MATHEMATICS
TEST PATTERN
AIOT (JEE ADVANCE) - 2
TEST DATE : 03-05-2015
BATCH :
Subject
1 to 8
Nature of Questions
Total
MCQ
24
18
18
MCQ
24
18
35 to 40
18
41 to 48
MCQ
24
18
55 to 60
18
9 to 14
Maths
15 to 20
21 to 28
29 to 34
Physics
Total
60
180
MCQ 8
1.
[FN-IN] [307]
x 2 |x|
|x|
, f(x)
1
2
d k ifjl j [b, ), g(x) = (4cos4x 2cos2x cos4 x x7)1/7 , g(x) d k izkUr v kSj ifjl j] okLrfod
l a[ ;kv ksad k l eqPp ; gSfuEu esal sd kSu l k l gh gS?
(A*) a = 2
2
(C*) f(gog(b)) =e
(B*) b + a = 1
(D) f(x), g(x) nks
u ksaizfry kse
Q y u ughagSA
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P2JPT2(ADV.)170515C0-1
a = ( 3) + ( 4) + (5 2)=2
f(2) = f(2)
f(x) cgq
,Sd h gSA
MATHEMATICS
MATHEMATICS
Sol.
non invertible
iz
fry kse h; ughagSA
b = 1
a + b = 1
1
2
7 1/7
g(x) =((1 + cos 2x) 2cosx
(2cos 2x1)x )
2
1
2
2
7 1/7
=(1 + 2cos 2x+cos 2x 2cos2xcos 2x +
x )
2
f(x) [1, )
g(x) = x 7
2
1/ 7
1/ 7
1/ 7
2.
Sol.
3 3
= x 7
2
2
7 1/7
= (x )
= x
f(gog(b)) = f(b)
1+1
2
= e
= e
r 1 + r 2 = 3R
= 3.
4
sa sb
2 (c )
3
abc
(s a)(s b) 4
4s(s c) = 3ab
4(a b c ) (a b c )
= 3ab
2
2
a + b c = ab
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P2JPT2(ADV.)170515C0-2
MATHEMATICS
r2 + r3 = 2R
angles are d ks
.k 60, 90, 30
smallest l cl sN ks
V k 10n = 103
3
2
cubic ?kuh; x 6x + 11x 30 = 0
= 5, (+ i)( i) = 6
2
+ = 6
3.
4.
n=3
2
(x 5) (x x + 6) = 0
x 2 y 1
z 1
=
=
intersects the curve x2 y2 = a2, z = 0 if a is equal to
2
1
3
x 2 y 1
z 1
=
=
o x2 y2 = a2, z = 0 d ksizfrPN sn d jrh gS] ;fn a cjkcj
2
1
3
The line
js[ kk
Sol.
MATHEMATICS
1
cos c =
2
cos A = 0
(A*) 4
(B) 5
(C*) 4
(D)
For the point where the line intersects the curve, we have z = 0, so
fcUnqd sfy ,] js[ kk o d sfy , izfrPN sn d jrh gSA z = 0, bl fy ,
x 2 y 1 0 1
=
=
x = 5 and v kS
j y=3
2
1
3
Put these values in x2 y2 = a2, we get a2 = 16 a = 4
x2 y2 = a2 es
abu ekuksad ksj[kusij, a2 = 16 a = 4
gS&
5
Revi. PT-3-29-4-2015
[TD-MS] [303]
x 3
n
Consider the graph of the function f(x) = e x 1 then which of the following is correct
(A) Range of the function is (1, )
[FN-DN] [302]
(B*) f(x) has no zeroes
(C*) Graph lies completely above the x-axis
(D*) Domain of f is ( , 3) (1, )
x 3
n
x3
> 0 x < 3 or
x 1
or ;k x 3
x 1
(0, 1) (1, )
y =
5.
If
a .a
i
i 0 j 0
;fn
a .a
i
i 0 j 0
(A) 1
Sol.
;k x > 1
a 2
(a 1) 2 (a 1)
x
x 1
a 2
(a 1) 2 (a 1)
(B) 2
(C*) 3
(D*) 4
S =
i 0 j 0
1 1
a2
1
.......
a i .a j a a 2
(a 1)2
[SS-GP] [303]
ij
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P2JPT2(ADV.)170515C0-3
MATHEMATICS
6.
(a 1)2 (a 1)
>2
,d gokbZ t gkt cukus d h d Eiuh] d qN bat u cukrh gS] m l d s fd l h nh xbZ m Mku d s [kjkc
gksu s d h izkf;d rk p gSA bl izd kj d s bat uksa l s nks gokbZ t gkt cuk, t krs gSA ,d gokbZ
t gkt esa bl izd kj d s 3 bat u gS v kSj nwl js gokbZ t gkt esa 5 bat u gSA ,d gokbZ t gkt d h
nq?kZV uk gksr h gSA ;fn y xk, x, v k/ks l s T;knk bat u [kjkc gksr s gSA nks gokbZ t gkt d h
nq?kZV uk ?kfVr gksu sd h izkf;d rk l eku gS] rc p d k eku gksl d rk gS&
Sol.
(A*) 0
(B*) 1
(C*) 1/2
The two engines have the same probability of failing if
C 3 p (1 p) + C 4 p (1p) + p = C 2 p (1p) + p
3
2
4
5
2
3
10p (1p) 5 + p (1 p) + p = 3p (1 p) + p
3
2
2p 5p + 4p 1 = 0
p = 0 or ;k p = or ;k p = 1
7.
(D) 3/5
sin[x]
, x0
a
x
b sin x x , x 0
x3
sin[x]
, x0
a
x
b sin x x , x 0
x3
(A*) a 2 1
(B*) a + 1
lim f(x) = lim a = a = 2
x 0
8.
Sol.
(D) a 2
x 0
Since p a
wfd
(C) a + 2
sin x x
x3
3
5
7
x x x x .... x
3 ! 5! 7 !
1
x2
x4
=
=
+
+ .....
3
3!
5!
7!
x
sin x x
lim f(x) = lim b +
=b1
x 0
x 0
x3
b = 3 = a2 1 = a + 1
(B*) 2
(C*) 1
(D) 2
Revi. PT-3-29-4-2015
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P2JPT2(ADV.)170515C0-4
MATHEMATICS
S =
MATHEMATICS
length of chord
t hok d h y EckbZ= |x 1 x 2 | 1 m2
4a2 4a
=
i.e.
i.e.
i.e.
MATHEMATICS
x 1 + x 2 = 2a
x1 x2 = a
1 4 =
40
;k
+ a 2 = 0
;k (a + 2) (a 1) = 0
;k a = 2, 1.
a2
x2
a
y2
b2
respectively.
[EL-EA] [301]
9.
Sol.
x2
a2
y2
b2
= 1 ij
=1
a2 b 2
ekuk nh?kZo`k
x2
a2
y2
b2
=1
] A(a cos, bsin), B(a cos, bsin) and C(a cos, bsin) fcUnqv ksa l s
cos sin 1
1 2
=
a cos sin 1
2
cos sin 1
10.
b
Area of PQR d k {ks
=kQ y .
a
The eccentric angles of the vertices of triangle of maximum area inscribed in an ellipse differ by
nh?kZo`k d sv UrxZr v f/kd re {ks=kQ y d sf=kHkqt d s'kh"kZd sm Rd sUnzd ks.kksad k v Urj gS&
3
QOR = 120
(A)
Sol.
(B)
(C*)
2
3
(D)
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P2JPT2(ADV.)170515C0-5
MATHEMATICS
MATHEMATICS
2
=
3
2
2
, =
3
3
Similarlybl h iz
d kj =
3
2
d s'kh"kks
Zd k m Rd sUnzd ks.kksad k v Urj
3
eccentric angle of vertices of Differ by
gSA
and let cn =
a k , dn =
k 1
. Suppose that the points An(an, cn), Bn(bn, dn) are all lying on the
k 1
v kSj ekuk cn =
a1 < b1
k 1
C: y = px + qx + r
11.
12.
Sol.
[SS-MS] [303]
a k , dn =
k 1
(B)
1
3
(C)
1
2
(D) 2
2d
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P2JPT2(ADV.)170515C0-6
MATHEMATICS
4p = 1
18.
1
2
( c1 = a1)
a1 = 0 or ;ka1 = 2
1 2
b1 + qb1
4
AlsorFkk d1 =
MATHEMATICS
1
p=
ans.
4
q and d1 b1
2
1 2 1
b1 +
b1
4
2
2
b1 2b1 = 0
b1 = 0 or ;kb1 = 2
a1 = 0 and v kS
j b1 = 2 ans.
[AR-MS] [307]
13.
The value of
( x )dx is
( x )dx
d k eku gS&
(A) 3
14.
(B)
(C*) 3
(D) 1
93
(C) 3 f 3
sq. units
8
(A*)
(B)
3 and x-axis is
f( 3 )
8 3 f 3
8
sq. units
f( 3 )
8 3 f 3
8
4f( 3 )
f( 3 )
8 3 f 3
8
oxZbd kbZ
93
(C) 3 f 3
(D) bues
al sd ksbZugha
oxZbd kbZ
8
6
f(x)[f(x) + 1] = x
6
f(0)[(f(0)) + 1] = 0
f(0) = 0
6
1
and v kS
j 7 (f(x)) .f(x) = 1 f (x)
6
f(x)[7(f(x)) + 1] = 1
f(x) > 0 x R
Hence f(x) is increasing function x R
v r% f(x) , x R ,d o/kZe ku Q y u gSA
1
so there exists an inverse of f(x) such that f (0) = 0
bl fy , f(x) d k izfry kse fo| eku gSt cfd f1(0) = 0
7
1
x + x = f (x)
Sol.
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P2JPT2(ADV.)170515C0-7
MATHEMATICS
x dx
x8 x2
8
2
=2+1=3
0
f (a )
Hence v r%
f( 3 )
1
f ( x)dx f
0
3f( 3)
f ( x)dx
0
( x )dx = af(a)
( x )dx 3 f ( 3 )
f( 3)
f(x)dx
3
MATHEMATICS
(x 7 x)dx
f( 3 )
8 3 f 3
8
4f ( 3 )
INTEGER TYPE - 6
15.
A game is played with special fair cubic die which has one red side, two blue sides, and three
green sides. The result is the colour of the top side after the dice is been rolled. If the die is rolled
repeatedly. The probability that second blue result occurs on or before the tenth roll can be
3p 2q
expressed in the form of
where p,q,r are positive integers then find the value of p + r q.
3r
3p 2q
3r
[PR-BT] [303]
[JPT-2_Adv. 2015]
07
nd
th
Now 2 blue result occur on or before the 10 roll is equivalent to the occurrence of blue face
atleast twice is 10 rolls
10oha ckj ;k m l l s igy s ikl k Q s
ad us ij nwl jh ckj uhy k ifj.kke v kus d h izkf;d rk] 10 ckj
29.4
211 39 211
1 9 1 9
3
3
39
p = 9 , q = 11, r = 9
p + r q = 9 + 9 11 = 7
n = 10, p =
16.
Let y be an element of the set A = {1, 2, 3, 5, 6, 10, 15, 30} and x1 x2 x3 = y, then the number of
positive integral solution of x1x2x3 = y is m. Find m.
[PC-MT] [304]
[JPT-2_Adv.
2015]
ekuk l eqPp ; A = {1, 2, 3, 5, 6, 10, 15, 30} d k v o;o y gSv kSj x1 x2 x3 = y, rc x1x2x3 = y d sgy ksa
64
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P2JPT2(ADV.)170515C0-8
The number of solutions of the given equation is the same as the number of solution of the
equation x1x2x3 x4 = 30 = 2 3 5 (here x4 is dummy variable)
If area of triangle formed by the points (2, ),(+ , 2+ ) and (2, 2) is 8 square unit then
area of triangle whose vertex are ( + , ), (3 , + 3) and (3 , 3 ) is
;fn (2, ),(+ , 2+ ) v kSj (2, 2) l s cus f=kHkqt d k {ks=kQ y 8 oxZ bd kbZ gS rFkk
( + , ), (3 , + 3) v kS
j (3 , 3 ) l s cus f=kHkqt d k {ks=kQ y gS& [JA_CT-2_2109-2014]
[JPT-2_Adv. 2015]
[SL- AR] [301]
Ans.32
R(2a ,b)
Sol.
C(3a b,3ba )
P(2b ,2a )
Q(a +b ,2b +a )
D(3ba ,b+3a )
Ans.
Sol.
If A1, A2, A3, A4 be the area of a triangular faces of a tetrahedron and h1, h2, h3, h4 be the
corresponding altitude of the tetrahedron. If volume of tetrahedron is 5 cubic units then find the
(A1 A 2 A 3 A 4 )(h1 h2 h3 h4 )
minimum value of
[SS-IG] [304]
[JPT-2_Adv.
24
2015]
;fn A1, A2, A3, A4 l s cus p rq"Q y d d s f=kHkqt kd kj l rgksa d k {ks=kQ y gS rFkk h1, h2, h3, h4
p rq"Q y d d s l ax r 'kh"kZ y Ec gSA ;fn p rq"Q y d d k v k;ru 5 ?ku bd kbZ gS rc
(A1 A 2 A 3 A 4 )(h1 h2 h3 h4 )
d k U;wu re eku gS&
24
10
1
3V
V = h1A1
h1 =
3
A1
h2 =
3V
A2
h3 =
3V
A3
h4 =
3V
A4
3V 3V 3V 3V
(A1 + A2 + A3 + A4)
A1 A 2 A3 A 4
1
3V(A1 + A2 + A3 + A4)
A1
A1 A 2 A 3 A 4
1
1
4
A1 A 2
1
1
1
A 2 A3 A 4
4
1
1
A3 A 4
1
1
1
1
(A1 + A2 + A3 + A4)
16
A1 A 2 A 3 A 4
Min value U;w
u re eku : 3V(16) = 48 V = 240
(A1 A 2 A 3 A 4 )(h1 h2 h3 h4 )
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P2JPT2(ADV.)170515C0-9
MATHEMATICS
MATHEMATICS
Sol.
MATHEMATICS
3
If roots of the cubic equation (z ab) = a , a 0 represents the vertex of a triangle, then the
length of one of the sides of the triangle will be , when a = 3
[JPT-2_Adv. 2015]
3
3
;fn ?kuh; l ehd j.k (z ab) = a , a 0 d s ewy f=kHkqt d s 'kh"kZ gS] rc f=kHkqt d h Hkqt kv ksa d s
,d d h y EckbZgksx h] t c a = 3
Ans.
Sol.
[CN-CR] [302]
03
3
3
(z ab) = a
1/3
2
z ab = a(1) , z ab = a, a, a
2
z1 = ab + a, z2 = ab + a, z3 = ab + a
|z1 z2| = |a a| = |a||1| = 3 | a |
= 3. 3 =3
(2x 3 1)dx
1 x 6 2x 3 9x 2 1 can be expressed in the form of
20.
A
C
cot 1 where A,B,C,D are rationals in their lowest form then the value of 2(A + B + C + D) is
B
D
equal to
[DI-II] [301]
x
1
Ans.
Sol.
A,B,C,D m ud sl jy re
18
1
dx
2x
2
x
=
1
1 x 4 2x 9
x2
t
2
dt
9
(2x 3 1)dx
2x 3 9x 2 1
d s eku d ks
A
C
cot 1 d s : i
B
D
put x +
1
= t j[kusij
x
1
1 2
cot
3
3
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P2JPT2(ADV.)170515C0-10
MATHEMATICS
19.
PHYSICS
1 to 8
Total
MCQ
24
18
15 to 20
18
21 to 28
MCQ
24
18
9 to 14
29 to 34
Maths
35 to 40
18
41 to 48
MCQ
24
18
55 to 60
18
60
Total
180
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P2JPJFJRAIOT220215C0-1
PHYSICS
A light wire of length and radius r is welded to another light wire of length 2 are radius 2r. The
st
nd
free end of 1 wire is fixed and the free end of 2 wire supports a mass m. The young's modulus
of each wire is Y.
[EC-GE](104)
y EckbZrFkk r f=kT;k d k rkj, 2 y EckbZrFkk 2r f=kT;k d svU; rkj d slkFk t q
M +k gqv k gS
A igy srkj d k eqDr
fljk t M+or~gSrFkk nwl jsrkj d seqDr fljslsfp=kkuql kj m nzO;eku y Vd k gqv k gSA iz
R;sd rkj d k ;ax xq.kkad
Y gS
A
2
m
mg
2r 2 Y
mg
(B*) Extension in lower wire is
2r 2 Y
mg
fupy srkj esaizl kj
gSA
2r 2 Y
mg
2r 2 Y
gSaA
5 mg
2 r 2 Y
5 mg
2 r 2 Y
gSaA
3 mg
2 r 2 Y
3 mg
gSA
2 r 2 Y
Here stretching force is same but stress will be different for wires.
;gkruu cy leku gS
]ijUrqnksuks
arkjks
aes
aiz
frcy fHkUu&fHkUu gS
A
For upper wire ijh rkj d sfy,
Stress iz
frcy = Y strain fo fr
Mg
= Y
r
mg
1 =
r 2 Y
for lower wire fupysrkj d sfy,
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P2JPJFJRAIOT220215C0-2
PHYSICS
PAPER-2
PHYSICS
total elongation d q
y
foLrkj =
3 mg
2 r 2 Y
22*.
A particle of mass 'm' is suspended with the help of an ideal string from the ceiling of a car as
shown in figure. Initially the whole system is at rest. At time t = 0 the car starts accelerating
towards right with uniform acceleration 'a' such that a << g. Then choose the correct statement(s).
[CM-VT](104)
,d vkn'kZjLlh d h lgk;rk ls'm' nzO;eku d k d .k fp=kkuql kj d kj d h Nr lsy Vd k gqv k gSA izkjEHk esa
lEiw.kZfud k; fLFkj gSA t = 0 ij d kj nka;h vksj le: i Roj.k a lsRofjr gksrh gS,oaa << g gSA rkslgh
d Fku@d Fkuksad k p;u d hft ,A
(A*) The particle will execute simple harmonic motion with respect to car.
nd
(B*) The particle will be at equilibrium position w.r.t. car for the 2 time at instant
3
t=
2
2
a g2
d kj d slkis{k d .k t =
3
2
a g2
(C) The maximum speed of the particle with respect to ground during subsequent motion will be
1 a
(g2 a2 )1/ 2 tan
g
a
A
gS
g
(D*) The speed of the particle with respect to ground at the instant the string becomes vertical
t c jLlh nqckjk izFke ckj /okZ/kj fLFkfr esavkrh gSrc d .k d h t ehu d slkis{k pky aT gSa;gkT = 2
a2 g2
Sol.
gSA
1 a
The particle will execute S.H.M with angular amplitude tan with respect to car and of time
g
period T = 2
a g2
a g2
3
T
4
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P2JPJFJRAIOT220215C0-3
PHYSICS
mg
2
mg
2=
2
Y
(2r)
2 r 2 Y
PHYSICS
g2 a2
g2 a2
. tan
a
.
g
a
A
gS
g
The particle will come to rest at with respect to car at the instant string becomes vertical & its
d kj d slkis
{k d .k d h vf/kd re pky A =
. tan
d kj d slkis{k d .k fojkekoLFkk es
arc vkrk gSt c jLlh /okZ
/kj gks
rh gSrFkk bld h pky bl le; d kj d h pky d s
cjkcj gks
rh gSvFkkZr~
, aT d scjkcj gks
rh gS;gkT = 2
23.
a g2
gS
A
The figure here shows a water tank provided with a square gate (of side 2m) which can rotated
freely about z axis passing through shown point A. The gate is held in its place due to buoyant
force acting on the light balloon attached to the gate via a light thread. Considering the information
that the gate just opens when level of water reaches the height of 4m above point A and hinge
force is zero, the shown point P is point at which the thread is attached to the gate
[FL-BY](103)
iznf'kZr fp=k esaoxkZd kj njokt s(Hkqt k 2m) ;qDr ,d ikuh d k VSad iznf'kZr gSA njokt k fp=k esaiznf'kZr fcUnqA
lsxqt jusoky h z-v{k d sifjr% eqDr : i ls?kw.kZu d j ld rk gSA njokt sd ksbllst qM +h gq
bZgYd h jLlh }kjk
ca/ksgq, gYd sxqCckjsij vkjksfir mRiy kod cy }kjk nh xbZfLFkfr esafLFkj j[kk t krk gSA ;g ekuk t krk gS]
t c ikuh d k Lrj fcUnqA ls ij 4m vkrk gS] rc njokt k Bhd [kqy t krk gSA fuy Ecu }kjk vkjks
fir cy
'kwU; gSA fp=kkuql kj fcUnqP ij jLlh njokt s}kjk cU/kh gq
bZgS
A
a = 4m
A
Gate
njokt k
Light
balloon
(gYd k
xqCckjk)
y
b = 2m
Water
(ikuh)
x
z
[kqy rsle;,
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PHYSICS
;g
3
nw
l jh ckj lkE;koLFkk ij le; t = T ij igq
prk gS
A
4
PHYSICS
Ffluid Fbuoyant
PHYSICS
PMID Area = Vg
b
2
g a b = Vg
2
3
V = a b 2 = 20m
2
gh bdh(h a) = Vgx
a b
h(h a)dh
x=
24.
1.06 m
A solid sphere of mass m is released on the plank of mass M which lies on an inclined plane of
inclination as shown in figure. There is sufficient frictional force between sphere and plank and
the minimum value of co-efficient of friction between plank and surfaces is to keep the plank at
rest. Then
[RB-CD](104)
m nz
O;eku d k Bksl xksy k M nzO;eku d sr[rsij NksM +k t krk gSA r[rk d ks.k oky surry ij fp=kkuql kj j[kk
gqv k gSA xksy rFkk r[rsd se/; mifLFkr ?k"kZ.k cy i;kZIr gS,oar[rso urry d se/; mifLFkr ?k"kZ.k xq.kkad
d k U;wure eku gS, t ksfd r[rsd sfLFkj j[kusd sfy, i;kZ
Ir gS] rks
m
M
2
mg sin gS
, tc
7
2
mg sin , when plank is at rest
7
7M 2m
tan
7(M m)
7M 2m
tan gS
A
7(M m)
(C) If there is no friction between the plank and inclined plane, then acceleration of plank is less than g
sin .
;fn r[rsrFkk urry d se/; d ksbZ?k"kZ.k cy vkjks
fir ughagksrksr[rsd k Roj.k g sin lsd e gSA
(D*) If there is no friction between plank and inclined plane, then friction force on the sphere is
zero.
Sol.
d k eku
gsin
5gsin
7
1
mR 2
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PHYSICS
2
mgsin
7
M
PHYSICS
2
mg sin f = ma f = mgsin
7
(M + m)g cos
Mg sin
2
mgsin = (M + m)g cos
7
7M 2m
=
tan
7(M m)
Mgsin +
25.
Consider an infinite mesh as shown in figure Each side of the mesh has resistance R. Consider
hexagonal part ABCDEF of infinite mesh and equivalent resistance between any two points of
hexagon is measured. Choose the correct option(s) : [CE-EQ](104)
fp=k esa,d vuUr vkd kj d k t ky iznf'kZr gSA izR;sd t ky d h izR;sd Hkqt k d k izfrjks/k R gSA vuUr t ky d s
,d "kV~d ks.kh; Hkkx ABCDEF d h d Yiuk d hft , rFkk bl Hkkx d sfd Ugh nksfcUnqv ksad se/; rqY; izfrjks/k ekik
A
B
F
C
E
2R
3
2R
gSA
3
(B*) equivalent resistance between A and C is R
A rFkk C d se/; rq
Y; izfrjks/k R gSA
7R
(C*) equivalent resistance between A and D is
6
7R
A rFkk D d se/; rq
Y; izfrjks/k
gSA
6
(D*) equivalent resistance between A and E is R
A rFkk E d se/; rq
Y; izfrjks/k R gSA
A rFkk B d se/;
Sol.
rqY; izfrjks/k
If we connect positive terminal of a battery to A and negative to infinity then the current through
branches will be as shown. If we connect negative to B and positive to infinity current will be in
2
opposite direction by supper -position of two situation net current in AB branch will be
.
3
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iz
d kj vU; fljksd sfy, Hkh Kkr d j ld rsgS
A
/3
/6
26.
/3 A /3
/6
/6
/6
D
A
C
B
G
H
E
F
An infinite large sheet of surface charge density passes through PQGF. P and Q are mid points
of AB and DC respectively. Out of six faces of cube the electric flux linked :
i`
"Bh; vkos'k ?kuRo d h ,d vUur vkd kj d h ifV~Vd k PQGF lsxqt jrh gSA P rFkk Q e'k% AB rFkk DC
d se/; fcUnqgSA bld sN% Q yd ksalslEcfU/kr y Dl esals:
(A*) is zero with three faces
gSA
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PHYSICS
PHYSICS
2
Potential difference between A and B will be
R . Effective resistance between A and B will be
3
2R
. Similarly we can do for other terminals.
3
;fn cS
Vjh d s/kukRed fljsd ksA lsrFkk _ .kkRed fljsd ksvuUr lst ks
M+nsrksbl ifjiFk d h 'kk[kkvks
aes
a/kkjk
fp=kkuql kj iz
okfgr gks
xhA ;fn cSVjh d s_ .kkRed fljsd ksB lsrFkk /kukRed fljsd ksvuUr lst ks
M+nsrks/kkjk
2
foifjr fn'kk es
aiz
kokfgr gks
xh] rFkk bu nksuks
afLFkfr;ks
aes
aiz
okfgr /kkjk d sv/;kjks
i.k }kjk 'kk[kk AB es
ad qy /kkjk
3
2
2R
iz
okfgr gksxhA A rFkkB d se/; foHkokUrj R gks
xkA blfy, A rFkkB d se/; rq
Y; iz
frjks/k
gks
xk] vkS
j blh
3
3
PHYSICS
PHYSICS
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Figure shows top view of a horizontal surface. Two blocks each of mass m are placed on the
surface and connected with a string. The friction coefficient is for each block. A horizontal force F
is applied on one of the block as shown in the figure. F is maximum so that there is no sliding at
any contact.
[FR-SG](104)
,d {kS
frt lrg d k ijh n`'; fp=k esaiznf'kZr gSA leku nzO;eku m d snksCy kWd bl lrg ij fLFkr gSrFkk
vkil esa,d jLlh lscU/ksagq
, gSA iz
R;sd Cy kWd d sfy , ?k"kZ.k xq.kkad gSA fp=kkuql kj ,d Cy kW
d ij ,d
{kSfrt cy F vkjksfir fd ;k t krk gS
A F vf/kd re gSft ld sd kj.k fd lh Hkh lEid Zij fQ ly u ughagSA
m
Top view
F
(A*) If
;fn = 30 F =
(B*) If ;fn = 45 F =
2mg
3
& T < mg
2mg & T = mg
3mg & T = mg
Sol.
f
F
T cos = f sin
but T mg
T cos = mg sin
F = T sin + f cos
sin
= mg
sin + mg cos
cos
cos( )
= mg
cos
For Fmax = < 45 Fmax = mg sec
Fmax d sfy ,] = < 45 Fmax = mg sec
But tension in the string can not be more than mg
jLlh esaruko mg lsT;knk ughagksld rk
mg sin
T=
< mg should be less than 45
cos
mg sin
T=
< mg ] 45 d e gks
uk pkfg,A
cos
Now if (vc ;fn) > 45 T = mg = 90
F = mg sin + mg cos = 2mg sin
If (;fn) < 45 then (rks
) Fmax = mg sec
If (;fn) > 45 then (rks
) Fmax = 2mg sin
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PHYSICS
PHYSICS
27.
Consider a hemisphere of radius R with centre of curvature at origin O, as shown. Refractive index
2R
of material of the hemisphere varies as =
. Where x is x-coordinate of material point. A
2R x
ray travelling in air in xy-plane is grazingly incident at O, as shown
R f=kT;k d s,d v) Z
xksy sd h d Yiuk d hft ,] ft ld k o rk d sUnzewy fcUnqO ij fp=kkuql kj gS
A v) Zxksy sd s
2R
inkFkZd k viorZukad =
d svuql kj ifjofrZr gksrk gSA t gkx inkFkZd sfcUnqd k x-funsZ'kkad gSA ,d
2R x
fd j.k ok;qesaxfr d jrh gqbZ] fp=kkuql kj xy-ry esafcUnqO ij i`"BLi'khZvkifrr gksrh gSA [GO-RP](105)
y
O
90
The figure shows a strip at a distance x of thickness dx. As of material increases with x, ray will
deviate continuously as shown. By snell's law, between O and A,
fp=k esax nwjh ij dx eksVkbZd h ifd k iznf'kZr gSA pqafd nwjh x d slkFk inkFkZd k viorZukad c<+rk gS] bl
d kj.k fd j.k fp=kkuql kj y xkrkj fopfy r gksrh gS
A O lsA rd Lusy d sfu;e }kjk
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PHYSICS
PHYSICS
28.
PHYSICS
dy
dx
2R x
2
dy
PHYSICS
2R
1 sin90 =
sin
2R x
2R x
tan =
2
(2R) (2R x)2
2R x
dx
2R 2 2R x 2
y=
2
y + (x-2R) = (2R)
which is equation of circle of radius 2R centered at (2R, 0)
t ksfd ,d 2R f=kT;k d so`k d h lehd j.k gSft ld k d sUnz(2R, 0) ij
also, equation of hemispherical surface is
gSA
x + y = (R)
2
2
2
y =R x
2
Putting this value of y in equation of trajectory we can find coordinates of point where the ray
comes out of hemisphere, as
bl y2 d seku d ksiFk lehd j.k esaj[kusij mu fcUnqv ksad sfunsZ'kkad d j ld rsgSt gkij fd j.k v) Zxksy sls
ckgj vkrh gS
2
R + x + (x 2R) = 4R
R
x=
4
y=
15R
R
R2 x 2 R2
0.97R
4
4
2R
y
Clearly Li"V
: i ls, sin =
y
15
16 1
or
2R
8
8
2
0 < < 30
P2JPJFJRAIOT220215C0-11
Comp.
The rectangular box shown in the figure has a partition which can slide without friction along the
length of the box. Initially each of the two chambers of the box has one mole of a monatomic ideal
gas at a pressure P0, volume V0 and temperature T0. The chamber on the left is slowly heated by
an electric heater. The walls of box and partition are thermally insulated. Heat loss through lead
wire of heater is negligible. The gas in left chamber expands, pushing the partition until final
243
pressure in both chambers becomes
P0. (Take R = 8.3 J/mol K)
[TH-FL](104)
32
fp=k esaiznf'kZr ?kukd kj fMCcsesafLFkr fiLVu fcuk ?k"kZ.k d sfMCcsd h y EckbZd svuqfn'k fQ ly ld rk gSA
izkjEHk esafMCcsd snksuksaHkkxksaesa,d eksy ,d ijek.kq
d vkn'kZxSl ] nkc P0, vk;ru V0 rFkk rkieku T0 ij Hkjh
gqbZgSA cka;soky sHkkx esafLFkr xSl d ksfo|qr ghVj }kjk /khjs& /khjsxeZfd ;k t krk gSA fMCcsd h nhokjsrFkk
fiLVu "eh; d qp ky d gSrFkk ghVj d srkj }kjk "eh; gkfu ux.; gSA cka;soky sHkkx esafLFkr xSl Q Sy rh gS
vkSj fiLVu d ksrc rd nckrh gSt c rd fd nksuksaHkkxksad k nkc
29.
243
P0 u
32
[TH-FL](104)
T0
Tright
(B) 4.5 T0
(D*) 12.93 T0
P 32
= 0
243P0
T0
2
=
Tright
3
Tright = 2.25 T0
For the left chamber, the process of heating is slow. Initial parameters are P0, V0, T0.
nka;sHkkx d sfy ,, iz e vuql kj /khsjs& /khjsxeZd jrsgSA izkjfEHkd izkap y P0, V0, T0 gSA
243
Final parameters are vfUre iz
kap y
P0 , V1, T1
32
P0 V0
243P0 V1
=
T0
32 T1
243 V1
T0
.(1)
32 V0
Adiabatic compression occurs in right chamber. Initial parameters are P0, V0, T0.
nka;sHkkx esa: ) ks"e lEihM+u gksxkA bld siz
kjfEHkd izkap y P0, V0, T0 gSA
T1 =
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PHYSICS
PHYSICS
bl [k.M esafl) karksa] ;ksxksavkSj vkd M+ksavkfn d ksn'kkZusoky s3 v uqPN sn gSaA rhuksavuqPNsnksalslacaf/kr N %
'u gSa] ft uesalsgj vuqPNsn ij nks'u gSaA fd lh Hkh vuqPNsn esagj 'u d spkj fod Yi (A), (B), (C) vkSj
(D) gS
a] ft uesalsd soy ,d gh l gh gSA
PHYSICS
izkap y
243
P0, V2, T2 gS
A
32
PHYSICS
243
P0V0 = P0
V2
32
5/3
V2
32
=
243
V0
V2
8
=
V0
27
V1 + V2 = 2V0
8
V1 = 2V0
V0
27
46
V1 =
V0
.(2)
27
by equation lehd j.k(1) & o (2) ls
T1 = 12.93 T0
30.
[TH-FL](104)
(A) 5.58 T0 J
(B) 10.58 T0 J
(C) 25.58 T0 J
(D*) 15.58 T0 J
Work done by gas on right chamber. nka
;sHkkx
P2 V2 P0 V0
W=
1
3 9
=
1 P0V0
2 4
15
=
8.3 T0
8
= (15.58 T0) J
[YE-YE](104)
10
y (in mm)
Wave length of light used is 400 nm and distance between the two slits is 1 mm.
iz;qDr izd k'k d h rjaxnS/;Z400 nm rFkknksuksafLy Vksad se/; nwjh 1 mm. gSA
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PHYSICS
31.
If the distance between two slits is reduce to 0.5 mm then the intensity :
[YE-YE](104)
PHYSICS
;fn nksuksafLy Vksad se/; nwjh 0.5 mm rd d e gkst k;srks] izkIr rhozrk
(A) will become zero at y = 4 mm and y = 8 mm
y = 4 mm rFkk y = 8 mm ij
Sol.
32.
If the distance between the two slits is kept 1 mm and then a thin film of refractive index 1.5 and
thickness 2.2 m is used to cover the one of the slit. What will be intensity at y = 2 mm.
;fn nksuksafLy Vksad se/; nwjh 1 mm j[kh t k;srFkk fd lh ,d fLy V d slkeus1.5 viorZukad d h 2.2 m
Sol.
[YE-YE](104)
(A*) /2
(D) zero
(B)
Shift foLFkkiu =
t( 1)
2.2 10 6 0.5
4 10 7
11
vr% rhozrk
0
2
(C) /4
0
2
gkst k;sxhA
P2JPJFJRAIOT220215C0-14
Position (1)
Position (2)
Position (3)
Position (4)
20.0
30.0
32.5
33.5
20
16
9
11
fLFkfr (1)
fLFkfr (2)
fLFkfr (3)
fLFkfr (4)
L1
F1
Collimator
d ksy hehVj
Prism
L2
fiz
Te
Telescope
F2
nwjn'khZ
EYE
vk[k
33.
[GO-OI](104)
(A) 1222
(B) 1319
(C) 335
(D*) 1321
29 division of main scale coincides with 30 divisions of vernier scale Hence one division of vernier
scale
eq[; iSekusd s29 Hkkx ofuZ;j iSekusd s30 Hkkx d slEikrh gSA vr% ofuZ;j iSekusd k ,d Hkkx
30 29
of main scale
30
1
0.5
=
30
1
0.5 60 min
=
30
eq[; iSekuk
= 1 min.
Position fLFkfr (1) 20 20
Position fLFkfr (2) 30 16
Position fLFkfr (3) 32 39
Position fLFkfr (4) 33 41
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PHYSICS
PHYSICS
PHYSICS
34.
If we find angular derivation for different colours then percentage error in derivation will be
maximum for
[GO-OI](104)
(A*) Red
(B) Yellow
(C) Violet
(D) Same for all
100
is minimum for red is same for all, so percentage error will be maximum for Red.
y ky jax d sfy , U;wure gSlHkh d sfy, leku gS, vr% y ky jax d sfy , izfr'kr =kq
fV vf/kd re
Percentage error iz
fr'kr
=kqfV =
gksxhA
A particle starts from rest and moves on a circular path with an angular acceleration which is
proportional to square root of instantaneous angular velocity. Find the mean angular velocity (in
1
rad/sec) averaged over the time it takes to acquire an angular velocity of 12 rad sec
,d d .k fLFkj voLFkk lso`kkd kj iFk ij d ks.kh; Roj.k d slkFk xfr izkjEHk d jrk gS
A bld k d ks.kh; Roj.k
bld srkR{kf.kd d ks.kh; osx d soxZewy d slekuqikrh gSA 'kwU; ls12 rad sec1 d ks.kh; os
x izkIr d jusesay xs
le;kUrjky d snkSjku vkSl r : i lsbld k ek/; d ks.kh; osx (rad/sec esa) Kkr d jksA
[CM-KN](104)
Ans.
Sol.
4
= k
d
k
d
d k d
3/2
= K
3/2
23 / 2
3k
d
k
dt
k dt
1/2
= kt
2
t=
k
1
2 k
wavg = 4 rad/sec.
t 3
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PHYSICS
36.
A piece of metal weighs 46 g in air. When it is immersed in a liquid of specific gravity 1.24 at 37C it
weighs 30 g. When the temperature of the liquid is raised to 42C, the metal piece weighs 30.5 g.
The specific gravity of the liquid at 42C is 1.20. Coefficient of linear expansion of the metal is nearly
N
69 10 , find N.
[FL-BY](104)
/kkrqd s,d Vqd M+sd k gok esaHkkj 46 g gSA t c bld ks37C rkieku ij 1.24 fof'k"V xq
: Ro d snzo esaMqcks;k
t krk gS] rc bld k Hkkj 30 g gSA t c nzo d k rkieku 42C rd c<+k;k t krk gS] rks/kkrqd sVqd M+sd k Hkkj 30.5
g gkst krk gS
A 42C rkieku ij nzo d k fof'k"V xq: Ro 1.20 gSA ;fn /kkrqd k js[kh; izl kj xq.kkad y xHkx 69
N
10 , gksrksN d k eku Kkr d jks
A
Ans. 06
Sol. We have ge t kursgS
,
Upthrust mRiy kod cy , FB = Vg
Apparent weight vkHkklh Hkkj = mg 0Vg = 30g
When temperature is increased t c rkieku c<+
k;k t krk gS
FB = Vg
Apparent weight vkHkklh Hkkj = mg 0Vg = 30.5g
= mg 0V(1 + 3 )g = 30.5g
on solving gy d jusij
5
1
and rFkk
= 6.9 10 C
37.
(i)
(ii)
A conducting tube is passing through a bath. A liquid at temperature 90C and specific heat s is
entering at one end of tube. Rate of flow of liquid is 1 kg/s and exit temperature is 50C. In bath
another liquid having specific heat 2s and inlet temperature 20C is entering at a rate of 2 kg/s.
Find the exit temperature of the liquid coming out of the bath. (Assume steady state condition)
[CT-CL](104)
,d pkyd uy h LukuVc lsxqqt jrh gSA uy h d s,d fljsls90C ij s fof'k"V "ek d k nzo izokfgr fd ;k
t krk gSA bl nzo d h izokg nj 1 kg/s rFkk ckgj fud y rsle; rkieku 50C gSA LukuVc esaHkjsgq, vU; nzo
d h fof'k"V "ek 2s rFkk izos
'k d jrsle; rkieku 20C gSrFkk ;g 2 kg/s d h nj lsizos'k d jrk gSrks
LukuVc lsckgj fud y usoky snzo d k rkieku Kkr d jksA (LFkkbZvoLFkk ekursgq,)
90C
20C
50C
2s
[Ans 30C ]
38.
A conductor carrying current 60A is in the form of a semicircle AB of radius R and lying in xy-plane
2
2
with its centre toat origin as shown in the figure. The magnitude of B.d for the circle x + z =
2
[EM-AL](104)
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P2JPJFJRAIOT220215C0-17
PHYSICS
PHYSICS
O
Z
Ans.
Sol.
30
Bnet .d B1.d B 2 .d
R 3
0 = B1 2R 3 +
0=
B2 .d
2R 3 + B2 .d
4R 3
0 = 0 + B2 .d
2
0
= B2 .d
2
39.
The energy that can be obtained from 1 kg of water through the fusion reaction 2H + 2H 3H + p is
8
2
P 10 J. Assume that 1.5 10 % of natural water is heavy water D2O (by number of molecules )
and all the deuterium is used for fusion. Find the value of P.
Atomic masses are m( 12 H ) = 2.014102 u , m ( 13 H ) = 3.016049 u
[NP-FF](104)
Mass of proton mp = 1.007276 u
1u = 931
MeV
c2
"ek P 108J gksrksP d seku
H + 2H 3H + p
;g eku y hft ;sfd izk frd t y esa1.5 10 2 % Hkkjh ikuh D2O gS(v.kq
v ksad h la[;k d svk/kkj ij) vkSj
leLr M~;wfVfj;e lay ;u esaiz;qDr gkst krk gSA
ijek.kqHkkj m( 12 H ) = 2.014102 u , m ( 13 H ) = 3.016049 u
izksVksu d k nzO;eku mp = 1.007276 u
Ans :
Sol.
37
Energy released in one fusion ,d
1u = 931
MeV
c2
lay ;u esamRiUu t kZ
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P2JPJFJRAIOT220215C0-18
PHYSICS
PHYSICS
d sUnzfp=kkuql kj ewy fcUnqij gSA xz ry esao`k x2 + z2 = 3R2 d sfy , B.d d k ifjek.k y wi AB esaizokfgr
PHYSICS
1
ikuh d k nzO;eku
NA 1.5 10 4
v.kqHkkj
A capillary tube of radius 0.50 mm is dipped vertically in a pot of water. The difference between the
pressure of the water in the tube 5.0 cm below the surface and the atmospheric pressure is 10x
2
N/m . Surface tension of water = 0.075 N/m contact angle between glass and water is zero
2
degree. Find the value of x. (g = 9.8 m/s )
[SF-EX](103)
0.50 feeh f=kT;k d h d s
'kuy h d kst y
d sik=k esam/okZ/kj Mq
ck;k x;k gSA uy h esap<sgq, t y d h lrg ls5.0
lseh uhpsnkc ,oaok;qe.My h; nkc d k vUrj 10x N/m2 gksrksx d k eku Kkr d hft ;sA t y d k i`"B ruka
o=
2
0.075 N/m rFkk d kW
p o ikuh d se/; Li'kZd ks.k 'kwU; fMxzh gSA (g = 9.8 m/s )
Ans.
Sol.
19
A
2S
pgh
R
= P0 300 + 490
= P0 +190
PA = P0
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P2JPJFJRAIOT220215C0-19
PHYSICS
Q = [2m( H) m( H) m( H)]c
mass of water
Number of fusion =
NA 1.5 10 4
moleculer weight
Page # 1
PAPER-2
MCQ (6)
41.
A 5g sample containing Fe3O4 (FeO + Fe2O3) and an inert impurity is treated with excess of KI solution in
the presence of dilute H2SO4. The entire iron converted to Ferrous ion along with liberation of Iodine. The
resulting solution is diluted to 100 ml. 20 ml of the diluted solution requires 10 ml of 0.5M Na2S2O3 solution
to reduce the iodine present. Amongs the following select correct statements.
(A*) % of Fe2O3 in sample is 40%
(B) % of FeO in sample is 28%
(C*) % of inert impurity in sample is 42%
(D) % of inert impurity in sample is 32%
Fe3O4 (FeO + Fe2O3) rFkk ,d vf ; v'kq
f) ;qDr] ,d 5g izkn'kZd k ruqH2SO4 d h mifLFkfr esaKI foy ;u d svkf/kD;
d slkFk mipkfjr fd ;k t krk gSA lEiw.kZvk;ju] Q sjl vk;u esaifjofrZr gksrk gSrFkk lkFk gh vk;ksM hu eqDr gksrh gSA
ifj.kkeh foy ;u d ks100ml rd ruqfd ;k x;kA 20ml ruqfoy ;u esamifLFkr vk;ksM hu d ksvipf;r d jusd sfy,
0.5M Na2S2O3 d k10ml vko';d gks
rk gSA fuEu esalslgh d Fkuksad k p;u d hft ,A
(A*) iz
kn'kZesaFe2O3 d k 40% gSA
(B) iz
kn'kZesaFeO d k 28% gSA
(C*) iz
kn'kZesavf ; v'kqf) 42% gSA
(D) iz
kn'kZesavf ; v'kq
f) 32% gSA
Sol.
Sol.
40
Let the moles of Fe3O4 is x. So mole of Fe2O3 (in Fe3O4) = x
eq of Fe2O3 (in Fe3O4) = eq of K = eq of 2 = eq of Na2S2O3.
or
2x = 0.025
or
x = 0.0125 mol of Fe2O3
So mass of Fe2O3 = 0.0125 160 = 2g
2
% of Fe2O3 = 100 = 40%.
5
40
ekuk fd Fe3O4 d seksy x gSA vr% Fe2O3 d seksy (Fe3O4 esa) = x
Fe2O3 d srq
Y;kad (Fe3O4 esa) = K d srqY;kad = 2 d srqY;kad = Na2S2O3 d srqY;kad
vFkok 2x = 0.025
vFkok x = 0.0125 mol of Fe2O3
vr% Fe2O3 d seksy = 0.0125 160 = 2g
2
100 = 40%.
5
-bond results due to overlap of :
(A*) dxy and py along xaxis
(C*) dxy and px along yaxis
Fe2O3 d k iz
fr'kr =
42.
(CBO-VBT)_203
(B) dx2y2 and py along xaxis
(D) dx2y2 and py along yaxis
d sd kj.k
(C*) y-v{k d h vks
j dxy rFkk px d svfrO;kiu d sd kj.k
(D) y-v{k d h vks
j dx2y2 rFkk py d svfrO;kiu d sd kj.k
Sol. -bond are formed by parallel overlaping of same orbitals. So, correct options are :
(A) dxy and py along xaxis
(C) dxy and px along yaxis
gy
leku d {kd ksad slekukUrj ikf'oZd vfrO;kiu d sd kj.k - ca/k d k fuekZ.k gksrk gSA vr% lgh fod Yi gSa%
(A) x-v{k d h vks
j dxy rFkk py d svfrO;kiu d sd kj.k
(C) y-v{k d h vks
j dxy rFkk px d svfrO;kiu d sd kj.k
43.
The vapour pressure of two miscible liquids A and B are 300 and 500 mm of Hg respectively. In a flask,
2 moles of A are mixed with 6 moles of B. Further to the mixture, 32 g of an ionic non-volatile solute MCl
(partially ionised, mol. mass = 70 u) were also added. Thus, the final vapour pressure of solution was
found to be 420 mm of Hg. Then, identify the correct statement(s) : (Assume the liquid mixture of A and B
to behave ideally).
(SCP-RLVP)_206
(A*) The numerical value of relative lowering in vapour pressure upon addition of solute MCl is 1/15.
Page # 1
nksfeJ.kh; nzoksaA rFkk B d sok"i nkc e'k% 300 rFkk 500 mm Hg gSaA ,d y kLd esa] 2 eksy A d ksB d s6 eksy d s
lkFk fefJr fd ;k t krk gS
A bld sckn bl feJ.k esa] ,d vok"i'khy vk;fud foy s; MCl vkaf'kd : i lsvk;fur]
vkf.od nzO;eku = 70 u d k 32 g Hkh fey k;k t krk gSA bl d kj foy ;u d k vfUre ok"i nkc 420 mm Hg ik;k
t krk gSA rc lgh d Fku@d Fkuksad h igpku d hft , % (A rFkkB d snzo feJ.k d k O;ogkj vkn'kZekusaA)
(A*) MCl foy s
; fey kusij ok"i nkc esavkisf{kd voueu d k vkafd d eku 1/15 gSA
(B*) mijks
Dr iz'u esafoy s; MCl, 25% vk;fur gksrk gS
A
(C) mijks
Dr iz'u esafoy s; MCl 23.33% vk;fur gksrk gSA
(D*) Pb(NO3)2 d k vkf/kD; fey kusij] vo{ks
fir PbCl2 d seksy ksad h la[;k2/35 gSA
Sol.
2
6
300 +
500 = 450 mm of Hg.
8
8
P PS 450 420
1
Now, vc]RLVP = 0
=
=
P0
450
15
P0 = XAPA + XBPB =
in
Also, lkFk ghRLVP =
in N
32i
1
= 70
=
Cl
Cl
100 70 35
1 4
2
nPbCl2 precipitated vo{ks
fir nPbCl2 = =
2 35 35
44.
Which of the following properties is/are common to both K2Cr2O7 & KMnO4 ?
(DBC-IDM)_203
(A*) Both on heating form an oxosalt, a metal oxide & oxygen gas.
(B*) Both have their colour because of charge transfer spectrum.
(C) Both behave as primary titrants as well as self-indicators in redox titrations.
(D*) Both form a slightly coloured precipitate with hydrogen sulphide in acidic medium.
fuEu esalsd kSulk@d kSulsxq.k/keZK2Cr2O7 rFkkKMnO4 nksuksd sfy , leku gS@ gSa\
(A*) nks
uksad ksxeZd jusij
(B*) nks
uksd k jax
(C) nks
uksajsM kWDl
(D*) nks
uksvEy h;
Sol.
ek/;e esgkbMkst u lYQ kbM d slkFk gYd k jaxhu vo{ksi cukrk gSaA
(A) Both on heating form an oxosalt (K2CrO4 & K2MnO4), a metal oxide (Cr2O3 & MnO2) & oxygen gas.
(B) Both have their colour (orange and purple respectively) because of charge transfer spectrum (since no
unpaired electrons).
(C) Only K2Cr2O7 behaves as primary titrant, while KMnO4 behave as self-indicator in redox titrations.
K2Cr2O7 requires diphenyl amine indicator for end point detection while KMnO4 behaves as secondary
titrant.
(D) Both form a slightly coloured precipitate (S) with hydrogen sulphide in acidic medium.
Page # 2
gy -
(A)
nksuksad ksxeZd jusij vkDlksy o.k (K2CrO4 & K2MnO4)] /kkrqvkWDlkbM (Cr2O3 & MnO2) o vkWDlht u xSl
curh gSA
(B)
nksuksd k jax e'k% ukjaxh o cSaxuh vkos'k LFkkukUrj.k LisDVe pqafd d ksbZv;qfXer by s
DVkWu ughagksrk gS d sd kj.k
gksrk gSA
(C)
45.
ek/;e esgkbMkst u lYQ kbM d slkFk gYd k jaxhu vo{ksi (S) cukrk gSaA
F2 + dil. NaOH A + B + C
(PBC-XVII, SBC-CAM)_204
F2 + conc. NaOH A + D + C
(A*) A is NaF
(B) B is O2
(C*) C is H2O
F2 + ruqNaOH A + B + C
(PBC-XVII, SBC-CAM)_204
F2 + lka
nzNaOH A + D + C
(A*) A, NaF gS
(B) B, O2
Sol.
(D) D is OF2
gS
(C*) C, H2O
gS
(D) D, OF2
gS
gy -
46.
(CHK-PRFO)_205
[B]
=;
[C]
[C]
=
[D]
(B) = 4/3
(C*) = 0.375
(D*) = 16/15
Page # 3
Sol.
[B] 3k1 3
[C] 8k1 8
[C]
8k1
8
MCQ (2)
47.
Observed the following reaction sequence and identify the correct options ?
O
CH2C
CH2C
Zn Hg
PCl5
AlCl3
AlCl3
Zn Hg HCl
(A)
(B)
(C)
(D)
(E)
HCl
PdC/
(F)
(A*) F reacts with KMnO4/OH gives phthalic acid which upon heating gives phthalic anhydride.
(B*) E upon monochlorination (Cl2/h) gives total four products.
(C*) F upon complete catalytic hydrogenation gives saturated compound which show geometrical
isomerism.
(D*) Compound (A) gives the NaHCO3 test.
(A*) ;kS
fxd F, KMnO4/OH d slkFk f ;k d jd sFkSfy d
O
CH2C
Sol.
+
CH2C
C
O
AlCl3
HOC
CH2
Zn Hg
HCl
CH2
PCl5
Cl
O
(B)
O
(A)
O
(C)
AlCl3
COOH
COOH
H2O
KMnO4
ZnHg + HCl
PdC/
OH
(F)
(E)
(D)
Pd + H2 /
Cl2/h
Cl
* H
H
O
O
H cis.
+
H
(d)
+
* Cl
H
(d)
H trans.
(G)
Page # 4
48.
Conc. H2SO4
Reaction-I
Product (X)
80C
Conc. H2SO4
160C
Conc. H2SO4
Reaction-II
Product (Y)
160C
Which of the following option(s) is/are correct for above give reactions
(SSS Sir) (AC-EAS) (MCQ) (204) (M)
(A*) In the reaction-I product is formed by most stable intermediate and product (X) is converted into (Y) by
conc. H2SO4 at 160C
(B) In the reaction-II product is -naphthalene sulphonic acid
(C*)Product 'X' is converted into product Y by conc.H2SO4/ and it is a thermodynamically controlled
process.
(D) In the reaction I & II electrophile attacks on naphthalene with same regioselectivity.
lkUnzH2SO4
vfHkf ;k-I
mRikn (X)
80C
lkUnzH2SO4
160C
lkUnzH2SO4
vfHkf ;k-II
mRikn (Y)
160C
mijksDr nh xbZvfHkf ;kvksad sfy , fuEu esalsd kSulsfod Yi lgh gS@ gSa& (SSS Sir) (AC-EAS) (MCQ) (204) (M)
(A*)
vfHkf ;k-I esamRikn lokZf/kd LFkk;h e/;orhZlscurk gSrFkk mRikn (X) 160C ij lkUnzH2SO4 d h mifLFkfr esa
;kSfxd (Y) esaifjofrZr gkst krk gSA
(B)
(C*)
(D)
vfHkf ;k I o II esaby sDVkWu Lusgh leku fjft ;ksp ;ukRed rk d slkFk usFksy hu ij vk e.k d jrk gSA
H
Sol.
SO3/80C
SO3
SO3H
SO3/160C
SO3
SO3H
Page # 5
Page # 6
For the calomel half-cell Hg, Hg2Cl2 | Cl (aq), values of electrode oxidation potential are plotted at different
log [Cl]. Variation is represented by : ( E0
Hg22 /Hg
(ECH-NE)_205
d Sy ksey v) Zlsy ] Hg, Hg2Cl2 | Cl t y h; d sby sDVksM vkWDlhd j.k foHko d sekuksad kslog [Cl] d sfofHkUu ekuksaij
vkjs
f[kr fd ;k t krk gSA rc bld k ifjorZu fuEu }kjk n'kkZ;k t krk gS% ( E0 2 = 0.79 V ; Ksp(Hg2Cl2) = 1018
Hg2 /Hg
(A)
Sol.
(B*)
EOP = (0.79 +
(C)
(D)
1
[Cl ]
0.06
log101018) + 0.06 log [Cl]
2
(ECH-ANE)_205
Pt(s) | H2 (g, 1 atm) | H (aq, pH 6.5) || 1 N KCl(aq) | Hg2Cl2 (s) |Hg( l ) | Pt(s)
Calculate ECl
/Hg Cl
2
298 K ij
/Hg
(calomel electrode).
Pt(s) | H2 (g, 1 atm) | H (aq, pH 6.5) || 1 N KCl(aq) | Hg2Cl2 (s) |Hg( l ) | Pt(s)
ECl
/Hg Cl
2
/Hg
(A*) 0.28 V
Sol.
H2 + Hg2Cl2
Ecell = E
(B) 0.30 V
2Hg +
Cl /Hg2Cl2 /Hg
0.67 = E
Cl /Hg2Cl2 /Hg
0.67 = E
0.28 = E
2Cl
(C) 0.26 V
(D) 0.4 V
2H+
H /H2
0.06
log [H+]2 (1)2
2
+ 0.06 pH
Cl /Hg2Cl2 /Hg
+ 0.06 6.5
Cl /Hg2Cl2 /Hg
The coordination number of iron in both the complexes (A) and (B) is six. (QUA-IIG)_204
Now answer the following questions.
Page # 7
(COR-ACFT)_203
Sol.
52.
uhy k jax
(COR-ACFT)_203
(A) Complex A - K3[Fe(CN)6] absorbs radiation of greater frequency because it contains Fe3+, so greater
O.
(B) Complex B - K4[Fe(CN)6] has zero spin magnetic moment.
(C) Both complexes have same hybridisation (d2sp3) of central atom/ion.
(D) Complex B is thermodynamically less stable (O.N. stability).
(A) la
d qy A - K3[Fe(CN)6] mPp vkorZd h fofd j.ksavo'kks
f"kr d jrk gSA D;ksafd ;g Fe3+ vk;u j[krk gSA blfy , O
Cl
r
2
The mechanism by which they speed up the reactions is known as neighbouring group participation.
S
H2O
PhS
PhS
Ph
OH
Cl
Three membered
ring intermediate
In this, ionization of the starting material is assisted by the lone pair of an electron-rich functional group.
Page # 8
In neighbouring group participation relation of configuration is observed. Observe the following reaction
also
OTs
OAc
AcOH
OAc
OAc
Which follows through the mechanism.
CH3
CH3
OAc
AcOH
OTs
OAc
Neighbouring group participation is only possible when leaving group and neighbouring group are anti to
each other.
(RSS Sir) (RM-MX) (207) (NGP) (Tough)
uhpsnh xbZizR;sd vfHkf ;ksaesami;qDr foyk;d d h mifLFkfr esafu"d klu lewg (OTs ;k Cl) d k izfrLFkkiu gksrk
gSA
PhS
Cl
HO
r1
HO
Cl
r
2
PhS
H 2O
PhS
Cl
S
Ph
OH
rhu lnL;h
oy ; e/;orhZ
mijksDr vfHkf ;k esiz
kjfEHkd inkFkZd k vk;uu ,d by sDVkWu /kuh f ;kRed lewg d s,d kd h ;qXe }kjk lEiUu gksrk gSA
iM+kSl h lewg ;ksxnku esafoU;kl d k lEcU/k izs
f{kr gksrk gS
A fuEu vfHkf ;k Hkh izsf{kr gksrh gS%
OTs
OAc
AcOH
OAc
OAc
CH3
O
OAc
AcOH
OTs
OAc
OTs
OAc
Page # 9
(B)
(C*) Me
Cl
OSO2Ph
SMe
(D)
Me
HO
HO
with H2O.
OTs
(A)
d h f ;k
d h rqy uk esvf/kd rs
t h lsgksrh gSA
OAc
OAc
Cl
d h f ;k
OSO2Ph
Cl
d h f ;k Me
SMe
(D)
Sol.
I HO
HO
Me
Me
SMe
OSO2Ph
Me
SMe
OTs
AcOH
Product, mRikn
54.
OAc
Product is mRikn
gS
OAc
OAc
(A)
(B*)
OAc
OAc
Sol.
In
OTs
(C)
OAc
OAc
(D)
OAc
OAc
esaiM+kSl h lew
g d k ;ksxnku lEHko ugh gS
A
OAc
[Au(CN)x] is a very stable complex (though EAN = 82) under certain conditions and Kf of [Au(CN)x] is 4
1028. z 10y M concentration of cyanide ion is required to maintain the equilibrium at which 99 mole % of
the gold is in the form of cyanide complex. Then determine (y + z). Atomic number of Au = 79. z is a
natural number & 1 z 9.
(CEQ-HOEL, COR-BICC)_205
fuf'pr fLFkfr;ksad svUrxZr [Au(CN)x] ,d vR;f/kd LFkk;h lad qy gS(;|fi EAN = 82) rFkk [Au(CN)x] d k Kf 4
gSA lk;ukbM vk;u d h vko';d lkUnzrk z 10y M gS] t ksfd lkE;koLFkk cuk;sj[krsgq, 99 eksy % lksusd ks
lk;ukbM lad qy d s: i esacuk;sj[kusd sfy , vko';d gS
A rc (y + z) Kkr d hft ,A Au d k ijek.kq ekad = 79. z
,d iz
kd `r la[;k gSrFkk 1 z 9.
1028
Ans.
19
Page # 10
Au+ + 2CN
Sol.
[Au(CN)2]
99 mol% [Au(CN)2]
[Au(CN2 )]
It means
[Au ] [Au(CN2 )]
bld k vFkZgS
99
100
[Au(CN2 )]
[Au ] [Au(CN2 )]
99
100
K =
[Au(CN2 )]
(I)
99
[Au(CN2 )]
[Au ] [CN ]2
99
4 1028 =
56.
j[kusij
[CN ]2
[CN] = 5 1014 M
A sparingly soluble salt MX is dissolved in water to prepare 1 L saturated solution. Now 106 mole NaX
(assume 100% dissociation) is added into this. Conductivity of this solution is 29 106 S/m. If Ksp of MX is
a 10b, then find value of (a + b). a is a natural number & 1 a 9.
(ECH-EC)_206
Given : 0 4 10 3 S m2 mol
x
Na
5 10 3 S m2 mol
0 6 10 3 S m2 mol
M
,d vYi foy s;h yo.k MX d kst y esa?kksy d j 1 y hVj lar`Ir foy ;u cuk;k t krk gS
A vc blesa106 eksy NaX
(100%
fo?kVu ekusa) fey k;k t krk gSA bl foy ;u d h fof'k"V pky d rk 29 106 S/m gS
A ;fn MX d k Ksp a 10b
0 4 10 3 S m2 mol
x
Na
5 10 3 S m2 mol
0 6 10 3 S m2 mol
M
Ans.
18
Sol.
MX
M + + X
6
x
x + 10
[Na+] = 106 M
KSol = K
+ K
+K
Na
Page # 11
Two moles of an ideal gas is changed from their initial state (16 atm, 6L) to final state (4 atm, 15L) in such
a way that this change can be represented by a straight line in PV curve. Let 'y' L atm be the maximum
average translational kinetic energy possessed by the gas sample during the above change. Report your
answer as y/2. (Take R =
1
L atm K1 mol1)
12
(GST-KTG)_207
,d vkn'kZxSl d snkseksy d ksizkjfEHkd voLFkk (16 atm, 6L) lsvfUre voLFkk (4 atm, 15L) rd bl izd kj ifjofrZr
fd ;k t krk gS] fd PV o esabl ifjorZu d ks,d lh/kh js[kk }kjk iznf'kZr fd ;k t k ld rk gS
A ekusafd mijksDr
ifjorZu d snkSjku xSl izkn'kZ}kjk izkIr vf/kd re vkSl r LFkkukUrj.k xfrt t kZ'y' L atm gSA viuk mkj y/2 d s: i
esanhft ,A
(y hft ,
%R =
1
L atm K1 mol1)
12
Ans.
81
Sol.
y y1
(y y1) = 2
(x x1)
x 2 x1
4 16
(P 16) =
(V 6)
15 6
3P + 4V = 72
Tmax =
(PV)max
nR
72
72
and (rFkk) 4V =
2
2
P = 12, V = 9
Tmax =
KEmax =
58.
12 9
= 648K.
2 (1/ 12)
3
3
1
nRTmax = 2
648 = 162 L atm.
2
2
12
[H+] concentration in 0.01 M H2O2 solution ( K a1 = 3 1012 and K a2 0) is x M. Fill first two digits of 108 x
(IEQ-PPAB)_205
as answer.
0.01 M H2O2 ( K a1 = 3
1012
[H+]
lkanzrk x M gSA
108
x d sigy snksva
d ksad ksmkj d s: i
esaHkfj,A
Ans.
20
Sol.
[H+] =
K a C0 K w 3 10 12 102 10 14
= 2 107 M = x
108 x = 20
Page # 12
How many cyclic structural isomer of C6H10 possible which after ozonolysis give diketones that show Intra
molecular Aldol condensation. (Only between ketone).
d sfd ruspf ; lap ukRed leko;oh lEHko gSt ksvkst ksuh vi?kVu d si'pkr~d soy MkbZd hVksu nsrk gSt ks
vUr%vkf.od ,YMksy la?kuu iz
nf'kZr d jrk gSA d soy fd Vksu d se/;
C6H10
Ans.
03
OH
O
Intra molecule aldol vUr%vkf.od
O
O3
ZnH O
Sol.
O3
ZnH O
2
O3
ZnH O
2
60.
,YMksy
How many reactions will proceed through free radical addition mechanism.
(i)
NBS
(ii)
HCl
R 2O 2
HBr
h
(iii) CH3C=CHCH3
CH3
HI
(iv) CH3CCCH2CH3
R 2O2
HBr
(v) CH3CH=CH2
R 2O2
CH=CHCH3
(vi)
Ans.
02
Sol.
Sol.
NBS
Page # 13