Experiment A
Propionic
acid
Titration
of
Titration
of
(mL)
5
3
1
Propionic
Propionic
acid
acid
(organic)
(aqueous)
concentratio
concentratio
(mL)
(mL)
n in aqueous
n in organic
25.5
12.3
7.9
46.9
30.5
20.0
layer, Y
0.938
0.610
0.400
layer, X
0.510
0.246
0.158
Experiment B
Flow
rate
of
aqueous
phase (L/min)
Sodium
hydroxide
0.20
0.20
0.1 M
0.025M
Feed (mL)
0.40
0.20
Raffinate (mL)
0.30
1.40
Extract (mL)
0.5
3.30
concentration (M)
Propionic
acid
extracted
0.008
K=Y/X
1.8392
2.480
2.532
Propionic
acid
extracted
0.007734
(mol/min)
0.003732
: 0.20 L/min
: 0.20 L/min
Packing dimension
: Length
= 1.2 m
Diameter = 50 mm
CALCULATIONS
Upper (Y)
M1V1 = M2V2
(0.1M) (46.9mL) = (M2) (5mL)
Bottom (X)
M1V1 = M2V2
(0.1M) (25.5mL) = (M2) (5mL)
M2 = 0.938 M
M2 = 0.510 M
= Y/X
= 0.938 M / 0.510 M
= 1.8392
Upper (Y)
M1V1 = M2V2
(0.1M) (30.5mL) = (M2) (5mL)
M2 = 0.610 M
Bottom (X)
M1V1 = M2V2
(0.1M) (12.3mL) = (M2) (5mL)
M2 = 0.246 M
= Y/X
= 0.610 M / 0.246 M
= 2.480
Upper (Y)
M1V1 = M2V2
(0.1M) (20.0mL) = (M2) (5mL)
M2 = 0.400 M
= Y/X
= 0.400 M / 0.158 M
= 2.532
Bottom (X)
M1V1 = M2V2
(0.1M) (7.90mL) = (M2) (5mL)
M2 = 0.158 M
M1V1 = M2V2
Where:
M1 = concentration of NaOH
M2 = concentration of propionic acid
V1 = volume of NaOH
V2 = volume of propionic acid
50 10
2
= 0.025m
= M2V2
(0.1)(0.30mL) = M2 (15mL)
M2
M1V1
= M2V2
Feed:
(0.1)(0.40mL) = M2 (15mL)
M2
M1V1
= M2V2
Extract:
(0.1)(0.50mL) = M2 (15mL)
= 0.00333 M of propionic acid Y1
M2
Vo (X1-X2)
= Vw (Y1 -0)
= 0.00067 mol/min
X2
= -0.00027 mol/L @ M
K = Y1 / X*
X* = Y1 / K
= 0.00333 / 0.9273
= 3.5911 x 10-3 M
X2 = (X1-X1*)
= -0.00027 M 3.5911 x 10-3 M
= -3.8611 x 10-3 M
Log mean driving force = (X1-X2) / ln (X1/X2)
= (-0.00027 + 3.8611 x 10-3) M / ln (-0.00027 / -3.8611 x 10-3)
= -1.350 x10-3
= M2V2
(0.025)(1.40mL)
= M2 (15mL)
M2
M1V1
= M2V2
Feed:
(0.025)(0.20mL)
= M2 (15mL)
M2
M1V1
= M2V2
Extract:
(0.025)(3.30mL)
M2
= M2 (15mL)
= 0.0055 M of propoinic acid Y1
= 0.0011 mol/min
Vo (X1-X2)
= Vw (Y1 -0)
= 0.0011 mol/min
X2
= - 0.00063 mol/L @ M
K = Y1 / X*
X* = Y1 / K
= 0.0055 / 0.9273
= 0.0059 M
X2 = (X1-X1*)
= - 0.00063 M 0.0059 M
= -0.0065 M
Log mean driving force = (X1-X2) / ln (X1/X2)
= (-0.00063 + 0.0065) M / ln (-0.00063 / -0.0065)
= -0.0025
= -0.0086 mol/L.min
= -0.0086 M/min
= -0.0086 kg/min
DISCUSSION
In this experiment, we want to identify the distribution of coefficient and to identify the mass
transfer coefficient. This experiment is referred to the solubility which is the solvent is also
soluble with a specific solute contained in the solution and also about the separation of a
substance from a mixture by preferentially dissolving the substance in a suitable solvent.
For the first experiment, which is to determine the distribution coefficient, we used the titration
method from the upper (Y) and bottom (X) layer sample. By titration with 0.1 M, the values are
6.5333 in 1.0 ml of propionic acid, 2.7143 in 3.0 ml of propionic acid and 1.8913 in 5.0 ml of
propionic acid. From the result in this experiment, if titrated with 0.1 M NaOH, it shows that the
value of distribution coefficient decrease as the volume of propionic acid increase. This
experiment is totally successful because those results followed the actual results which is the
value of distribution coefficient must be decrease when the volume of propionic acid is
increasing.
For the second experiment, which is to determine the mass transfer coefficient, we used the
liquid-liquid extraction column to get the feed, raffinate and extract solution to be the samples.
The samples then are titrated with 0.1 M NaOH and 0.025 M NaOH. The value of mass transfer
coefficient when titrated with 0.1 M NaOH is 0.003732 kg/min while titrated with 0.025 M, the
value of mass transfer coefficient is-0.06026 kg/min. Result for this experiment shows that the
experiment is failed because the values of mass transfer coefficient supposedly in positive.
Besides that, we cannot show that the relation between mass transfer rate with the concentration
of NaOH. For the actual result, this experiment can shows the increment of mass transfer rate
when the concentration of NaOH is decreasing.
Several errors occurred during this experiment progress that totally affects the result of second
experiment which is for finding the mass transfer coefficient. The most common error is the
position of the eye during taking the volume value at the burette. As the solution, the eye position
should be straight to the scale and must be perpendicular to the meniscus. Besides that, the error
also occurred while using the apparatus that is not properly clean. We should use the clean
apparatus to avoid the oil emission and impurities at the beaker, conical flask or burette. If the
apparatus not clean, we should use the distilled water to clean up those apparatus.
Besides that, the experiment should be repeated at least 2 or 3 times to get the accurate values
and the mistake during the experiment progress can be identified. However, the first experiment
only done with one trial those cause the experiment being failed. Furthermore, we choose light
pink color for the color indicator during titration, but to get all the same color might be hard
enough to identify. As the color is not same in each titration, the value of mass transfer
coefficient will be different from the actual and made the experiment failed. This is because the
color indicates that the NaOH is at equilibrium with the sample solution.