of
the following arrangement represents the order of increasing reactivity of the three metals?
A. X < Y < Z
B. Y < Z < X
C. X < Z < Y
D. Z < Y < X
Ans: B
7. 1995 Q23
Which of the following substances can cause acid rain?
A. lead compounds from the burning of leaded petrol in motor cars
B. carbon dioxide from the complete combustion of town gas
C. carbon soots from the incomplete combustion of coal
D. nitrogen dioxide from the burning of fuels in power stations
Ans: D
8. 1995 Q35
Which of the following substances, when mixed with lemon juice, would give off gas bubbles?
(1) iron nails
(2) milk of magnesia
(3) polyethene wrap
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: A
9. 1995 Q38
Which of the following statements concerning the contact process is/are correct?
(1) The sulphur dioxide used in the process can be produced by roasting sulphur ores.
(2) A gaseous mixture of sulphur dioxide and oxygen in the mole ratio of 1:2 is passed into the catalytic
conversion chamber.
(3) The sulphur trioxide produced is absorbed by water in the absorption tower.
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: A
10. 1996 Q4
Consider the following chemical equation:
2HNO3(aq) + CaCO3(x) Ca(NO3)2(y) + H2O(z) + CO2(g)
Which of the following combinations is correct?
x
A. aq
aq
B. aq
aq
aq
C. s
aq
D. s
aq
Ans: C
11. 1996 Q6
Which of the following substances is used by farmers to increase the pH of soil?
A. ammonium nitrate
B. calcium hydroxide
C. citric acid
D. potassium hydroxide
Ans: B
12. 1996 Q9
Which of the following experiments can be used to show that concentrated sulphuric acid is a dehydrating
agent?
A. adding it to copper(II) oxide powder
B. adding it to copper(II) sulphate crystals
C. adding it to calcium carbonate powder
D. adding it to sodium chloride crystals
Ans: B
C.
B.
D.
Ans: C
14. 1996 Q 33
A mixture contains only copper(II)
er(II) oxide and anhydrous copper(II) sulphate. Which of the following methods
can be used to separate copper(II) oxide from the mixture?
(1) add water to the mixture and then filter.
(2) add dilute nitric acid to the mixture and then filter.
(3) add concentrated
ntrated hydrochloric acid to the mixture and the filter.
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: A
A. hydrogen
pale green
B. hydrogen
yellow
C. sulphur dioxide
pale green
D. sulphur dioxide
yellow
Ans: D
26. 1998 Q9
Which of the following substances has a pH less than 7?
A. lemon juice
B. soap solution
C. glass cleaner
D. milk of magnesia
Ans: A
27. 1998 Q13
In an experiment, 10 cm3 of 1 M HCl is added slowly into 10 cm3 1M NaOH solution. Which of the following
statements concerning this experiment is correct?
A. The temperature of the mixture increases.
B. The pH of the mixture increases.
C. The mixture does not conduct electricity at the end of the experiment.
D. The concentration of sodium ions in the mixture remains unchanged.
Ans: A
28. 1998 Q16
The formula of a solid dibasic acid is H2X. 2.88 g of the acid is dissolved in some distilled water and the
solution is then diluted to 250.0 cm3 with distilled water. 25.0 cm3 of the diluted solution requires
16.0 cm3 of 0.40 M sodium hydroxide solution for complete neutralization. What is the molar mass of H2X?
A. 22.5 g
B. 45.0 g
C. 90.0 g
D. 180.0 g
Ans: C
29. 1998 Q23
Which of the following is NOT the appropriate substance for preparing zinc sulphate by directly mixing with
dilute sulphuric acid?
A. zinc
B. zinc carbonate
C. zinc hydroxide
D. zinc nitrate
Ans: D
Observation
A. ammonium chloride
white ppt.
B. lead(II) nitrate
yellow ppt.
C. potassium dichromate
orange ppt
D. iron(III) sulphate
brown ppt.
Ans: D
34. 1999 Q6
The concentration of an aqueous solution of an acid is 1.0 M. 25.0 cm3 of this acid solution requires 37.5 cm3 of
2.0 M sodium hydroxide solution for complete neutralization. What is the basicity of the acid?
A. 1
B. 2
C. 3
D. 4
Ans: C
35. 1999 Q7
Substance X gives identical product(s) when treated with dilute sulphuric acid or concentrated sulphuric acid. X
may be
A. zinc.
B. cane sugar.
C. ammonia.
D. hydrated copper(II) sulphate crystals.
Ans: C
36. 1999 Q20
Which of the following solutions would produce a white precipitate with sodium hydroxide solution?
A. lead(II) nitrate solution
B. iron(III) nitrate solution
C. copper(II) nitrate solution
D. potassium nitrate solution
Ans: A
37. 1999 Q25
In an experiment, 1.00 M sodium hydroxide solution was added to 25.0 cm3 of 1.00 M sulphuric acid until the
acid was completely neutralized. What is the concentration of sodium sulphate (correct to two decimal places)
in the resulting solution?
A. 1.00 M
B. 0.50 M
C. 0.33 M
D. 0.25 M
Ans: C
10
A.
20.0
40.0
B.
30.0
30.0
C.
40.0
20.0
D.
45.0
15.0
Ans: C
12
46. 2001 Q6
When potassium carbonate solution and calcium chloride solution are mixed, calcium carbonate is precipitated.
What of the following mixtures would produce the greatest amount of precipitate?
A. 5 cm3 of 1 M K2CO3(aq) + 15 cm3 of 1 M CaCl2(aq)
B. 10 cm3 of 1 M K2CO3(aq) + 10 cm3 of 1 M CaCl2(aq)
C. 15 cm3 of 1 M K2CO3(aq) + 8 cm3 of 1M CaCl2(aq)
D. 18 cm3 of 1 M K2CO3(aq) + 5 cm3 of 1 M CaCl2(aq)
Ans: B
47. 2001 Q 15
A mixture consists of one mole of sodium carbonate and one mole of sodium hydrogencarbonate. What is the
least number of moles of hydrochloric acid required to liberate all the available carbon dioxide from the
mixture?
A. 1.5
B. 2.0
C. 3.0
D. 4.0
Ans: C
48. 2001 Q 23
Phosphoric acid is a tribasic acid with formula H3PO4. Which of he following formulae is INCORRECT?
A. CaH2PO4
B. Mg3(PO4)2
C. (NH4)2HPO4
D. Na2HPO4
Ans: A
49. 2001 Q33
Consider the information below about the reaction of hydrogen with chlorine:
H2(g) + Cl2(g) 2HCl(g)
H < 0
Which of the following statements can be deduced from the above information?
(1) Heat is liberated when hydrogen chloride is formed.
(2) Hydrogen and chlorine react at room temperature.
(3) When measured at room temperature and pressure, the total gas volume before the reaction equals that after
the reaction.
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: C
13
14
15
A.
air
water
B.
air
oleum
C.
oxygen
sulphur trioxide
D.
oxygen
water
oleum
Ans: B
16
(2)
(3)
17
18
B.
C.
D.
10
Ans: B
HCl
B.
HCOOH
C.
H2SO4
D.
CH3COOH
Ans: C
20
following
hazard
warning
labels
are
displayed
on
the
reagent
bottle
of
an
acid.
What information about this acid can be obtained from the labels?
A.
B.
C.
D.
0.05 M
B.
0.10 M
C.
0.13 M
D.
0.26 M
Ans: B
A.
zinc
B.
copper
C.
zinc
D.
Copper
21
B.
C.
D.
They require the same number of moles of sodium hydroxide for complete neutralisation.
Ans: D
B.
C.
D.
2005 Q39-41
Directions: Questions 79 to 81 refer to the following information.
In an experiment to determine the concentration of sulphuric acid in a brand of toilet cleaner, 25.0 cm3 of the
cleaner was first diluted to 250.0 cm3 with distilled water. Upon titration with 0.950 M sodium hydroxide solution
using phenolphthalein as indicator, 25.0 cm3 of the diluted cleaner required 27.1 cm3 of the sodium hydroxide
solution to reach the end point.
79. Which of the following types of apparatus should be used to measure 25.0 cm3 of the toilet cleaner?
A.
pipette
B.
burette
C.
measuring cylinder
D.
volumetric flask
Ans: A
80. What is the colour change at the end point of the titration?
A.
B.
C.
D.
81. What is the concentration of sulphuric acid in the undiluted toilet cleaner?
A.
1.29 M
B.
2.58 M
C.
5.15 M
D.
10.3 M
Ans: C
82. 2006 Q7
Compound X is soluble in water.
precipitate. The precipitate does not dissolve upon the addition of excess alkali. X may be
A.
MgCl2.
B.
ZnCl2.
C.
FeSO4.
D.
(NH4)2SO4.
Ans: A
1.5 M
B.
1.7 M
C.
3.0 M
D.
3.3 M
Ans: C
B.
C.
D.
The following hazard warning label should be displayed on a bottle of concentrated sulphuric acid.
Ans: B
23
using scrubbers to remove sulphur dioxide from flue gas in a power station
(2)
(3)
using sodium hydroxide solution to remove copper(II) ions in industrial waste water
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: A
86. 2006 Q31
Oxalic acid is a dibasic acid.
10.0 cm3 of an aqueous solution of oxalic acid requires 30.0 cm3 of 0.10 M
KOH(aq) for complete neutralisation. What is the concentration of the oxalic acid solution?
A.
0.15 M
B.
0.20 M
C.
0.30 M
D.
0.60 M
Ans: A
B.
C.
Reaction 3 can be brought about by adding very dilute nitric acid to magnesium.
D.
24
B.
C.
D.
(2)
(3)
B.
C.
D.
burette
(2)
pipette
(3)
conical flask
A.
B.
C.
D.
25
91. 2007 Q5
Metal Y and calcium are both in the same group of the Periodic Table.
respectively reacts with excess hydrochloric acid under the same condition, Y gives more hydrogen than
calcium does. Which of the following deductions is correct?
A.
B.
C.
D.
50 cm3
B.
100 cm3
C.
200 cm3
D.
260 cm3
Ans: C
1.0 10 4 M
B.
2.5 10 4 M
C.
2.5 10 1 M
D.
5.0 10 1 M
Ans: C
26
94.
Which of the following combinations of solution X and solution Y can be used to show that sulphur dioxide
and carbon dioxide are produced?
Solution Y
Solution X
A.
bromine water
B.
C.
D.
95. Which of the following statements concerning the reaction between carbon and concentrated sulphuric acid
are correct?
(1)
(2)
(3)
Concentrated sulphuric acid acts both as a dehydrating agent and an oxidising agent.
A.
B.
C.
D.
27
B.
C.
D.
(2)
(3)
A.
B.
C.
D.
98. 2008 Q7
3
30.0 cm 3 of 0.10 M KOH is completely neutralized by 20.0 cm of dilute H 2SO 4 to form K 2 SO 4 solution.
0.03 M
B.
0.05 M
.0.06 M
D.
0.10 M
Ans: A
B.
C.
the number of moles of any base which can completely react with one mole of the acid.
D.
the number of hydrogen ions which can be produced by complete ionization of one acid
molecule.
Ans: D
28
B.
C.
D.
Temperature Rise /
25 cm of 1 M HCl + 25 cm of 1 M NaOH
50 cm 3 of 1 M HCl + 50 cm 3 of 1 M NaOH
25 cm of 2 M HCl + 25 cm of 2 M NaOH
50 cm 3 of 2 M HCl + 50 cm 3 of 2 M NaOH
<
<
<
B.
<
<
C.
<
D.
<
z
Ans: D
Reaction 2
B.
C.
D.
29
burette
(2)
pipette
(3)
conical flask
A.
B.
C.
D.
(2)
(3)
A.
(1) only
B.
(2) only
C.
D.
B.
C.
D.
4
Ans: C
30
2009 Q35-36
solution Y
40 cm of 0.2 M acid A
20 cm of 0.4 M acid B
10 cm of distilled water
30 cm of distilled water
0.2 M
B.
0.16 M
C.
0.01 M
D.
0.008 M
Ans: B
107. Two identical zinc strips are added to solutions X and Y. The diagrams below show how gas bubbles are given
out when the zinc strips are just added to the solutions.
B.
C.
D.
0.5 M NH3(aq)
A.
higher pH
lower pH
B.
C.
D.
31
(l) only
B.
(2) only
C.
D.
111. 2010 Q5
Which of the following set-ups can be used to dry hydrogen chloride gas ?
Ans: D
32
burette
B.
conical flask
C.
volumetric flask
D.
measuring cylinder
Ans: C
B.
C.
D.
B.
C.
D.
4
Ans: C
33
1.3 M
B.
1.5 M
C.
2.0 M
D.
3.0 M
Ans: C
B.
C.
D.
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: A
119. 2010 Q43
Solution Y is added dropwise to a solution of NaOH containing several drops of phenolphthalein. The mixture
suddenly changes from pink to colourless. Which of the following substances may Y be ?
(1) HCl(aq)
(2) KCl(aq)
(3) Cl2(aq)
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: C
34
CH3COOCH2CH3 + H2O
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
Ans: B
35