PROJECT REPORT
ON
INDIAN OIL
CORPORATION
LIMITED, PANIPAT
SUBMITTED BY:
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ACKNOWLEDGEMENT
We take this opportunity to express a deep sense of gratitude to Mr Ajay Gupta, Mr Rajeev
Ranjan, & Mr Kushal Chaudhary for their cordial support, valuable information and guidance,
which helped us in completing this task through various stages.
We also take this opportunity to express our profound gratitude and deep regards to our guide Mr.
Asheesh Chaturvedi and Mr. M. Sharma for their exemplary guidance, monitoring and constant
encouragement throughout the course of this training. Their blessing, help and guidance given by
them time to time shall carry us a long way in the journey of life on which our about to embark.
We would also like to thank sanjeev sir, saurabh sir, prashant sir, satyabrata sir, chandrabhan sir,
viman sir, Ekta mam, kanhaiya lal sir for their guidance in field visits.
We are obliged to staff members of IOCL for the valuable information provided by them in their
respective fields. We are grateful for their cooperation during the period of our assignment.
Lastly, we thank almighty, our parents, brother, sisters and friends for their constant
encouragement without which this assignment would not be possible.
CERTIFICATE
This is to certify that the project work entitled Design of heat
exchanger 13-E-5718 is a bonafide work carried out by Jyoti
Ranjan
Paikaray,
Gyanendra
Pratap
Chhotray
&
Pushpendra Kumar under our guidance and direction.
INDIAN OILCORPORATION
LIMITED
INTRODUCTION
Indian Oil Corporation Limited, or Indian Oil, is an Indian stateowned oil and gas corporation with its headquarters in New Delhi, India. It is
one of the sevenMaharatna status companies of India, apart from Coal India
Limited, NTPC Limited, Oil and Natural Gas Corporation, Steel Authority of
India Limited, Bharat Heavy Electricals Limited and Gas Authority of India
Limited It is the world's 83rd largest corporation, according to the Fortune
Global 500 list, and the largest public corporation in India when ranked by
revenue.
Indian Oil began operations in 1959 as Indian Oil Company Ltd. The Indian
Oil Corporation was formed in 1964, with the merger of Indian Refineries
Ltd.
Indian Oil and its subsidiaries account for a 49% share in the petroleum
products market, 31% share in refining capacity and 67% downstream
sector pipelines capacity in India. The Indian oil Group of companies owns
and operates 10 of India's 22 refineries with a combined refining capacity of
65.7 million metric tonnes per year. In FY 2012 IOCL sold 75.66 million
tonnes of petroleum products and reported a PBT of 37.54 billion, and
the Government of India earned an excise duty of 232.53 billion and tax of
10.68 billion.The company is mainly controlled by Government of
India which owns approx. 79% shares in the company.
Indian
oil is the highest ranked Indian company in the Fortune Global 500
listing, at the 88th position in 2013. It is also the 18th largest petroleum
company in the world and the No. 1 petroleum trading company among
the national oil companies in the Asia-Pacific region.
IOCL was featured on the 2011 Forbes Global 2000 at position 243.
It is the fifth most valued brand in India according to an annual survey
conducted by Brand Finance and The Economic Times in 2010.
IOCL has various refineries across India.
In Assam
1.Digboi Refinery is India's oldest refinery and was commissioned in 1901.
Originally a part of Assam Oil Company, it became part of Indian oil in 1981.
Its original refining capacity had been 0.5 MMTPA since 1901. Modernisation
project of this refinery was completed by 1996 and the refinery now has an
enhanced capacity of 0.65 MMTPA. UOP licensed the technology for the
Coking process in this refinery.
2.Guwahati Refinery, the first public sector refinery of the country, was built
with Romanian collaboration and was inaugurated on 1 January 1962. Its
capacity is 1 MMTPA.
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3.Bongaigaon Refinery became the eighth refinery of Indian oil after merger
of Bongaigaon Refinery & Petrochemicals Limited w.e.f. 25 March 2009. It is
located at Dhaligaon in Chirang district of Assam, 200 km west of Guwahati.
In Bihar: Barauni Refinery, in Bihar, was built in collaboration with Russia
and Romania. It was commissioned in 1964 with a capacity of 1 MMTPA. Its
current capacity is 6 MMTPA.
In Gujarat: Gujarat Refinery, at Koyali (near Vadodara) in Gujarat, is Indian
oils second largest refinery. The refinery was commissioned in 1965. It also
houses the first hydrocracking unit of the country. Its present capacity is
13.70 MMTPA.
In West Bengal: Haldia Refinery is the only coastal refinery of the
Corporation, situated 136 km downstream of Kolkata in the PurbaMedinipur
(East Midnapore) district. It was commissioned in 1975 with a capacity of
2.5 MMTPA, which has since been increased to 7.5 MMTPA.
In Uttar Pradesh: Mathura Refinery was commissioned in 1982 as the sixth
refinery in the fold of Indian oil and with an original capacity of 6.0 MMTPA.
Located strategically between Delhi and Agra, the capacity of Mathura
refinery has been increased to 8.8 MMTPA.
In Haryana: Panipat Refinery is the seventh and largest refinery of Indian oil.
The original refinery with 6 MMTPA capacity was built and commissioned in
1998. Panipat Refinery has since expanded its refining capacity to 12
MMTPA. There are plans to further expand the capacity to 21 MMTPA. [7]
In Odisha (Orissa): Paradip Refinery - The commissioning of 15 million
tonnes per annum refinery in November 2012 has been delayed and is now
expected to be operational only in September 2013. [8]
The main products of Indian oil are petrol, diesel, LPG, auto LPG, aviation
turbine fuel, lubricants and petrochemicals: naphtha, bitumen, kerosene etc.
Indian oil operates the largest and the widest network of fuel stations in the
country, numbering about 20,575 (16,350 regular ROs & 4,225 KisanSeva
Kendra). It has also started Auto LPG Dispensing Stations (ALDS). It
supplies Indane cooking gas to over 66.8 million households through a
network of 5,934 Indane distributors.
Brands:
Propel - Petrochemicals
The main services offered by Indian oil are Refining, Marketing, Pipelines,
R&D and Training. Indian oil's Research and Development Center (R&D)
at Faridabad supports, develops and provides the necessary technology
solutions to the operating divisions of the corporation and its customers
within the country and abroad.
IOCL-PANIPAT
Panipat Refinery is the seventh refinery of Indian Oil. It is located in the
historic district of Panipat in the state of Haryana and is about 23 km from
Panipat City. The original refinery with 6 MMTPA capacity was built and
commissioned in 1998 at a cost of Rs. 3868 crore (which includes
Marketing & Pipelines installations).
The major secondary processing units of the Refinery include Catalytic
Reforming Unit, Once Through Hydrocracker unit, Resid Fluidised Catalytic
Cracking unit, Visbreaker unit, Bitumen blowing unit, Sulphur block and
associated Auxiliary facilities. In order to improve diesel quality, a Diesel
Hydro Desulphurisation Unit (DHDS) was subsequently commissioned in
1999.
Referred as one of Indias most modern refineries, Panipat Refinery was
built using global technologies from IFP France; Haldor-Topsoe, Denmark;
UNOCAL/UOP, USA; and Stone &Webster, USA. It processes a wide range
of both indigenous and imported grades of crude oil. It receives crude
from Vadinar through the 1370 km long Salaya-Mathura Pipeline which
also supplies crude to Koyali and Mathura Refineries of Indian Oil.
Petroleum products are transported through various modes like rail, road
as well as environment-friendly pipelines. The Refinery caters to the highconsumption demand centres in North-Western India including the States
of Haryana, Punjab, J &K, Himachal, Chandigarh, Uttaranchal, as well as
parts of Rajasthan and Delhi.
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WHAT IS CRACKING???
Cracking is a process to break large molecules of hydrocarbons into
smaller ones by heating. It may be carried out in 3 ways Catalytic,
hydrocracking & Thermal cracking. Thermal cracking is the process of
cracking naphtha into ethylene and propylene.
Steam is used as a diluent to inhibit coking in the tubes and to increase
the percentage of Ethylene. Low molecular wt. Feedstock such as ethane
and propane give a higher percentage of ethylene whereas high
molecular wt. Feedsock such as naphtha and gas oil is used if propylene is
required in significant qty.
HEATER SECTION
Naphtha and C4, C5, C6 recycles from associated units are fedto the short
residence time(SRT VI) liquid cracking heaters where naphtha and C4, C5,
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C6 recycle feeds get cracked. There are six such SRT VI heaters out of
which 5 are normally in operation. There is one SRT III gas cracking heater
where ethane & propane recycles are cracked. Two SRT VI heaters can
also be operated as SRT III heater when the regulator SRT III heater is
under decoking/maintenance. Dilution steam is added to each of these
coils to reduce coke deposition. There are six transfer line exchangers
(TLE) per heater, which reduce the temp of cracked products drastically
within a fraction of seconds. The heat recovered by cooling is used to
generate super high pressure (SHP) steam at a temp of 525 OC.
The effluent from SRT VI heater is routed to Gasoline Fractionators after
oil quenching. Effluent from SRT III heater is partly routed to Quench
tower and balance to PFO stripper. All the SRT VI and SRT III heaters
operate using fuel gas only. The primary fuel gas is methane rich offgas
produced in NCU. Makeup fuel is C3/C4 LPG supplied from refinery or
RLNG vapour.
The water from Quench water settler is sent to process water stripper
which is stripped with live dilution steam and LP steam to the bottom of
tower, to remove acid gases and volatile hydrocarbons. The vapour
leaving process water stripper is sent to quench tower. The water from
stripper bottom isused for steam generation against circulating quench oil
and medium pressure steam in Dilution steam drum. Provisions for dilute
caustic injection to dilution steam drum feed, process water stripper feed
and quench tower bottoms are provided for pH control. To prevent a buildup of non-volatiles, a blowdown stream from the dilution steam drum is
drawn, cooled to 40 OC against cooling water and sent to OSBL, waste
treatment facility.
Charge gas from the 3rd stage of charge gas compressor is heated against
QW to about 45 OC and then fed to the bottom section of Mono Ethanol
Amine(MEA) acid gas absorber. Superheated charge gas shall be
introduced to acid gas absorber to avoid HC condensation. Lean MEA
coming from regenerator is introduced to middle of absorber. Charge gas
contacts with lean MEA by counter current flow. MEA absorbs both H 2S
and CO2 in charge gas. The rich MEA is sent to gasoline wash column.
Treated charge gas flows to water wash stripper at absorber top. Charge
gas contacts with water to remove entrained MEA. Water from
regenerator reflux drum is introduced to top of absorber, then, returned
to regenerator reflux drum.
DEMETHANISER
The condensed liquid from the charge gas chilling train along with the
vent gas from ethylene fractionation and light gas recycle from
polypropylene plant are sent to the appropriate feed location of the
demethaniser. Provision for reprocessing off spec ethylene is also
provided in the demethaniser. The bottom product is reheated against
ethylene and propylene refrigerant in the cold box, after which it is split
into 2 streams. The methane refrigeration is condensed by the lowest
level ethylene refrigeration. The system provides liquid methane as reflux
to the tower. The over head of DM is split into 2 streams, one stream is
mixed with reflux drum liquid. The other stream is heated and
compressed. Part of liquid from the reflux drum is sent to DM as reflux.
The remainderof reflux is mixed with DM overhead and sent to cold box as
methane refrigerant.
DE-ETHANISATION, ACETYLENE
HYDROGENATION AND ETHYLENE
FRACTIONATION
The demethaniser bottom products which is split into 2 streams, feeds the
deethaniser to separate c2 from c3+ material.Deethaniser overhead is
partially condensed and collected in reflux drum. Deethaniser also
processes treated FCC dry c2 and FCC c3 stream received from refinery. A
2- bed acetylene converter having silver promoted palladium catalyst for
selective hydrogenation of acetylene to ethylene and ethane.
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DEPROPANISER
Deethanizer bottoms and condensate stripper bottoms are the feed to
depropaniser to separate C3 components stripper bottom from C4 and
heavier components, after condensate is used as flux and balance is fed
to Methyl acetylene and Propadiene converter. Depropanizer bottom
product containing C4 and heavier material is sent as debutanizer feed.
MAPD HYDROGENATION
In this section methyl acetylene (MA) and Propadiene (PD) present in the
depropaniser overhead are removed by selective hydrogenation to
propylene and propane in a single bed MAPD reactor containing SubChemie G-681 IX hydrogenation catalyst.
Reactor feed stream combined with recycle liquid from <APD converter
effluent separate vapour leaving the separator, is cooled and returned to
charge gas compressor to recover H2, CH4 and C3 hydrocarbons. Part of
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liquid from the separator drum is combined with C3 recycle from PP Plant
and sent to the propylene fractionator-2.
PROPYLENE FRACTIONATOR
The Propylene Fractionator uses a two tower system to separate the feed
into polymer grade propylene and propane.
The Polymer grade Propylene product is withdrawn as a side draw from
tower2 and delivered to OSBL downstream polymer plant. A portion of
side draw product can be chilled and routed to low pressure OSBL
cryogenic storage at -450C.
Bottoms from tower 2 are fed to tower 1. The propane rich product is
withdrawn from tower 1 bottom and sent to the propane recycle drum.
The recycle is vaporized and mixed with ethane recycle before entering
into SRT-III Cracking heater.
DEBUTANIZER
Depropanizer bottom flows to the debutanizer where the raw C4 product
is separated, the debutanizer overhead product consisting of mixed C4s,
which is pumped to butadiene extraction unit or C4 hydrogenation unit.
Debutanizer bottom is combined with gasoline from gasoline stripper and
sent PGHU for hydrogenation.
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but as catalyst is not selective a portion of the olefins also saturate. The
equipment in the C4HU is designed for upto 70% olefins saturation.
Process Flow Diagram of C4HU
C4 mix comes from Debutanizer overhead (60 MT/Hr) and hydrogen from
methanator (1.53 MT/Hr), hdrogenated C4 LPG is forwaded to Heater and
LPG Pool. In alteration operation, when BDEU is notoperating, C4HU will
process raw C4mix. Butadiene and portion of butenes are hydrogenated
in this mode of opertion.
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Given data:
Temperature
Process fluidInlet-
T1- 740C
24
Outlet-
T2- 450C
24
t1- 300C
Allocation
Shell Side
--
t2- 400C
Tube Side
--
R=
= 23.220C
= 2.9 S=
= 0.23
Physical properties:
(From Kern, Process Heat Transfer, McGraw-Hill)
Water, from steam tables:
Temperature, 0C
Cp, kJ kg-1 0C-1
K kW m-10C-1
Kg m-1 s-1
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Process Fluid:
60
1.848
150x10-6
4.2
625x10-6
0.734x10-3
.512x10-3
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Kg m-3
993.7
836
Duty:
Oil flow-rate = 24 kg/s
Water flow-rate =
From Figure 12.1, for cooling tower water and low organic liquid, take
U=650 Wm-2C-1
Area required =
m2
Tube-side coefficient:
Select 20 mm o.d., 16 mm i.d. tubes, 4 m long, triangular pitch 1.25do,
carbon steel.
Surface area of one tube =
20
10_3
5 = 0.314 m2
) =2.011 10-3
-3 2
-3
=595 10-4 m2
Shell-side
Bundle
coefficient:
diameter, Db
mm
Use 25 per cent cut baffles, baffle arrangement for divided shell as shown
below:
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Cross-flow area,As
Mass velocity, Gs
Equivalent diameter, de
Linear Velocity,us
Re
From figure 12.29(Coulson & Richardsons),
jh= 2.8 10-3
Pr
hs
m-2 0C-1
Overall coefficient:
Take fouling factors as 0.00025 for cooling tower water and 0.0002 for gas oil
(light organic). Thermal conductivity for carbon steel tubes 45 Wm -2 0C-1
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.0002
Or
Or
.001219
U0 = 820 Wm-2 0C-1
Well above the initial estimate of 500 Wm -2 0C-1, so design has adequate
area for the duty required.
Pressure drops:
Tube-side
Re
From Figure 12.24(Coulson & Richardsons),
jf = 4
i.e.
m-2 =0.68 kgcm-2
Shell-side
i.e.
, too high
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ho= 2438
C-1
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