Section A

[15 marks]

Four suggested labelled A, B, C, and D are given for each question. Choose one correct answer.
1.

Which set of m/e values is most likely to correspond to mass spectrum of chlorine gas?

35
/
/
/
/

A
B
C
D
2.

35.5
/
/

m/e values
37
70
/
/
/
/
/
/
/

72
/
/

74
/
/
/

On heating, 0.02 mol of the element M reacts with 0.025 mol of oxygen gas. What is the
empirical formula of the oxide of M?
A.
B.

M2 O
MO2

C.
D.

MO3
M2O5

Given the balanced chemical equation, C4H4 + 5O2
4CO2 + 2H2O. If 0.3618 moles of
C4H4 are allowed to react with 1.818 moles of O2, and this is the only reaction which occur,
what is the maximum quantity of water that could be produced?

3.

A.
B.
4.

11.02 g
13.02 g

C.
D.

13.20 g
19.64 g

To identify an oxide of nitrogen, 0.10 mol of the oxide is mixed with an excess of hydrogen
and passed over a catalyst at a suitable temperature.
NxOy + H2 x NH3 + y H2O
The water produced weighs 7.20g. The ammonia produced is neutralised by 200cm3 of 1.0
mol dm-3 HCl. What is the formula of the oxide of nitrogen?
A.
B.

5.

N2O
NO

C.
D.

NO2
N2O4

Wavelength of emission spectral series of hydrogen atom can be calculated using Rydbergs
equation, where the Rydbergs constant is 1.097 x 107 m-1.
1
1
1
=  



 
What is the wavelength, in nanometer, produced by the third line of Balmer Series?
A.

6.

290 nm

B.

434 nm

C.

210 nm

D.

450 nm

The statements that the ground state configuration of an atom is generated by filling in levels
lowest (energy wise) to the highest with electrons observing the maximum for each of these
A
B.

the Aufbaus Principle

Schrodingers Rule

C.
D.

Hunds Rule
the Pauli Exclusion Principle

7.

What is the energy in joules of one mole of electrons associated with radiation which has a
frequency of 6.336 x 1015 s-1?
[ Plancks Constant = 6.63 x 10-34 J s ; Avogadros Constant = 6.02 x 1023 e- mol-1]
A.
B.

2.528 x 106 J
3.882 x 1014 J

C.
D.

3.955 x 10-7 J
4.198 x 10-18 J

What is the wavelength of radiation which has an energy of 216.1 kJ mol-1?

[Plancks Constant = 6.63 x 10-34 J s ; Avogadros Constant = 6.02 x 1023 e- mol-1 ;
Rydbergs constant = 1.097 x 107 m-1]

8.

A.
B.
9.

655.9 nm
546.1 nm

C.
D.

108.8 nm
589.3 nm

The following molecules undergoes sp hybridisation except

A.
B.

10.
I
A.
B.
11.

A.
B.
12.

CO2
BeCl2

C.
D.

Which of the following molecules have tetrahedral shape?

NH4+

II

KrF4

IV SO42-

III SF4

I and IV only correct

II, and III only correct

C.
D.

I and III only correct

II and IV only correct

Valence Shell Electron Pair Repulsion(VSEPR) theory can be used to deduce the molecular
shape of a covalent compound. Which of these compound have the shape as shown in
diagram below.

SF4
ICl4-

C.
D.

SF6
SiCl4

In which of the following reactions is the bond angle in the product underlined greater than
that in the reactant underlined?

I
H2O(l) + H+(aq)
H3O+(aq)
III CO32-(g) + 2H+(aq)
CO2(g) + H2O(aq)
A.
B.

SO2
CO

I, II and III only correct

I, II, and IV only correct

II C2H4(g) + H2(g)
C2H6(g)

IV NH3(aq) + H+(aq)
NH4+(aq)
C.
D.

I, III and IV only correct

II, III and IV only correct

13.

Dimethyl ether, ethanol and water are compounds with an oxygen in its molecule.

What is the correct sequence of these compound according to descending order of

their boiling point?
A.
B.
14.

dimethyl ether, ethanol, water

water, ethanol, dimethyl ether

ethanol, water, dimethyl ether

dimethyl ether, water, ethanol

A mixture of 5.00 moles of neon and 3.00 moles of nitrogen occupy a volume of 36.0 dm3 in
a vessel where the total pressure is 6.00 atm. The partial pressure of the neon in the
container is

A.
B.
15.

C.
D.

0.375 atm
0.625 atm

C.
D.

2.25 atm
3.75 atm

A gas sample occupies a volume of 1.264 dm3 when the temperature is 168.0OC and the
pressure is 126.2 kPa. How many molecules are there in the sample?
[Gas constant, R = 8.31 J mol-1 K-1; Avogadros Constant = 6.02 x 1023 e- mol-1]

A.
B.

2.072 x 1022
2.616 x 1022

C.
D.

Answer
1.B

6.A

11.B

2.D

7.A

12.C

3.B

8.B

13.B

4.D

9.C

14.D

5.B

10.A

15.B

2.654x 1022
2.654x 1022

MAKTAB SULTAN ABU BAKAR

UJIAN PENILAIAN PRA-PENTAKSIRAN (1) SEM 1 2015
SUBJECT : CHEMISTRY
Name : ____________________________________
Section A

Tingkatan : LOWER 6 ___________

[15 marks]

11

12

13

14

10

15

Section B

[15 marks]

Answer all questions in this section

16 (a) An element Q has the mass spectrum as below.
80
70

Relative abundance

60
50
40
30
20
10
0

63

65

m/e

i)

Calculate the relative atomic mass of Q.

[2 marks]

ii)

Name element Q.

[1 mark]

....................................................................................................................................................
iii)

Write an atomic symbol, in the form , for the two isotopes of Q.

[1 mark]

...................................................................................................................................................

b)

In an experiment, 3.5 g of potassium is burned completely in air. The product is dissolved

completely in water and made up to 500 cm3 solution. What is the concentration, in mol
dm-3, of the resulting solution?
[3 marks]

17 (a)

State Daltons Law of partial pressure.

[2 marks]

(b)

1 mol of methane, CH4, is heated with 4 mol of excess oxygen until all the methane has
been converted to carbon dioxide and water vapour.
i)

Calculate the mole fractions of oxygen, carbon dioxide and water vapour in the resulting
mixture.
[4 marks]

ii)

If the total pressure of the mixture is 1.38 atm, calculate the partial pressures of oxygen,
in the resulting mixture.
[2 marks]

Section C

[30 marks]

Answer any two questions in this section.

18.

a)

i) Sketch a labelled energy level diagram to show the electronic transitions corresponding to
the formation of the first four lines in the Lyman series of the emission spectrum of
atomic hydrogen.
[3 marks]
ii) Explain how the emission spectrum of atomic hydrogen is formed.
[3 marks]

b) i) Sketch the energy level diagram of the orbitals of an atom , which is not hydrogen, for the
principal quantum numbers n = 1 to n = 3.
[2 marks]
ii) Draw a labelled diagram of all orbitals in the principal quantum number n = 2 in an atom.
[2 marks]
c) The proton number of chromium is 24
i) Write the valence electronic configuration of the chromium atom and the chromium (III)
ion.
[2 marks]
ii) Draw an energy level diagram of orbitals to show the filling of electrons in the valence
orbitals of a chromium atom.
[3 marks]
19.

a) Draw the Lewis structure of BrO3- ion and state its shape. Using the VSEPR theory, predict
the expected bond angle in the ion.
[3 marks]
b) i) Describe both the intramolecular and the intermolecular bonding in carbon dioxide.
[4 marks]
ii) Draw a dot-and-cross diagram to show the arrangement of electrons in CO2 molecule.
[1 mark]
c) i) Explain what is meant by orbital hybridisation.
[1 mark]
ii) Describe the bonding in ammonia, NH3, using orbital hybridisation.
[6 marks]

20.

a) i) Using ice and water as an example, explain the major differences in the structure of solid
and liquid.
[4 marks]
ii) Discuss the process that occurs when ice converts into liquid water.
[3 marks]
b) 100 dm3 of nitrogen gas at a temperature of 25 C and a pressure of 1.2 x 105 Pa is known to
contain traces of carbon dioxide and water. When the gas was bubbled through concentrated
sulphuric acid, the loss in mass is 0.20 g. When it is passed through aqueous solution of
sodium hydroxide, the loss in mass observed is 9.6 g. Calculate the percentage composition
by volume and the partial pressures of each component in the gas sample.
[8 marks]

MAKTAB SULTAN ABU BAKAR

UJIAN PENILAIAN PRA-PENTAKSIRAN (1) SEM 1 2015
SUBJECT : CHEMISTRY
Name : ____________________________________
Section A

Tingkatan : LOWER 6 ___________

[15 marks]

11

12

13

14

10

15

16 a) i. A = 63(30) + 65(70)
R

[1] - AR = 64.4

[1]

Energy

___ ___ ___ ___ ___

3d
___ ___ ___
3p

30 + 70

ii. Copper / cuprum / zinc

[1]
iii. 6329Cu and 6529Cu / 6330Zn and 6530Zn
[1]
b) mol = 3.5 / 39.1 @ 0.08951 mol
[1]
2 K + 2O2
2KO2 ; 2 KO2 + 2 H2O
2 KOH + H2O2
- M = mol / V @ 0.08951 / (500/1000)
[1]
- M = 0.179 @ 0.18 mol dm-3 (2 / 3 s.f. + unit)
[1]
17. a) total pressure of a mixture of gases is the summation
of the pressures that each gas
[1]
Ptotal = PA + PB + .
[1]
b) i. CH4 + 2 O2
CO2 + 2 H2O
[1]
- moltot = 2 mol O2 + 1 mol CO2 + 2 mol H2O @ 5 mol [1]
- XO2 = 2 / 5 ; XCO2 = 1 / 5 ; XH2O = 2 / 5
[2]
ii. PO2 = 2 / 5 x 1.38 atm
[1]
= 0.552 atm (3 s.f. + unit)
[1]
18. a) Energy (m1) (line converge with increasing energy level) [1]
n=
n= 5
n= 4
n= 3
n= 2
n= 1
Lyman Series (m2)
* Show all 4 1 electron transfer)

[1]
[1]
ii. when electron falls from higher energy level to ground
energy level, n = 1
[1]
- and formed discreet lines
[1]
- as frequency increased, the line spectra converges [1]

___
3s
___ ___ ___
2p
___
2s
___
1s

[1]

[2]

ii.
2s
2px
2py
2pz
5
1
c) i. a) Cr : 3d 4s
[1]
ii. 3d3
ii.
E
___ ___ ___ ___ ___
___
3d
4s
ii. E
___
4s
___ ___ ___ ___ ___
3d
19. a) Each correct [1] x 3
Lewis diagram
Shape
Trigonal
pyramidal

[1]
[1]

[2]

[3]
Bonding angle
107 - 1080

b) i. intromolecular forces : C is hold by strong covalent to

2 oxygen atom
[1]
- via a sigma bond and pi bond ; C=O (with label)
[1]
- CO2 is a simple covalent molecule
[1]
- hold by weak Van Der Waals forces
[1]
ii.

[1]

c) - several orbitals merge / combine / hybdridised to

overlap with other orbitals
ii. a) Ground
state :

[1]

[1]
c)Hybridise
state :
Diagram of
overlapping
of
ammonia,
NH3 and
water, H2O
Shape and
angle

[1]

[1]
Shape : trigonal pyramidal [1]
Angle : 1070 [1]
Bond pair electron : 3
Lone pair electron : 1 [1]

20. a) i. - arranged in order of 3-dimensional network [1]

- hold by strong hydrogen bond / have open hexagonal
structure
[1]
- arranged loosely / in tetrahedral structure
[1]
- each water has 2 hydrogen bond and 2 covalent bond [1]
ii. As pressure increased, hydrogen bond in ice broken [1]
- some water molecule enter the space of open structure[1]
- shortening the distance between water molecules
[1]
b) PV = nRT @ (1.2 x 105) (100 x 10-3) = n (8.31)(298) [1]
- ntot = 4.8458 mol
[1]
- mol of H2O = 0.20 / 18.0 @ 0.01111 mol
[1]
- mol of CO2 = 9.6 / 44.0 @ 0.2182 mol
[1]
- % of H2O = 0.229 ; % of CO2 = 4.50 % ;
% of N2 = 95.5 %
[2]
- PH2O = 275 Pa ; PCO2 = 5400 Pa ;
PN2 = 1.15 x 105 Pa
[2]