Th Tc 1 + (ZT)M 1
te =
(1)
Th
1 + (ZT)M + TThc
where Tc is the cold-side temperature, Th the hot-side temperature,
and (ZT)M the effective ZT of the thermoelectric material
between Tc and Th . According to equation (1), an efficiency of
approximately 8.6% can be reached by imposing a temperature
difference of 200 C across an ideal thermoelectric device with
(ZT)M = 1 and Tc = 20 C. In recent years, significant progress
has been made on improving thermoelectric materials820 , however
the application of thermoelectrics in large-scale renewable energy
conversion has not been demonstrated21 . Conventional wisdom
is that thermoelectrics are most suitable for waste heat recovery
and that materials with significantly higher ZT are needed for
large-scale applications7,22,23 . We will show that thermoelectrics are
an attractive alternative for converting solar energy into electricity.
1 Mechanical Engineering Department, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA, 2 GMZ Energy, 11 Wall St., Waltham,
Massachusetts 02458, USA, 3 Department of Physics, Boston College, Chestnut Hill, Massachusetts 02467, USA, 4 Masdar Institute of Science and
Technology, PO Box 54224, Abu Dhabi, United Arab Emirates. These authors contributed equally to this work. *e-mail: renzh@bc.edu; gchen2@mit.edu.
532
ARTICLES
Wavelength-selective
solar absorber
= ot te
Thermoelectric
element
Cold side
Load
Sunlight
Heat flow
Solar absorber/
thermal concentrator
TE elements
Absorber area Aa
TE element crosssectional area ATE
Thermal
concentration
Cth =
(2)
Aa
ATE
533
ARTICLES
a
V (1.5 kW m2)
Voltage (mV)/Power (mW)
5
4
3
2
m2
1 kW
(sim)
1 kW m2 (exp)
1.5 kW m2 (sim)
1.5 kW m2 (exp)
1
0
0.5
1.0
1.5
Current (A)
2.0
40
P (1 kW m2)
20
STEG efficiency
1 kW m2 (sim)
1 kW m2 (exp)
1.5 kW m2 (sim)
1.5 kW m2 (exp)
1
0
100
150
LInes: model
Symbols: experiment
1.0
V (1 kW m2)
1.5
Current (A)
2.0
2.5
P (1.5 kW m2)
60
0
0.5
2.5
80
Selective absorber,
in vacuum, bulk TE
Black absorber,
in vacuum, bulk TE
2
1
200
250
300
Thermal concentration
350
400
100
200
300
Thermal concentration
400
Figure 2 | STEG cell performance characteristics. Typical STEG cell characteristics at incident solar radiation fluxes of 1 kW m2 and 1.5 kW m2 .
Open/filled squares and circles are experimental data, lines are modelling results with thermal concentrations Cth = 299 (red solid line) and Cth = 196
(black dash line). a, Efficiency as a function of the cell current. b, IV and IP characteristics of the STEGs. c, Efficiency as a function of the thermal
concentration. For all experimental data, the cold side was maintained at 20 C. d, Simulated efficiency of STEGs with different designs (neglecting
electrical contact resistance): black absorber with traditional bulk thermoelectric materials in air (solid line); black absorber with traditional bulk
thermoelectric materials in vacuum (dash-dotted line); wavelength-selective solar absorber with bulk TE materials in vacuum (dashed line); and
wavelength-selective solar absorber with nanostructured bulk thermoelectric materials in vacuum (dotted line).
the rear side of the selective absorber. The size of the solar absorber
must be optimized specifically for the properties and dimensions of
the thermoelectric elements used and also for the absorber properties. The ratio between the absorber area, Aa , and the cross-sectional
area of the thermoelectric elements, ATE , is defined as the thermal
concentration, Cth , (Fig. 1e). The devices are tested in a vacuum
chamber. (See Methods for details of the experiment).
Figure 2a and b show the typical performance curves
of STEGs under illumination intensities corresponding to
AM1.5G (1 kW m2 ) and low optical concentration conditions
(1.5 kW m2 ). The corresponding thermal concentrations of the
STEGs used for 1 and 1.5 kW m2 are 299 and 196, respectively.
The peak efficiency is 4.6% at AM1.5G conditions and 5.2%
with a solar intensity of 1.5 kW m2 when the cold side is
maintained at 20 C (Fig. 2a). To experimentally simulate an
optically concentrated solar flux of 1.5 kW m2 , the power input
of the solar simulator is adjusted. Figure 2b illustrates the typical
I V and I P characteristics of the STEGs. The voltage output of a
STEG comprising a p-type and an n-type leg can be expressed as
Z Th
Z Th
p
1
V =
[Sp (T ) Sn (T )]dT I
dTp
Ap dTp /dx
Tc
Tc
Z Th
n
1
+
dTn
(4)
An dTn /dx
Tc
Equation (4) shows that if Th , dTp /dx and dTn /dx are independent
of the current, the voltagecurrent relation is linear. In reality,
534
ARTICLES
b
7
6
5
4
3
Cth = 299 (sim)
1
0.6
1.0
1.4
4
3
1 kW m2 (sim)
1 kW m2 (exp)
1.5 kW m2 (sim)
1.5 kW m2 (exp)
2
1
1.8
10
d
1.0
0.8
0.6
0.4
0.2
0
4
5
Time (min)
50
60
70
20
30
40
Cold-side temperature (C)
60
50
40
30
104
103
102
101
Pressure (Pa)
Figure 3 | Performance under varying ambient conditions. a, Efficiency dependence of STEGs on solar radiation intensity (open circles for Cth = 299 and
open squares for Cth = 168). b, Efficiency dependence on the cold-side temperature for STEG cells optimized for 1 kW m2 and 1.5 kW m2 . c, Open circuit
voltage decay as a function of time. d, Dependence of open circuit voltage on pressure. The arrow in d shows the typical operating pressure of the widely
used evacuated solar collectors for hot-water systems. Symbols indicate experimental data and lines indicate modelling results.
535
ARTICLES
536
10
9
8
7
6
5
4
3
2
1
0
0.5
Copt = 1
= 0.03
= 0.07
= 0.12
1.5
1.0
Effective figure of merit (ZT)M
2.0
12
10
8
6
4
2
0
0.5
Copt = 1
Th = 220 C
= 0.03
Copt = 3
Copt = 10
1.0
1.5
Effective figure of merit (ZT)M
2.0
c
14
12
10
8
6
4
2
0
0.5
Copt = 1
= 0.06
1.0
1.5
Effective figure of merit (ZT)M
Copt = 3
Copt = 10
2.0
Methods
To vary the cold-side temperature the copper plates are mounted onto a
ceramic plate for electrical insulation and put in good thermal contact with a
temperature-controlled sample holder. In practical applications, the cooling
mechanism and the operational cold-side temperature will depend on the
application. A passive heat sink to the environment based on natural convection
will be sufficient to maintain the cold-side at a temperature similar to the
operational temperature of PV cells. A commercial solar absorber is used, which
is a multi-layer thin-film spectrally-selective surface on a copper substrate. The
copper side of the solar absorber is in both thermal and electrical contact with
the thermoelectric elements (Fig. 1). The selective surface has a specified solar
absorptance of 94.4% and a thermal emittance of 5% at 100 C (Supplementary
Information). The rear side of the solar absorber and the front side of each
bottom copper plate are polished to reduce their emittance. The vacuum levels
are maintained in the range of 5 104 3 102 Pa during the experiments.
In comparison, the typical vacuum level of evacuated solar hot-water tubes is
5 104 Pa (ref. 34).
The optimum design of the STEGs depends on the incident solar radiation
power, the solar absorber properties, the thermoelectric material properties,
the cold-side temperature, and the device geometry. Numerical simulations
determine the optimum absorber plate sizes for the thermoelectric elements that
are used in the experiments (Supplementary Information). The actual energy
flux concentration provided to the thermoelectric elements is the product of the
thermal concentration, the optical concentration, and the opto-thermal efficiency
(equation (3)) at the operational temperature. The thermal flux concentration is
system specific and dependent on operational conditions such as incident flux
and cold-side temperature. Modelling results show that the temperature drop
within the solar absorber is smaller than 2 C for the thermal concentrations used
(Supplementary Information). The temperature drop along the bottom copper
plates is even smaller.
A solar simulator with an AM1.5G filter is used as the light source. The incident
flux is measured with a calibrated power meter provided by the manufacturer
of the solar simulator. In addition, we also use an NREL-calibrated solar cell to
cross-check the radiation flux. The thermoelectric devices, similar to PV, need
load optimization to maximize the power output. We determine the optimal load
condition by using a current source as a variable resistor41 , and we simultaneously
measure both the current and the voltage drop across the copper electrodes on the
cold side. The STEG efficiency, = IV /(qi Aa ), is calculated from the voltage V ,
the current I , the absorber area Aa and the incident solar radiation flux qi . This
efficiency includes the glass transmission loss and the solar absorber loss as well as
possible parasitic electrical and thermal losses of the system. The transmittance of
the glass enclosure is measured to be 94%.
References
1. Lewis, N. et al. Basic Research Needs for Solar Energy Utilization. (DOE Office of
Science, 2005); available at http://www.er.doe.gov/bes/reports/abstracts.html.
2. Luque, A. & Hegedus, S. Handbook of Phovoltaic Science and Engineering
(Wiley, 2003).
3. Green, M. A. Third Generation Photovoltaics: Advanced Solar Energy Conversion
(Springer, 2003).
4. Mills, D. Advances in solar thermal electricity technology. Sol. Energy 76,
1931 (2004).
5. Roeb, M. & Muller-Steinhagen, H. Concentrating on solar electricity and fuels.
Science 329, 773774 (2010).
6. Goldsmid, H. J. Thermoelectric Refrigeration (Plenum, 1964).
7. Rowe, D. M. Thermoelectrics Handbook Nano to Macro
(CRC Taylor & Francis, 2006).
8. Venkatasubramanian, R., Siivola, E., Colpitts, T. & OQuinn, B. Thin-film
thermoelectric devices with high room-temperature figures of merit. Nature
413, 597602 (2001).
9. Harman, T. C., Taylor, P. J., Walsh, M. P. & LaForge, B. E. Quantum
dot superlattice thermoelectric materials and devices. Science 297,
22292232 (2002).
ARTICLES
10. Hsu, K. F. et al. Cubic AgPbm SbTe2+m : Bulk thermoelectric materials with high
figure of merit. Science 303, 818821 (2004).
11. Dresselhaus, M. S. et al. New directions for low-dimensional thermoelectric
materials. Adv. Mater. 19, 10431053 (2007).
12. Poudel, B. et al. High-thermoelectric performance of nanostructured bismuth
antimony telluride bulk alloys. Science 320, 634638 (2008).
13. Heremans, J. P. et al. Enhancement of thermoelectric efficiency in
PbTe by distortion of the electronic density of states. Science 321,
554557 (2008).
14. Boukai, A. I. et al. Silicon nanowires as efficient thermoelectric materials.
Nature 451, 168171 (2008).
15. Hochbaum, A. I. et al. Enhanced thermoelectric performance of rough silicon
nanowires. Nature 451, 163167 (2008).
16. Snyder, G. J. & Toberer, E. S. Complex thermoelectric materials. Nature Mater.
7, 105114 (2008).
17. Rhyee, J-S. et al. Peierls distortion as a route to high thermoelectric performance
in In4 Se3 -delta crystals. Nature 459, 965968 (2009).
18. Zhao, X. B. et al. Bismuth telluride nanotubes and the effects on the
thermoelectric properties of nanotube-containing nanocomposites.
Appl. Phys. Lett. 86, 062111 (2005).
19. Tang, X. F. et al. Preparation and thermoelectric transport properties of
high-performance p-type Bi2 Te3 with layered nanostructure. Appl. Phys. Lett.
90, 012102 (2007).
20. Tritt, T. M. & Subramanian, M. A. (eds) Energy harvesting through
thermoelectrics: Power generation and cooling. MRS Bull. 31, 188194 (2006).
21. Vining, C. B. An inconvenient truth about thermoelectrics. Nature Mater. 8,
8385 (2009).
22. Yang, J. H. & Stabler, F. R. Automotive applications of thermoelectric materials.
J. Electron. Mater. 38, 12451251 (2009).
23. Bell, L. Cooling, heating, generating power, and recovering waste heat with
thermoelectric systems. Science 321, 14571461 (2008).
24. Telkes, M. Solar thermoelectric generators. J. Appl. Phys. 25, 765777 (1954).
25. Tobias, I. & Luque, A. Ideal efficiency and potential of solar thermophotonic
converters under optically and thermally concentrated power flux. IEEE Trans.
Electron Devices 49, 20242030 (2002).
26. Goldsmid, H. J., Giutronich, J. E. & Kaila, M. M. Solar thermoelectric
generation using bismuth telluride alloys. Sol. Energy 24, 435440 (1980).
27. Rush, R. Solar Flat Plate Thermoelectric Generator Research. Tech. Doc. Rep. Air
Force AD 605931 (General Electric Corp., 1964).
28. Dent, C. L. & Cobble, M. H. Proc. 4th Int. Conf. on Thermoelectric Energy
Conversion 7578 (IEEE, 1982).
29. Mgbemene, C. A., Duffy, J., Sun, H. & Onyegegbu, S. O. ASME Conf. Proc.
ES2008 (ASME, 2008).
30. Li, P. et al. Design of a concentration solar thermoelectric generator. J. Electron.
Mater. 39, 15221530 (2010).
31. Fuschillo, N. & Gibson, R. Germanium-silicon, lead telluride, and bismuth
telluride alloy solar thermoelectric generators for venus and mercury probes.
Adv. Energy Conversion 7, 4352 (1967).
32. Raag, V., Berlin, R. E., Bifano, & Bifano, W. J. Intersociety Energy Conversion
Engineering Conf. (1968).
33. Scherrer, H., Vikhor, L., Lenior, B., Dauscher, A. & Poinas, P. Solar
thermolectric generator based on skutterudites. J. Power Source 115,
141148 (2003).
34. Yin, Z. Q. Development of solar thermal systems in China. Sol. Energy Mater.
Sol. Cells 86, 427442 (2005).
35. Weiss, W., Bergmann, I. & Stelzer, R. Solar Heat Worldwide, Markets and
Contribution to the Energy Supply 2007 (International Energy Agency, 2009).
36. Wang, S., Xie, W., Li, H. & Tang, X. High performance n-type
(Bi,Sb)2 (Te,Se)3 for low temperature thermoelectric generator. J. Phys. D 43,
335404 (2010).
37. Xie, W., Tang, X., Yan, Y., Zhang, Q. & Tritt, T. M. High thermoelectric
performance BiSbTe alloy with unique low-dimensional structure. J. Appl. Phys.
105, 113713 (2009).
38. Bulat, L. P. et al. Bulk nanostructured polycrystalline pBiSbTe
thermoelectrics obtained by mechanical activation method with hot
pressing. J. Electron. Mater. 39, 16501653 (2010).
39. Ma, Y. et al. Enhanced thermoelectric figure-of-merit in p-type nanostructured
bismuth antimony tellurium alloys made from elemental chunks. Nano Lett. 8,
25802584 (2008).
40. Yan, X. et al. Experimental studies on anisotropic thermoelectric properties
and structures of n-type Bi2 Te2.7 Se0.3 . Nano Lett. 10, 33733378 (2010).
41. Muto, A., Kraemer, D., Hao, Q., Ren, Z. F. & Chen, G. Thermoelectric
properties and efficiency measurements under large temperature differences.
Rev. Sci. Instrum. 80, 093901 (2009).
Acknowledgements
This material is partially based on work supported as part of the Solid State Solar-Thermal
Energy Conversion Center (S3 TEC), an Energy Frontier Research Center funded by the
537
ARTICLES
US Department of Energy, Office of Science, Office of Basic Energy Sciences under Award
Number: DE-SC0001299/DE-FG02-09ER46577 (G.C. and Z.F.R.) and MIT-Masdar
program (G.C. and M.C.).
Author contributions
D.K. carried out modelling and simulation, initial STEG-efficiency experiments, and
contributed to the manuscript preparation; B.P. conducted the experiments reported in
the paper; H-P.F., J.C.C. and B.Y. contributed to the development of electrical contacts
used for devices; X.Y. made the n-type TE elements; Y.M. fabricated the devices; X.W.
prepared the absorbers; D.W. assisted in making the TE elements and electrical contacts;
A.M. performed device testing; K.M. participated in device modelling and manuscript
538
Additional information
The authors declare competing financial interests: details accompany the paper at
www.nature.com/naturematerials. Supplementary information accompanies this paper
on www.nature.com/naturematerials. Reprints and permissions information is available
online at http://www.nature.com/reprints. Correspondence and requests for materials
should be addressed to Z.F.R. or G.C.