Imprtant Guess for 2nd Year By KDK Sir !

Section A
1.Which one is not an alkali metal
a. Fr. b. b .Cs C. Rb d. Ra (d)
2.Strongest reducing agent among the halogen is
a. Cl2. b. b .F2 .c. C. Br2 d. D. I2 (d)
3. The dry ice is
a.Solid ice. b . Solid CO2 . C. Solid SO2 D. Solid C6H6 (a)
4. Which one of the following is acidic in nature?
a.Al2O3. b .CO2 . C. CO D. Cao (b)
5. When sodium is heated with excess of O2 which of the following is formed
a.NaO b .NaO2 . C. Na2O D. Na2 O d. none of these (a)
6. The inert Pair effect dominates
a. Pb. b .Sn . C. c D. Si (a)
7. The elements of group IVA which has no tendency to from dichlorides are
a. Carbon and Silicon. b .P and Sn . C. Ga and C D. Sn and Si (a)
8. The highest b.p of HF among the hydrogen halides is due
a. Lowest E.N of Fluorine. b. Highest E.N of Fluorine.
C. Lowest atomic weight of Fluorine d. All of these (b)
9. Third period elements that initially reacts rapidly with oxygen to from a protective oxide
coating that prevents further reaction is
a. sodium . b. Alumimium . C. Silicon d. Magnesium (b)
10. Which one has greater affinity for oxygen?
a. B. b .Na . c. k d Mg. (c)
11. The transition element copper and ____________ are the best electrical conductors.
a. Iron. b Vanadium. C. Chromium. d. Manganese (a)
12. The Co ordination compound [Cu(Cl4)]2 exist in
a.Tetrahedral. b .Octahedral . c. Square planer D. Rhombic (a)
13. Acidified KMnO4 act as an _______ agent
a.Oxidizing. b .reducing . C. bleaching D. collaring (a)
14. The paramagnetic nature of a substance depends on
a. The number of electron in the outer most orbits . b .The number of electron that easily ejected.
c. The unpaired electrons d.The number of unpaired electrons. (c)
15. Select a ligand which is bidentate
a. H2O b.NH3 . C.CO D .C2O4-2 (d)
16. Cu+2 salt solution is blue in colour due to transition of electron from
a. S to P- orbital b. d- d orbital. c . P-d orbital. d. P to P orbital (b)
17. All the substances are organic except
a. graphite .b. Urea .c. methane .d. acetic acid (a)
18. Which one cannot be detected in a given organic compound directly?
a. chlorine .b. Phosphorus . c. nitrogen d. oxygen (b)
19. Which one of the following compound is expected to exhibit geometrical isomerism?
a.1- butane .b.2-butene. c.2- Methyl propane .d. 2- butyne (b)
20. The overlapping of orbitals in benzene is of the type
a. sp-sp b. sp2 sp2 c.sp3-sp3 d .s-s (b)

21. How many isomers are possible for C2H6O

a.2 .b 4 c.8 d.5 (a)
22. Dehydrohalogenation of alkyl halide is carried out in the presence of
a. Zinc dust b. H2SO4 c. alcoholic KOH d. aqueous KOH (c)
23. Which one of the following has planar structure?
a. alkane b. alkene c. alkyne d. cycloalkane (c)
24. Nitrobenzene reacts with chlorine in the presence of AlCl3 .The product obtained is
a. o- chloronitrobenzene .b. m- chloronitrobenzene c. P- chloronitrobenzene d.All of these (b)
25. Which one is more reactive towards nucleophile substitutions reaction?
a.C2H5Br b. C2H5I c.C2H5F .d C2H5Br (b)
26. All electron deficient species are classified as
Nucleophiles .b. Electrophiles .c. Bases All of these (b)
27. The C-atom carrying positive charge and attached to three other atoms or groups is called
Carbonium ion .b.Carbonium .c.Oxonium ion .d.Carbonion (a)
28. The reaction of alcohol with sodium produces
Ethane .b. Ethane .c. Alkoxide . d.Aldehyde (c)
29. Oxidation of secondary alcohol gives
Organic acid .b. Ether. c. Aldehyde. d. Ketone (d)
30. The compound x when heated with dry silver oxide forms ether identify x
Alcohol b. Phenol c .Alkyl halide d.Ether (a)
31. Denatured alcohol is known as
Absolute alcohol .b.Wood spirit c. Methylated spirit d. Rectified spirit (c)
32. A compound x is formed when the vapour of phenol an passed over red hot zinc dust the
compound x is called
Toluene .b. Xylene .c. Benzene .d.Benzol (C)
33.The appearance of cloudiness in the Lucas test for alcohol is due formation of
Alkyl halide b. Acid chloride .d. Aldehyde .c. Ketone (a)
34. Which of the following compounds can react with ammoniacal silver nitrate solution to form
silver mirror?
Acetone .b. Ethanol. c. Ether d. Ethanol (D)
35. Which of the following compounds precipitate Cu2O from Fehlings reagent but does not
react with sodium metal?
C2H5OH. b. C2H5CHO. c. CH3CH.d.CH3. e. CH3COCH3 (B)
36. When propanol is heated with Fehlings solution there is
A colour from green to orange b A colour from blue to red
A negative test with tollens regent d.No colour change (B)
.Which one of the following represents the formula of an aromatic carboxylic acid
HCOOH .b. C2H5OH .c. C6H5COOH. d. C6H5CH2OH (C)
.Which is the strongest acid
A. Ethanol.Acetic acid. B. Chloro acetic acid. C. Flouro acetic acid (D)
Estrification is the reaction between
Acid and ester .B .An acid and alcohol. C. An acid halide and ester D.All of these
The hydrolysis of an ester is in the presence of alkali (NaOH) is known as
Saponification .B. Decarboxylation. C. Esterification d.All of these (A)
Steroids belong to the family of
a.Carbohydrates .B. Protein. C .Lipid

d.Enzymes
42.Protein present in haemoglobin has the structure known as
a.Primary. b.Secondary c.Tertiary d.Quaternary (d)
43.The optimum PH of pepsin is
A. 1.5 . B.1. C.2.5. D.2 (D)
Ethanol is produced from starch by the process of
a.Hydrolysis b.Hydrogenation c.Decomposition (d)Fermentation (d)
Specificity of enzymes depend upon
Active site b.Linear sequence c.Turn over number d.None of these (a)
The best source of iron is
a.Organ meat b.Milk c. Tomato d. Potato (a)
47 In competitive inhibition, the inhibitor
Competes with enzymes
Irreversibly binds with enzymes
Bind with substrate (d)
Competes with substrate
Liquids forms of triglycerides at room temperature are called
Oils b.Fats c.Solid d.None of these (a)
Which is true for DDT?
a.Not a pollutant b.An antibiotics c. An anticeptics d. A non degradable pollutant (d)
What is black gold?
a.Petroleum b.Coal c.Coal tar d.Natural gas (b)
Which one is condensation polymer?
a.PVC b.Polythene c.Nylon d. None of these (c)
Pollutants have adverse effect over
Biosphere. b.B.Ecosystem c.Hydrosphere d.All of these (d)
Photo chemical smog is primarily caused by
CO.b.CO2. c O3. D.NO2 (d)
The temperature range of the troposphere is
15 to- 56 C. b. 56 to -2 C c.-2 to -92 C d.-92 to 1200 C (a)
Which of the following is quantitative chemical analysis
Salt analysis .b. Titration .c. Flame test. d. Borax bead test (b)
56 Which one of the following technique is used for determination of functional group in a
compound?
IR spectroscopy. b. NMR c. UV spectroscopy. d. MASS spectroscopy
Which one method would be best for finding the identity of an organic compound?
Mass spectroscopy. B. NMR. C. IR. D.UV (B)
UV ranges from
400 to 800 nm. B.800 to 1200 nm. c. 1200 to 1600 nm. d.10 to 400 nm (d)
SECTION-B
Q1. Why NaCl does not conduct electricity in solid state?
Q2. What is a flame test?
Q3. Why beryllium is differ from the members of its group?
Q4.Why Fluorine is stronger oxidizing agent than chlorine?
Q5.Why BeCl2 is covalent and not ionic?
Q6.Explain the amphoteric nature of Be(OH)2 ?

Q7.why the atomic radius of argon is larger than all the members of the 3rd periods?
Q8. Comment on the electronic configuration of chromium and copper?
Q9. Explain the catalytic behavior of transition elements?
Q10. Why dilute HNO3 is added to the sodium extract before detection of halogens in organic
compounds?
Q11. Although Bucky ball is an allotropic form of carbon but it is included in organic chemistry?
Q12. Differentiate between acylic and cyclic organic compounds?
Q13. How coal can be converted into petroleum?
Q14. What is the difference between aliphatic and aromatic hydrocarbons?
Q15.How double bond in an organic compound can be identified?
Q16.How the triple covalent bond in an organic compound can be identified?
Q17.What is Markownikoffs rule?
Q18.Why benzene is less reactive than ethane but more reactive than ethane?
Q19.Why there is no geometrical isomers of 1- butane?
Q20.What is the different between Tautomerism and metamerism?
Q21.Why anhydrous ether is used to prepare RMGX?
Q22.Why tertiary carbonation is more stable?
Q23.What is Lucas test?
Q24.Phenol is more acidic than alcohols?
Q25.What is Tollens test and Fehling test?
Q26.Methanoic acid is stronger acid than ethanoic acid?
Q27.Chloroacetic acid is stronger acid than acetic acid?
Q28 Differentiate between addition and condensation polyners?
Q29 What is an acid rain?
Q30What is greenhouse effect?
Q31.Write a short note on NMR.
Q32.Explain the amphoteric nature of Be(OH)2?
Q33.Explain structure of CO2?
Q34.Explain O/P orientation in benzene?
Q35.What do you about Friedal craft reaction?
SECTION-C
S & P block elements
Q1.What is meant by bond enthalpy? Explain the bond enthalpies in hydrogen halides.
Q2.What is meant by inert pair effect .Explain the inert pair effect in the formation of ionic and
covalent bond?
Transition Elements
Q1.Explain the following characteristics of transition elements
Variable oxidations state
Magnetic properties.
Alloy formation
Colour of complexes.
Q2.Explain shapes of four and six co-ordinated complexes.
Q3.Explain role of iron in Habers process.
Q4.Write note on Bucky balls
HYDROCARBONS
Q1.What are HCs how they are classified.?

Q2.Explain free radical substitution Rxn.?

Q3.How alkenes are prepared.?
Q4.Explain the following chemical properties of alkene
Hydro-halogenation
Hydration.
Ozonolysm
Epoxidation.
Q5.What do know about conjugation of alkene.?
Q6.Describe any two methods of preparation of alkynes.?
Q7,Describe the structure of benzene on the basis of M.O.T?
Q8.Describe the electrophilic substitution reaction in benzene ?.
Q9.Explain the nitration, sulphonation and halogenations in benzene.?
Alkyl halides
Q1.What are monohaloalkanes, how they are prepared
Q2.Different between E1 and E2 Rxns.
Q3.Explain substitution Rxn in alkyl halides
Q4.How RMgx reacts with
Carbindioxide
Aldehydes
Esters
Alcohol, phenols & ethers
Q1.What are phenol, how they are prepared.
Q2.Wgat are thiols
Aldehydes & ketones
Q1.How aldehydes and ketones are prepared.
Q2.Explain clemmenson and wolf Kishner reduction.
Carboxylic acids & derivatives
Q1.Write down various methods of preparation of carboxylic acid.
Biochemistry
Q1.What are carbohydrates, how they are classified.
Q2.What are lipids. Describe their classification.
Q3.Define enzymes. Describe their role in digestion of fat, carbohydrates, and protein.
Industrial chemistry
Q1.Define dyes how they are classified.
Q2.What are adhesive and discuss their types.
Environmental chemistry
Q1.What is water pollution and what are its main sources.
Explain the role of ozone layer.
Analytical Chemistry
Q1. Define mass spectroscopy. Explain its construction and working.
Q2. Differentiate between atomic emission and atomic absorption spectra.
Q3.What is meant by NMR. Explain chemical shift in different case.
Q4.What do you know about combustion analysis