Maximum Marks : 70
General instruction :
(i) All questions are compulsory.
(ii) Marks for each question are indicated against it.
(iii) Question number 1 to 8are very short answer question and carry 1 mark each.
(iv) Question numbers 9 to 18 are short answer question and carry 2 marks each.
(v) Question numbers 19 to 27 are also short answer question and carry 3 marks each.
(vi) Question numbers 28 to 30 are long answer question and carry 5 marks each.
(vii) Use log tables if necessary, use of calculators is not allowed.
Q1
Which series of lines of the hydrogen spectrum lie in the visible region ?
Q2
What would be the IUPAC name and symbol for the element with atomic number 119 ?
Q3
Q4
Q5
Q7
Name the alkali metal which shows diagonal relationship with magnesium.
Q8
Q9
Q10
Na
CH CH
The mass of an electron is 9.1 10-31 kg. If its K.E. (kinetic energy) is 3 10-25 j. Calculate
its velocity.
Q11
S.C.O. No. 203, SECOND FLOOR, SECTOR 14, PANCHKULA. Phone : 9417655033, 9888019721
Anhy,AlCl3
CH3Cl
(i)
(ii)
+
CH2 + H2O H
CH3
Q12
Q13
1g mixture of CaCO3 and MgCO3 on strong heating gave 0.96g of residue. What is
percentage by mass of CaCO3 and MgCO3 in mixture ?
Q14
Compare the relative stability of the following species on the basis of molecular orbitals
theory and indicate their magnetic properties : O2 , O2
Q15
(a)
CH3
Compare the alkali metals and alkaline earth metals with respect to :
(a) ionization enthalpy
Q18
Q19
Q20
Q21
S.C.O. No. 203, SECOND FLOOR, SECTOR 14, PANCHKULA. Phone : 9417655033, 9888019721
(a) Write the conjugate acids for the Bronsted base NH 2 and HCOO-.
(b) The concentration of hydrogen ion in a sample of soft drink is 3.8 10 -3 M. What is its
pH ? [log 3.8 = 0.5798]
(c) Equilibrium constant for a reaction is 4.0, what will be the equilibrium constant for the
reverse reaction.
Q23
Q24
Q25
Q26
(a) The reaction quotient of a reversible reaction is Q c and the equilibrium constant is Kc.
what do you conclude for the reaction if Qc<Kc ?
(b) State Le Chateliers principle.
(c) What happens to the basic strength of NH4OH in presence of NH4Cl ?
Q27
(a) What type of isomerism is shown by pentane and 2-Methyl butane (isopentane).
(b) Why is an organic compound fused with sodium for testing halogen, nitrogen, sulphur
and phosphorus ?
(c) Write the I.U.P.A.C. name of CH2=CHCH2CH(OH)CH3
Q28
may occur
spontaneously.
OR
(a) For the reaction at 298 K 2A B C H = 400 kj mol-1 and S = 0.2 kj mol-1 K-1
At what temperature will the reaction become spontaneous considering H and S to be
constant over the temperature range.
(b) State first law of thermodynamics.
(c) Give one point to differentiate the following thermodynamic terms :
(i) Extensive properties and intensive properties,
(ii) Isothermal process and isobaric process.
Q30
(ii) B2 H 6 6 NH3
S.C.O. No. 203, SECOND FLOOR, SECTOR 14, PANCHKULA. Phone : 9417655033, 9888019721
(ii) B2 H 6 3O2
S.C.O. No. 203, SECOND FLOOR, SECTOR 14, PANCHKULA. Phone : 9417655033, 9888019721