domain spectroscopy
Angelica P. Cano1*
Institute of Mathematical Sciences and Physics
University of the Philippines Los Baos, Laguna
*Corresponding author: apcano@up.ed
1
Abstract
The goal of this experiment is to calculate the terahertz conductivity of
PAni-PE composite using measurements obtained from Terahertz Time domain
spectroscopy technique in the transmission configuration. The data was
processed using IGOR software. The frequency dependence of the absorption of
the sample was used in obtaining the absorption coefficient, while the frequency
dependence of the phase of the sample was used in obtaining the refractive
index. The experimentally computed values were then used to compute for the
dielectric permittivity of the PAni-PE composite. The conductivity can then
determined using the optoelectronic parameters
1. Introduction
The dielectric behavior and carrier dynamics are important properties of materials, especially in the field of
photonics and phononics. The Terahertz Time domain spectroscopy technique provides an efficient way to obtain the
time-dependence of the field transmission of a certain material [2]. THz TDS enables the characterization of the
optoelectronical parameters of materials by determining their frequency dependence. It can provide measurements
for both the amplitude and phase that can be used in determining the real and complex dielectric properties of a
certain material [2].
2. Methodology
The technique used in measuring the conductivity of PAni-PE composites is Terahertz Time domain
spectroscopy. The raw data was processed using IGOR software. First, the FFT of the sample and reference signals
were computed. Then a portion of the spectra was processed with pre-defined wave transformation and unwrapping
functions in IGOR. The phase difference of the two signals is used in determining the refractive index of the PAniPE composite. After obtaining the refractive index, the determination of the absorption coefficient and dielectric
characteristics will follow.
Transmission
6
4
reference
sample
2
0
10
20
30
40
50
60
Figure 2. Time dependence of the field transmission of PAni-PE composite relative to a reference
1200
Phase
1000
800
reference
sample
difference
600
400
200
0
0.0
0.1
0.2
0.3
0.4
0.5
Frequency (THz)
Figure 3. Frequency dependence of the phase of PAni-PE composite relative to a reference
Figure 4 shows the power spectra of the sample and the reference material. From this we can obtain the
absorption spectra of the two signals using the formula given by,
1
P
ln
d
Po
( )
where d is the sample thickeness, P is the magnitude of the power of the sample and P o is the magnitude of the
power of the reference signal. The resulting plot is shown in Figure 5, which shows the absorbance spectra. The
absorption coefficient can be determined from this plot.
600
Power
500
400
300
200
reference
sample
difference
100
5
10
Frequency (THz)
15x10
-3
Figure 4. Processed spectra of power spectra of PAni-PE composite and a reference spectra
Absorbance
4000
3000
2000
1000
0
0
20
40
60
80
100
120
140
160
Frequency (THz)
Figure 5. Frequency dependence of the absorbance spectra of the sample
=1+i2
where
1 is the real component and the 2 is the imaginary component. The real component is also given by
the expression,
1 =
n2k 2
1
where n is the refractive index and k is the absorption coefficient of the material. The refractive index is
experimentally obtained by getting the phase difference of the two spectra shown in Figure 4.
4. Conclusion
The THz conductivity of the PAni-PE composite is determined by using THz TDS technique. The
experimentally determined absorption coefficient, refractive index and dielectric constant were used in computing
the THz conductivity. IGOR software was used in processing of data.
5. References
[1]
[2]