CHEMICAL ENGINEERING,

MEHRAN UET,JAMSHORO.

Ikram zardari (13CH16)

1. The rate of reaction
Ans :Decreases as the reaction proceeds.
2. With increase of 10C temperature,the rate of reaction doubles.This
increases in the rate of reaction is due to
Ans :Increase in no: of effective collision
3. The unit of rate constants is the same as that of the rate of reaction
in
Ans : Zero order reaction.
4. Which order of reaction completes first
Ans : Zero order reaction
5. The unit of reaction is
Ans : moles/dm^3sec
6. The rate of reaction b/w two specific time interval is called
Ans : average rate
7. At the beginning,the decrease in concentration of reactants is
Ans : Rapid
8. The substance which alters the rate of reaction called
Ans : catalyst
9. In human body,the catalysts are
Ans : Enzymes
10. The decomposition of ozone (O3) has order
Ans : (-ve)
11. The experimental relationship b/w a reaction rate & the
concentration of reactants called
Ans : specific rate
12. When the rate of reaction is entirely independent of the
concentration of reactants molecule then order of reaction is
Ans : Zero
13. Diamond formation from carbon has order
Ans : 3rd
14. In zero order reaction,the rate is independent of
Ans : Concentration of reactants

CHEMICAL ENGINEERING,

MEHRAN UET,JAMSHORO.

Ikram zardari (13CH16)

15. The excess energy of reactants required to dissociate into product
is known as
Ans : Activation energy
16. Activation energy speeds up the rate of reaction
Ans : false
17. The rate at which a chemical substance reacts is directly
proportional to its
Ans : Active mass
18. For the reaction
H2+CL2-2HCL
the order of reaction is
Ans : Zero
19.The rate of reation b/w two reactants A & B decreases by a factor of
4 if the
concentration of reactant B is doubled.The order in
reaction w-r-t reactant B is
Ans : -2
20. In a zero order reaction for every 10C rise of temperature ,the rate
is doubled.If the temperature is increased from 10C to 100C,the
rate of reaction will become
Ans :512 times
21.The time taken for 10 % completion of a first order is 20 minutes
then for 19 % completion, the reaction will take
Ans : 40 minutes

CHEMICAL ENGINEERING,

MEHRAN UET,JAMSHORO.

Ikram zardari (13CH16)

22.The time needed for the concentration of reactant to drop to onehalf the original value
Ans : Half life of reaction
23.An imbalanced equation is against the
Ans : law of mass action
24.A chemical reaction occurs spontaneously at constant temperature
& pressure ,if the free energy is
Ans : -ve
25.The reaction in which rate equation corresponds to a stoichiometric
equation is called
Ans : elementary reaction
26.Equilibrium of ma chemical reaction as viewed by kinetic is
Ans : dynamic (steady state)
27.For a zero order reaction,concentration of product increases with
Ans : rate of reaction time increases.
28.Arrhenius equation shows the variation of ..,with temperature.
Ans : Rate constant
29.Chemical kinetics can predict the

CHEMICAL ENGINEERING,

MEHRAN UET,JAMSHORO.

Ikram zardari (13CH16)

Ans : rate of reaction
30.With the increase in temperature, the rate constant obeying
Arrhenius equation
Ans : increases
31.According to Arrhenius equation of temperature dependency of rate
constant for an elementary reaction is
Ans :k directly proportionality to e^E/RT.
32.A reaction which is catalyzed by a base is
substances which have tendency to

catalyzed by all

Ans : Gain of proton

33.The rate of reaction does not decrease appreciably as the reaction
proceeds in case of .reactions.
Ans : Autocatalyst.
34.Space time equals the mean residence time
Ans : When the density of the reaction mixture is constant.
35.In a first order reaction ,the time required to reduce the
concentration of reactant from 1 mol/litre to 0.5 mol/litre will
be..that required to reduce it from 10 mol/litre to 5 mol/litre
in the same volume
Ans : same as

CHEMICAL ENGINEERING,

MEHRAN UET,JAMSHORO.

Ikram zardari (13CH16)

36.A Limiting reactant which
Ans : consumes first
37. Inversion of sugar-cane is an example of
Ans : Bio-molecular reaction with first order
38. Differential method for analyzing the kinetic data is used
Ans : For testing complicated mechanism
39.Integral method for analyzing the kinetic is used
mechanisms with

Ans :When the data is scattered & for testing the specific
simple rate expression.

40.A catalyst promoter

Ans : Improves the activity of catalyst
41.A reaction
A3B
is conducted in a constant pressure
vessel.Starting with pure A,the volume of reaction mixture
increases 3 times in 6 minutes.The fractional conversion is
Ans : 1
42.The study of kinetics is the easiest in the case of
Ans : Irreversible reactions
43.If delta G (free energy change) for a chemical reaction is very large
& negative,then the reaction is

CHEMICAL ENGINEERING,

MEHRAN UET,JAMSHORO.

Ikram zardari (13CH16)

Ans :Very much feasible.
44.Photochemical reaction rate does not depend significantly on
temperature because
activation energy by absorption

Ans :The energy of reacting molecules exceeds the

of light.

45.In an exothermic reaction ,the energy of reacting substances as

compared to that of production is
Ans : More.