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Application
The AQUASWEEP CRW85838 pipeline
hydrostatic test cocktail is a water soluble
blend of filming amines, a filming quaternary
salt and an oxygen scavenger, formulated
for a broad application in the oil and gas
market. It is water soluble and oil dispersible.
In addition to providing corrosion and fouling
protection against carbon dioxide and
organic acids, the cocktail can be used in the
performance of hydrotesting pipelines during
pre-commissioning services and laying a
pipeline in wet stagnant conditions.
The AQUASWEEP CRW85838 inhibitor cocktail
absorbs oxygen and inhibits the development
of bacteria-related corrosion. This includes
microbial-influenced corrosion (MIC) caused
by oxygen, sulfate reducing bacteria (SRB), or
other bacteria in the hydrotest water or preexisting bacteria in the pipeline. The inhibitor
Typical properties
(may include other properties not listed below)
Appearance
Amber liquid
Specific gravity
at 20C (68F)
~
~1.04
Pour point
~
~-15C (5F)
~
~16 cSt
Flash point
pH
~
~7
Solubility: Brine
Soluble
Water
Soluble
1 to 3 months
300 ppm
6 to 18 months
500 ppm
18 to 24 months
700 ppm
Environmental data
CEFAS Gold-rated with no product or
substitution warning. ECOTOX reports
available upon request.
Materials compatibility
Materials suitability is based on analysis of
test results obtained under specified laboratory
conditions. All materials selection should be based
on actual application. Testing results for materials
will be made available on request.
Applications
Subsea
pipelines
Land-based
easily monitored
Effective treatment in
pipeline systems
Combination
formula
Filtration
methodology available to
lower residuals in environmentally
sensitive areas
Meets the most rigid permit
requirements for discharge to
open sea
Good
thermal stability
2014 Baker Hughes Incorporated. All rights reserved. 40960 BPPOCRW85838 05/2014
pipelines
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
:
:
:
:
CRW85838
CRW85838
Corrosion Inhibitor
Liquid.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Not available.
1.3 Details of the supplier of the safety data sheet
Baker Hughes
Kirkby Bank Road,
Knowsley Industrial Park,
Liverpool,
L33 7SY, UK
Tel: +44 (0)151 545 3899
Fax: +44 (0)151 547 3590
e-mail address of person
responsible for this SDS
: paul.chapman2@bakerhughes.com
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CRW85838
Indication of danger
Risk phrases
: Harmful
: R22- Harmful if swallowed.
R36- Irritating to eyes.
: Not applicable.
:
: Not applicable.
Safety phrases
Hazardous ingredients
Supplemental label
elements
2.3 Other hazards
Substance meets the
criteria for PBT according
to Regulation (EC) No.
1207/2006, Annex XIII
Not applicable.
P: Not available. B: Not available. T: Not available.
Not applicable.
vP: Not available. vB: Not available.
: Not available.
: Mixture
Classification
Product/ingredient
name
ethoxylated amine /
acid salt
ethanediol
Identifiers
-
EC: 203-473-3
CAS: 107-21-1
Index: 603-027-00-1
2-(2EC: 203-961-6
butoxyethoxy)ethanol
CAS: 112-34-5
Index: 603-096-00-8
didecyldimethylammonium EC: 230-525-2
chloride
CAS: 7173-51-5
Index: 612-131-00-6
67/548/EEC
Type
10 - 30
Xn; R22
[1]
10 - 30
Xn; R22
[1] [2]
5 - 10
Xi; R36
[1] [2]
1-5
Xn; R22
C; R34
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
Type
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CRW85838
Ingestion
Protection of first-aiders
: Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
: Wash out mouth with water. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. If vomiting occurs, the
head should be kept low so that vomit does not enter the lungs. Get medical
attention. Get medical attention if adverse health effects persist or are severe. If
unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway.
: No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact
: Irritating to eyes.
Inhalation
: Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin contact
: May cause skin irritation.
Ingestion
: Harmful if swallowed.
Over-exposure signs/symptoms
Eye contact
: Adverse symptoms may include the following:
irritation
watering
redness
Inhalation
: No specific data.
Skin contact
: No specific data.
Ingestion
: No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to medical doctor
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: Not available.
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CRW85838
Special protective
equipment for fire-fighters
Additional information
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 8).
6.2 Environmental
precautions
: If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also Section 8 for
additional information on hygiene measures.
6.3 Methods and materials for containment and cleaning up
Small spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Use spark-proof tools
and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Large spill
: Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilt product.
: Note: see section 8 for personal protective equipment and section 13 for waste
disposal.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CRW85838
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and
smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing
vapour or mist. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Do not enter storage areas and confined spaces
unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use non-sparking tools. Take precautionary measures against electrostatic
discharges. To avoid fire or explosion, dissipate static electricity during transfer by
earthing and bonding containers and equipment before transferring material. Empty
containers retain product residue and can be hazardous. Do not reuse container.
: Corrosion Inhibitor
Not available.
2-(2-butoxyethoxy)ethanol
Recommended monitoring
procedures
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CRW85838
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Respiratory protection
Hand protection
Eye protection
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
: Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Skin protection
Environmental exposure
controls
: Not available.
:
:
:
:
:
:
Density
Relative density
Solubility
Partition coefficient: noctanol/water
:
:
:
:
Not available.
1.005 to 1.075 (16C)
Viscosity
Vapour density
Evaporation rate (butyl
acetate = 1)
Decomposition
temperature
: Not available.
Flash point
Explosive properties
Explosion limits
Oxidising properties
Vapour pressure
Auto-ignition temperature
9.2 Other information
Not available.
: Not available.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CRW85838
: Not available.
: No specific test data related to reactivity available for this product or its ingredients.
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions will not occur.
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
: Reactive or incompatible with the following materials:
oxidizing materials
10.5 Incompatible
materials
10.6 Hazardous
decomposition products
General
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
Inhalation
Ingestion
Skin contact
Eye contact
Result
Species
Dose
Exposure
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LD50 Dermal
Rabbit
Rat
Rabbit
Rat
Rabbit
9530 uL/kg
4700 mg/kg
2700 mg/kg
4500 mg/kg
4177 mg/kg
LD50 Oral
LD50 Oral
Rat
Rat
84 mg/kg
560 mg/kg
:
:
:
:
:
:
:
:
:
:
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CRW85838
Conclusion/Summary
Species
Fish - Oncorhynchus mykiss
Fish - Lepomis macrochirus - 33
to 75 mm
Algae
Exposure
96 hours
96 hours
48 hours
Test
Result
Dose
OECD 303 A
91 % - 50 days
OECD 302 B
87 to 94 % - 28
302B Inherent
days
Biodegradability:
ZahnWellens/EMPA
Test
OECD 301 B
72 % - Readily - 28 days
Conclusion/Summary
: Not available.
Product/ingredient name
Aquatic half-life
Photolysis
didecyldimethylammonium chloride
12.3 Bioaccumulative potential
Product/ingredient name
Not available.
LogPow
BCF
96 hours
96 hours
3 hours
48 hours
96 hours
21 days
34 days
Inoculum
-
Biodegradability
Readily
Potential
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CRW85838
Hazardous waste
Packaging
Methods of disposal
Special precautions
: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.
14.1 UN
number
14.3 Transport
14.4 PG*
hazard class(es)
ADR/RID Class
Not
regulated.
IMDG Class
Not
regulated.
IATA Class
Not
regulated.
Label
14.5
Environmental
hazards
Additional
information
ADR/RID Class
No.
IMDG Class
No.
IATA Class
No.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
: Not available.
: Not available.
: Not available.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CRW85838
: Not determined.
: Not listed
: Listed
: This product contains substances for which Chemical Safety Assessments are still
required.
: Not available.
Justification
Calculation method
Calculation method
Calculation method
: H301
Toxic if swallowed.
H302
Harmful if swallowed.
H314
Causes severe skin burns and eye damage.
H315
Causes skin irritation.
H318
Causes serious eye damage.
H319
Causes serious eye irritation.
: Acute Tox. 3, H301
ACUTE TOXICITY: ORAL - Category 3
Acute Tox. 4, H302
ACUTE TOXICITY: ORAL - Category 4
Eye Dam. 1, H318
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Skin Corr. 1B, H314
SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2, H315
SKIN CORROSION/IRRITATION - Category 2
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CRW85838
Version
: 1
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy
himself as to the suitability of such information for his own particular use.
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