Ionization Energy - Ionization energy is the amount of energy required to remove the
outermost electron. It is closely related to electronegativity. The
larger the
ionization energy, the more difficult it is to remove an electron. It is a
measure of how tightly the electron is held in the atom.
Period - ionization energy increases as you go from left to right across a period.
Why? Elements on the right of the chart want to take electrons from other atoms
(not give them up) because they are close to achieving the octet. This means it
will require more energy to remove the outermost electron. Elements on the left of
the chart would prefer to give up their electrons so it is easy to remove them,
requiring less energy (low ionization energy).
Group - ionization energy decreases as you go down a group.
Why? The shielding effect makes it easier to remove the outermost electrons from
those atoms that have many electrons (those near the bottom of the chart).
Electron Affinity - Electron affinity is the energy change that accompanies the
addition of an electron to a gaseous atom. It gives an indication of the
relative ease by which atoms gain an electron. A negative electron affinity
means a gain of an electron is favorable because energy is released. Positive
electron affinities are unfavorable. (The accepted convention is to assign a
negative sign to an electron affinity when energy is released upon gain of an
electron.)
Period - electron affinity increases as you move from left to right across a period
Why? Decreasing atomic size
Group - electron affinity decreases as you go down a group.
Why? Increasing atomic size
b) Mg, P