Solutions

1
FIITJEE
JEE(Advanced)-2015
ANSWERS, HINTS & SOLUTIONS
CRT II
(Paper-1)
Q. No.
1.
ALL INDIA TEST SERIES
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AITS-CRT-II-(Paper-1) PCM(Sol)-JEE(Advanced)/15
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
1.
2.
3.
4.
5.
PHYSICS
CHEMISTRY
MATHEMATICS
A,B
B, D
B,D
B, C
C, D
C,D
A, B, C, D
A, D
A, B, C
A, C, D
A,B,C
A, C
A,B,D
C, D
A, B
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2
Physics
1.
PART I
SECTION A
Optical path length of ray entering through S1

L
x1 dx L
0
aL2
2
Path difference of ray from S1 and S2 x
aL2
2
For minima at O
aL2
2
2
2.
Fundamental frequency f0
v
2L
Beat frequency = f1 f2
3.
v
L
2 L
2
v
L
2 L
2
v
2
2
2 L 2L L 2L
4L 8f0 L
2f0L 2
2
l
L 4L
When mirror rotates, by , reflected ray
rotates by 2 36 rad/s.
dH d 10cot
speed of spot =
dt
dt
d
10 cos ec 2
dt
10
36
2
0.6
= 1000 m/s
H 10cot
Wall
10m
4.
Energy of nth state in H-atom is same as energy if 3nth state in Li .
5.
v 2f0 l2 l1
f
l l1
v
0 2
f0
l2 l1
v max
1
0.1 0.1
100 74 24
1.2%
3
6.
Magnitude
B
of
field
at
Point
is
0Ir
0I
0I
R
2
2
2R
2 2 2R
Unit vector in the direction of field, B
R
2
i k
2
P
45
10
1A ; V iR 1 4 4V
10
7.
8.
12
2 2
4x x = 25 cm.
8
8 16
9.
R R
P , y,
2
2
Ammeter and 0.9 is in series

10 10 3 9.9 i 0.1 = i 0.99
So current = 0.99 + 0.01 = 1 Amp.
4
Chemistry
PART II
SECTION A
1.
VBT and MOT both consider wave nature of e-.
2.
H3PO4 can act as a dehydrating agent.
4.
Hydrocarbon part is hydrophobic part
5.
Cr H2O 6
6.
has maximum CFSE
v
and both v and r can be determined by Bohrs theory .
2 r
7.
8.
OH is aromatic hence
Gf of
O is maximum in acidic medium.
LiAlH4
RX
Alkene
OH
9.
is major at high T, at high temperature para hydrogen convert into ortho hydrogen.
SO3H
10.
Cu NH3 4
12.
(C) : [Cr(NH3)5Cl]NO2
: [Cr(NH3)5NO2]Cl
: [Cr(NH3)5ONO]Cl
15.
has square planar shape
Cl
Xe
F
Cl
I
Cl
Cl
5
SECTION C
1.
In H2O and CH3CH2OH mixing shows +ve deviation while in other cases it shows ve deviation.
2.
Electron will reach n = 4, so the maximum possible transitions for single electron are 4 3,
3 2, 2 1.
3.
nM MnnA ne
at anode
Mnnc ne
2M
at cathode
Net all reaction: Mnnc

MnnA
Mnn
0.059
C
0.0295
log
n
n
Mn
A
n = 2
4
4.
Pt en 3
5.
N1V1 N2 V2
H2O2
is optically active but does not show geometrical isomerism.
KMnO4 / H
2 x 25 = N x 25
N=2
Again
NV
1 1
KMnO4 / H
= gm eq. of (X)
2 x 1 = gm eq. of (X)
and n factor of x = 2
o
Since X is converted into single e species Hence X is Li2+ and light radiation of 114 A
corresponds to 108.77 eV.
e is excited into 3rd energy level and total 3 transitions are possible.
6
Mathematics
PART III
SECTION A
1.
f(x) = x 2 x
3
2
4 x
x
1
1
f(x) = x
3 x
4 x
2
x
x
x
1
Let x
= t (x > 0)
x
3
2
Let g(t) = t 3t 4t + 8
3
2
Now g(t) = t 4t 3t + 8 where t [2, )
g'(t) = 3t2 8t 3 = (t 3)(3t + 1); g'(t) = 0 t = 3 (t 1/3)
g''(t) = 6t 8
g''(3) = 10 > 0 g(3) is minimum
g(3) = 27 9 36 + 8 = 10
2010
2.
Substituting lnx = t, we get
2010 ln 2010
1 t
1
du (u = t ln t)
1
dt = 2009
u
t t (ln t)
1
= 2009 ln(2010 ln 2010)

3.
Since, |z1| = |z2| = |z3| = 1 and z1 + z2 + z3 = 0

Triangle ABC is an equilateral triangle
2
1 2 = 2 3 = 3 1 =
3
cos(1 2) + cos(2 3) + cos(3 1) =
3
2
4.
In (0, 2) check for 1, 2, 3, 4, 5, 6 function is not continuous for 4

Hence, (x, y) is (4, 1)
2x3ydy + (1 y2)(x2y2 + y2 1) dx = 0, Let 1 y2 = t 2y dy = dt

3
2
3
2
2 2
2
x dt + t(x (1 t) t) dx = 0 x dt + tx dx t x dx t dx = 0
tdx xdt x 2 1
1
x
2 dx d 1 2 dx
x2(t dx x dt) = t2(x2 + 1) dx
2
t
x
t
x
x
1
x2 1
x c x
(1 y 2 ) c(1 y 2 )
t
x
x
x2 = (x2 1)(1 y2) + xc(1 y2) 0 = x2y2 1 + y2 + xc xcy2
x2y2 = (cx 1)(1 y2)
Integrate
6.
Total number of coordinates in S = 3 4 5 = 60

Total no. of way of selecting two points = 60C2
Now the selection of (x1, y1,z1 ) and (x 2 ,y 2 ,z2 ) should be in such a way that
x1 + x2, y1 + y2 and z1 + z2 are even
Now x1, x2, may be
Favourable points = 5 8 13 = 520
520
52
Probability =
30 59 177
7
7.
Number of ways = total those in which at least three boys between the girls = 17 a
Now, x G1 y G2 z
x + y + z = 15
Min x = 0 max x = 12
Min y = 3 max y = 15
Min z = 0 max z = 12
Total solution = coefficient of x15 in (x0 + .. x12)(x3 + x4 + .. + x15)(x0 + .. + x12)
3
1 x13
12
13 3
3
= .. x12 in (1 + x + .. x 12)3 = .. x12 in
= .. x in (1 x ) (1 x)
1
12 3 1
C2 14 C2
a 14 C2 2 15 ways = 17 91 2 15
8.
Let d makes angle from a, b and c then cos2 + cos2 + cos2 = 1
( a, b, c mutually perpendicular)
1
cos
3

| a b c d |2 | a |2 | b |2 | c |2 | d |2 2(a b a c a d b c b d c d)
= 1 + 1 + 1 + 1 + 2 (0 + 0 + cos + 0 + cos + cos ) = 4 + 6 cos = 4 2 3
9.
The line makes equal angle with planes hence with normal

a n
an
i.e. 1 2
| a || n1 | | a || n2 |
n 2i j 3k,
n i 2j 3k
a k i 2j 12k,
1
2k 2 36
14
10.
k 4 36
14
k 74
f(x) = 12x2 2x 2
= 2[6x2 x 1]
= 2(3x + 1)(2x 1)
1/3
11.
1/2
S1: x2 + y2 4x 81 = 0
S2: x2 + y2 + 24x 81 = 0
S1 S 2 = 0
28x = 0
x = 0 equation of AB
Now let A (0, a) A is on x = 0
Now put A in S1 or S2
0 + a2 + 0 81 = 0
a=9
A = (0, 9), B = (0, 9)
Now PA, y 9 = mx y = mx + 9
BQ, y + 9 = mx y = mx 9
Now let P(x1, y1) and Q(x2, y2)
9m2 24m 9
18m 24
Now solve S1 and PA then x1
and y1
2
m 1
m2 1
9m2 4m 9
18m 4
Now solve S2 and BQ then x 2
and
y
2
m2 1
m2 1
Let mid pt of PQ is (h, k) then x 1 + x2 = 2h and y1 + y2 = 2k
20
x1 x 2 2
2h
m 1
8
h 1
k m
20
20m
2k
2h
2
2
m 1
k
1
h
h(h2 + k2 + 10h) = 0
y1 y 2
12.
For one local max and min f(x) = 0 will have two real and unequal roots
2
2
2
f(x) = 6x 6(2 + )x + 12 D = (2 + ) 8 > 0 ( 2) > 0 R {2}
13
P lies on the line 2x + 3y + 1 = 0

.. (1)
|PA PB| is maximum if P, A, B are collinear.
Equation of the line AB is x + y = 2
.. (2)
P is the point of intersection of (1) and (2) which is (7, 5)
Equation of perpendicular bisector of AB is
y=x
.. (3)
1 1
For minimum value of |PA PB|, P is the point of intersection of (1) and (3) which is ,
5 5
14.
Since x2 3x + 2 is factors of x 4 px2 + q, then roots of x 2 3x + 2 = 0

i.e. 2, 1 are also roots of x4 px2 + q = 0
but if a is roots of x4 px2 + q = 0, then a is also
roots of x4 px2 + q = 0 are 1, 2
and 1 p + q = 0 and 16 4p + q = 0, p = 5 and q = 4
15.
f(x) = ae2x + bex + cx

Since f(0) = a + b i.e. a + b = 1
f(x) = 2ae2x + bex + c
f(log 2) = 2ae2 log 2 + belog 2 + c
= 8a + 2b + c = 8a + 2b + c = 31
n 4
.. (1)
.. (2)
n 4
(ae2x + ex + cx cx) dx =
(ae2x + bex) dx
log 4
ae
a
a
15a
39
a e2 n4
=
bex
=
+ be n 4 b = 8a + 4b
b=
+ 3b =
2
2
2
2
2
2
0
i.e. 15a + 6b = 39
.. (3)
From (1), (2) and (3) we get 9a = 45
a = 5, b = 6 and c = 3
2x
SECTION C
1.
Straight line from Origin is y = mx

3
3m
4x + 2y = 3, y = mx , x1
, y1
(2m 4)
(2m 4)
6
6m
2x + y + 6 = 0, y = mx, x 2
, y2
(m 2)
(m 2)
6m
3mk
6
3k
3k
6
(m 2) 2(m 2)
m 2 2(m 2)
2 0 3 k 6 , k 12 4
O
O
k 1
k 1
k 1
2
3
9
2.
cos1 x + cos1 2x = , cos1 x [0, ]

cos1 x + cos1 2x = no solution
3.
abc = 1, trace A = a + b + c > 0

a2 b2 c 2 ab bc ca ac ab bc
a b c a b c
I = b c a b c a = ab bc ca b2 c 2 a2 bc ca ab
2
2
2
c a b c a b
ca ab bc bc ca ab c a b
a2 + b2 + c2 = 1, ab + bc + ca = 0
(a + b + c)2 = a2 + b2 + c2 + 2(ab + bc + ca) = 1
a+b+c=1
a3 + b3 + c3 = 3abc + (a + b + c) (a2 + b2 + c2 ab bc ca) = 3 + 1(1 0) = 4
4.
f 3 (x) t f 2 (t)dt
.. (1)
Differentiate with respect to x

x
3
3f 2 (x) f '(x) x f 2 (x) f '(x)
x2
C
.. (2)
6
But from (1) f 3(0)= 0 f(0) = 0
x2
62
From (2) C = 0 f(x)
f(6)
6
6
6
f(x)
5.
The line x 3 5 y = 0 and

passes through this point,
5 x 2y = 13 intersect at the point. Since the given hyperbola
(3 5 )2 1
45
1
= 1 or 2 2 = 1
2
2
a
b
a
b
Also length of the latus rectum =

From (1) and (2) we get
.. (1)
2b2
4
=
(given)
a
3
.. (2)
45
3
=1
2
2a
a
15
2
a > 0 therefore we have a = 6
b2 = 4
10
2
2
e =
hence 9e 1 = 10 1 = 9
9
a = 6 or

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1

ALL INDIA TEST SERIES

Optical path length of ray entering through S1

Path difference of ray from S1 and S2 x

Energy of nth state in H-atom is same as energy if 3nth state in Li .

Unit vector in the direction of field, B

Ammeter and 0.9 is in series

VBT and MOT both consider wave nature of e-.

H3PO4 can act as a dehydrating agent.

Hydrocarbon part is hydrophobic part

has maximum CFSE

O is maximum in acidic medium.

has square planar shape

Net all reaction: Mnnc

is optically active but does not show geometrical isomerism.

Substituting lnx = t, we get

= 2009 ln(2010 ln 2010)

Since, |z1| = |z2| = |z3| = 1 and z1 + z2 + z3 = 0

In (0, 2) check for 1, 2, 3, 4, 5, 6 function is not continuous for 4

2x3ydy + (1 y2)(x2y2 + y2 1) dx = 0, Let 1 y2 = t 2y dy = dt

Total number of coordinates in S = 3 4 5 = 60

Let d makes angle from a, b and c then cos2 + cos2 + cos2 = 1

P lies on the line 2x + 3y + 1 = 0

Since x2 3x + 2 is factors of x 4 px2 + q, then roots of x 2 3x + 2 = 0

f(x) = ae2x + bex + cx

Straight line from Origin is y = mx

cos1 x + cos1 2x = , cos1 x [0, ]

abc = 1, trace A = a + b + c > 0

Differentiate with respect to x

3f 2 (x) f '(x) x f 2 (x) f '(x)

The line x 3 5 y = 0 and

5 x 2y = 13 intersect at the point. Since the given hyperbola

Also length of the latus rectum =

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