1.

Question
(a)
(i)
(ii)
(b)

(i)
(ii)

(c )
(d)
(e )

2.

(i)
(ii)
(iii)

(a)
(b)

(i)

(c )

(ii)
(i)

(d)

(ii)
(iii)
(i)

Rubric
+1
The number of protons is more than the number of electrons
by one unit.
P // T
Two shells filled with electrons//Two occupied shells
Proton number = 6
Nucleon number = 12 or 13
Because Q and R have the same number of valence electron
that is 1.
QS
Ionic bond
High melting and boling point//
Soluble in water//
Insoluble in organic solvent//
Can conduct electricity in molten state or aqueous solution
Any one
TOTAL
MARKING SCHEME
PART A
Electrical energy to chemical energy
Cu2+, SO42- , H+, OH- // Copper(II)ion, Sulphate ion,
Hydrogen ion, Hydroxide ion
Cu2+(aq) + 2e- Cu(s)
From magnesium plate to copper plate through external
circuit
Mg(s) Mg2+(aq) + 2eThe cell voltage will increase

Mark
1
1
1
1
1
1
1
1
1

1
1
1
1
1
1
2

Silver plate
Silver nitrate
solution
Iron spoon

(ii)

3.

(a)
(b)
(c )
(d)

(e)

(f)

4.

(a)
(b)

(c )

(i)
(ii)

Functional diagram 1
Labelling are correct - 1
Use a low electric current//
The iron spoon is rotated slowly throughout the process
TOTAL

blue
CuO + H2SO4 CuSO4 + H2O

1
2

Formula of reactants and products are correct

Acid completely reacts with copper(II)oxide //
Acid is completely neutralized by copper(II)oxide
Mass of CuSO4 = Number of mole of CuSO4 x molar
mass of CuSO4
= 0.1 mol x [64 + 32 + 64]g mol-1
- 1
= (0.1 x 160) g
= 16.0 g
-1
1. NaOH/NH3 solution is added drop by drop until in
excess
2. Blue precipitate is insoluble/blue precipitate is
soluble in excess NaOH/NH3 solution.
Carbon dioxide r: formula
CuCO3
TOTAL
pH scale is a scale of 0 to 14 that shows the degree of acidity
or alkalinity of a solution.
1. Hydrochloric acid is a strong acid that ionizes
completely in water to produce a high concentration
of hydrogen ions.
2. Ethanoic acid is a weak acid that ionizes partially in
water to produce a low concentration of hydrogen
ions. (Any one)
Mg + 2HCl MgCl2 + H2

1
2

1
1
10
1
2

(d)

(i)
(ii)

(e )
(f)
(g)

5.

(i)
(ii)

(a)
(b)
(c )

Number of mol of NaHCO3 = 2.1 / 84

= 0.025 mol
Molarity of NaHCO3 = 0.025 x 1000/250
= 0.10 mol dm-3
Sodium hydrogen carbonate is basic
M1V1 = M2V2
0.10 x 250 = 0.05 x (250 + V)
V = 250 cm3
Effervescence occurs
NaHCO3 + HCl NaCl + H2O + CO2
TOTAL

1
1
1
2
- 1
- 1

Zinc / zink
atom
(i)
(ii)

[ particles touch
Closed arrangement
Condition : rows 3]
zarah bersentuhan
Zinc atom/ Atom
susunan tertutup
zink
syarat : barisan 3 ]
Copper atom /
Atom kuprum

1
1
11

1
1
1
2

[ drawing shows zinc atom in the lattice of copper

Lukisan menunjukkan atom zink dalam kekisi
kuprum
]
1

(d)

[ Label zinc and copper correct.

Label zink dan kuprum betul ]
1
copper has orderly arrangement of atom when force is
applied, atoms are easily to slide.
In brass, the presence of zinc atom disrupt the orderly
arrangement of copper atom when force is applied, atom
difficult to slide.
kuprum mempunyai susunan atom sekata/teratur
apabila dikenakan daya, atomnya mudah menggelongsor
Dalam loyang kehadiran atom zink mengganggu susunan
teratur atom kuprum apabila dikenakan daya, atomnya
sukar menggelongsor
1

1
1
1

(e)

(i)
(ii)

tin // stanum // timah

to beautify // to improve the appearance
untuk mencantikkan // membaiki rupa
to withstand corrosion
mengelak hakisan
TOTAL

Question
number
6 (a)

1
1
1
11

Answer

Mark

hydrogen peroxide
solution
manganese(IV) oxide
functional diagram
label
(b)

(i) Oxygen
(ii) 2H2O2 2 H2O + O2

(c)

[formula correct and balanced]

[Formula correct but not balanced, 1 mark]

(i) Experiment II
(ii) Concentration of hydrogen peroxide in Expt II is higher than in Expt I

1
1
1
2
1
1

(iii)
II
I

2
(d)

Lower the activation energy ( 1)

Frequency of effective collision increases (1)

2
Total

11

PART B
7

(a)

Butan-1-ol

Butan-2-ol

2-methylpropan-1-ol

2-methylpropan-2-ol
Choose any two structural formula and correct name.

(b)
Aspect
Type of
compound
Homologous
series
Type of atom
present
Solubility in
water
Functional
group
Reaction with
bromine water

(c)

P
hydrocarbon
alkene
Contains carbon
atoms and
hydrogen atoms
only
Insoluble in
water
Carbon-carbon
double bond
Decolourises
brown bromine
water

Reaction with
acidified
potassium
manganate(VII)
solution

Decolourises
purple colour of
potassium
manganate(VII)
solution

General formula

CnH2n, n=2,3,

Q
Nonhydrocarbon
Carboxylic acid
Contains carbon
atoms, hydrogen
atoms and
oxygen atom
Soluble in water
Carboxyl group
Does not change
the brown
colour of
bromine water
Does not change
the purple
colour of
potassium
manganate(VII)
solution
CnH 2n+1COOH,
n=0,1,

Apparatus : test tubes, dropper

Materials: bromine water // acidified potassium
manganate(VII) solution, hexane, hexene
Procedure:
1. 2 cm3 of liquid in bottle X is poured into two
separate test tubes.
2. 2 to 3 drops of bromine water are added to two
test
Tubes

1
1

1
1
1
1

1
Max 6

1
1
1
1

3.The mixture is shaken.

4.Any observation is recorded.
5. Step 1 to 3 are repeated using liquid in bottle Y to
replace liquid in bottle X.

Observation:
Liquid in bottle X
Brown bromine water
decolourises // purple
acidified potassium
manganate (VII) solution
decolourises

No.
8

Liquid in bottle Y
No visible change.

1+1

Liquid in bottle X is hexene

Liquid in bottle Y is hexane

1
1
__
10

T0TAL

20
Mark Scheme

(a)
(i)

1
1

(ii)

Blue solution X = Copper (II) sulphate

Colurless solution Y = potassium carbonate //
sodium carbonate // ammonium carbonate
Double decomposition method

(iii)

CuSO4 + K2CO3 CuCO3 + K2SO4 //

Sub
Mark
1
1

Total
Mark
2

1
1

1
1

CuSO4 + Na2CO3 CuCO3 + Na2SO4 //

CuSO4 + (NH4 )2CO3 CuCO3 + (NH4 )2SO4
Correct rectants and products
Balanced equations
(iv)

(b)

Add sodium hydroxide solution (until excess)

Blue precipitate formed
//
- Add ammonia aqueous / ammonium
hydroxide solution (until excess)
Blue precipitate soluble in excess

(i)
(ii)

Copper(II) oxide
Materials : [25 100] cm3 of [0.5 2.0] moldm-3
copper (II)sulphate solution(any suitable answer)
[25 100] cm3 of [0.5 2.0] moldm-3 sodium
carbonate solution
(any suitable answer) Filter paper
Apparatus : Filter funnel, beakers, retort stand and
clamp, glass rod and 100cm3 measuring cylinder.
Procedures :
- About [25 100] cm3 of [0.5 2.0] moldm-3
copper (II) sulphate solution is measured into
a beaker.
- About [25 100] cm3 of [0.5 2.0] moldm-3
sodium carbonate solution is measured and
mixed with the solution in the beaker.
- The mixture is stirred with a glass rod.
- The precipitate formed is removed by
filtration.
- The precipitate is rinsed with distilled water.
- The precipitate is dried between the filter
paper

1
1
1
1

1
1
1
1
1
1
10

(iii)
2AgNO3 + MgCl2 2AgCl + Mg(NO3)2
No of moles AgNO3 = 50 x 1.0 / 1000 = 0.05 mol

1
2

2 mol AgNO3 2 mol AgCl from the reaction

0.05 mol AgNO3 0.05 mol AgCl
Mass of AgCl = 0.05 x 143.5
= 7.175 g

1
TOTAL

20

PART C
Question
No.

Explanation

Mark

Mark

9 (a)(i)
(a)(ii)

Correct apparatus set up

Correct labelling

1
1

Volume of gas / cm3

Time/min
Curve
labelling axes with units
(b) (i)

CaCO3

2HCl CaCl2

1
1
+ CO2 + H2 O

No. of moles acid = (0.1)(50) = 5 x 10-3

1000
2 mol of HCl reacted evolve 1 mol of CO2
0.005 mol of HCl reacted evolve 0.005 mol of CO2
2
= 0.0025 mol CO2
Volume of CO2 =(0.0025)(24)
= 0.06 dm3
= 60 cm3
(ii)

Overall average rate of reaction =Total volume of CO2

Total time
= 60 cm3
300 s
= 0.2 cm3 s-1

1
1

1
1
4
1
1

(c)

Rate of reaction in Expt II is higher than Expt I

Experiment II is at a higher temperature,
the kinetic energy of the reacting particles increases
and the particles move faster
Frequency of collision between marble and hydrogen

1
1
1

ions increases
Frequency of effective collision increases
Rate of reaction in Expt III is higher than Expt I
Powdered marble in Expt III has greater total surface
area/ bigger surface area per unit volume
Powdered marble is more exposed to collision
Frequency of collision between marble and hydrogen
ions increases
Frequency of effective collision increase

1
1

1
1
1
1
1

Total

20

[ -1 if students use HCl or particles in the explaination]

10 (a)

Position of ions effect the product of electrolysis process

Ions presence in the solutions are Cu2+, SO42-, and H+
In set I
ion move to cathode is H+

1
1
1

H+ ions is discharged at cathode to form hydrogen gas

2 H+ + 2e
H2

In set II
Ions move to cathode are Cu2+ and H+
Cu2+ is discharged due to the lower position in the ECS // it is
easier to be discharged
Cu2+ + 2e
Cu

1
1
1
1
1
max 6

(b)

1. Zinc is more electropositive // Negative terminal :

Zn
Zn2+ + 2e

2. Copper is less electropositive // Positive terminal:

Cu2+ + 2e
Cu

3. The electron move (from negative terminal to the positive

terminal ) / (electrode zinc to electrode copper)

4. The flow of electron, produce the electric current//

The needle of the voltmeter deflected, shows the electric current is
produced

1
4

(c)

Copper(II) sulphate solution

Iron spoon

Copper electrode

Functional diagram : [switch on, battery, shade of the solution]

Label diagram : [iron spoon at cathode, copper rod at anode, copper(II)

sulphate solution]

(i) 100 cm3 of 1.0 moldm-3 of copper(II) sulphate solution is poured into 1
a beaker
(ii) An iron spoon is connected to the negative terminal of the battery //
1
is connected to the cathode

(iii) Copper rod is connected to the positive terminal of the battery // is

connected to the anode
(iv) The switch is on // can infer from the diagram
(v) The observations is recorded in the table after 15 minutes.

1
1

(vi)
Electrodes
Anode
Cathode

Observation
Copper electrode become thinner
Iron spoon is coated with brown solid / metal

1
1

(vi) Half equations :

Anode :

Cu

Cathode : Cu 2+ + 2e

Cu 2+ + 2e

Cu
JUMLAH

10
20