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XYZ/EHS/OEP/01

Address Of Your Company

ON SITE EMERGENCY PLAN


Month & Year
REVISION -I

Prepared By

Safety Officer
[Names & Signature]

Page 1 of 49

Checked By

Safety Manager

Approved By

Unit Head

XYZ/EHS/OEP/01

INDEX
CHAPTER
NO.

PAGE NO.

TOPIC

PREFACE

PREAMBLE

5 -9

1
Emergency
2
Nature of Emergency
3
Process Description
4
Identification of Hazardous Area
5
Objectives of the Plan
6
Emergency Control Center
7
Assembly Points
8
Codification of Sirens
9
Training
& Education
Training
& Education
10 Mock drill
11 Updating the Plan

EMERGENCY ORGANISATION

KEY PERSONNEL AND THEIR


RESPONSIBILITIES
1
2
3
4
5
6
7

Site Controller
Incident Controller
Personnel / Administrative Manger
Security Officer
Departmental Heads
First Aid team
Factory Fire Squad Personnel

5
5
6
6
7
7
8
8
9
9
9

10

10
11 - 15
11
12
13
13
14
14
15

EMERGENCY ACTION PLAN

16-22

6.

LIST OF ANNEXURES

23-49

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------------------------------

LIST OF ANNEXURES
A.

Brief description of the manufacturing process

B.

Telephone numbers of Police, Fire Brigade, Hospitals & other outside


Emergency Services

C.

Telephone numbers & addresses of Key Personnel

D.

Telephone numbers of MARG members.

E.

List of Fire and Rescue Squad Members

F.

Information on Fire hydrant System

G.

List of fire Extinguisher.

H.

List of Personnel Protective Equipment.

First aid medical facilities.

List of Some hazardous Chemical and action.

Scenario Based Emergency action.

Emergency organization Chart

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------------------------------

CHAPTER 1
PREFACE
1.1 The enclosed On-site Emergency Plan is made for the Bulk drug manufacturing
plant of M/s XYZ Ltd. Plot No: XYZ, MIDC, ___________
1.2

The plant has a manufacturing facility to produce Bulk Drug viz..

1.3

The plant is designed and equipped to handle hazardous chemical and to carry
out various processes and operations on these chemicals. The plant is provided
with Fire Hydrant system, Fire extinguishers and Scrubber system. In addition to
this adequate types and number of Personal Protective Equipement, First Aid
Boxes, Eye washers, Ventilation system has been provided.

1.4

Considering the types of operations carried out in the plant and the nature, extent
of hazards existing, the management of M/s XYZ LTD thought it necessary to
have some system of tackling an emergency.

1.5

The formulation of this document is an outcome of the above thought process.

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CHAPTER 2
PREAMBLE
In spite of various preventive and precautionary measures taken in the plant, the
possibility of a mishap cannot be totally ruled out. Hence, the need to prepare a
Contingency Plan for dealing with incidences which may still occur and are likely to
affect LIFE and / or PROPERTY, both within the plant and in the immediate
neighborhood.
Such an emergency could be the result of malfunction of the Plant & Equipment or nonobservance of operating instructions. It could, at times, be the consequence of acts
outside the control of plant management like severe storm, earthquake, flooding, or
deliberate acts of arson or sabotage.

A Major Emergency in the plant is one that may cause serious injury or loss of life and
damage to the property.
This On Site Emergency Plan (OEP) explains the code of conduct of all personnel in the
plant along with the actions to be carried out in case of an Emergency. This plan gives
the guidelines for employees, contractors, transporters, etc. It not only defines
responsibilities but also informs about prompt rescue operations, evacuations,
rehabilitation, co-ordination and communication.
1.

EMERGENCY:
An Emergency is a situation, which may lead to or cause large-scale damage or
destruction of life, property or environment within or out side the Factory. Such
an unexpected situation may be too difficult to handle

for the normal work force

within the plant.


2.

NATURE OF EMERGENCY:
The emergency specified in the OEP refers to occurrence of one or more of the
following events: -

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a.

Fire/Explosion.

b.

Major accident such as structural or building collapse, overturning of road


tanker containing flammable substances.

3.

c.

Natural calamities like storm, flood, earthquake, etc.,

d.

Sabotage act of terrorism, civil commotion, air raid etc.

PROCESS DESCRIPTION:
A brief description of the Manufacturing Process is given in Annexure A.

4.

IDENTIFICATION OF HAZARDOUS AREAS:

HAZARD

Explosion

AREA

Boilers / Transformers Malfunctioning of the


/ Receivers for the Air Safety Valve
compressors.

Flammable Petroleum
Product Storage Tank
/ Drum Storage
area
Fire

PROBABLE CAUSE OF THE


ACCIDENT

External fire causing


pressure built up in the
tanks / barrels

H.S.D. / FO Storage Flammable vapor / air


Area
mixture and source of
ignition.
Flammable Petroleum Formation on pool in the
Product
Storage dyke wall and source of
Tank / Drum Storage ignition.
Shed /Production Area
External fire Built up of
internal pressure Failure
of the top cover Tank on
Fire

Spillage

.
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Acid / Alkali Storage Spillage of Acid / Alkali due


Area
to rupture of the pipe line,
collapse of the storage tank

XYZ/EHS/OEP/01

5.

OBJECTIVES OF THE PLAN:


a)

To control the emergency, localise it and if possible eliminate it.

b)

To avoid confusion, panic and to handle the emergency with clear cut
actions.

c)

To minimize loss of life and property to the plant as well as to the


neighbourhood.

d)

To make head count and carry out rescue operations.

e)

To treat the injured persons.

f)

To preserve records and to take steps to prevent


recurrence.

g)
6.

To restore normalcy.

EMERGENCY CONTROL CENTRE:


For the purpose of handling emergency, the following Emergency Control
Centres has been identified.

During normal working hours - The Administrative Office

During other times - The Security Office.

All communications to and from will originate at this CONTROL CENTRE. The
Emergency Control Center will have the following: a)

A copy of ON-SITE EMERGENCY PLAN.

b)

List of important telephone numbers such as Police, Fire


Brigade, Hospitals, and other outside Emergency Services, etc.
(Refer Annexure B).

c)

List of key Personnel with addresses and telephone numbers.


(Refer Annexure C).

7.

d)

List of Fire and Rescue Squad Members (Refer Annexure E).

e)

Plant layout indicating storage of hazardous materials

f)

List Fire Extinguisher. (Refer Annexure G).

g)

Fire Fighting System (layout of Fire Hydrants)

h)

List of Personal Protective Equipment (Refer Annexure H)

i)

First Aid box.

ASSEMBLY POINTS

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In case of an EMERGENCY the employees should assemble near the defined


Assembly Points, as indicated below:

Fire Fighters - Area near Security Gate.

First Aiders - Area near Security Gate.

Others - Area near Security Gate.

Wind direction to be determined by the WIND SOCKS installed on top of the


Engineering Building. THE EMPLOYEES SHOULD RUN PERPENDICULAR TO
THE WIND DIRECTION AND NOT AGAINST / ALONG THE WIND DIRECTION.
8.

CODIFICATION OF SIRENS
Sr.
1.

SIRENS
30 SECOND

INDICATES
ON SITE

AUTHORITY
INCIDENT

2.

CONTINUOUS
1 MINUTE

EMERGENCY (ALERT)
EMERGENCY

CONTROLLER
SITE CONTROLLER

CONTINOUS

CONTROLLED
(ALL CLEAR)

NOTE: 1)

EMERGENCY SIREN TO BE SOUNDED ONLY IF REQUIRED

2)

ALL EMPLOYEES IN AREAS OTHER THAN AFFECTED TO CONTINUE


WORK UNLESS DISASTER SIREN IS BLOWN.

3)

NO EMERGENCY ORGANIZATION MEMBER WILL LEAVE THE


EMERGENCY SPOT UNLESS `ALL CLEAR SIREN BLOWN.

------------------------------

9.

TRAINING AND EDUCATION:

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Experience with on site emergency planning has proved the need of training and
rehearsal. Major emergency procedure should be laid down clearly and convincingly to
everyone on site particularly Key Personnel and Essential workers.
It is obvious that in house or outdoor training is essential. The duties and responsibilities
of each person and the emergency procedure to be followed by him should be very
clear.
a. Seminar/refresher guidance On Site Emergency Plan.
b. Emergency instruction Booklet.
Seminar: Seminar is conducted in house/. Site controller will explain the plan to all
associated concerned employees.
Expert from outside explain the plan to all associated concerned employees. Expert
from also may be invited to impart training.
Emergency instruction Booklet:
Emergency instruction Booklet contains all detailed emergency duties. The booklet
contains
Emergency duties,
Reporting relationship.
Thus everyone is conspicuous about his role in the Emergency Plan.

10.

MOCK REHEARSAL:
Inform all the employees about mock drill.
Fix the date for mock drill.
Observers will not be involved in the exercise. They will monitor the Mock drill.
Emergency Siren / alarm will be raised.
After hearing the Siren / alarm, Emergency procedure will be followed as
mentioned in the OEP.
Observer will note down the activities with respect to the time.

11.

UPDATING THE PLAN:

As and when required the On Site Emergency Management plan will be updated. After
each drill the plan will be thoroughly received to take account of shortcoming and
accordingly plan will be updated.

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CHAPTER - 3
EMERGENCY ORGANISATION
Responsibility will be automatically delegated in absence of concern person/s in
following manner.
SITE CONTROLLER:
xyz
INCIDENT CONTROLLER:
DUTY OFFICER ON SUNDAYS/HOLIDAYS
ADVISORY COMMITTEE:
ALL HODs, Sachin K. Thorat
COMMUNICATION COMMITTEE:
P&A DEPARTMENTS

------------------------------

CHAPTER - 4
KEY PERSONNEL & THEIR RESPONSIBILITIES

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Key Personnels Responsibility during normal working hours :1.

Site Controller:
He will retain overall responsibility for the factory and its personnel. As soon as
he is informed of the emergency he shall proceed to the control room and meet
the P&A. Manager. His duties shall be:
i)

Assess the magnitude of the situation and decide if staff needs to be


evacuated from their assembly points.

ii)

Exercise direct operational control over areas other than those affected.

iii)

Maintain a continuous review of possible development and assess in


consultation with Incident Controller and other Key personnel as to whether
shutting down of the plant or any section of the plant and evacuation of
persons is required.

iv)

Liaison with Senior Officials of Police, Fire Brigade, Directorate of Industrial


Safety, provide advice on possible effects on areas outside the factory
premises.

v)

Control rehabilitation of affected areas on discontinuation of emergency.

vi)

Issue authorised statements to news media, and ensure that evidence is


preserved for inquiries to be conducted by statutory authorities.

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2.

Incident Controller:
On hearing of an emergency siren he will rush to the scene of the occurrence
and take overall charge and report to Site Controller. On arrival he will assess
the scale of emergency and decide if major emergency exists or is likely and
inform the Communication Officer accordingly.
(1)

Direct all operations within the affected areas with the priorities for safety of
personnel minimise damage to the plant, property and minimise loss of
materials.

(2)

Pending arrival of Site Controller, assume the duties of his post and, in
particular.

(3)

(a) Direct the shutting down and evacuation of plant and areas likely to be
adversely affected by the emergency.
(b)

(4)

Ensure that all Key personnel and outside help are called in.

Provide advice and information to the Fire squad & Security Officer and the
local fire service as and when they arrive.

(5)

Ensure that all non-essential workers/staff of the areas affected are


evacuated to the appropriate assembly points, and the areas are searched
for casualties.

(6)

In the event of failure of electric supply and internal telephones, set up


communication point and establish contact with Emergency Control Centre.

(7)

Report on all significant developments to the P. & A manager.

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(8)

Have regard to the need for preservation of evidence so as to facilitate any


inquiry into the causes and circumstances, which caused or escalated the
emergency.

3.

Human Resources Manager:


He will also work as liaison Officer and will be stationed at the Main Entrance
(Security Office near Main Gate) during the emergency.

He will under the

direction of the site Controller handle police, press and other inquiries, receive
reports from roll-call leaders from assembly points and pass on the absentee
information to the Incident Controller. His responsibilities shall include (1)

To ensure that casualties receive adequate attention, to arrange additional


help if required and information relatives.

(2)

To control traffic movements into the factory and ensuring that alternative
transport is available when need arises.

(3)

When emergency is prolonged, arrange for the relief of personnel and


organise refreshments / catering facility.

(4)

From information received, advise the Site Controller of the situation,


recommending (if necessary) evacuation of staff from assembly points.

(5)

Recruit suitable staff to act as runners between the Incident Controller and
himself if the telephone and other system of communication fails due to
whatsoever reasons.

(6)

Maintain prior agreed inventory in the control centre.

(7)

In case of prolonged emergency involving risk to outside areas by windblown materials, contact local Meteorological Office to receive early
notification of changes in weather conditions.

4.

Security Officer:
On hearing alarm advise fire squad and security staff in the factory of the incident
zone and cancel the alarm. He will also announce through telephone or
messengers to the HR Manager, Incident Controller and Site Controller that
incident has occurred in such and such zone. He will open the gates nearest to
the incident and stand by to direct the emergency service.

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If told of a large escape of gas he shall inform the Incident Controller by


telephone and stand-by the telephone to receive further messages.
On hearing the emergency alarm, he will immediately contact Site Controller and
on his advice call the local fire brigade. In case fire is discovered but no alarm is
sounding he shall receive information about location from the person discovering
the fire and thereafter immediately consult the Site Incident Controller and make
announcement on telephone telling the staff location of the incident and to
evacuate to their assembly points. He will continue to operate the switchboard
advising the calls connected with the incident to the Communications Officer.
5.

Departmental Heads:
The Departmental head wherein the incident has taken place will report to
Incident Controller and provide assistance as required. They will decide which
members of their staff they require at the scene.

6.

First-aid Teams:
The Personnel Manager shall keep in security the roll call lists for the fire
and first-aid teams on duty. Each Departmental Head for his shift-team
appoints roll call leaders and first aiders. Roll call leaders shall check their
rolls as members of the services report for emergency duty. Names of any
unaccounted for absentees will be informed to the Security Officer.
Members of first-aid Teams will report to the Incident Controller on hearing
of the alarm in day time. The Emergency vehicle driver, if safe to do so,
shall collect the emergency vehicle and park nearest to the scene of the
incident. First aider shall inform the incident controller that the Emergency
Vehicle is leaving the site, giving the name of the patient and destination i.e.
hospital or doctors room and request the Incident Controller to inform the
destination (hospital, etc.) advising them about the casualties reaching
there.

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7. Factory Fire Squad Personnel:


The duty Fire fighting Squad under the command of the Security Officer
shall be responsible for fire fighting and rescue. On hearing the alarm, they
shall proceed to the place of incident. The men at security gate shall find
out the location of the emergency and proceed to the site of the occurrence.
At the incident scene, a team members detailed for this purpose will check
squad members against roll-call sheet. At the site, all the squad members
will respond to the advice and information given by the Incident Controller
On arrival of the local fire brigade, they will also assist in fire-fighting work
with the advice of the Incident Controller.

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CHAPTER - 5
EMERGENCY ACTION PLAN
ANY ONE NOTICING EMERGENCY SITUATION LIKE FIRE, EXPLOSION, TOXIC
GAS LEAKAGE ETC. MUST
DOs

Attract the nearby person/employee by shouting FIRE FIRE FIRE.

Seek help from the persons working nearby.

Try to control the incident at its initial stage with available means/sources quickly.

Inform Shift In-charge / Duty Officer (In Night Shift ) about the Incident.

DONTs

Do not be panicky.

Do not run Walk fast.

INCIDENT CONTROLLER MUST


DOs
A. IF FIRE / OTHER INCIDENTS ARE CONTROLLABLE

Approach the emergency site immediately taking note of wind direction.

Assess the situation.

Inform Security Officer, Tell NAME, TYPE OF INCIDENT, ACTION TAKEN, HELP
NEEDED and Order Security Officer/Guard to inform all KEY persons.

Take lead in controlling emergency until such time concerned Section Manager takes
over the charge.

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DONTS

Do not be panicky.

Do not lose temperament.

B. IF FIRE/OTHR INCIDENTS ARE NOT CONTROLLABLE


In Addition to Above (A)

Order to blow emergency `ALERT Siren (30 second continuous).

Organize Fire fighting / rescue team members to control the Incident.

Take stock of situation if required shut down the plant / process in affected area.

Call Fire Brigade if situation demands.

Evacuate affected area.

Organize head count of the plant.

Act as INCIDENT CONTROLLER till such time senior person takes charges as
indicated in Emergency organisation

NOTE: 1) Messenger will wait until such time Security Officer arrives.
2) Also inform Telephone Operator.
SECURITY OFFICER / GUARD
DOs
Do not allow any vehicle to come inside the factory.
Do not entertain any outside call except for emergency purpose.
Do not allow visitors to move around.
Inform all key persons about location and type of emergency.
Follow this sequence Inform concerned HOD/Section Head, Main Site Controller,
Main Incident Controller & Safety Officer and other KEY persons.
Inform Main Site Controller about Government visitors, if any.
DONTs
Do not entertain any outside call except for emergency purpose.

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Do not allow visitor to move around, from reception.

SECURITY GUARD
DOs

Immediately report at Security Gate in shortest possible time.

Follow instructions of Officer In-charge.

Assist in controlling emergency.

Assist in controlling contractors, vehicle movement and mob.

Assist in cordoning off the area.

Take note of wind direction while approaching emergency site.

Render all possible help for controlling overall situation.

DONTs

Do not leave the site unless asked to do so.

EMERGENCY VEHICLE DRIVER


DOs
Immediately start vehicle and reach rescue squad assembly point (near security
gate).
Rescue squad members to emergency site.
Take vehicle near to emergency site as directed.
Take note of wind direction.
Reverse the emergency vehicle for quick transports of injured, if any.
Keep vehicle engine running.
Always be on Drivers seat of the vehicle.
Take the injured to the hospital as directed.
DONTs
Do not leave the vehicle.
Do not take the vehicle very near to the site.

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INCIDENT CONTROLLER
DOs
Approach emergency site as early as possible taking note of wind direction.
Take stock of situation.
Interact with all concerned departments as the situation demands.
Keep Main Site Controller informed about the latest emergency situation on
continuous basis.
SITE CONTROLLER
DOs
Will approach emergency site immediately / Assess the situation.
Consult Incident Controller.
Consult advising Committee Members.
Instruct Main Incident Controller.
Communicate to higher ups and Govt. authorities, if required.
Decide upon need for evacuation and blow `Disaster Siren.

After getting satisfied with the situation, give instruction to blow ALL CLEAR Siren.

DONTs
Do not instruct to blow ALL CLEAR siren unless the situation is fully under control.
Dont evacuate the entire plant unless the situation demands.

FIRE FIGHTING SQUAD ON HEARING SIREN


DOs

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Inform fellow employees/Officers.

Report to Fire Squad Assembly point.

Find out emergency location.

Approach emergency site immediately.

Take quick action as per the instructions from Incident controller.

Bring emergency under control as early as possible.

DONTs

Do not leave process/equipment in UNSAFE CONDITION.

Do not leave emergency site unless ALL CLEAR siren blown.

Do not use improper fire extinguisher.

Do not be panicky.

RESCUE SQUAD
DOs
Report to assembly point near Gate.
Get in touch with security about location and type of emergency.
Approach emergency site quickly with Breathing Apparatus set and First Aid box.
Get in touch with incident controller.
Follow instructions of Incident controller.
Render first aid to the injured, hospitalize, if required.
Accompany him to hospital and assist Doctor / Nurse.
Search for missing person in that area, if required.
Help in head count.
ALL GENERAL EMPLOYEES EXCEPT THOSE WHO ARE IN EMERGENCY
ORGANIZATION ON HEARING SIREN
DOs
Be alert and be available if required.
Wait for further instructions.

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Bring down the process/plant/equipment in SAFE CONDITION in case of DISASTER


siren as per instructions from Incident Controller.
Approach respective safe assembling points route as taking note of wind direction.
Help in taking roll call.
After hearing ALL CLEAR, go back to the departments.
Start the work again after setting instruction from Incident controller.

DONTs
Do not be panicky. Do not run.
Do not approach emergency site unless asked for.
Do not engage telephone except for emergency purpose. Keep lines free.
TECHNICAL TEAM: ENGINEERING DEPARTMENT / ENVIRONMNET, SAFETY AND
HEALTH DEPARTMENT ON HEARING SIREN
DOs
Be available in Engineering Department at respective location for any help.
Approach emergency site with required with tools and equipments and should work
on instructions of Incident controlle.
Help Incident Controller to provide technical assistance.
Isolate lines, process equipments, if required by Incident Controller.
Provide emergency equipments like Fire Extinguisher, Hoses, etc., if asked by
Incident Controller.
Provide stop gap arrangements as per the requirement of Incident Controller.
Carry out electrical isolation of area as per instructions from Incident Controller.
ADVISORY COMMITTEE (ALL DEPARTMENT HEADS)
DOs
Approach emergency site as early as possible.

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Render advise to Main Incident Controller and Main Site Controller to control
emergency.
COMMUNICATION COMMITTEE (P&A)
DOs
Consult Main Site Controller
Give necessary instructions to security / Telephone Operator.
Give instruction to Security to control traffic / crowd.
Look after injured, communicate with the family members, if situation demands.
Arrange transportation, if required.
DONTs
Do not communicate to any one or brief press without permission of Main Site
Controller.
GENERAL INTRUCTIONS
DOS
Stop work at height. / Stop all hot works.
Stop all vessel entry.
Take note of wind direction.
On hearing Disaster Siren evacuates as per evacuation route without running and
panicky and assembles at respective safe Assembly Points.
DONTs
Do not use telephone except for emergency purpose.
Do not start work at height, vessel entry, hot work unless permit conditions are
verified.
Do not allow unauthorized person to approach emergency site.

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-------------------ANNEXURE A
BRIEF DESCRIPTION OF THE MANUFACTURING PROCESS
BRIEF MANUFACTURING PROCESS OF ---------------------Stage I:
Stage II:
Stage III:
Stage IV:
BRIEF MANUFACTURING PROCESS OF --------------------Stage I:
Stege II:

Stage III:
BRIEF MANUFACTURING PROCESS OF --------Stage I:

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Stage II:

BRIEF MANUFACTURING PROCESS OF -----------------

----------------------------

ANNEXURE B
TELEPHONE NUMBERS OF POLICE, FIRE BRIGADE, HOSPITALS, AND
OTHER OUTSIDE EMERGENCY SERVICES

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POLICE DEPT-

FIRE BRIGADE

M.S.E.B. OFFICE: -

GRAMPANCHAYAT OFFICE :-

HOSPITALS :-

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------------------------------

ANNEXURE C
TELEPHONE NUMBERS AND ADDRESSESOFKEY PERSONNEL
LIST OF KEY PERSONS

NAME

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RESIDENCE TEL. NO.

XYZ/EHS/OEP/01

------------------------------

ANNEXURE D
MUTUAL AID SCHEME MEMBERS
MUTUAL AID RESPONSE GROUP
NAME

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COMPANY

OFFICE PHONE

XYZ/EHS/OEP/01

------------------------------

ANNEXURE E
LIST OF FIRE AND RESCUE SQUAD MEMBERS

FIRE FIGHTING SQUAD

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FIRST AIDER(RESCUE SQUAD)

XYZ/EHS/OEP/01

------------------------------

ANNEXURE F
EMERGENCY CONTROL SYSTEM FIRE HYDRANT SYSTEM
An underground Fire Hydrant System has been installed in the plant with rings around all
blocks to achieve maximum coverage. Water reservoir of 135m3 (Hydrant tank) + 20 m3
(MIDC Storage tank with feed from the MIDC water supply has been provided at highest
point in the plant. Following are the details of the system.
a. Water Reservoir- 135+20 m3.
b. Type of Hazard- Pharamaceutical, Ordinary Hazard.
c. Design Code-TACs Fire Protection Manual.
d. Total no. of Fire Hydrant including landing Values, Watermonitor-19 Nos.
e. Automatic Operation-Jockey pump of 10.8 m3/hrs@70Mhead capacity
with pressure switches.
f.

Stand by arrangement-Diesel Generator with AMF control panel.

g. Nos of Hose Boxes-External-18 nos


h. Nos of Hoses-36
i.

Nos of Nozzles-15 mm bore-17 nos.

j.

Hydrant flexible rill-6 nos.

k. Electric Driven main pump


-No 1

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- 70 M head 38 M3/hour flow at 7 kg./cm2

XYZ/EHS/OEP/01

l.

One Jockey pump provided of capacity 23 m3 /hr 91 M Head.

m. Auto changeover switch operated DG set System ensures that the


hydrant pump is kept working.

--------------------------------------------

ANNEXURE G
FIRE EXTINGUSHER
List of Fire Extinguishers
The company has trained personnel for fire fighting and its intends to improve the fire
fighting skills of their employee by conducting training on Fire fighting. There are 44
portable fire extinguishers, the break-up of which is as under: -

Sr.No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17

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Area

Location

Type
DCP
DCP
DCP
FOAM
DCP
DCP
DCP
DCP
DCP
DCP
FOAM
DCP
DCP
FOAM
DCP
CO2
DCP

Capacity
5 KG
5 KG
5 KG
50 Lit
5 KG
5 KG
5 KG
5 KG
5 KG
5 KG
50 Lit
5 KG
5 KG
50 Lit
5 KG
3.0 KG
5 KG

XYZ/EHS/OEP/01
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35

Sr.No.

Location

36
37
38
39
40
41
42
43
44

CO2
DCP
CO2
CO2
DCP
DCP
FOAM
DCP
CO2
DCP
DCP
CO2
DCP
DCP
DCP
CO2
CO2
DCP

6.5 KG
10 KG
3.0KG
3.0 KG
5 KG
10 KG
50 Lit
5 KG
6.5 KG
5 KG
5 KG
3.0 KG
5 KG
5 KG
5 KG
3.0 KG
3.0 KG
5 KG

Type
CO2
DCP
DCP
DCP
DCP
CO2
FOAM
DCP
DCP

Capacity
3.0 KG
5 KG
5 KG
5 KG
5 KG
3.0 KG
9 KG
5 KG
5 KG

Total Fire Extinguisher:


Sr. No
1

Types of Extinguisher
DCP

CO2

Foam

Sand Buckets: 05 Nos

Page 31 of 49

Total Nos.
29
06
09

XYZ/EHS/OEP/01

------------------------------

ANNEXURE H
LIST OF PERSONAL PROTECTION EQUIPMENT
LIST OF PERSONEL PROTECTIVE EQUIPMENTS
ITEM
Safety Helmet
Safety Goggles
Safety Shoes
PVC Apron
Asbestos Gloves
Rubber Gloves
Eye Wash Fountain
Gum Boots
Cloth Mask
Safety Belt
Organic Vapor Mask
Self Contained Breathing Apparatus

Page 32 of 49

NOS.
100
20
52
05
05
50
05
02
10
04
10
01

XYZ/EHS/OEP/01

ANNEXURE I
FIRST AID MEDICAL FACILITIES.
The company has provided First AID boxes at security office. Following are the
contents of First aid.
1.

Tincture iodine.

2.

Eye wash solution.

3.

Burnol

4.

Soframycin (ointment)

5.

Sterilized cotton wool.

6.

Band-aid.

7.

Antiseptic Solution (Dettol)

8.

Bandage.

9.

Paracetamol tablets.

10.

Iodex.

11.

Pair of scissor.

The company has got its own transport facilities to take the injured to the hospital.
The nearest hospitals are _________________________________

Page 33 of 49

XYZ/EHS/OEP/01

------------------------------

Sr.

Name

Boiling points

No

Flash
points

Methanol

64

11

Explosive limits

TLV

Action to be taken

in

Lower %

Upper

VOL
6

% VOL
36
200

PPM
Use AFFF For
extinguishing fire.

Use SCBA and Othe


2

Toluene

110

1.3

6.8

100

PPE.
Use AFFF For
extinguishing fire.

Use SCBA and Othe


3

MDC

39.8

12

23

50

PPE
Use SCBA and Othe

Ethyl

77

-4

11.5

400

PPE
Use AFFF For

Acetate

extinguishing fire.

Use SCBA and Othe


5

IPA

82

12

12

400

PPE
Use AFFF For
extinguishing fire.

Use SCBA and Othe


6

Ethanol

Page 34 of 49

77

13

3.3

19

PPE
1000 Use AFFF For

XYZ/EHS/OEP/01

extinguishing fire.

Use SCBA and Othe


7

n-Hexane

68

-21

1.1

7.5

50

PPE
Use AFFF For
extinguishing fire.

Use SCBA and Othe


PPE

ANNEXURE J
List of some Hazardous Chemicals and Action

List of some Hazardous Chemicals and Action


Sr

Name

No

DMF

Boiling

Flash

Explosive

TLV

points

points

limits
Lower

in
Upper

VOL
2.2

VOL
15.2

153

58

Action to be taken

PPM

10

Use AFFF For


extinguishing fire.
Use SCBA and

Acetone

56.5

-20

2.5

12.8

500

Other PPE
Use AFFF For
extinguishing fire.
Use SCBA and

10

THF

66

-14

11.8

200

Other PPE
Use AFFF For
extinguishing fire.
Use SCBA and

11

Di-ethyl ether

35

-45

1.9

36

400

Other PPE
Use AFFF For
extinguishing fire.
Use SCBA and
Other PPE

Page 35 of 49

XYZ/EHS/OEP/01

12.

TriethylAmine

90

-9

1.2

10

Use AFFF For


extinguishing fire.
Use SCBA and

13

Dimethylamine 7.4

-6

2.8

14.4

10

Other PPE
Use AFFF For
extinguishing fire.
Use SCBA and
Other PPE

ANNEXURE K
SCENARIO BASED EMERGENCY ACTION
Based on the reactions involved during the production process and the raw
material involved the possible hazards are indentified. The action for the
emergency situation is given.
Product Name

Sr.

Type of Reaction

Critical raw material

Possible Hazards

Action

no
1

Oximination

Methylene chloride

Irritating to eyes, skin

Immediately flush

with burning pain

with large amount of

etching and redness.

water; if inhaled

Gastrointestinal

remove to fresh air.

irritation with nausea,


vomiting and diarrhea,
may cause kidney
damage. CNS
depression, followed
by headache, dizziness,
drowsiness.
Liq. Ammonia

Page 36 of 49

Ammonia vapors are

Immediately flush

highly irritant and

with large amount of

corrosive.

water. Use respiratory

XYZ/EHS/OEP/01

protection.
Hydroxylamine

Harmful if swallowed,

Immediately flush

hydrochloride

inhaled or absorbed

with large amount of

through skin, causes

water to any area of

burn to any area of

contact.

contact.
Triethylamine

Methanol

Corrosive and

Immediately flush

irritating to the eyes,

with large amount of

skin, all living tissues

water to any area of

and respiratory tract.

contact.

Flammable liquid,

Follow fire action in

causes severe eye

case of fire.

irritation, may cause

Immediately flush

blindness if

with large amount of

swallowed; may cause

water to any area of

skin irritation, CNS

contact.

depression, and liver,


kidney damage.
2

Silylation

2-Methoxy propane

Flammable liquid and

Follow Fire action in

vapor may cause flash

case of Fire.

fire, harmful if

Immediately flush

swallowed, inhaled or

with large amount of

absorbed through skin,

water to any area of

causes burn to any area body contact.


of contact.
Hexamethyldisilazane Highly flammable,

Follow Fire action in

corrosive and harmful

case of Fire.

to any area of contact.

Immediately flush
with large amount of
water.

Page 37 of 49

Pyridine

Irritant to eyes and

Immediately flush

hydrobromide

skin.

with large amount of

XYZ/EHS/OEP/01

water.
Toluene

Keep away from heat

Follow Fire action in

and ignition source;

case of Fire.

harmful if swallowed,

Immediately flush

inhaled or absorbed

with large amount of

through skin; causes

water.

burns to any area of


contact.
Sodium carbonate

May cause eye burn;

Immediately flush

irritation to skin and

with large amount of

respiratory tract;

water.

harmful if swallowed
3

Methylation

Methyl iodide

or inhaled.
Potentially fatal if

If breathing is difficult

inhaled; harmful if

oxygen should be

swallowed, respiratory

administered by

tract irritation, skin

qualified personal and

irritation, eyes

wash with water if

irritation and CNS

contact with skin and

depression.

eyes.
Immediately flush

Dimethylsulfoxide

Corrosive and

with large amount of

irritating to the eyes

water.

and skin, all living


tissues and respiratory
tract.

Follow Fire action in

Dimethylamine

Extremely flammable

case of Fire.

(40%)

liquid and vapor may

Immediately flush

cause flash fire,

with large amount of

harmful if swallowed,

water.

inhaled or absorbed
through skin, causes
burn to any area of
contact.

Page 38 of 49

Immediately flush

XYZ/EHS/OEP/01

Potassium hydroxide

May causes burn to the

with large amount of

eyes, skin, respiratory

water.

and gastrointestinal
4

Deprotection

Sodium bisulfite

tract.
Harmful if swallowed,

If swallowed, induce

may cause irritation.

vomiting immediately
after giving two glass
of water.
Immediately flush
with large amount of
water.

Formic acid

Corrosive and

Immediately flush

irritating to the eyes,

with large amount of

skin, all living tissues

water.

and respiratory tract.


Ethanol

Flammable liquid

Follow fire action in


case of fire.

Sodium Hydroxide

May causes burn to the

Immediately flush

eyes, skin, respiratory

with large amount of

and gastrointestinal

water.

tract.
2. Product Name

Sr.

Type of

Critical raw

no
1

Reaction
material
Cycloalkylation 1,3dibromopropane

Possible Hazards

Action

Flammable liquid and

Follow Fire action in case

vapor; harmful if

of Fire. Remove to fresh

swallowed or inhaled;

air; If not breathing give

affects CNS; causes

artificial respiration; if it

irritation to skin, eyes

is difficult give oxygen.

and respiratory tract.

Give large amount of


water to drink.

DMSO

Page 39 of 49

Corrosive and irritating

Immediately flush with

to the eyes and skin, all

water.

living tissues and

Immediately flush with

XYZ/EHS/OEP/01

respiratory tract.

large amount of water to


any area of contact.

Toluene

Keep away from heat

Follow Fire action in case

and ignition source;

of Fire. Immediately flush

harmful if swallowed,

with large amount of

inhaled or absorbed

water.

through skin; causes


burns to any area of
contact.
Methylene

Irritating to eyes, skin

Immediately flush with

chloride

with burning pain

large amount of water; if

etching and redness.

inhaled remove to fresh

Gastrointestinal

air.

irritation with nausea,


vomiting and diarrhea,
may cause kidney
damage. CNS
depression, followed by
headache, dizziness,
drowsiness.

4-Chloro

Hazardous in case of

Immediately flush with

phenylacetonitrile

skin contact, eye contact

plenty of water. If inhaled

or inhalation, severe

remove to fresh air. If not

exposure can result in

breathing give artificial

death.

respiration.

Tandem

Bromomethyl

Flammable liquid and

Follow Fire action in case

Grignard

propane

vapor; harmful if

of Fire. Remove to fresh

swallowed or inhaled;

air; If not breathing give

affects CNS; causes

artificial respiration; if it

irritation to skin, eyes

is difficult give oxygen.

and respiratory tract.

Give large amount of

reduction

water to drink.
Magnesium metal

Page 40 of 49

Highly inflammable,

Follow fire action in case

XYZ/EHS/OEP/01

and harmful if

of fire. Immediately flush

swallowed or inhaled.

with large amount of

Irritating to eyes, nose,

water.

throat, skin and CNS;


over exposure to the
vapor may cause
headache, drowsiness.
Isopropyl alcohol

Flammable liquid;

Follow fire action in case

harmful if swallowed or

of fire. Immediately flush

inhaled. Irritating to

with large amount of

eyes, nose, throat, skin

water.

and CNS; over exposure


to the vapor may cause
headache, drowsiness.
Tetrahydrofuran

Keep away from heat

Follow Fire action in case

and ignition source;

of Fire. Immediately flush

harmful if swallowed,

with large amount of

inhaled or absorbed

water.

through skin; causes


burns to any area of
contact.
Ethyl acetate

Flammable liquid and

Follow Fire action in case

vapor. Harmful if

of Fire. Remove to fresh

swallowed or inhaled.

air; If not breathing give

Affects CNS; causes

artificial respiration; if it

irritation to skin, eyes

is difficult give oxygen.

and respiratory tract.

Give large amount of


water to drink.
Immediately flush with
water.

Page 41 of 49

Sodium

Highly flammable,

In case of skin, eyes

borohydride

toxic, contact with water

contact flush with copious

liberate flammable

amount of water. Follow

gases. Toxic in contact

fire action in case of fire.

XYZ/EHS/OEP/01

with skin and if


swallowed, very toxic
by inhalation; causes
burns and react violently
with water.
Hexane

Flammable liquid;

Follow fire action in case

harmful if swallowed or

of fire. Immediately flush

inhaled. Irritating to

with large amount of

eyes, nose, throat, skin

water.

and CNS; over exposure


to the vapor may cause
3

Methylation

Formic acid

headache, drowsiness.
Corrosive and irritating

Immediately flush with

to the eyes, skin, all

large amount of water.

living tissue and


respiratory tract.
Formaldehyde

Poison, danger; suspect

Follow Fire action in case

cancer hazard; may

of Fire. Remove to fresh

cause cancer; vapor

air; If not breathing give

harmful if inhaled or

artificial respiration; if it

absorbed through skin.

is difficult give oxygen.

Causes irritation to skin,

Give large amount of

eyes, and respiratory

water to drink.

tract; Strong sensitizer,

Immediately flush with

causes blindness if

water.

swallowed; flammable
liquid and vapor.
IPA. HCl

Flammable liquid;

Follow fire action in case

harmful if swallowed or

of fire. Immediately flush

inhaled. Irritating to

with large amount of

eyes, nose, throat, skin

water.

and CNS; over exposure


to the vapor may cause
headache, drowsiness.

Page 42 of 49

XYZ/EHS/OEP/01

3. Product Name
Sr.

Type of Reaction

Critical raw

Possible Hazards

Action

no
1

Cyanation

material
2,3-Dichloro

Corrosive

In case of contact wash

benzoyl

off immediately with

chloride

water.

Cuprous

Poison; Danger; may be

A cyanide antidot kit

cyanide

fatal if swallowed,

should be available in

inhaled or absorbed

any cyanide work area.

through skin. Contact

In case of cyanide

with acid liberates

poisoning start first air

poisonous gas; causes

treatment and flush

severe eye irritation and

skin with plenty of

possible burn. Affect

water.

blood, cardiovascular
system, CNS and thyroid.
Acetonitrile

Keep away from heat and

Follow Fire action in

ignition source; harmful if case of Fire.


swallowed, inhaled or

Immediately flush with

absorbed through skin;

large amount of water.

causes burns to any area


of contact.
Toluene

Keep away from heat and

Follow Fire action in

ignition source; harmful if case of Fire.


swallowed, inhaled or

Immediately flush with

absorbed through skin;

large amount of water.

causes burns to any area


of contact.
Hexane

Page 43 of 49

Flammable liquid;

Follow fire action in

harmful if swallowed or

case of fire.

inhaled. Irritating to eyes,

Immediately flush with

XYZ/EHS/OEP/01

nose, throat, skin and

large amount of water.

CNS; over exposure to


the vapor may cause
2

Condensation and

Sulfuric acid

cyclisation

headache, drowsiness.
Vapor may cause pulm

Remove to fresh air,

irritation and eye

Resuscitate if not

irritation; severe chem.

breathing; flush with

burn to eyes and skin

plenty of water.

4. Product Name
Sr.
no
1

Type of Reaction

Critical raw

Possible Hazards

Action

Dehydroiodination

material
Iodine

Vapor severely irritate and

Follow Fire action in

can burn mucous membrane

case of Fire. Remove

and respiratory tract; excess

to fresh air; If not

tears, tightness in chest,

breathing give artificial

headache; inflammation of

respiration; if it is

the nasal mucous, bronchitis,

difficult give oxygen.

rapid heart beat, diarrhea and

Give large amount of

wt. loss.

water to drink.
Immediately flush with
water. Iodine stains can
be removed by
immediate washing
skin by 5% sodium
thiosulphate solution.

Pyridine

Irritation of eyes, skin,

Inhalation remove to

respiratory tract, chest pain,

fresh air, Resuscitate if

difficulty in breathing, CNS

not breathing; flush

effects like headache,

with plenty of water.

dizziness, nausea and


vomiting, redness or burns of
eyes/skin lever or kidney
damage.
Methanol
Page 44 of 49

Flammable liquid, causes

Follow fire action in

XYZ/EHS/OEP/01

severe eye irritation, may

case of fire.

cause blindness if swallowed;

Immediately flush with

may cause skin irritation,

large amount of water

CNS depression, and liver,

to any area of contact.

kidney damage.
HCl

Poison; danger; corrosive

Remove to fresh air. If

liquid and mist cause severe

not breathing give

burns to all body tissue; may

artificial respiration; if

be fatal if swallowed or

it is difficult give

inhaled. Inhalation may cause

oxygen. Do not induce

lung damage. Extreme heat of vomiting. Give large


contact with metal can

amount of water to

release flammable hydrogen

drink. In case of

gas.

contact, immediately
flush with plenty of
water. Follow fire
action in case of fire.

Sulfuric

Vapor may cause pulm

Remove to fresh air,

acid

irritation and eye irritation;

Resuscitate if not

severe chem. burn to eyes

breathing; flush with

and skin.

plenty of water.

Sodium

Inhalation, irritation to

Flush with plenty of

thiosulphate

mucous membrane, mild

water.

irritation of eyes and skin.


Sodium

May causes burn to the eyes,

Immediately flush with

hydroxide

skin, respiratory and

large amount of water.

gastrointestinal tract.
Hesperidin

May cause skin and eye

Immediately flush with

irritation; may cause

large amount of water

respiratory and digestive tract


irritation.
5. Product Name
Sr. Type of

Critical raw

no

material

Reaction

Page 45 of 49

Possible Hazards

Action

XYZ/EHS/OEP/01

Condensation

Methanol

Flammable liquid, causes severe

Follow fire action in

eye irritation, may cause

case of fire.

blindness if swallowed; may

Immediately flush with

cause skin irritation, CNS

large amount of water

depression, and liver, kidney

to any area of contact.

damage.
Dimethyl
Formamide

Poison; danger, combustible;

Inhalation remove to

may be fatal if swallowed;

fresh air, Resuscitate if

inhaled or absorbed through skin.

not breathing; flush

Keep away from heat, sparks and

with plenty of water.

flame. Irritation of breathing


vapors.
Acetic acid

Strongly corrosive and causes

Immediately flush with

serious burns. Lachrymator; may

plenty of water.

cause irritation to eyes, skin and

Remove from exposure

respiratory tract.

and move to fresh air.


If breathing is difficult,
give oxygen.

Hydrochloric
acid

Poison; danger; corrosive liquid

Remove to fresh air. If

and mist cause severe burns to all

not breathing give

body tissue; may be fatal if

artificial respiration; if

swallowed or inhaled. Inhalation

it is difficult give

may cause lung damage. Extreme oxygen. Do not induce


heat of contact with metal can

vomiting. Give large

release flammable hydrogen gas.

amount of water to
drink. In case of
contact, immediately
flush with plenty of
water. Follow fire
action in case of fire.

Toluene

Page 46 of 49

Keep away from heat and

Follow Fire action in

ignition source; harmful if

case of Fire.

swallowed, inhaled or absorbed

Immediately flush with

XYZ/EHS/OEP/01

through skin; causes burns to any

large amount of water.

area of contact.
May cause eye, skin, digestive

Immediately flush with

Chloromethyl

tract irritation, liver and kidney

plenty of water.

aniline

damage

Remove from exposure


and move to fresh air.
If breathing is difficult,
give oxygen.

ANNEXURE L
EMERGENCY ORGANIZATION CHART

Page 47 of 49

XYZ/EHS/OEP/01

Site controller

Incident Controller

Fire
fighting
Squad

Page 48 of 49

First aid

P & .A.

Squad

Dept

Engineering Security
Dept.

EHS Manager

Shift In
charge

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