II.
of the requirements the fire: oxygen, fuel, heat). This material can provide oxygen
in a reaction even though there is no air. Besides that, oxidizing agents can react
with reducing agents to generate heat and products that may be gaseous (causing
pressurization of closed containers). Explosive mixtures of oxidizing agents with
reducing agents often persist unchanged for long periods if initiation is prevented.
Actual reactivity varies greatly with the identity of the organic compound.
Oxidizing agents can react violently with active metals, cyanides, esters, and
thiocyanates.
III.
IV.
Bromine
Chromic acid
Sodium perchlorate
Hydrogen peroxide
Ammonium permanganate
Barium peroxide
Potassium peroxide
Calcium chlorate
Fluorine
Magnesium peroxide
etc
Storage of Oxidizing Materials
e. Label Storage
Containers and storage areas must be labeled to include the name
of the material, the level of danger, date received and used. For example,
red for flammable materials, oxidizing materials yellow, blue for toxic
materials, white to corrosive materials, and green for low danger materials.
For oxidizing materials requiring temperature control, the
recommended storage temperature range should be plainly marked on the
container. It is also a good practice to mark the date that the container was
received and the date it was first opened.
f. Container
Before storing, inspect all incoming containers to ensure that they
are undamaged. Repackaging can be very dangerous especially when
using contaminated or incompatible containers. Protect containers against
banging or other physical damage when storing, transferring or using
them. Do not use wooden pallets or other combustible pallets for storing
containers of oxidizing materials.
Normally keep containers tightly closed when storing unless the
supplier's instructions state otherwise. This helps to avoid contamination
of the material or evaporation of solvents used to dilute oxidizers, such as
organic peroxides, to safer concentrations.Keep only the smallest amounts
possible (not more than one day's supply) of oxidizers in work
areas.Empty drums, bottles, bags, sacks and other "oxidizing agent"
containers usually have hazardous oxidizing residues inside them
Hazard of Oxidizing Materials
V.
Intensify combustion
VI.
chemical.
Clean work areas carefully when done.
Dispose of contaminated material in the hazardous waste storage container.
Do not dispose of waste with incompatible material.
Paper towels or other similar material may pose a fire risk when
contaminated. Proceed with caution when working with oxidizers around
other organic material (paper, wood, cloth).
6. Avoid touching yourself (e.g., scratching your nose or rubbing your eyes) with
contaminated hands.
7. Wash thoroughly at the end of the workday even though you have done
everything mentioned before.
Pic 2. Googles
Ordinary glasses do not provide adequate protection. (Contrary to
popular opinion these glasses cannot pass the rigorous test for industrial
safety glasses). Adequate safety glasses must meet the requirements of the
Practice for Occupational and Educational Eye and Face Protection and
must be equipped with side shields. Safety glasses with side shields do not
provide adequate protection from splashes; therefore, when the potential
for splash hazard exists other eye protection and/or face protection must be
worn. Always wear eye protection when working with oxidizers. Avoid
ordinary safety glasses. Use chemical safety goggles instead.
b. Hand Protection
Pic 3. Gloves
Gloves should be worn when handling oxidizing materials.
Disposable gloves provide adequate protection against accidental hand
contact with small quantities of most laboratory chemicals. Gloves are
made of thick rubber and fireproof.
c. Face Protection
Source :
www.hc-sc.gc.ca/ewh-semt/occup-travail/whmis-simdut/oxidizing-comburanteseng.php
www.ccohs.ca/oshanswers/chemicals/oxidizing/oxiziding_hazards.html
www.brandeis.edu/ehs/labs/oxidizers.html
www.ihsa.ca/whmis_review/oxidizing_materials.html
www.ccohs.ca/oshanswers/legisl/whmis_classifi.html
Conclution
materials, materials that have a low flame poin and special ventilation.
Safety Equipmentsof oxidizing materials are eye protection,eyewash, fume
hood,glove (dry) box, gloves, hazard assessment, EHRS Notification,
protective apparel, safety shielding, safety shower, speciall ventilation,