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Graphical Solution of

the Finite Square Well

This section provides a more detailed understanding of the solution of the Schrödinger

equation for a one-dimensional square well of finite depth, a physically more realistic

potential whose understanding will be helpful in many future discussions. Let us first

shift the V(x) and x axes so as to arrange the potential symmetrically about x 0 with

the walls at ; a as shown in Figure 6-8b. The purpose is to enable us to simplify the

mathematics a bit. As above, we will only be concerned with energies inside the well;

that is, 0 E V0.

Equation 6-33 is the Schrödinger equation for a x a where V(x) V0

and its general solution is

1x2 = B1 e x + B2 e -x

6-36

**where B1 and B2 are constants. The condition that (x) S 0 as x S means that
**

B2 0 for x a. Similarly, B1 0 for x a and we conclude that

1x2 = B1 e x

x 6 -a

6-37a

1x2 = B2 e -x

x 7 {a

6-37b

**Equation 6-26 is the Schrödinger equation for a x a where V(x) 0, and
**

its general solution, we have already noted, is

1x2 = A1 sin kx + A2 cos kx

6-38

**where A1 and A2 are constants. In contrast with the infinite square well, however, we
**

cannot eliminate either the sine or cosine functions by requiring that they be zero at

the boundaries of the well because the boundaries are not infinitely high. However,

because of their particular symmetry (cosine is even, sine is odd), we can consider

them separately with the symmetric arrangement that was chosen for V(x).

Equations 6-37 and 6-38 are all continuous functions with continuous first

derivatives; therefore, the complete (x) and (x) for the finite square well will also

be continuous, as required by the acceptability conditions, if they are also continuous

at x a and x a. How do we ensure continuity at those two points? Let us consider first the even solution in the well, 1x2 = A2 cos kx.

For x a:

For continuity of 1x2

**For continuity of 1x2
**

20

A2 cos ka = B2 e -a

6-39a

-kA2 sin ka = -B2 e -a

6-39b

indicated by1 the small arrows. an equivalent discussion leads to the condition that -cot ka = k 6-43 Though tedious to solve analytically. 1x2 = A1 sin kx. we have that A2 e -a e -a = = B2 cos ka k sin ka or sin ka = tan ka = cos ka k 6-41 Substituting values of k and from above.More Chapter 6 For x a: For continuity of 1x2 A2 cos 1 -ka2 = A2 cos ka = B1 e -a 6-40a For continuity of 1x2 -kA2 sin1 -ka2 = kA2 sin kA = B1 e -a 6-40b We note immediately that B1 B2.75. Figure 6-15 illustrates the tan ka α /k – cot ka 4 tan ka 3 –cot ka α /k 2 n= 2 n= 3 n= 4 1 n= 5 n= 6 0 π /2 π 3π /2 2π 5π/2 3π ka FIGURE 6-15 Graphical solutions of Equations 6-41 and 6-43. The solutions are those points where the graphs of tan ka and cot ka have values in common with >k. the top >k curve has >k = 0 for ka 2. 21 . Allowed values of E are those given by the values of ka at the intersections of the >k and tan ka and >k and cot ka curves. which the symmetry of the potential might also have suggested to us. Equation 6-41 can also be written as tana V0 . For example.75. Combining Equation 6-39 and 6-40. or 12mV0 2 2 a>h = 2. Two different curves of >k are shown. each corresponding to a different value of V0. The value of V0 in each case is given by the value of ka where >k = 0. the solutions to these transcendental equations can be readily found graphically.E 22mE ab = A E U 6-42 Considering the odd solutions in the well.

The “angle” ka contains both the particle’s energy E and the half width of the well a. it corresponds to the top of the well. Some features of the finite square well solutions are worth noting: 1. 2. just the curves of tan versus and the negative of the curves of cos versus that you first saw in trigonometry. As the well gets deeper—that is. Note that there is always at least one quantized energy in the well no matter how shallow it gets. noting that L 2a there. as the point where >k = 0 moves to the left in Figure 6-15—a solution is lost out of the top of the well each time that point passes an integer multiple of >2. as long as V0 0. as the point where >k = 0 moves to the right in Figure 6-15—a new quantized energy and solution appear each time the point where >k = 0 reaches an integer multiple of >2. of course. The value of >k is also graphed against ka. the ka axis is the energy axis. As the well gets more shallow—that is. . The point where the >k curve intersects the ka (energy) axis is the point where E V0. that is.22 More Chapter 6 graphical solution. The solution intersections move up the tan and cot curves with ka S n>2. The tan ka and cot ka are both graphed versus ka. (See Figure 6-12. thus.) Using the graphical technique outlined. as for the infinite square well. They are. Obtaining the values of the constants in the general expressions for V(x) is not particularly useful for our purposes here since we have already found the general form of the wave functions for the finite square well. you can now construct energy-level diagrams for finite square wells.

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