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MATHEMATICS

MATHEMATICS

TEST PATTERN
AIOT (JEE ADVANCE) - 2
TEST DATE : 03-05-2015

BATCH :

Paper-2 (AIOT-2 JEE ADVANCE)


S.No.

Subject

1 to 8

Nature of Questions

No. of Questions Marks Negative

Total

MCQ

24

Comprehension (3 Comp. x 2 Q.)

18

Integer Type Questions (Double Digits Answer)

18

MCQ

24

Comprehension (3 Comp. x 2 Q.)

18

35 to 40

Integer Type Questions (Double Digits Answer)

18

41 to 48

MCQ

24

49 to 54 Chemistry Comprehension (3 Comp. x 2 Q.)

18

55 to 60

18

9 to 14

Maths

15 to 20
21 to 28
29 to 34

Physics

Integer Type Questions (Double Digits Answer)


Total

Total

60

180

MCQ 8
1.

Let a = sin (sin3) + sin (sin4) + sin (sin5),


f(x) = e

[FN-IN] [307]

x 2 |x|

, domain of f(x) be [a, ), range of f(x) be [b, ),


1
4
7 1/7
g(x) = (4cos x 2cos2x cos4 x x ) , domain and range of g(x) is set of real numbers. Which
2
of the following are CORRECT ?
(A*) a = 2
(B*) b + a = 1
2
(C*) f(gog(b)) =e
(D)both f(x), g(x) are non-invertible functions

ekuk a = sin 1 (sin3) + sin 1 (sin4) + sin 1 (sin5), f(x) = e x

|x|

, f(x)

d k izkUr [a, ) gS] f(x)

1
2

d k ifjl j [b, ), g(x) = (4cos4x 2cos2x cos4 x x7)1/7 , g(x) d k izkUr v kSj ifjl j] okLrfod
l a[ ;kv ksad k l eqPp ; gSfuEu esal sd kSu l k l gh gS?
(A*) a = 2
2
(C*) f(gog(b)) =e

(B*) b + a = 1
(D) f(x), g(x) nks
u ksaizfry kse

Q y u ughagSA

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P2JPT2(ADV.)170515C0-1

a = ( 3) + ( 4) + (5 2)=2
f(2) = f(2)

f(x) is many one


f(2) = f(2)

f(x) cgq
,Sd h gSA

MATHEMATICS

MATHEMATICS

Sol.

non invertible
iz
fry kse h; ughagSA

Let ekuk t = x + |x|


t )
t

b = 1
a + b = 1
1
2
7 1/7
g(x) =((1 + cos 2x) 2cosx
(2cos 2x1)x )
2
1
2
2
7 1/7
=(1 + 2cos 2x+cos 2x 2cos2xcos 2x +
x )
2

f(x) [1, )

g(x) = x 7
2

1/ 7

gog(x) = (g( x ))7


2

1/ 7

1/ 7

2.

Sol.

3 3

= x 7
2
2

7 1/7
= (x )
= x
f(gog(b)) = f(b)
1+1
2
= e
= e

Following usual notation, if in a


[ST-HA] [303]
triangle ABC, r 1 + r 2 = 3R, r 2 + r 3 = 2R, then smallest angle is 10n, n N.
The equation (x 1) (x 2)(x 3) = 24 has real root and imaginar y root iR.
W hich of the following are CORRECT ?
ABC es
al kekU; l ad sr kuql kj r 1 + r 2 = 3R, r 2 + r 3 = 2R, rc l cl sN ksV k d ks.k 10n, n N.
l ehd j.k (x 1) (x 2)(x 3) = 24 d s okLrfod ewy v kSj d kYifud ewy iR. fuEu
esal sd kSu l k l gh gS?
2
2
(A*) n = 3
(B*) n + = 8
(C*) + = 6
(D*) + 2 = 2n
abc

r 1 + r 2 = 3R

= 3.
4
sa sb
2 (c )
3
abc
(s a)(s b) 4
4s(s c) = 3ab
4(a b c ) (a b c )
= 3ab
2
2

a + b c = ab

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P2JPT2(ADV.)170515C0-2

MATHEMATICS

r2 + r3 = 2R

angles are d ks
.k 60, 90, 30
smallest l cl sN ks
V k 10n = 103
3
2
cubic ?kuh; x 6x + 11x 30 = 0
= 5, (+ i)( i) = 6
2
+ = 6
3.

4.

n=3
2
(x 5) (x x + 6) = 0

x 2 y 1
z 1
=
=
intersects the curve x2 y2 = a2, z = 0 if a is equal to
2
1
3
x 2 y 1
z 1
=
=
o x2 y2 = a2, z = 0 d ksizfrPN sn d jrh gS] ;fn a cjkcj
2
1
3

The line

js[ kk
Sol.

MATHEMATICS

1
cos c =
2
cos A = 0

(A*) 4
(B) 5
(C*) 4
(D)
For the point where the line intersects the curve, we have z = 0, so
fcUnqd sfy ,] js[ kk o d sfy , izfrPN sn d jrh gSA z = 0, bl fy ,
x 2 y 1 0 1
=
=
x = 5 and v kS
j y=3
2
1
3
Put these values in x2 y2 = a2, we get a2 = 16 a = 4
x2 y2 = a2 es
abu ekuksad ksj[kusij, a2 = 16 a = 4

gS&

5
Revi. PT-3-29-4-2015
[TD-MS] [303]

x 3
n

Consider the graph of the function f(x) = e x 1 then which of the following is correct
(A) Range of the function is (1, )
[FN-DN] [302]
(B*) f(x) has no zeroes
(C*) Graph lies completely above the x-axis
(D*) Domain of f is ( , 3) (1, )
x 3
n

ekukfd Q y u f(x) = e x 1 d k v kjs[ k d sfy , rc fuEu esal sd kSu l k l gh gS&


(A) Q y u d k ifjl j (1, ) gS
A
(B*) f(x) 'kw
U; ughagSA
(C*) v kjs
[ k iw.kZr ;k x- v {k l s ij gSA
(D*) f d k iz
kUr ( , 3) (1, ) gSA
Sol.

x3
> 0 x < 3 or
x 1
or ;k x 3
x 1
(0, 1) (1, )
y =

5.

If

a .a
i

i 0 j 0

;fn

a .a
i

i 0 j 0

(A) 1
Sol.

;k x > 1

a 2
(a 1) 2 (a 1)

x
x 1

where i j and a >1 then possible values of may be

a 2
(a 1) 2 (a 1)

t gki j v kSj a > 1 rc d sl aHko eku gksl d rsgS&

(B) 2

(C*) 3

(D*) 4

W hen no restriction on i and j


t c i v kSj j ij d ksbZizfrcU/k ughagSA

S =

i 0 j 0

1 1
a2

1
.......

a i .a j a a 2
(a 1)2

[SS-GP] [303]

ij

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P2JPT2(ADV.)170515C0-3

MATHEMATICS

6.

(a 1)2 (a 1)

>2

A manufacturer of airplane parts makes a certain engine that has a probability p of


failing on any given flight. There are two planes fitted with this type of engine. One
plane has 3 such engines and other planes has 5. A plane crashes if more than half
the engines fitted in it fail. If the two plane models have the same probability of
crashing then the value of p can be
[PR-BT] [301]

,d gokbZ t gkt cukus d h d Eiuh] d qN bat u cukrh gS] m l d s fd l h nh xbZ m Mku d s [kjkc
gksu s d h izkf;d rk p gSA bl izd kj d s bat uksa l s nks gokbZ t gkt cuk, t krs gSA ,d gokbZ
t gkt esa bl izd kj d s 3 bat u gS v kSj nwl js gokbZ t gkt esa 5 bat u gSA ,d gokbZ t gkt d h
nq?kZV uk gksr h gSA ;fn y xk, x, v k/ks l s T;knk bat u [kjkc gksr s gSA nks gokbZ t gkt d h
nq?kZV uk ?kfVr gksu sd h izkf;d rk l eku gS] rc p d k eku gksl d rk gS&
Sol.

(A*) 0
(B*) 1
(C*) 1/2
The two engines have the same probability of failing if

nksbat u l eku izkf;d rk d sgS


5

C 3 p (1 p) + C 4 p (1p) + p = C 2 p (1p) + p
3
2
4
5
2
3
10p (1p) 5 + p (1 p) + p = 3p (1 p) + p
3
2
2p 5p + 4p 1 = 0

p = 0 or ;k p = or ;k p = 1

7.

(D) 3/5

sin[x]
, x0
a
x

Let [.] denotes the greatest integer function and f(x) =


2 ,
x0 .

b sin x x , x 0

x3

If f(x) is continuous at x = 0 , then b is equal to :


[CD-MS] [301]

sin[x]
, x0
a
x

ekukfd [.] egke iw.kkd Q y u d ksiznf'kZr d jrk gSrFkk f(x) =


2 ,
x0 .

b sin x x , x 0

x3

;fn f(x), x = 0 ij lr~r gksrksb =


Sol.

(A*) a 2 1
(B*) a + 1
lim f(x) = lim a = a = 2
x 0

8.

Sol.

(D) a 2

x 0

Since p a
wfd

(C) a + 2

sin x x
x3

3
5
7

x x x x .... x

3 ! 5! 7 !
1
x2
x4

=
=
+

+ .....
3
3!
5!
7!
x

sin x x
lim f(x) = lim b +
=b1
x 0
x 0
x3
b = 3 = a2 1 = a + 1

The parabola x 2 = ay makes an intercept of length 40 on the line y 2x = 1, if a is


equal to
[PB-PL] [301]
2
ijoy ; x = ay js[ kk y 2x = 1 ij 40 y EckbZd k v Ur[k.M cukrh gS] rc a cjkcj gS&
(A) 1
x 2 = a(1 + 2x)
x 2 2ax a = 0

(B*) 2

(C*) 1

(D) 2
Revi. PT-3-29-4-2015

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P2JPT2(ADV.)170515C0-4

MATHEMATICS

S =

MATHEMATICS

length of chord

t hok d h y EckbZ= |x 1 x 2 | 1 m2
4a2 4a

=
i.e.
i.e.
i.e.

MATHEMATICS

x 1 + x 2 = 2a
x1 x2 = a

1 4 =

40

;k
+ a 2 = 0
;k (a + 2) (a 1) = 0
;k a = 2, 1.
a2

Paragraph for Question Nos. 9 to 10 (iz


'u 9 l s10 d sfy , v uqPN sn)
Let A,B,C be the three points on the ellipse

x2
a

y2
b2

= 1 having eccentric angles

respectively.

[EL-EA] [301]

ekuk A,B,C nh?kZo`k

9.

Sol.

x2
a2

y2
b2

= 1 ij

rhu fcUnqgSA ft ud sm Rd sUnzd ks.k gSA

Area of triangle PQR formed by corresponding points on auxiliary circle is


JPT-2 Adv. 2015
a
b
2a
(A*)
(area ABC)
(B)
(area ABC)
(C)
(area ABC)
(D) (area ABC)
b
a
b
l gk;d o`k ij l ax r fcUnqv ksal scuk f=kHkqt PQR d k {ks=kQ y gS&
a
b
(A*)
(ABC d k {ks
=kQ y )
(B)
(ABC d k {ks
=kQ y )
b
a
2a
(C)
(ABC d k {ks
=kQ y )
(D) (ABC d k {ks
=kQ y )
b
Let ABC is formed by the points A(a cos, bsin), B(a cos, bsin) and C(a cos, bsin) on
x2 y2

=1
a2 b 2

ekuk nh?kZo`k

x2
a2

y2
b2

=1

] A(a cos, bsin), B(a cos, bsin) and C(a cos, bsin) fcUnqv ksa l s

,d f=kHkqt cuk;k t krk gSA


Let ekuk P(a cos, asin)
Q(a cos, asin) ; R(a cos, asin) be point on auxiliary circle.
Q(a cos, asin) ; R(a cos, asin) l gk;d o`
k ij gSA
a cos b sin 1
cos sin 1
1
1
Area of ABC d k {ks
=kQ y =
acos b sin 1 = ab cos sin 1
2
2
a cos b sin 1
cos sin 1

cos sin 1
1 2
=
a cos sin 1
2
cos sin 1

area of PQR d k {ks


=kQ y

Area of ABC d k {ks


=kQ y =

10.

b
Area of PQR d k {ks
=kQ y .
a

The eccentric angles of the vertices of triangle of maximum area inscribed in an ellipse differ by

nh?kZo`k d sv UrxZr v f/kd re {ks=kQ y d sf=kHkqt d s'kh"kZd sm Rd sUnzd ks.kksad k v Urj gS&

3
QOR = 120

(A)
Sol.

(B)

(C*)

2
3

(D)

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P2JPT2(ADV.)170515C0-5

MATHEMATICS

MATHEMATICS

2
=
3
2
2
, =
3
3

Similarlybl h iz
d kj =

3
2
d s'kh"kks
Zd k m Rd sUnzd ks.kksad k v Urj
3
eccentric angle of vertices of Differ by

gSA

Paragraph for Question Nos. 11 to 12 (iz


'u 11 l s12 d sfy , v uqPN sn)
Let < an> and < bn> be the arithmetic sequences each with common difference 2 such that a1 < b1
n

and let cn =

a k , dn =

k 1

. Suppose that the points An(an, cn), Bn(bn, dn) are all lying on the

k 1

parabola C: y = px + qx + r where p,q,r are constants.


ekuk < an> v kSj < bn> l ekUrj v uq e gS ft uesa izR;sd
n

v kSj ekuk cn =

a1 < b1

k 1

C: y = px + qx + r

11.

12.

Sol.

[SS-MS] [303]

d k l koZv Urj 2 bl izd kj gS fd

a k , dn =

ekukfd fcUnq An(an, cn), Bn(bn, dn) ijoy ;

k 1

ij fLFkr gSt gkp,q,r v p j gSA

The value of p equals


p d k eku cjkcj gS
&
1
(A*)
4

(B)

1
3

(C)

1
2

(D) 2

If r = 0 then the value of a1 and b1 are


1
3
1
(A)
and 1
(B) 1 and
(C*) 0 and 2
(D)
and 2
2
2
2
;fn r = 0 gks] rksa1 v kSj b1 d seku gS&
1
3
1
(A)
v kSj 1
(B) 1 v kS
j
(C*) 0 v kS
j2
(D)
v kSj 2
2
2
2
17. Given fn;k x;k gScn =a1 + a2 + a3 + .. + an
where a1, a2, ., an are in A.P. with d = 2
t gka1, a2, ., an l ekUrj J s< h esagSft l d k l koZv Urj d = 2 gSA
and
dn = b1 + b2 + b3 + + bn are in A.P. with d = 2
v kSj
dn = b1 + b2 + b3 + + bn l ekUrj J s
< h esagSA ft l d k l koZv Urj d = 2 gSA
2
also
(an, cn) lies on y = px + qx + r
rFkk (an, cn) o y = px2 + qx + r ij fLFkr gSA
Nowv c cn = pan + qan + r
..(1)
2
cn1 = pa n1 + qa n1 + r
.(2)

From (1) and (2), we get


(1) v kS
j (2) l sgesaizkIr gksr k gSA
2
2
cn cn1 = p(a n a n1) + q(an an1)

an = p(an + an1) (an an1) + q(an an1)

an = (an an1) [p(an + an1)+q]


.(3)
(an an1 = d)
on putting n = 2 and 3 in equation (3), we get
n = 2 v kS
j 3 esaj[kusij (3), we get
.(4)
a2 = d[p(a2 + a1) + q]
a3 = d[p(a3 + a2) + q]
.(5)
Now v c (5) (4) , we get
a3 a2 d[p(a3 a1 )]

2d

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P2JPT2(ADV.)170515C0-6

MATHEMATICS

4p = 1

adding (4) andv kS


j (5) t ksM usij q =
if ;fn r = 0, then t c
2
c1 = pa1 + qa1
1 2 1
a1 = a1 + a1
4
2
2
a 1 = 2a1 = 0

18.

1
2

( c1 = a1)

a1 = 0 or ;ka1 = 2

1 2
b1 + qb1
4

AlsorFkk d1 =

MATHEMATICS

1
p=
ans.
4

q and d1 b1
2

1 2 1
b1 +
b1
4
2
2
b1 2b1 = 0

but ijUrqa1 < b1


d1 =

b1 = 0 or ;kb1 = 2

a1 = 0 and v kS
j b1 = 2 ans.

Paragraph for Question Nos. 13 to 14 (iz


'u 13 l s14 d sfy , v uqPN sn)
7

If f : R R be a differentiable function such that (f(x)) = x f(x) then


;fn f : R R v od y uh; Q y u bl izd kj (f(x))7 = x f(x) rc

[AR-MS] [307]

13.

The value of

( x )dx is

( x )dx

d k eku gS&

(A) 3
14.

(B)

(C*) 3

(D) 1

The area bounded by curve y = f(x) between the ordinates x = 0, x =


7
f( 3 )

8 3 f 3 4f( 3 ) sq. units

93

(C) 3 f 3
sq. units
8

(A*)

(B)

3 and x-axis is

f( 3 )
8 3 f 3
8

sq. units

(D) none of these

o y = f(x) d ksfV x = 0, x = 3 v kSj x-v {k l sifjc) {ks=k d k {ks=kQ y gS&


(A*)

f( 3 )
8 3 f 3
8

4f( 3 )

oxZbd kbZ (B)

f( 3 )
8 3 f 3
8

oxZbd kbZ

93

(C) 3 f 3
(D) bues
al sd ksbZugha
oxZbd kbZ
8

6
f(x)[f(x) + 1] = x
6
f(0)[(f(0)) + 1] = 0

f(0) = 0
6
1
and v kS
j 7 (f(x)) .f(x) = 1 f (x)
6

f(x)[7(f(x)) + 1] = 1

f(x) > 0 x R
Hence f(x) is increasing function x R
v r% f(x) , x R ,d o/kZe ku Q y u gSA
1
so there exists an inverse of f(x) such that f (0) = 0
bl fy , f(x) d k izfry kse fo| eku gSt cfd f1(0) = 0
7
1

x + x = f (x)

Sol.

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P2JPT2(ADV.)170515C0-7

MATHEMATICS

x dx

x8 x2

8
2

=2+1=3
0
f (a )

Now, we know that v c

gesaizkIr gksr k gS f ( x )dx


0

Hence v r%

f( 3 )
1

f ( x)dx f
0

3f( 3)

f ( x)dx
0

( x )dx = af(a)

( x )dx 3 f ( 3 )

f( 3)

f(x)dx
3

MATHEMATICS

(x 7 x)dx

f( 3 )
8 3 f 3
8

4f ( 3 )

INTEGER TYPE - 6
15.

A game is played with special fair cubic die which has one red side, two blue sides, and three
green sides. The result is the colour of the top side after the dice is been rolled. If the die is rolled
repeatedly. The probability that second blue result occurs on or before the tenth roll can be
3p 2q
expressed in the form of
where p,q,r are positive integers then find the value of p + r q.
3r

,d [ksy ] ,d fof'k"V fu"i{kikrh ?kuh; ikl s l s [ksy k t krk gS ft l d h ,d Hkqt k y ky ] nks


Hkqt k,a uhy h rFkk rhu Hkqt k,a gjh gSA ikl s d ks Q sd us d s ckn ijh Hkqt k ij jax ifj.kke gSA
;fn ikl s d ks y xkrkj Q sad k t krk gS] rks 10 ckj esa ;k m l l s igy s ikl k Q sad us ij nwl jh ckj
uhy k ifj.kke v kusd h izkf;d rk d ks

3p 2q
3r

d s: i esaO;Dr fd ;k t krk gSA t gkp,q,r /kukRed

iw.kkd gS] rc p + r q d k eku gS&


Ans.
Sol.

[PR-BT] [303]
[JPT-2_Adv. 2015]

07
nd
th
Now 2 blue result occur on or before the 10 roll is equivalent to the occurrence of blue face
atleast twice is 10 rolls
10oha ckj ;k m l l s igy s ikl k Q s
ad us ij nwl jh ckj uhy k ifj.kke v kus d h izkf;d rk] 10 ckj

esad e l sd e nksckj uhy h l rg v kusd srqY; gSA


1
2
q=
3
3
P(r 2) = 1 (P(0) + p(1))
9
2 10
1 2
= 1 10.
3
3 3

29.4
211 39 211
1 9 1 9
3
3
39
p = 9 , q = 11, r = 9
p + r q = 9 + 9 11 = 7
n = 10, p =

16.

Let y be an element of the set A = {1, 2, 3, 5, 6, 10, 15, 30} and x1 x2 x3 = y, then the number of
positive integral solution of x1x2x3 = y is m. Find m.
[PC-MT] [304]
[JPT-2_Adv.
2015]
ekuk l eqPp ; A = {1, 2, 3, 5, 6, 10, 15, 30} d k v o;o y gSv kSj x1 x2 x3 = y, rc x1x2x3 = y d sgy ksa

d s/kukRed iw.kkd gy ksad h l a[ ;k m gSA m K kr d hft ,A


Ans.

64

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P2JPT2(ADV.)170515C0-8

The number of solutions of the given equation is the same as the number of solution of the
equation x1x2x3 x4 = 30 = 2 3 5 (here x4 is dummy variable)

fn, x, l ehd j.k d s gy ksa d h l a[ ;k] l ehd j.k x1x2x3 x4 = 30 = 2 3 5 d s gy ksa d h l a[ ;k d s


cjkcj gS(;gkx4 xqIr p j gS)
3

Hence number of solutions is 4 = 64


v r% gy ksad h l a[ ;k 43 = 64
17.

If area of triangle formed by the points (2, ),(+ , 2+ ) and (2, 2) is 8 square unit then
area of triangle whose vertex are ( + , ), (3 , + 3) and (3 , 3 ) is
;fn (2, ),(+ , 2+ ) v kSj (2, 2) l s cus f=kHkqt d k {ks=kQ y 8 oxZ bd kbZ gS rFkk
( + , ), (3 , + 3) v kS
j (3 , 3 ) l s cus f=kHkqt d k {ks=kQ y gS& [JA_CT-2_2109-2014]
[JPT-2_Adv. 2015]
[SL- AR] [301]

Ans.32

R(2a ,b)

Sol.

C(3a b,3ba )

P(2b ,2a )

Q(a +b ,2b +a )

D(3ba ,b+3a )

Area of ABC = 4(PQR)


ABC d k {ks
=kQ y = 4(PQR)
=48
= 32 square unit oxZbd kbZ
18.

Ans.
Sol.

If A1, A2, A3, A4 be the area of a triangular faces of a tetrahedron and h1, h2, h3, h4 be the
corresponding altitude of the tetrahedron. If volume of tetrahedron is 5 cubic units then find the
(A1 A 2 A 3 A 4 )(h1 h2 h3 h4 )
minimum value of
[SS-IG] [304]
[JPT-2_Adv.
24
2015]
;fn A1, A2, A3, A4 l s cus p rq"Q y d d s f=kHkqt kd kj l rgksa d k {ks=kQ y gS rFkk h1, h2, h3, h4
p rq"Q y d d s l ax r 'kh"kZ y Ec gSA ;fn p rq"Q y d d k v k;ru 5 ?ku bd kbZ gS rc
(A1 A 2 A 3 A 4 )(h1 h2 h3 h4 )
d k U;wu re eku gS&
24
10
1
3V
V = h1A1
h1 =
3
A1
h2 =

3V
A2

h3 =

3V
A3

h4 =

3V
A4

3V 3V 3V 3V
(A1 + A2 + A3 + A4)

A1 A 2 A3 A 4
1
3V(A1 + A2 + A3 + A4)

A1
A1 A 2 A 3 A 4

1
1
4

A1 A 2

1
1
1

A 2 A3 A 4
4
1
1

A3 A 4

1
1
1
1
(A1 + A2 + A3 + A4)

16
A1 A 2 A 3 A 4
Min value U;w
u re eku : 3V(16) = 48 V = 240
(A1 A 2 A 3 A 4 )(h1 h2 h3 h4 )

min value of U;w


u re eku
= 10
24

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P2JPT2(ADV.)170515C0-9

MATHEMATICS

MATHEMATICS

Sol.

MATHEMATICS
3

If roots of the cubic equation (z ab) = a , a 0 represents the vertex of a triangle, then the
length of one of the sides of the triangle will be , when a = 3
[JPT-2_Adv. 2015]
3
3
;fn ?kuh; l ehd j.k (z ab) = a , a 0 d s ewy f=kHkqt d s 'kh"kZ gS] rc f=kHkqt d h Hkqt kv ksa d s

,d d h y EckbZgksx h] t c a = 3
Ans.
Sol.

[CN-CR] [302]

03
3
3
(z ab) = a
1/3
2
z ab = a(1) , z ab = a, a, a
2
z1 = ab + a, z2 = ab + a, z3 = ab + a
|z1 z2| = |a a| = |a||1| = 3 | a |
= 3. 3 =3
(2x 3 1)dx
1 x 6 2x 3 9x 2 1 can be expressed in the form of

20.

If the value of the definite integral

A
C
cot 1 where A,B,C,D are rationals in their lowest form then the value of 2(A + B + C + D) is
B
D
equal to
[DI-II] [301]

;fn fuf'p r l ekd y =

x
1

Ans.
Sol.

A,B,C,D m ud sl jy re
18
1

dx
2x
2
x

=
1
1 x 4 2x 9
x2

t
2

dt
9

(2x 3 1)dx
2x 3 9x 2 1

d s eku d ks

A
C
cot 1 d s : i
B
D

esa O;Dr d jrs gS t gk

: i esaifjes; l a[ ;k,agS] rc 2(A + B + C + D) d k eku cjkcj gS&

put x +

1
= t j[kusij
x

1
1 2
cot
3
3

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P2JPT2(ADV.)170515C0-10

MATHEMATICS

19.

PHYSICS

AIOT-2 (JEE ADVANCE)


PHYSICS

BATCH : JP, JF, JR


DATE : 03-05-2015
SYLLABUS : (XI & XII SYLLABUS)

Paper-2 (AIOT-2 JEE ADVANCE)


S.No.

Subject Nature of Questions

1 to 8

No. of Questions Marks Negative

Total

MCQ

24

Comprehension (3 Comp. x 2 Q.)

18

15 to 20

Integer Type Questions (Double Digits Answer)

18

21 to 28

MCQ

24

18

9 to 14

29 to 34

Maths

Physics Comprehension (3 Comp. x 2 Q.)

35 to 40

Integer Type Questions (Double Digits Answer)

18

41 to 48

MCQ

24

49 to 54 Chemistry Comprehension (3 Comp. x 2 Q.)

18

55 to 60

18

Integer Type Questions (Double Digits Answer)


Total

60

Total

180

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P2JPJFJRAIOT220215C0-1

PHYSICS

SECTION 1 : (One or more options correct Type)


[k.M 1 : (,d ;k v f/kd l gh fod Yi d kj)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE are correct.
bl [k.M esa8 cgqfod Yi 'u gSaA R;sd 'u esapkj fod Yi (A), (B), (C) vkSj (D) gSa] ft uesals,d ;k

v f/kd lgh gSA


21.

A light wire of length and radius r is welded to another light wire of length 2 are radius 2r. The
st
nd
free end of 1 wire is fixed and the free end of 2 wire supports a mass m. The young's modulus
of each wire is Y.
[EC-GE](104)
y EckbZrFkk r f=kT;k d k rkj, 2 y EckbZrFkk 2r f=kT;k d svU; rkj d slkFk t q
M +k gqv k gS
A igy srkj d k eqDr
fljk t M+or~gSrFkk nwl jsrkj d seqDr fljslsfp=kkuql kj m nzO;eku y Vd k gqv k gSA iz
R;sd rkj d k ;ax xq.kkad
Y gS
A

2
m

(A*) Extension in upper half of upper wire is

mg
2r 2 Y
mg
(B*) Extension in lower wire is
2r 2 Y
mg
fupy srkj esaizl kj
gSA
2r 2 Y

ijh rkj d s ijh v) ZHkkx esaizl kj

mg
2r 2 Y

gSaA

(C) Total elongation in the composite wire is

la;qDr rkj esad qy izl kj

5 mg
2 r 2 Y

5 mg
2 r 2 Y

gSaA

(D*) Total elongation in the composite wire is

3 mg
2 r 2 Y

3 mg
gSA
2 r 2 Y
Here stretching force is same but stress will be different for wires.

la;qDr rkj esad qy izl kj


Sol.

;gkruu cy leku gS
]ijUrqnksuks
arkjks
aes
aiz
frcy fHkUu&fHkUu gS
A
For upper wire ijh rkj d sfy,
Stress iz
frcy = Y strain fo fr
Mg

= Y

r
mg
1 =
r 2 Y
for lower wire fupysrkj d sfy,

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P2JPJFJRAIOT220215C0-2

PHYSICS

PAPER-2

PHYSICS

total elongation d q
y

foLrkj =

3 mg
2 r 2 Y

22*.

A particle of mass 'm' is suspended with the help of an ideal string from the ceiling of a car as
shown in figure. Initially the whole system is at rest. At time t = 0 the car starts accelerating
towards right with uniform acceleration 'a' such that a << g. Then choose the correct statement(s).

[CM-VT](104)
,d vkn'kZjLlh d h lgk;rk ls'm' nzO;eku d k d .k fp=kkuql kj d kj d h Nr lsy Vd k gqv k gSA izkjEHk esa
lEiw.kZfud k; fLFkj gSA t = 0 ij d kj nka;h vksj le: i Roj.k a lsRofjr gksrh gS,oaa << g gSA rkslgh
d Fku@d Fkuksad k p;u d hft ,A

(A*) The particle will execute simple harmonic motion with respect to car.

d .k d kj d slkis{k ljy vkorZxfr d jsxk

nd

(B*) The particle will be at equilibrium position w.r.t. car for the 2 time at instant
3

t=
2
2
a g2

d kj d slkis{k d .k t =

3
2

a g2

le; i'pkr~okil ek/; fLFkfr ij nw


l jh ckj igqp rk gS
A

(C) The maximum speed of the particle with respect to ground during subsequent motion will be
1 a
(g2 a2 )1/ 2 tan
g

a
A
gS
g
(D*) The speed of the particle with respect to ground at the instant the string becomes vertical

again for the first time is aT where T = 2


a2 g2

v/kksfyf[kr xfr d snkSjku t ehu d slkis{k d .k d h vf/kd re pky

(g2 a2 )1/ 2 tan

t c jLlh nqckjk izFke ckj /okZ/kj fLFkfr esavkrh gSrc d .k d h t ehu d slkis{k pky aT gSa;gkT = 2

a2 g2

Sol.

gSA

1 a
The particle will execute S.H.M with angular amplitude tan with respect to car and of time
g

period T = 2

a g2

d .k d kj d slkis{k d ks.kh; vk;ke tan1 rFkk vkorZ


d ky T = 2
g

It will be at eqb. position for second time at time t =

a g2

d slkFk ljy vkorZxfr d jrk gS


A

3
T
4

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P2JPJFJRAIOT220215C0-3

PHYSICS

mg
2
mg
2=

2
Y
(2r)
2 r 2 Y

PHYSICS

The max. speed of the particle with respect to car will be A =

g2 a2

g2 a2

. tan

a
.
g

a
A
gS
g
The particle will come to rest at with respect to car at the instant string becomes vertical & its

speed will be same as speed of car i.e., aT where T = 2


2
a g2

d kj d slkis
{k d .k d h vf/kd re pky A =

. tan

d kj d slkis{k d .k fojkekoLFkk es
arc vkrk gSt c jLlh /okZ
/kj gks
rh gSrFkk bld h pky bl le; d kj d h pky d s
cjkcj gks
rh gSvFkkZr~
, aT d scjkcj gks
rh gS;gkT = 2
23.

a g2

gS
A

The figure here shows a water tank provided with a square gate (of side 2m) which can rotated
freely about z axis passing through shown point A. The gate is held in its place due to buoyant
force acting on the light balloon attached to the gate via a light thread. Considering the information
that the gate just opens when level of water reaches the height of 4m above point A and hinge
force is zero, the shown point P is point at which the thread is attached to the gate

[FL-BY](103)
iznf'kZr fp=k esaoxkZd kj njokt s(Hkqt k 2m) ;qDr ,d ikuh d k VSad iznf'kZr gSA njokt k fp=k esaiznf'kZr fcUnqA
lsxqt jusoky h z-v{k d sifjr% eqDr : i ls?kw.kZu d j ld rk gSA njokt sd ksbllst qM +h gq
bZgYd h jLlh }kjk
ca/ksgq, gYd sxqCckjsij vkjksfir mRiy kod cy }kjk nh xbZfLFkfr esafLFkj j[kk t krk gSA ;g ekuk t krk gS]
t c ikuh d k Lrj fcUnqA ls ij 4m vkrk gS] rc njokt k Bhd [kqy t krk gSA fuy Ecu }kjk vkjks
fir cy
'kwU; gSA fp=kkuql kj fcUnqP ij jLlh njokt s}kjk cU/kh gq
bZgS
A

a = 4m
A

Gate

njokt k

Light
balloon
(gYd k
xqCckjk)
y

b = 2m

Water
(ikuh)

x
z

(A*) Volume of water displaced by the balloon is 20 m

xqCckjs}kjk foLFkkfir ikuh d k vk;ru 20 m3 gS


A
(B) Volume of water displaced by the balloon is 30 m

xqCckjs}kjk foLFkkfir ikuh d k vk;ru 30 m3 gS


A
(C*) distance between A and P is approximately 1.06 m.
A rFkk P d se/;

nwjh y xHkx 1.06 m gSA

(D) Force on gate due to Water is 15kN

njokt sij ikuh }kjk vkjks


fir cy 15kN gSA
Sol.

At the instant of just opening of gate njokt sd sBhd

[kqy rsle;,

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P2JPJFJRAIOT220215C0-4

PHYSICS

;g

3
nw
l jh ckj lkE;koLFkk ij le; t = T ij igq
prk gS

A
4

PHYSICS

Ffluid Fbuoyant

PHYSICS

PMID Area = Vg
b

2
g a b = Vg
2

3
V = a b 2 = 20m
2

Also, about the axis passing through A ; A lsxq


t jusokyh v{k d sifjr%
fluid tension
ab

gh bdh(h a) = Vgx

a b

h(h a)dh
x=
24.

1.06 m

A solid sphere of mass m is released on the plank of mass M which lies on an inclined plane of
inclination as shown in figure. There is sufficient frictional force between sphere and plank and
the minimum value of co-efficient of friction between plank and surfaces is to keep the plank at
rest. Then
[RB-CD](104)
m nz
O;eku d k Bksl xksy k M nzO;eku d sr[rsij NksM +k t krk gSA r[rk d ks.k oky surry ij fp=kkuql kj j[kk

gqv k gSA xksy rFkk r[rsd se/; mifLFkr ?k"kZ.k cy i;kZIr gS,oar[rso urry d se/; mifLFkr ?k"kZ.k xq.kkad
d k U;wure eku gS, t ksfd r[rsd sfLFkj j[kusd sfy, i;kZ
Ir gS] rks
m
M

(A*) Frictional force between sphere and plank is

xksy srFkk r[rsd se/; ?k"kZ.k cy


(B*) The value of is

2
mg sin gS
, tc
7

2
mg sin , when plank is at rest
7

r[rk fLFkj gSA

7M 2m
tan
7(M m)

7M 2m
tan gS
A
7(M m)
(C) If there is no friction between the plank and inclined plane, then acceleration of plank is less than g
sin .
;fn r[rsrFkk urry d se/; d ksbZ?k"kZ.k cy vkjks
fir ughagksrksr[rsd k Roj.k g sin lsd e gSA
(D*) If there is no friction between plank and inclined plane, then friction force on the sphere is
zero.

Sol.

d k eku

;fn r[rsrFkk urry d se/; d ksbZ?k"kZ.k cy vkjks


fir ughagksrksxksy sij vkjksfir ?k"kZ.k cy 'kwU; gSA
If plank is at rest acceleration of cylinder ;fn r[rk fLFkj gksrksxks
y sd k Roj.k
a=

gsin
5gsin

7
1
mR 2

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P2JPJFJRAIOT220215C0-5

PHYSICS

2
mgsin
7
M

PHYSICS

2
mg sin f = ma f = mgsin
7

(M + m)g cos

Mg sin

2
mgsin = (M + m)g cos
7
7M 2m
=
tan
7(M m)
Mgsin +

25.

Consider an infinite mesh as shown in figure Each side of the mesh has resistance R. Consider
hexagonal part ABCDEF of infinite mesh and equivalent resistance between any two points of
hexagon is measured. Choose the correct option(s) : [CE-EQ](104)
fp=k esa,d vuUr vkd kj d k t ky iznf'kZr gSA izR;sd t ky d h izR;sd Hkqt k d k izfrjks/k R gSA vuUr t ky d s
,d "kV~d ks.kh; Hkkx ABCDEF d h d Yiuk d hft , rFkk bl Hkkx d sfd Ugh nksfcUnqv ksad se/; rqY; izfrjks/k ekik

t krk gSA rkslgh fod Yiksad k p;u d hft ,A

A
B
F
C
E

(A*) equivalent resistance between A and B is

2R
3

2R
gSA
3
(B*) equivalent resistance between A and C is R
A rFkk C d se/; rq
Y; izfrjks/k R gSA
7R
(C*) equivalent resistance between A and D is
6
7R
A rFkk D d se/; rq
Y; izfrjks/k
gSA
6
(D*) equivalent resistance between A and E is R
A rFkk E d se/; rq
Y; izfrjks/k R gSA
A rFkk B d se/;

Sol.

rqY; izfrjks/k

If we connect positive terminal of a battery to A and negative to infinity then the current through
branches will be as shown. If we connect negative to B and positive to infinity current will be in
2
opposite direction by supper -position of two situation net current in AB branch will be
.
3

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P2JPJFJRAIOT220215C0-6

iz
d kj vU; fljksd sfy, Hkh Kkr d j ld rsgS
A

/3
/6

26.

/3 A /3
/6
/6
/6

Consider an imaginary cube of side '' as shown in figure : [ES-GT](103)

fp=k esaiznf'kZr '' Hkqt k d s,d d kYifud ?ku d h d Yiuk d hft , :


Q

D
A

C
B
G

H
E

F
An infinite large sheet of surface charge density passes through PQGF. P and Q are mid points
of AB and DC respectively. Out of six faces of cube the electric flux linked :
i`
"Bh; vkos'k ?kuRo d h ,d vUur vkd kj d h ifV~Vd k PQGF lsxqt jrh gSA P rFkk Q e'k% AB rFkk DC
d se/; fcUnqgSA bld sN% Q yd ksalslEcfU/kr y Dl esals:
(A*) is zero with three faces

rhu Q y d ksad sfy , 'kwU; gSA


(B*) with face ADHE and face BCGF are equal
Q y d ADHE rFkk Q y d BCGF d sfy , leku gSA
(C*) is minimum (non zero) with FGHE
FGHE d sfy , U;w
ure (v'kwU;) gSA
(D) is zero with two faces

nksQ y d ksad sfy , 'kwU; gSA


Sol.

Consider the projected area of any face to calculate the flux

y Dl Kkr d jusd sfy , fd lh Q y d d s{kS=kQ y d h d Yiuk d jrsgSA


Electric flux with ABCD, ABEF, DCGH is zero
r y Dl 'kwU;
ABCD, ABEF, DCGH lslEcfU/kr fo|q

gSA

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P2JPJFJRAIOT220215C0-7

PHYSICS

PHYSICS

2
Potential difference between A and B will be
R . Effective resistance between A and B will be
3
2R
. Similarly we can do for other terminals.
3
;fn cS
Vjh d s/kukRed fljsd ksA lsrFkk _ .kkRed fljsd ksvuUr lst ks
M+nsrksbl ifjiFk d h 'kk[kkvks
aes
a/kkjk
fp=kkuql kj iz
okfgr gks
xhA ;fn cSVjh d s_ .kkRed fljsd ksB lsrFkk /kukRed fljsd ksvuUr lst ks
M+nsrks/kkjk
2
foifjr fn'kk es
aiz
kokfgr gks
xh] rFkk bu nksuks
afLFkfr;ks
aes
aiz
okfgr /kkjk d sv/;kjks
i.k }kjk 'kk[kk AB es
ad qy /kkjk
3
2
2R
iz
okfgr gksxhA A rFkkB d se/; foHkokUrj R gks
xkA blfy, A rFkkB d se/; rq
Y; iz
frjks/k
gks
xk] vkS
j blh
3
3

PHYSICS

PHYSICS

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P2JPJFJRAIOT220215C0-8

Figure shows top view of a horizontal surface. Two blocks each of mass m are placed on the
surface and connected with a string. The friction coefficient is for each block. A horizontal force F
is applied on one of the block as shown in the figure. F is maximum so that there is no sliding at
any contact.
[FR-SG](104)
,d {kS
frt lrg d k ijh n`'; fp=k esaiznf'kZr gSA leku nzO;eku m d snksCy kWd bl lrg ij fLFkr gSrFkk
vkil esa,d jLlh lscU/ksagq
, gSA iz
R;sd Cy kWd d sfy , ?k"kZ.k xq.kkad gSA fp=kkuql kj ,d Cy kW
d ij ,d
{kSfrt cy F vkjksfir fd ;k t krk gS
A F vf/kd re gSft ld sd kj.k fd lh Hkh lEid Zij fQ ly u ughagSA
m

Top view

F
(A*) If

;fn = 30 F =

(B*) If ;fn = 45 F =

2mg
3

& T < mg

2mg & T = mg

(C) If ;fn = 60 F = 2mg & T < mg


(D*)If ;fn = 60 F =

3mg & T = mg

Sol.
f

F
T cos = f sin
but T mg
T cos = mg sin
F = T sin + f cos
sin
= mg
sin + mg cos
cos
cos( )
= mg
cos
For Fmax = < 45 Fmax = mg sec
Fmax d sfy ,] = < 45 Fmax = mg sec
But tension in the string can not be more than mg
jLlh esaruko mg lsT;knk ughagksld rk
mg sin
T=
< mg should be less than 45
cos
mg sin
T=
< mg ] 45 d e gks
uk pkfg,A
cos
Now if (vc ;fn) > 45 T = mg = 90
F = mg sin + mg cos = 2mg sin
If (;fn) < 45 then (rks
) Fmax = mg sec
If (;fn) > 45 then (rks
) Fmax = 2mg sin

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P2JPJFJRAIOT220215C0-9

PHYSICS

PHYSICS

27.

Consider a hemisphere of radius R with centre of curvature at origin O, as shown. Refractive index
2R
of material of the hemisphere varies as =
. Where x is x-coordinate of material point. A
2R x
ray travelling in air in xy-plane is grazingly incident at O, as shown
R f=kT;k d s,d v) Z
xksy sd h d Yiuk d hft ,] ft ld k o rk d sUnzewy fcUnqO ij fp=kkuql kj gS
A v) Zxksy sd s
2R
inkFkZd k viorZukad =
d svuql kj ifjofrZr gksrk gSA t gkx inkFkZd sfcUnqd k x-funsZ'kkad gSA ,d
2R x
fd j.k ok;qesaxfr d jrh gqbZ] fp=kkuql kj xy-ry esafcUnqO ij i`"BLi'khZvkifrr gksrh gSA [GO-RP](105)
y

(A*) Trajectory followed by ray as it travels inside the hemisphere is circular

v) Zxksy seasxfr d snkSjku fd j.k d k iFk o`kkd kj gSA


(B) y-coordinate of the point of hemisphere where the ray comes out of the hemisphere lies
between 0.5R and 0.75R
fd j.k v) Zxksy sd sft l fcUnqlsckgj fud y rh gS] v) Zxksy sd sml fcUnqd k y-funsZ'kkad 0.5R ls0.75R d s

e/; fLFkr gSA


(C*) Deviation suffered by the ray just before it comes out of the hemispherical surface lies
between 0 and 30
xksy h; lrg lsBhd ckgj fud y rsle; fd j.k }kjk iz
kIr fopy u 0 ls30 d se/; fLFkr gSA
(D) Deviation suffered by the ray just before it comes out of the hemispherical surface lies between
30 and 45
xksy h; lrg lsBhd ckgj fud y rsle; fd j.k }kjk iz
kIr fopy u 30 ls45 d se/; fLFkr gSA
Sol.

O
90

The figure shows a strip at a distance x of thickness dx. As of material increases with x, ray will
deviate continuously as shown. By snell's law, between O and A,
fp=k esax nwjh ij dx eksVkbZd h ifd k iznf'kZr gSA pqafd nwjh x d slkFk inkFkZd k viorZukad c<+rk gS] bl
d kj.k fd j.k fp=kkuql kj y xkrkj fopfy r gksrh gS
A O lsA rd Lusy d sfu;e }kjk
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P2JPJFJRAIOT220215C0-10

PHYSICS

PHYSICS

28.

PHYSICS

dy

dx

2R x
2

(2R) (2R x)2

dy

PHYSICS

2R
1 sin90 =
sin
2R x
2R x
tan =
2
(2R) (2R x)2

2R x

dx

(2R) (2R x)2

2R 2 2R x 2

y=
2

y + (x-2R) = (2R)
which is equation of circle of radius 2R centered at (2R, 0)
t ksfd ,d 2R f=kT;k d so`k d h lehd j.k gSft ld k d sUnz(2R, 0) ij
also, equation of hemispherical surface is

gSA

blh izd kj v) Zxksy sd h lrg d h lehd j.k fuEu gS


2

x + y = (R)
2
2
2
y =R x
2
Putting this value of y in equation of trajectory we can find coordinates of point where the ray
comes out of hemisphere, as
bl y2 d seku d ksiFk lehd j.k esaj[kusij mu fcUnqv ksad sfunsZ'kkad d j ld rsgSt gkij fd j.k v) Zxksy sls

ckgj vkrh gS
2

R + x + (x 2R) = 4R
R
x=
4

y=

15R
R
R2 x 2 R2
0.97R
4
4

Now, to find deviation () consider the diagram here


vc, fopy u () Kkr d jusd sfy , fuEu fp=k d k iz;ksx d jrsgSA

2R
y

Clearly Li"V

: i ls, sin =

y
15
16 1

or
2R
8
8
2

0 < < 30

SECTION 2 : (Paragraph Type)

[k.M 2 : (v uqPN sn d kj)


This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions
relate to three paragraphs with two questions on each paragraph. Each question of a paragraph
has only one correct answer among the four choices (A), (B), (C) and (D).
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P2JPJFJRAIOT220215C0-11

Paragraph for Question Nos. 29 to 30


iz'u 29 l s30 d sfy , v uqPN sn

Comp.
The rectangular box shown in the figure has a partition which can slide without friction along the
length of the box. Initially each of the two chambers of the box has one mole of a monatomic ideal
gas at a pressure P0, volume V0 and temperature T0. The chamber on the left is slowly heated by
an electric heater. The walls of box and partition are thermally insulated. Heat loss through lead
wire of heater is negligible. The gas in left chamber expands, pushing the partition until final
243
pressure in both chambers becomes
P0. (Take R = 8.3 J/mol K)
[TH-FL](104)
32

fp=k esaiznf'kZr ?kukd kj fMCcsesafLFkr fiLVu fcuk ?k"kZ.k d sfMCcsd h y EckbZd svuqfn'k fQ ly ld rk gSA
izkjEHk esafMCcsd snksuksaHkkxksaesa,d eksy ,d ijek.kq
d vkn'kZxSl ] nkc P0, vk;ru V0 rFkk rkieku T0 ij Hkjh
gqbZgSA cka;soky sHkkx esafLFkr xSl d ksfo|qr ghVj }kjk /khjs& /khjsxeZfd ;k t krk gSA fMCcsd h nhokjsrFkk
fiLVu "eh; d qp ky d gSrFkk ghVj d srkj }kjk "eh; gkfu ux.; gSA cka;soky sHkkx esafLFkr xSl Q Sy rh gS
vkSj fiLVu d ksrc rd nckrh gSt c rd fd nksuksaHkkxksad k nkc

29.

Final temperature of gas in left chamber is :

243
P0 u
32

gkst k;sA (R = 8.3 J/mol K y sa)

[TH-FL](104)

cka;sHkkx esaxSl d k vfUre rkieku gksxk &


(A) 2.25 T0
(C) 8.75 T0
Sol.

T0

Tright

(B) 4.5 T0
(D*) 12.93 T0

P 32
= 0

243P0

T0
2
=
Tright
3
Tright = 2.25 T0

For the left chamber, the process of heating is slow. Initial parameters are P0, V0, T0.
nka;sHkkx d sfy ,, iz e vuql kj /khsjs& /khjsxeZd jrsgSA izkjfEHkd izkap y P0, V0, T0 gSA
243
Final parameters are vfUre iz
kap y
P0 , V1, T1
32
P0 V0
243P0 V1
=

T0
32 T1

243 V1
T0
.(1)
32 V0
Adiabatic compression occurs in right chamber. Initial parameters are P0, V0, T0.
nka;sHkkx esa: ) ks"e lEihM+u gksxkA bld siz
kjfEHkd izkap y P0, V0, T0 gSA
T1 =

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P2JPJFJRAIOT220215C0-12

PHYSICS

PHYSICS

bl [k.M esafl) karksa] ;ksxksavkSj vkd M+ksavkfn d ksn'kkZusoky s3 v uqPN sn gSaA rhuksavuqPNsnksalslacaf/kr N %
'u gSa] ft uesalsgj vuqPNsn ij nks'u gSaA fd lh Hkh vuqPNsn esagj 'u d spkj fod Yi (A), (B), (C) vkSj
(D) gS
a] ft uesalsd soy ,d gh l gh gSA

PHYSICS

Final parameters are vfUre

izkap y

243
P0, V2, T2 gS
A
32

PHYSICS

243

P0V0 = P0
V2
32
5/3

V2
32
=

243
V0
V2
8
=
V0
27
V1 + V2 = 2V0
8
V1 = 2V0
V0
27
46
V1 =
V0
.(2)
27
by equation lehd j.k(1) & o (2) ls
T1 = 12.93 T0

30.

[TH-FL](104)

The work done by the gas in the left chamber is

cka;sHkkx esaxSl }kjk fd ;k x;k d k;Zgksxk


Sol.

(A) 5.58 T0 J
(B) 10.58 T0 J
(C) 25.58 T0 J
(D*) 15.58 T0 J
Work done by gas on right chamber. nka
;sHkkx
P2 V2 P0 V0
W=
1
3 9

=
1 P0V0
2 4
15
=
8.3 T0
8
= (15.58 T0) J

esafLFkr xSl }kjk fd ;k x;k d k;ZA

Paragraph for Question Nos. 31 to 32


iz'u 31 l s32 d sfy , v uqPN sn
Comprehension # 1
In standard YDSE the intensity on screen varies with position according to following graph as we
move away from the central maxima :
]
ekud YDSE iz;ksx esad sfUnz; mfPp"B lsnwj t kusij fLFkfr d slkFk insZij izkIr rhoz
rk fuEu vkjs[k d s

vuql kj ifjofrZr gksrh gSA

[YE-YE](104)

10

y (in mm)

Wave length of light used is 400 nm and distance between the two slits is 1 mm.
iz;qDr izd k'k d h rjaxnS/;Z400 nm rFkknksuksafLy Vksad se/; nwjh 1 mm. gSA
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P2JPJFJRAIOT220215C0-13

PHYSICS

31.

If the distance between two slits is reduce to 0.5 mm then the intensity :

[YE-YE](104)

PHYSICS

;fn nksuksafLy Vksad se/; nwjh 0.5 mm rd d e gkst k;srks] izkIr rhozrk
(A) will become zero at y = 4 mm and y = 8 mm
y = 4 mm rFkk y = 8 mm ij

'kwU; gkst k;sxhA

(B) will remain same 0 at y = 4 mm and y = 8 mm


y = 4 mm rFkk y = 8 mm ij

rhozrk0 d sleku jgsxhA

(C*) will become zero at y = 4 mm and will remain 0 at y = 8 mm


y = 4 mm ij

'kwU; gkst k;sxh rFkk y = 8 mm ij eku 0 d sleku jgsxhA

(D) will become zero at y = 8 mm and will remain 0 at y = 4 mm


y = 8 mm ij

'kwU; gkst k;sxh rFkk y = 4 mm ij eku 0 d sleku jgsxhA


f Ut pkSM +kbZnqxuh gkst k;sxhA

Sol.

Fringe width will become double.

32.

If the distance between the two slits is kept 1 mm and then a thin film of refractive index 1.5 and
thickness 2.2 m is used to cover the one of the slit. What will be intensity at y = 2 mm.

;fn nksuksafLy Vksad se/; nwjh 1 mm j[kh t k;srFkk fd lh ,d fLy V d slkeus1.5 viorZukad d h 2.2 m

Sol.

eksVkbZoky h iry h fQ Ye j[kusij y = 2 mm ij rhozrk D;k gksxh?

[YE-YE](104)

(A*) /2

(D) zero

(B)

Shift foLFkkiu =

t( 1)

2.2 10 6 0.5

4 10 7

11

So, intensity will become

vr% rhozrk

0
2

(C) /4

0
2

gkst k;sxhA

Paragraph for Question Nos. 33 to 34


iz'u 33 l s34 d sfy , v uqPN sn
Passage
The common prism telescope is shown in figure is generally made up of three parts, viz., a prism and two
telescopes. One of these telescopes is used to render the rays which fall on the prism parallel to
each other, and is therefore called the collimator, the other telescope is made movable so that it
can be turned into the proper direction for observing any desired color, and is, therefore, called the
view-telescope. A circular scale is also provided to major angular position of telescope.
On the circular scale 29 divisions of the main scale exactly coincide with the 30 divisions of the
vernier scale. If the smallest division of the main scale is half-a-degree (0.5).
[GO-OI](104)
First telescope is focused to collect rays directly from collimator and position of telescope is
measured. This is position (1). Now a prism is placed as shown in the figure and telescope is
focused for red, yellow and violet. The respective positions of telescope are (2), (3) and (4).
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P2JPJFJRAIOT220215C0-14

Reading of main scale


20.0
30.0
32.5
33.5

Position (1)
Position (2)
Position (3)
Position (4)

eq[; iSekusd k ikB~;kad

ofuZ;j iSekusd k ikB~;kad

20.0
30.0
32.5
33.5

20
16
9
11

fLFkfr (1)
fLFkfr (2)
fLFkfr (3)
fLFkfr (4)

L1

F1

Reading of veriner scale


20
16
9
11

Collimator

d ksy hehVj

Prism

L2

fiz
Te

Telescope

F2

nwjn'khZ

EYE

vk[k

33.

What is deviation for violet light :

[GO-OI](104)

cSaxuh jax d sfy , fopy u D;k gksxk %


Sol.

(A) 1222
(B) 1319
(C) 335
(D*) 1321
29 division of main scale coincides with 30 divisions of vernier scale Hence one division of vernier
scale
eq[; iSekusd s29 Hkkx ofuZ;j iSekusd s30 Hkkx d slEikrh gSA vr% ofuZ;j iSekusd k ,d Hkkx
30 29
of main scale
30
1
0.5
=
30
1
0.5 60 min
=
30

eq[; iSekuk

= 1 min.
Position fLFkfr (1) 20 20
Position fLFkfr (2) 30 16
Position fLFkfr (3) 32 39
Position fLFkfr (4) 33 41
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P2JPJFJRAIOT220215C0-15

PHYSICS

PHYSICS

fp=k esaiznf'kZr ,d la;qDr nwjn'khZlk/kkj.kr;k rhu Hkkxksalsfey d j cuk gksrk gS


A t Sl sfizTe rFkk nksnwjn'khZA
buesals,d nwjn'khZd k iz;ksx fizTe ij fd j.kksad kslekUrj izsf{kr d juk gksrk gS] blfy, bld ksd kWy hehVj
d grsgSrFkk blh izd kj nwl jk nwjn'khZpy k;eku : i esacuk gksrk gSA ft ld sd kj.k bld ks,d fuf'pr fn'kk
esaO;ofLFkr d jd sbPNkuql kj jax izsf{kr d j ld rsgSA blfy , bld ksn`'; nwjn'khZd grsgSA o`fk; iSekuk
nwjn'khZd svy x&vy x o`gn d ks.kh; fLFkfr d ksiznf'kZr d jrk gSA o`
fk; iSekusij eq[; iSekusd s29 Hkkx]
ofuZ;j iSekusd s30 Hkkxksalsla
ikrh gSA eq[; iSekusd k ,d Hkkx vk/kk fMxzh (0.5) d ksiznf'kZ
r d jrk gSA
izFke nwjn'khZd ksd kWy hehVj lsfd j.ksaiz
kIr d jusd sfy , Q ks
d 'khr fd ;k t krk gS] rFkk nwjn'khZd h fLFkfr ekih
t krh gSA ;g fLFkfr (1) gSA vc fp=kkuql kj ,d fizTe j[kk t krk gSrFkk ;g fd j.kksad ksy ky ] ihy srFkk cSaxuh
jax esaQ ksd flr d jrk gS] vksj bud sfy , nwjn'khZd h fLFkfr;k e'k% (2), (3) rFkk(4) lsiznf'kZr gSA

PHYSICS

34.

If we find angular derivation for different colours then percentage error in derivation will be
maximum for
[GO-OI](104)
(A*) Red
(B) Yellow
(C) Violet
(D) Same for all

;fn ge vy x jaxksad sfy , d ks


.kh; fopy u Kkr d jsrksizfr'kr fopy u =kqfV fd l jax d sfy , T;knk gksxhA
(A) y ky
(B) ihy k
(C) cS
axuh
(D) lHkh d sfy , leku gS
A
Sol.

100

is minimum for red is same for all, so percentage error will be maximum for Red.
y ky jax d sfy , U;wure gSlHkh d sfy, leku gS, vr% y ky jax d sfy , izfr'kr =kq
fV vf/kd re
Percentage error iz
fr'kr

=kqfV =

gksxhA

SECTION 3 : (Integer value correct Type)


[k.M 3 : (iw.kkd eku l gh d kj)
This section contains 6 questions. The answer to each question is a Two digit integer, ranging
from 00 to 99 (both inclusive).
bl [k.M es
a6 'u gS
A R;s
a
d 'u d k mkj 00 ls99 rd nksuks
a'kkfey d schp d k nksv a
d ksaoky k iw
.kk
d gS
A
35.

A particle starts from rest and moves on a circular path with an angular acceleration which is
proportional to square root of instantaneous angular velocity. Find the mean angular velocity (in
1
rad/sec) averaged over the time it takes to acquire an angular velocity of 12 rad sec

,d d .k fLFkj voLFkk lso`kkd kj iFk ij d ks.kh; Roj.k d slkFk xfr izkjEHk d jrk gS
A bld k d ks.kh; Roj.k
bld srkR{kf.kd d ks.kh; osx d soxZewy d slekuqikrh gSA 'kwU; ls12 rad sec1 d ks.kh; os
x izkIr d jusesay xs
le;kUrjky d snkSjku vkSl r : i lsbld k ek/; d ks.kh; osx (rad/sec esa) Kkr d jksA
[CM-KN](104)
Ans.
Sol.

4
= k
d

k
d

d k d

3/2

= K
3/2

23 / 2
3k

d
k
dt

k dt

1/2

= kt

2
t=

k
1
2 k


wavg = 4 rad/sec.
t 3

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P2JPJFJRAIOT220215C0-16

PHYSICS

DV = 3341 2020= 1321

36.

A piece of metal weighs 46 g in air. When it is immersed in a liquid of specific gravity 1.24 at 37C it
weighs 30 g. When the temperature of the liquid is raised to 42C, the metal piece weighs 30.5 g.
The specific gravity of the liquid at 42C is 1.20. Coefficient of linear expansion of the metal is nearly
N
69 10 , find N.
[FL-BY](104)

/kkrqd s,d Vqd M+sd k gok esaHkkj 46 g gSA t c bld ks37C rkieku ij 1.24 fof'k"V xq
: Ro d snzo esaMqcks;k
t krk gS] rc bld k Hkkj 30 g gSA t c nzo d k rkieku 42C rd c<+k;k t krk gS] rks/kkrqd sVqd M+sd k Hkkj 30.5
g gkst krk gS
A 42C rkieku ij nzo d k fof'k"V xq: Ro 1.20 gSA ;fn /kkrqd k js[kh; izl kj xq.kkad y xHkx 69
N
10 , gksrksN d k eku Kkr d jks
A
Ans. 06
Sol. We have ge t kursgS
,
Upthrust mRiy kod cy , FB = Vg
Apparent weight vkHkklh Hkkj = mg 0Vg = 30g
When temperature is increased t c rkieku c<+
k;k t krk gS
FB = Vg
Apparent weight vkHkklh Hkkj = mg 0Vg = 30.5g
= mg 0V(1 + 3 )g = 30.5g
on solving gy d jusij
5
1
and rFkk
= 6.9 10 C
37.

(i)

(ii)

A conducting tube is passing through a bath. A liquid at temperature 90C and specific heat s is
entering at one end of tube. Rate of flow of liquid is 1 kg/s and exit temperature is 50C. In bath
another liquid having specific heat 2s and inlet temperature 20C is entering at a rate of 2 kg/s.
Find the exit temperature of the liquid coming out of the bath. (Assume steady state condition)

[CT-CL](104)
,d pkyd uy h LukuVc lsxqqt jrh gSA uy h d s,d fljsls90C ij s fof'k"V "ek d k nzo izokfgr fd ;k
t krk gSA bl nzo d h izokg nj 1 kg/s rFkk ckgj fud y rsle; rkieku 50C gSA LukuVc esaHkjsgq, vU; nzo
d h fof'k"V "ek 2s rFkk izos
'k d jrsle; rkieku 20C gSrFkk ;g 2 kg/s d h nj lsizos'k d jrk gSrks
LukuVc lsckgj fud y usoky snzo d k rkieku Kkr d jksA (LFkkbZvoLFkk ekursgq,)
90C

20C

50C

2s

[Ans 30C ]

38.

A conductor carrying current 60A is in the form of a semicircle AB of radius R and lying in xy-plane

2
2
with its centre toat origin as shown in the figure. The magnitude of B.d for the circle x + z =
2

3R in xz-plane due to current in curve AB is n0. Find the value of n.

[EM-AL](104)

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P2JPJFJRAIOT220215C0-17

PHYSICS

PHYSICS

/kkjk d sd kj.k n0 gS] rksn d k eku Kkr d jks


A
Y
B

O
Z

Ans.
Sol.

30

Bnet .d B1.d B 2 .d

B1 magnetic field due to straight part lh/ksHkkx }kjk mRiUu pq


Ecd h; {ks=k

B2 magnetic field due to curved part o`


kd kj Hkkx }kjk mRiUu pqEcd h; {ks=k

R 3
0 = B1 2R 3 +
0=


B2 .d


2R 3 + B2 .d

4R 3


0 = 0 + B2 .d
2

0
= B2 .d
2

39.

The energy that can be obtained from 1 kg of water through the fusion reaction 2H + 2H 3H + p is
8
2
P 10 J. Assume that 1.5 10 % of natural water is heavy water D2O (by number of molecules )
and all the deuterium is used for fusion. Find the value of P.
Atomic masses are m( 12 H ) = 2.014102 u , m ( 13 H ) = 3.016049 u
[NP-FF](104)
Mass of proton mp = 1.007276 u

fuEu lay ;u vfHkf ;k }kjk 1 fd xzk ikuh esamRiUu


2

1u = 931

MeV

c2
"ek P 108J gksrksP d seku

d h x.kuk d hft ;s%

H + 2H 3H + p

;g eku y hft ;sfd izk frd t y esa1.5 10 2 % Hkkjh ikuh D2O gS(v.kq
v ksad h la[;k d svk/kkj ij) vkSj
leLr M~;wfVfj;e lay ;u esaiz;qDr gkst krk gSA
ijek.kqHkkj m( 12 H ) = 2.014102 u , m ( 13 H ) = 3.016049 u
izksVksu d k nzO;eku mp = 1.007276 u
Ans :
Sol.

37
Energy released in one fusion ,d

1u = 931

MeV
c2

lay ;u esamRiUu t kZ

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P2JPJFJRAIOT220215C0-18

PHYSICS

PHYSICS

,d pky d esa60A /kkjk iz


okfgr gSA pky d R f=kT;k d k v) Zo`k AB gSt ksfd xy ry esafLFkr gS,oabld k

d sUnzfp=kkuql kj ewy fcUnqij gSA xz ry esao`k x2 + z2 = 3R2 d sfy , B.d d k ifjek.k y wi AB esaizokfgr

PHYSICS
1

lay ;uksad h la[;k =


40.

ikuh d k nzO;eku
NA 1.5 10 4
v.kqHkkj

A capillary tube of radius 0.50 mm is dipped vertically in a pot of water. The difference between the
pressure of the water in the tube 5.0 cm below the surface and the atmospheric pressure is 10x
2
N/m . Surface tension of water = 0.075 N/m contact angle between glass and water is zero
2
degree. Find the value of x. (g = 9.8 m/s )
[SF-EX](103)
0.50 feeh f=kT;k d h d s
'kuy h d kst y

d sik=k esam/okZ/kj Mq
ck;k x;k gSA uy h esap<sgq, t y d h lrg ls5.0
lseh uhpsnkc ,oaok;qe.My h; nkc d k vUrj 10x N/m2 gksrksx d k eku Kkr d hft ;sA t y d k i`"B ruka
o=
2
0.075 N/m rFkk d kW
p o ikuh d se/; Li'kZd ks.k 'kwU; fMxzh gSA (g = 9.8 m/s )
Ans.
Sol.

19
A

2S
pgh
R
= P0 300 + 490
= P0 +190
PA = P0

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P2JPJFJRAIOT220215C0-19

PHYSICS

Q = [2m( H) m( H) m( H)]c
mass of water
Number of fusion =
NA 1.5 10 4
moleculer weight

Course : JR AIOT (JEE ADVANCE) - 2


Test Type : JEE ADVANCED -2 (ELPD)

Test Date : 03-05-2015

Page # 1

PAPER-2
MCQ (6)
41.

A 5g sample containing Fe3O4 (FeO + Fe2O3) and an inert impurity is treated with excess of KI solution in
the presence of dilute H2SO4. The entire iron converted to Ferrous ion along with liberation of Iodine. The
resulting solution is diluted to 100 ml. 20 ml of the diluted solution requires 10 ml of 0.5M Na2S2O3 solution
to reduce the iodine present. Amongs the following select correct statements.
(A*) % of Fe2O3 in sample is 40%
(B) % of FeO in sample is 28%
(C*) % of inert impurity in sample is 42%
(D) % of inert impurity in sample is 32%
Fe3O4 (FeO + Fe2O3) rFkk ,d vf ; v'kq
f) ;qDr] ,d 5g izkn'kZd k ruqH2SO4 d h mifLFkfr esaKI foy ;u d svkf/kD;

d slkFk mipkfjr fd ;k t krk gSA lEiw.kZvk;ju] Q sjl vk;u esaifjofrZr gksrk gSrFkk lkFk gh vk;ksM hu eqDr gksrh gSA
ifj.kkeh foy ;u d ks100ml rd ruqfd ;k x;kA 20ml ruqfoy ;u esamifLFkr vk;ksM hu d ksvipf;r d jusd sfy,
0.5M Na2S2O3 d k10ml vko';d gks
rk gSA fuEu esalslgh d Fkuksad k p;u d hft ,A
(A*) iz
kn'kZesaFe2O3 d k 40% gSA
(B) iz
kn'kZesaFeO d k 28% gSA
(C*) iz
kn'kZesavf ; v'kqf) 42% gSA
(D) iz
kn'kZesavf ; v'kq
f) 32% gSA
Sol.

Sol.

40
Let the moles of Fe3O4 is x. So mole of Fe2O3 (in Fe3O4) = x
eq of Fe2O3 (in Fe3O4) = eq of K = eq of 2 = eq of Na2S2O3.
or
2x = 0.025
or
x = 0.0125 mol of Fe2O3
So mass of Fe2O3 = 0.0125 160 = 2g
2
% of Fe2O3 = 100 = 40%.
5
40
ekuk fd Fe3O4 d seksy x gSA vr% Fe2O3 d seksy (Fe3O4 esa) = x
Fe2O3 d srq
Y;kad (Fe3O4 esa) = K d srqY;kad = 2 d srqY;kad = Na2S2O3 d srqY;kad

vFkok 2x = 0.025
vFkok x = 0.0125 mol of Fe2O3
vr% Fe2O3 d seksy = 0.0125 160 = 2g
2
100 = 40%.
5
-bond results due to overlap of :
(A*) dxy and py along xaxis
(C*) dxy and px along yaxis
Fe2O3 d k iz
fr'kr =
42.

(CBO-VBT)_203
(B) dx2y2 and py along xaxis
(D) dx2y2 and py along yaxis

-cU/k] fuEu d svfrO;kiu d k ifj.kke gks


rk gS%
(A*) x-v{k d h vks
j dxy rFkk py d svfrO;kiu d sd kj.k
(B) x-v{k d h vks
j dx2y2 rFkk py d svfrO;kiu

d sd kj.k
(C*) y-v{k d h vks
j dxy rFkk px d svfrO;kiu d sd kj.k
(D) y-v{k d h vks
j dx2y2 rFkk py d svfrO;kiu d sd kj.k
Sol. -bond are formed by parallel overlaping of same orbitals. So, correct options are :
(A) dxy and py along xaxis
(C) dxy and px along yaxis

gy

leku d {kd ksad slekukUrj ikf'oZd vfrO;kiu d sd kj.k - ca/k d k fuekZ.k gksrk gSA vr% lgh fod Yi gSa%
(A) x-v{k d h vks
j dxy rFkk py d svfrO;kiu d sd kj.k
(C) y-v{k d h vks
j dxy rFkk px d svfrO;kiu d sd kj.k

43.

The vapour pressure of two miscible liquids A and B are 300 and 500 mm of Hg respectively. In a flask,
2 moles of A are mixed with 6 moles of B. Further to the mixture, 32 g of an ionic non-volatile solute MCl
(partially ionised, mol. mass = 70 u) were also added. Thus, the final vapour pressure of solution was
found to be 420 mm of Hg. Then, identify the correct statement(s) : (Assume the liquid mixture of A and B
to behave ideally).
(SCP-RLVP)_206
(A*) The numerical value of relative lowering in vapour pressure upon addition of solute MCl is 1/15.

Page # 1

(B*) The solute MCl is 25% ionised in the above question.


(C) The solute MCl is 23.33% ionised in the above question.
(D*) Upon addition of excess Pb(NO3)2, the number of moles of PbCl2 precipitated is 2/35.

nksfeJ.kh; nzoksaA rFkk B d sok"i nkc e'k% 300 rFkk 500 mm Hg gSaA ,d y kLd esa] 2 eksy A d ksB d s6 eksy d s
lkFk fefJr fd ;k t krk gS
A bld sckn bl feJ.k esa] ,d vok"i'khy vk;fud foy s; MCl vkaf'kd : i lsvk;fur]
vkf.od nzO;eku = 70 u d k 32 g Hkh fey k;k t krk gSA bl d kj foy ;u d k vfUre ok"i nkc 420 mm Hg ik;k
t krk gSA rc lgh d Fku@d Fkuksad h igpku d hft , % (A rFkkB d snzo feJ.k d k O;ogkj vkn'kZekusaA)
(A*) MCl foy s
; fey kusij ok"i nkc esavkisf{kd voueu d k vkafd d eku 1/15 gSA
(B*) mijks
Dr iz'u esafoy s; MCl, 25% vk;fur gksrk gS
A
(C) mijks
Dr iz'u esafoy s; MCl 23.33% vk;fur gksrk gSA
(D*) Pb(NO3)2 d k vkf/kD; fey kusij] vo{ks
fir PbCl2 d seksy ksad h la[;k2/35 gSA
Sol.

2
6
300 +
500 = 450 mm of Hg.
8
8
P PS 450 420
1
Now, vc]RLVP = 0
=
=
P0
450
15
P0 = XAPA + XBPB =

in
Also, lkFk ghRLVP =

in N
32i
1
= 70

i = 1.25 = (1 + (2 1)). So, = 0.25 (or 25%)


32i
15
8
70
25 32 4
n produced mRikfnr n ) =

=
Cl
Cl
100 70 35
1 4
2
nPbCl2 precipitated vo{ks
fir nPbCl2 = =
2 35 35
44.

Which of the following properties is/are common to both K2Cr2O7 & KMnO4 ?
(DBC-IDM)_203
(A*) Both on heating form an oxosalt, a metal oxide & oxygen gas.
(B*) Both have their colour because of charge transfer spectrum.
(C) Both behave as primary titrants as well as self-indicators in redox titrations.
(D*) Both form a slightly coloured precipitate with hydrogen sulphide in acidic medium.
fuEu esalsd kSulk@d kSulsxq.k/keZK2Cr2O7 rFkkKMnO4 nksuksd sfy , leku gS@ gSa\
(A*) nks
uksad ksxeZd jusij
(B*) nks
uksd k jax

vkos'k LFkkukUrj.k LisDVe d sd kj.k gksrk gS


A

(C) nks
uksajsM kWDl

vuqekiuksaesaizkFkfed vuqekid o Lor% lwp d d h rjg O;ogkj d jrsgSA

(D*) nks
uksvEy h;
Sol.

vkDlksy o.k] /kkrqvkWDlkbM o vkWDlht u xSl curh gSA

ek/;e esgkbMkst u lYQ kbM d slkFk gYd k jaxhu vo{ksi cukrk gSaA

(A) Both on heating form an oxosalt (K2CrO4 & K2MnO4), a metal oxide (Cr2O3 & MnO2) & oxygen gas.
(B) Both have their colour (orange and purple respectively) because of charge transfer spectrum (since no
unpaired electrons).
(C) Only K2Cr2O7 behaves as primary titrant, while KMnO4 behave as self-indicator in redox titrations.
K2Cr2O7 requires diphenyl amine indicator for end point detection while KMnO4 behaves as secondary
titrant.
(D) Both form a slightly coloured precipitate (S) with hydrogen sulphide in acidic medium.

Page # 2

gy -

(A)

nksuksad ksxeZd jusij vkDlksy o.k (K2CrO4 & K2MnO4)] /kkrqvkWDlkbM (Cr2O3 & MnO2) o vkWDlht u xSl

curh gSA
(B)

nksuksd k jax e'k% ukjaxh o cSaxuh vkos'k LFkkukUrj.k LisDVe pqafd d ksbZv;qfXer by s
DVkWu ughagksrk gS d sd kj.k

gksrk gSA
(C)

jsMkWDl vuqekiu esad soy K2Cr2O7 esavfUre fcUnqfu/kkZj.k d sfy, MkbZQ s


fuy ,ehu lqp d d h vko';d rk gksrh gS

t cfd KMnO4 f}rh;d vuqekid d h rjg O;ogkj d jrk gSA


(D) nks
uksvEyh;

45.

ek/;e esgkbMkst u lYQ kbM d slkFk gYd k jaxhu vo{ksi (S) cukrk gSaA

F2 + dil. NaOH A + B + C

(PBC-XVII, SBC-CAM)_204

F2 + conc. NaOH A + D + C
(A*) A is NaF
(B) B is O2

(C*) C is H2O

F2 + ruqNaOH A + B + C

(PBC-XVII, SBC-CAM)_204

F2 + lka
nzNaOH A + D + C
(A*) A, NaF gS
(B) B, O2
Sol.

(D) D is OF2

gS

(C*) C, H2O

gS

(D) D, OF2

gS

F2 + dil. NaOH NaF + OF2 + H2O


F2 + conc. NaOH NaF + O2 + H2O

gy -

F2 + ruqNaOH NaF + OF2 + H2O


F2 + lka
nzNaOH NaF + O2 + H2O

46.

(CHK-PRFO)_205

All reactions are of Ist order.


[B]
[C]
At time t = t1 (t1 > 0),
= ; At time t = t2 (where t2 t1),
=
[C]
[D]
Which of the following is/are correct ?

lHkh vfHkf ;k,iz


Fke d ksfV d h gSaA
le; t = t1 ij (t1 > 0),

[B]
=;
[C]

le; t = t2 ij (t gkt2 t1),

[C]
=
[D]

fuEu esalsd kSulkls lEcU/k lgh gSgSa \


(A) = 0.5

(B) = 4/3

(C*) = 0.375

(D*) = 16/15

Page # 3

Sol.

[B] 3k1 3


[C] 8k1 8

[C]
8k1
8

[D] 7.5k1 7.5

MCQ (2)
47.

Observed the following reaction sequence and identify the correct options ?

fuEu vfHkf ;k vuq e d k voy ksd u d j lgh fod Yi d k p;u d hft , \

(NAV Sir) (AC) (M) (MCQ)

O
CH2C

CH2C

Zn Hg
PCl5
AlCl3
AlCl3
Zn Hg HCl

(A)
(B)
(C)
(D)

(E)
HCl

PdC/

(F)
(A*) F reacts with KMnO4/OH gives phthalic acid which upon heating gives phthalic anhydride.
(B*) E upon monochlorination (Cl2/h) gives total four products.
(C*) F upon complete catalytic hydrogenation gives saturated compound which show geometrical
isomerism.
(D*) Compound (A) gives the NaHCO3 test.

(A*) ;kS
fxd F, KMnO4/OH d slkFk f ;k d jd sFkSfy d

vEy cukrk gSft lsxeZd jusij FkSfy d ,ugkbMkbM curk gS


A
(B*) ;kS
fxd E d s,d y Dy ksjksuhd j.k (Cl2/h) ij d qy pkj mRikn cursgS
A
(C*) ;kS
fxd F d siw.kZmRizsjd h; gkbM
kst uhd j.k ij lar`Ir ;kSfxd curk gSt ksT;kferh; leko;ork n'kkZrk gSA
(D*) ;kS
fxd (A) NaHCO3 ijh{k.k nsrk gS
A
O

O
CH2C

Sol.

+
CH2C

C
O

AlCl3

HOC

CH2

Zn Hg

HCl

CH2

PCl5

Cl

O
(B)

O
(A)

O
(C)
AlCl3

COOH
COOH
H2O

KMnO4

ZnHg + HCl

PdC/

OH

(F)

(E)
(D)

Pd + H2 /

Cl2/h

Cl
* H

H
O
O
H cis.
+
H

(d)
+
* Cl
H
(d)

H trans.

(G)

Page # 4

48.

Conc. H2SO4

Reaction-I

Product (X)

80C

Conc. H2SO4
160C
Conc. H2SO4

Reaction-II

Product (Y)

160C

Which of the following option(s) is/are correct for above give reactions
(SSS Sir) (AC-EAS) (MCQ) (204) (M)
(A*) In the reaction-I product is formed by most stable intermediate and product (X) is converted into (Y) by
conc. H2SO4 at 160C
(B) In the reaction-II product is -naphthalene sulphonic acid
(C*)Product 'X' is converted into product Y by conc.H2SO4/ and it is a thermodynamically controlled
process.
(D) In the reaction I & II electrophile attacks on naphthalene with same regioselectivity.

lkUnzH2SO4

vfHkf ;k-I

mRikn (X)

80C

lkUnzH2SO4
160C

lkUnzH2SO4

vfHkf ;k-II

mRikn (Y)

160C

mijksDr nh xbZvfHkf ;kvksad sfy , fuEu esalsd kSulsfod Yi lgh gS@ gSa& (SSS Sir) (AC-EAS) (MCQ) (204) (M)
(A*)

vfHkf ;k-I esamRikn lokZf/kd LFkk;h e/;orhZlscurk gSrFkk mRikn (X) 160C ij lkUnzH2SO4 d h mifLFkfr esa
;kSfxd (Y) esaifjofrZr gkst krk gSA

(B)
(C*)

vfHkf ;k-II esamRikn -uSFkSy hu lY;wfjd vEy gksrk gS


A
mRikn 'X' lkUnzH2SO4/ d h mifLFkfr esamRikn Y esaifjofrZr gkst krk gSrFkk ;g vfHkf ;k "ekxfrd h;
: i lsfu;af=kr iz e gS
A

(D)

vfHkf ;k I o II esaby sDVkWu Lusgh leku fjft ;ksp ;ukRed rk d slkFk usFksy hu ij vk e.k d jrk gSA
H

Sol.

SO3/80C

SO3

SO3H

SO3/160C

SO3

SO3H

Page # 5

Comp.(3 x 2Q.) (2)


Paragraph for Question Nos. 49 to 50
iz'u 49 l s50 d sfy , v uqPN sn
Calomel electrode : It consists of mercury at the bottom over which a paste of mercury-mercurous
chloride is placed. A saturated solution of potassium chloride is then placed over the paste. A platinum wire
sealed in a glass tube helps in making the electrical contact. The electrode is connected with the help of
the side tube on the left through a salt bridge with the other electrode to make a complete cell.

Fig. Calomel electrode


The potential of the calomel electrode depends upon the concentration of the potassium chloride solution.
If potassium chloride solution is saturated, the electrode is known as saturated calomel electrode (SCE)
and if the potassium chloride solution is 1 N, the electrode is known as normal calomel electrode (NCE)
while for 0.1 N potassium chloride solution, the electrode is referred to as decinormal calomel electrode
(DNCE). The electrode reaction when the electrode acts as cathode is :
1
Hg2Cl2 + e
Hg + Cl
2
(Given : 2.303 RT / F = 0.06)
Now answer the following questions.

d Sy ksey by sDVksM : bld svUrxZr ed Zjh ry sij gksrh gSft ld s ij ed Z


jh ejD;wjl Dy ks
jkbZM d k isLV j[kk t krk gSA
bl isLV d s ij iksVsf'k;e Dy ksjkbM d k lar`Ir foy ;u Mkyk t krk gSA fo|qr lEid Zd kscukusd sfy , d kp d h ufy d k
esa,d Iy sfVue d k rkj izR;kjks
fir fd ;k t krk gS
A lEiw.kZlSy cukusd sfy , by sDVksM d ksck;h vks
j fLFkr ik'oZufy d k
d h lgk;rk lsvU; by sDVksM d slkFk y o.k lsrqlst ksM +
k t krk gSA

fp=k % d Sy ksey by sDVksM


d Sy ksey by sDVksM d k foHko] iksVsf'k;e Dy ksjkbM foy ;u d h lkanzrk ij fuHkZ
j d jrk gSA ;fn iksVsf'k;e Dy ksjkbM d k
foy ;u lar`Ir gS] rksby sDVksM d kslar`Ir d Sy ksey by sDVksM (SCE) d gk t krk gSrFkk ;fn 1 N iksVsf'k;e Dy ksjkbM
foy ;u gS, rksby sDVksM d ksukeZy d Sy ksey by sDVksM (NCE) d gk t krk gS] t cfd 0.1 N iksVsf'k;e Dy ksjkbM foy ;u d s
fy , by sDVksM d ksMsl hukWeZy d Sy ksey by sDVksM (DNCE) d gk t krk gSA t c by sDVksM ,d d SFkks
M d h rjg d k;Zd jrk gS
rksby sDVksM vfHkf ;k fuEu gS%
1
Hg2Cl2 + e
Hg + Cl
2
(fn;k x;k gS: 2.303 RT / F = 0.06)

Page # 6

v c fuEu iz'uksad smkj nhft ,A


49.

For the calomel half-cell Hg, Hg2Cl2 | Cl (aq), values of electrode oxidation potential are plotted at different
log [Cl]. Variation is represented by : ( E0

Hg22 /Hg

= 0.79 V ; Ksp(Hg2Cl2) = 1018)

(ECH-NE)_205

d Sy ksey v) Zlsy ] Hg, Hg2Cl2 | Cl t y h; d sby sDVksM vkWDlhd j.k foHko d sekuksad kslog [Cl] d sfofHkUu ekuksaij
vkjs
f[kr fd ;k t krk gSA rc bld k ifjorZu fuEu }kjk n'kkZ;k t krk gS% ( E0 2 = 0.79 V ; Ksp(Hg2Cl2) = 1018
Hg2 /Hg

(A)

Sol.

(B*)

EOP = E0SOP 0.06 log

EOP = (0.79 +

(C)

(D)

1
[Cl ]

0.06
log101018) + 0.06 log [Cl]
2

EOP 0.25 0.06 log [Cl ]


y
c
m x
50.

(ECH-ANE)_205

E.M.F. of the following cell is 0.67 V at 298 K.

Pt(s) | H2 (g, 1 atm) | H (aq, pH 6.5) || 1 N KCl(aq) | Hg2Cl2 (s) |Hg( l ) | Pt(s)

Calculate ECl

/Hg Cl
2

298 K ij

/Hg

(calomel electrode).

fuEu lsy d kE.M.F. 0.67 V gSA

Pt(s) | H2 (g, 1 atm) | H (aq, pH 6.5) || 1 N KCl(aq) | Hg2Cl2 (s) |Hg( l ) | Pt(s)

ECl

/Hg Cl
2

/Hg

d Sy ksey by sDVksM d h x.kuk d hft ;sA

(A*) 0.28 V
Sol.

H2 + Hg2Cl2
Ecell = E

(B) 0.30 V
2Hg +

Cl /Hg2Cl2 /Hg

0.67 = E

Cl /Hg2Cl2 /Hg

0.67 = E
0.28 = E

2Cl

(C) 0.26 V

(D) 0.4 V

2H+

H /H2

0.06
log [H+]2 (1)2
2

+ 0.06 pH

Cl /Hg2Cl2 /Hg

+ 0.06 6.5

Cl /Hg2Cl2 /Hg

Paragraph for Question Nos. 51 to 52


iz'u 51 l s52 d sfy , v uqPN sn

The coordination number of iron in both the complexes (A) and (B) is six. (QUA-IIG)_204
Now answer the following questions.

Page # 7

nksuksalad qy ksa(A) o (B) esavk;ju d h leUo; la[;k N% gSA


v c fuEu iz'uksad smkj nhft ,A
51.

Which of the following options is incorrect ?


(A) A + Fe2+ = Prussion blue colour
(C*) B + Fe2+ = Light green colour

(B) A + Fe3+ = Brown colour


(D) B + Fe3+ = Prussion blue colour

fuEu esalsd kSulk fod Yi lgh ughagS\


(A) A + Fe2+ = iz
qf'k;u uhy k jax
2+
(C*) B + Fe = gYd k gjk ja
x

(B) A + Fe3+ = Hkw


jk jax
3+
(D) B + Fe = iz
qf'k;u

(COR-ACFT)_203

Sol.

B + Fe2+ = white colour


B + Fe2+ = lQ s
n jax

52.

Which statement is incorrect ?


(A) Complex A absorbs radiation of greater frequency.
(B) Complex B has smaller spin magnetic moment.
(C) Both complexes have same hybridisation of central atom/ion.
(D*) Complex B is thermodynamically more stable.

uhy k jax

(COR-ACFT)_203

fuEu esalsd kSulk d Fku xy r gS\


(A) la
d qy A mPp vkorhZd h fofd j.ksavo'kksf"kr d jrk gSA
(B) la
d qy B d e p .k pqEcd h; vk?kw.kZj[krk gSA
(C) nks
uksalad qy ksaesad sUnzh; ijek.kq@ vk;u d k lad j.k leku gksrk gSA
(D*) la
d qy B m"ekxfrd h; : i lsvf/kd LFkk;h gksrk gSA
Sol.

(A) Complex A - K3[Fe(CN)6] absorbs radiation of greater frequency because it contains Fe3+, so greater
O.
(B) Complex B - K4[Fe(CN)6] has zero spin magnetic moment.
(C) Both complexes have same hybridisation (d2sp3) of central atom/ion.
(D) Complex B is thermodynamically less stable (O.N. stability).
(A) la
d qy A - K3[Fe(CN)6] mPp vkorZd h fofd j.ksavo'kks
f"kr d jrk gSA D;ksafd ;g Fe3+ vk;u j[krk gSA blfy , O

mPp gksrk gSA


(B) la
d qy B - K4[Fe(CN)6] d k 'kwU; p .k pqEcd h; vk?kzw.kZgksrk gSA
(C) nks
uksalad qy d sd sUnzh; ijek.kq@ vk;u d k lad j.k (d2sp3) gksrk gSA
(D) la
d qy B m"ekxfrd h; : i lsd e LFkk;h gksrk gSA (vkWDlhd j.k vad LFkkf;Ro).
Paragraph for Question Nos. 53 to 54

iz'u 53 l s54 d sfy , v uqPN sn


Each of these reactions is a substitution of the leaving group (OTs or Cl) by solvent.
PhS
H 2O

(r1 > r2)


r1
Cl
HO

Cl
r
2

The mechanism by which they speed up the reactions is known as neighbouring group participation.

S
H2O
PhS
PhS
Ph
OH
Cl
Three membered
ring intermediate
In this, ionization of the starting material is assisted by the lone pair of an electron-rich functional group.

Page # 8

In neighbouring group participation relation of configuration is observed. Observe the following reaction
also
OTs
OAc
AcOH

OAc
OAc
Which follows through the mechanism.
CH3
CH3

OAc

AcOH
OTs

OAc
Neighbouring group participation is only possible when leaving group and neighbouring group are anti to
each other.
(RSS Sir) (RM-MX) (207) (NGP) (Tough)

uhpsnh xbZizR;sd vfHkf ;ksaesami;qDr foyk;d d h mifLFkfr esafu"d klu lewg (OTs ;k Cl) d k izfrLFkkiu gksrk
gSA
PhS
Cl

HO
r1

(r1 > r2)

HO

Cl
r
2

f ;kfof/k ft ld s}kjk vfHkf ;k d h nj c<+t krh gSmlsiM+


kS
l h lewg d k ;ksxnku d grsgSA

PhS

H 2O

PhS
Cl

S
Ph

OH

rhu lnL;h
oy ; e/;orhZ
mijksDr vfHkf ;k esiz
kjfEHkd inkFkZd k vk;uu ,d by sDVkWu /kuh f ;kRed lewg d s,d kd h ;qXe }kjk lEiUu gksrk gSA
iM+kSl h lewg ;ksxnku esafoU;kl d k lEcU/k izs
f{kr gksrk gS
A fuEu vfHkf ;k Hkh izsf{kr gksrh gS%
OTs

OAc
AcOH

OAc

OAc

t ksfuEu f ;kfo/kh d sek/;e lsgksrh gSA


CH3

CH3
O

OAc

AcOH
OTs

OAc

iM+kSl h lewg ;ksxnku d s


oy rHkh lEHko gSt c fu"d klu lewg o iM+
kSl h lew
g ,d &nwl jsd sfoifjr gksrsgSA.
(RSS Sir) (RM) (NGP) (Tough)
53.

Which of the following are true statement OTs


(A)

OTs

reacts with acetic acid faster than


OAc

OAc

Page # 9

(B)

Cl reacts with H2O slower than

(C*) Me

Cl

OSO2Ph reacts with ROH raster than Me

OSO2Ph

SMe

(D)

Me

HO

reacts faster than

HO

with H2O.

fuEu esalsd kSulk d Fku lR; gS&


OTs

OTs

(A)

,flfVd vEy d slkFk

d h f ;k

d h rqy uk esvf/kd rs
t h lsgksrh gSA
OAc

OAc

(B) H2O d slkFk

Cl

(C*) ROH d slkFkMe

d h f ;k

OSO2Ph

Cl

d h f ;k Me

SMe

(D)
Sol.

I HO

HO

d h rqy uk es/kheh gksrh gSA


OSO2Ph

d h rqy uk esavf/kd rst gksrh gSA

Me

fd rqy uk esaH2O d slkFk rst h lsvfHkf ;k d jrk gSA

OSO2Ph show neighbouring group participation.

Me
SMe

OSO2Ph

Me

iM+kSl h lewg d k ;ksxnku iznf'kZr d jrk gSA

SMe

OTs
AcOH

Product, mRikn

54.
OAc

Product is mRikn

gS
OAc

OAc

(A)

(B*)
OAc
OAc

Sol.

In

OTs

(C)
OAc

OAc

(D)
OAc

OAc

neighbouring group participation is not possible.


OAc
OAc

esaiM+kSl h lew
g d k ;ksxnku lEHko ugh gS
A
OAc

Integer (Double digit) (4)


55.

[Au(CN)x] is a very stable complex (though EAN = 82) under certain conditions and Kf of [Au(CN)x] is 4
1028. z 10y M concentration of cyanide ion is required to maintain the equilibrium at which 99 mole % of
the gold is in the form of cyanide complex. Then determine (y + z). Atomic number of Au = 79. z is a
natural number & 1 z 9.
(CEQ-HOEL, COR-BICC)_205

fuf'pr fLFkfr;ksad svUrxZr [Au(CN)x] ,d vR;f/kd LFkk;h lad qy gS(;|fi EAN = 82) rFkk [Au(CN)x] d k Kf 4

gSA lk;ukbM vk;u d h vko';d lkUnzrk z 10y M gS] t ksfd lkE;koLFkk cuk;sj[krsgq, 99 eksy % lksusd ks
lk;ukbM lad qy d s: i esacuk;sj[kusd sfy , vko';d gS
A rc (y + z) Kkr d hft ,A Au d k ijek.kq ekad = 79. z
,d iz
kd `r la[;k gSrFkk 1 z 9.
1028

Ans.

19

Page # 10

Au+ + 2CN

Sol.

[Au(CN)2]

99 mol% [Au(CN)2]
[Au(CN2 )]

It means

[Au ] [Au(CN2 )]

bld k vFkZgS

99
100

[Au(CN2 )]

[Au ] [Au(CN2 )]

99
100

100[Au(CN)2] = 99[Au+] + 99[Au(CN)2]


[Au+] =

K =

[Au(CN2 )]
(I)
99

[Au(CN2 )]
[Au ] [CN ]2

Putting the [Au+] from (I) in K


K es
a(I) ls[Au+] d k eku

99

4 1028 =

56.

j[kusij

[CN ]2

[CN] = 5 1014 M

A sparingly soluble salt MX is dissolved in water to prepare 1 L saturated solution. Now 106 mole NaX
(assume 100% dissociation) is added into this. Conductivity of this solution is 29 106 S/m. If Ksp of MX is
a 10b, then find value of (a + b). a is a natural number & 1 a 9.

(ECH-EC)_206

Given : 0 4 10 3 S m2 mol
x

Na

5 10 3 S m2 mol

0 6 10 3 S m2 mol
M

(Made by AKK SIR ON Jan.2014)

,d vYi foy s;h yo.k MX d kst y esa?kksy d j 1 y hVj lar`Ir foy ;u cuk;k t krk gS
A vc blesa106 eksy NaX
(100%

fo?kVu ekusa) fey k;k t krk gSA bl foy ;u d h fof'k"V pky d rk 29 106 S/m gS
A ;fn MX d k Ksp a 10b

gS] rks(a + b) d k eku Kkr d hft ,A a ,d izkd `r la[;k gSrFkk 1 a 9.


fn;k x;k gS%

0 4 10 3 S m2 mol
x

Na

5 10 3 S m2 mol

0 6 10 3 S m2 mol
M

Ans.

18

Sol.

MX

(Made by AKK SIR ON Jan.2014)

M + + X
6
x
x + 10

[Na+] = 106 M
KSol = K

+ K

+K

Na

Page # 11

29 106 = 103[6 103x + (4 103 (x + 106) + (5 103 106)]


x = 2 106
Ksp = 2 106 3 106 = 6 1012
57.

Two moles of an ideal gas is changed from their initial state (16 atm, 6L) to final state (4 atm, 15L) in such
a way that this change can be represented by a straight line in PV curve. Let 'y' L atm be the maximum
average translational kinetic energy possessed by the gas sample during the above change. Report your
answer as y/2. (Take R =

1
L atm K1 mol1)
12

(GST-KTG)_207

,d vkn'kZxSl d snkseksy d ksizkjfEHkd voLFkk (16 atm, 6L) lsvfUre voLFkk (4 atm, 15L) rd bl izd kj ifjofrZr
fd ;k t krk gS] fd PV o esabl ifjorZu d ks,d lh/kh js[kk }kjk iznf'kZr fd ;k t k ld rk gS
A ekusafd mijksDr
ifjorZu d snkSjku xSl izkn'kZ}kjk izkIr vf/kd re vkSl r LFkkukUrj.k xfrt t kZ'y' L atm gSA viuk mkj y/2 d s: i
esanhft ,A
(y hft ,

%R =

1
L atm K1 mol1)
12

Ans.

81

Sol.

Equation of straight line (lh/kh js


[kk d k lehd j.k esa) :

y y1
(y y1) = 2
(x x1)
x 2 x1
4 16
(P 16) =
(V 6)
15 6

3P + 4V = 72
Tmax =

(PV)max
nR

For (PV)max ((PV)max d sfy ,), 3P =

72
72
and (rFkk) 4V =
2
2

P = 12, V = 9
Tmax =
KEmax =

58.

12 9
= 648K.
2 (1/ 12)

3
3
1
nRTmax = 2
648 = 162 L atm.
2
2
12

[H+] concentration in 0.01 M H2O2 solution ( K a1 = 3 1012 and K a2 0) is x M. Fill first two digits of 108 x

(IEQ-PPAB)_205

as answer.
0.01 M H2O2 ( K a1 = 3

1012

rFkk K a2 0) foy ;u esa

[H+]

lkanzrk x M gSA

108

x d sigy snksva
d ksad ksmkj d s: i

esaHkfj,A
Ans.

20

Sol.

[H+] =

K a C0 K w 3 10 12 102 10 14

= 2 107 M = x

108 x = 20

Page # 12

Integer (Double digit) (2)


59.

How many cyclic structural isomer of C6H10 possible which after ozonolysis give diketones that show Intra
molecular Aldol condensation. (Only between ketone).

d sfd ruspf ; lap ukRed leko;oh lEHko gSt ksvkst ksuh vi?kVu d si'pkr~d soy MkbZd hVksu nsrk gSt ks
vUr%vkf.od ,YMksy la?kuu iz
nf'kZr d jrk gSA d soy fd Vksu d se/;
C6H10
Ans.

03
OH
O
Intra molecule aldol vUr%vkf.od
O

O3

ZnH O

Sol.

O3

ZnH O
2

O3

ZnH O
2

60.

,YMksy

How many reactions will proceed through free radical addition mechanism.

fuEu esalsfd ruh vfHkf ;k eq


Dr ewy d ;kSxkRed f ;kfof/k d sek/;e lslEiUu gksrh gS
A

(i)

NBS

(ii)

HCl

(PS Mam) (RM-MX) (M) (206) (Integer)

R 2O 2

HBr
h

(iii) CH3C=CHCH3

CH3
HI
(iv) CH3CCCH2CH3

R 2O2

HBr
(v) CH3CH=CH2

R 2O2

CH=CHCH3

(vi)
Ans.

02

Sol.

Only (iii) & (v)

Sol.

d soy (iii) o (v)

NBS

Page # 13

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