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Edited by Foxit PDF Editor

Copyright (c) by Foxit Software Company, 2004 - 2007


For Evaluation Only.

Robac
Chemicals

Ref: 08/2003

Contents
Introduction

Dithiocarbamates.

BiDD
CuDD
ZBeD/ZBEC
ZDBC
ZDEC
ZPD
Arbestab Z

Aqueous Dithiocarbamates

SDBC
SDEC
SDMC
Robosol
Robactivator

Activated Dithiocarbamates..

ZDBCX

Antioxidant Dithiocarbamates..

Arbestab N
NDBC
NiDD
ZDBC
Arbestab Z
NiDIBUD

Thiurams.

10

P25
TBZTD
TBUT
TETD
TMTD
TMTM
PTD

Thioureas

12

22 (ETU) PM
DETU
LATU
TRIBTU
DBTU

Xanthogens

14

AS100
ZIX
DIXD

Special Products..

14

Delta
Robosol
Robactivator

Robac PM Polymer Masterbatch Range.

16

Blowing Agents.

16

Chemicals for the Plastic Industry..

18

Applications in Rubber & Plastic.

19

Applications in Automotive & Engineering Sectors

20

Applications in Personal Protective Equipment & Consumer Products

21

Robinson Brothers Company Activities.

22

The Robac range of polymer chemicals and


masterbatch (PM) products is listed in the
following pages. The Masterbatch (PM) range
is comprehensive with customer specific
vulcanising mixtures available.
Specific customer requests for Chemicals not
listed in these pages will also be considered.
Pre-weighing to customer requirements may be
a further option.
Low Nitrosamine vulcanisation systems are
available as preformulated blends.

For Latex:

Arbestab Z Robac ZBeD


Robac ZIX
Robac AS100
Robosol
Robactivator
Arbestab 35% dispersion
Robac AS100 60% emulsion

For Dry Rubber: Robac AS100


Robac ZBeD PM70
Robac MBTS PM
Arbestab Z PM
Arbestab N
SAA30 PM50
Robac MBT PM, ZMBT PM, CBS PM, TBBS
PM, DPG PM, DOTG PM and TBZTD PM may
also be used in dry rubber systems. Arbestab
N PM may be considered as a low nitrosamine
antidegradent for certain polymers.
Customers are invited to request specific
Technical Booklets on the highlighted topics see index page.
In addition to our activities in the Polymer-area,
Robinson Brothers has particular expertise with
the synthesis of pharmaceutical intermediates.
This encompasses functions of the company
from marketing, research and development,
pilot plant trials, analytical method development
and production.
This expertise is applied to the Polymer
Chemicals business where there is an
emphasis on finding novel, cost effective
solutions to both application and legislative
problems.
Current related areas include Polymer
Chemicals being used in medical devices,
feeding systems and toys with further products
under development.
Sustainability issues are being addressed with
low temperature cure systems and heavy metal
reductions.

-3-

Introduction

Safe and Non nitrosatable chemicals suitable


for customers to prepare their own systems
include:

Chemical
Molecular Weight

CH3

S
N C

S Bi

CH3

Trade Name
Chemical Name

M.Pt
Relative
Density
Colour

Forms
Available

Packaging
Available

BiDD
Bismuth dimethyl
dithiocarbamate

>300C
2.1
Yellow

Powder
PM75

25kg bag
25kg bag

CuDD
Copper dimethyl
dithiocarbamate

>200C
1.6
Brown

Powder
PM75

25kg bag
25kg bag

C
C

FDA

ZBeD/ZBEC
Zinc dibenzyl
dithiocarbamate

180C
1.3
White

Powder
PM70

20kg bag
25kg bag

C
C

FDA
BGA

ZDBC
Zinc dibutyl
dithiocarbamate

105C
1.2
White

Powder
O/T Powder
PM 75

20kg bag
20kg bag
25kg bag

C
C
C

FDA
BGA

ZDEC
Zinc diethyl
dithiocarbamate

175C
1.5
White

Powder
O/T Powder
PM 75

20kg bag
20kg bag
25kg bag

C
C
C

FDA
BGA

ZPD
Zinc
pentamethylene
dithiocarbamate

220C
1.6
White

Powder

25kg bag

BGA

Arbestab Z
Zinc di-isononyl
dithiocarbamate

74C
0.9
White

Powder
PM75

25kg bag

C
C

Registered
Approval

570

CH3

Dithiocarbamates

N C

S Cu

CH3

304

CH2 S
N C

S Zn

CH2

610

C4H9

S
N C

C4H9

Zn
2

474

C2H5

S
N C

C2H5

Zn
2

362

S
N C

S Zn
2

386

C9H19

S
N C

C9H19

Zn
2

755

-6-

Description

Safe-processing secondary accelerator for use in black and dark colours.


Fast at high vulcanisation temperatures.
Used in SBR C>V> extrusions.

Safe-processing secondary accelerator. Can be used as primary in latex.


High resistance to hydrolysis; low solubility in rubbers.
Fast at higher vulcanisation temperatures.
Recognised to have low nitrosamine potential.
Used in sheeting, extrusions and latex.
Used in NR, IIR, SBR and EPDM.
Widely used active secondary accelerator for dry rubber.
Can be used as a primary accelerator in latex.
Will prevulcanise latex; gives high modulus and transparency.
High solubility in rubbers.
Used in IRP and latex industry.
Used in NR, SBR, NBR, IIR, EPDM.
Much used active secondary accelerator.
Can act as primary in latex.
Will prevulcanise latex.
Used in IRP mouldings and extrusions and in latex compounds.
Used in NR, SBR, NBR, EPDM.

Safer processing secondary accelerator.


Imparts good shelf life to dry rubber and latex compounds.
Used in latex, IRP moulding and both moulded and d.v. footwear.
Used in NR, SBR and latex.

Long chain dithiocarbamate, readily soluble in hydrocarbon polymers.


Recognised to have low potential for nitrosamine generation.
Maintains light colour, particularly in gum stocks.
Will prevulcanise latex systems.
Used for latex work and as a synergistic secondary in EPDM.
Used in NR, EPDM and NR latex compounds.

-7-

Dithiocarbamates

Safe-processing secondary accelerator.


Fast at high vulcanisation temperatures.
Suited to injection and transfer moulding.
Used in NBR, SBR.

Chemical
Molecular
Weight

Aqueous Dithiocarbamates

C4H9

S
N C S Na

C4H9

Trade Name
Chemical Name

M.Pt
Relative
Density
Colour

Forms
Available

Packaging
Available

SDBC
Sodium dibutyl
dithiocarbamate

Liquid
1.08
(solution)
Yellow/
Green

45%
aqueous
solution

25kg
poly bottles C
C
218kg
drums

SDEC
Sodium diethyl
dithiocarbamate

Liquid
1.08
Pale
Yellow to
Yellow/
Green

22%
aqueous
solution

25kg
S
poly bottles S
218kg
drums

BGA

SDMC
Sodium dimethyl
Dithiocarbamate

Liquid
1.18
Pale
Yellow/
orange to
green

40%
aqueous
solution

C
25kg
poly bottles C
218kg
drums

FDA
BGA

20% active
dispersion

25kg
poly bottle
200kg
C
drum
1000kg IBC

50% active
solution

25kg
poly bottle
200kg
C
drum
1000kg IBC

FDA
BGA

227

C2H5

S
N C S Na

C2H5

225

H3C

S
N C S Na

H3C

179

Robosol

Robactivator

Activated
Dithiocarbamates

Registered
Approval

S
(C4H9)2N C S
(C4H9)2NC S
S

Zn. (C4H9)2NH

ZDBCX
Amine-activated
zinc dibutyl
dithiocarbamate

603

-8-

Liquid
1.09
Brown

Liquid

25kg
C
poly bottles

Fast primary and secondary accelerator in latex.


Can rapidly prevulcanise latex compounds.
Gives light colour and good transparency in unfilled vulcanisates.
Easily added by simple dilution and stirring.
Good solubility in the polymer.
Synergises with TETD to give low modulus compounds from CR latex.
Used in NR, CR latex.
Fast primary and secondary accelerator for latex.
Can prevulcanise latex compounds.
Easily added by simple dilution and stirring.
Has been used to boost cure speed in heavily filled SBR latex compounds.
Used in NR, SBR.

Secondary accelerator for latex.


Can prevulcanise latex compounds.
Easily added by simple dilution and stirring.
Low solubility in the polymer.
Has been used to boost vulcanisation in heavily filled SBR latex.
Used in SBR latex

Safer nitrosamine latex accelerator system.


Applications: NR examination gloves
XNBR examination gloves
SBR and SBR/NR foamed latex applications

Aqueous Dithiocarbamates

Description

Fast primary and secondary accelerator.


Liquid form facilitates use in adhesives, sealants and doughs.
Readily emulsified for use in latex.
Good solubility in polymers.
Synergises strongly with ZIX to vulcanise rubbers at room temperature.
Does not need Zinc oxide to be effective.
Used in NR, SBR, NBR.

-9-

Activated
Dithiocarbamates

Primary thioamine water soluble booster for SNR, NR and XNBR latex.
Used in conjunction with latex.

Chemical
Molecular
Weight

Antioxidant Dithiocarbamates

CH2

H
N
C S

CH2

M.Pt
Relative
Density
Colour

Forms
Available

Packaging
Available

Arbestab N
Nickel
di-isononyl
dithiocarbamate

154C
Green

Powder
PM70 ECO

25kg bag
25kg bag

C
C

NDBC
Nickel dibutyl
dithiocarbamate

85C
1.3
Green

PM75

25kg bag

NiDD
Nickel dimethyl
dithiocarbamate

>330C
1.7
Green

PM75 ECO
PM75

25kg bag

ZDBC
Zinc dibutyl
dithiocarbamate

>105C
1.2
White

Powder
O/T Powder
PM75

25kg bag
25kg bag
25kg bag

C
C
C

Arbestab Z
Zinc di-isononyl
dithiobarbamate

74C
0.9
White

Powder
PM75

25kg bag

C
C

Powder
PM70 ECO

25kg bag

Trade Name
Chemical Name

N
H

Registered
Approval

748

C4H9

S
N

S Ni

C4H9

467

CH3

S
N

S Ni

CH3

299

C4H9

S
N

S Zn

C4H9

474

C9H19
N

S
C

S Zn

C9H19

755

(CH3)2CHCH2 S
N
(CH3)2CHCH2

S Ni
2

NiDIBUD
Nickel di-isobutyl
dithiocarbamate

467

- 10 -

FDA
BGA

Long chain dithiocarbamate with powerful antioxidant properties.


High solubility in hydrocarbon polymers.
Protects against heat and UV degradation.
Potentially low safer nitrosamine generation.
Used in cables, hose, under-bonnet applications.
Used in CR, ECO, NBR, EPDM/EP (peroxide and sulphur cured) and in polyolefins.
Powerful antioxidant in rubber and polyolefin systems.
Good solubility in rubbers.
Protects against thermal and UV degradation.
Used in cables and polyolefins and has been recommended as an anti-glaze additive for
NBR rollers.
Used in CSM, CR, ECO, EPDM, NBR and polyolefins.
Antioxidant for synthetic rubbers.
Low solubility in hydrocarbon polymers.
Resistant to extraction by oils and fuels.
Protects against thermal degradation.
Used in cables and I.R.P.
Used in CR, EPDM, NBR, ECO.
Good antioxidant for NR adhesives and certain T.P.Es.
High solubility in hydrocarbon polymers.
Resistant to extraction by oils and fuels.
Protects against thermal degradation.
Suitable for white and clear compounds.

Good antioxidant in adhesives, polyolefins and certain T.P.E.s.


Protects against degradation in high temperature melt processes.
High solubility in polymers.
Maintains good colour on ageing.

Antioxidant for synthetic rubbers.


Good solubility in rubbers.
Protects against thermal and UV degradation.
Low, potentially safer nitrosamine generation.
Used in CSM, CR, ECO, NBR, EPDM/EP, NBR

- 11 -

Antioxidant Dithiocarbamates

Description

Chemical
Molecular
Weight

S
N C Sx
2

CH2 S
N C S
CH2
2

Trade Name
Chemical Name

M.Pt
Relative
Density
Colour

Forms
Available

Packaging
Available

P25 (DPTT)
Dipentamethylene
thiuram tetra/
hexasulphide

115C
1.5
Cream
to beige

Powder
O/T Powder
PM70
PM75

25kg bag
25kg bag
25kg bag
25kg bag

C
C
C
C

TBZTD
Tetrabenzyl
thiuram disulphde

124C
1.4
White

Powder
O/T Powder
PM70

25kg bag
25kg bag
25kg bag

S
S
S

TBUT
Tetrabutyl thiuram
disulphide

Liquid*
1.1
Brown

Liquid
60% active
powder

TETD
Tetraethyl thiuram
disulphide

65C
1.3
White to
off white

Powder
PM75

25kg bag
25kg bag

C
C

FDA
BGA

138C
1.3
White to
off white

Powder
O/T Powder
Pellet
PM75

25kg bag
25kg bag
25kg bag
25kg bag

C
C
C
C

FDA
BGA

TMTM
Tetramethyl
thiuram
monosulphide

105C
1.4
Yellow

Powder
PM25

25kg bag
25kg bag

C
C

FDA
BGA

PTD
Dipentamethylene
thiuram disulphide

120C
1.35
Cream

Powder
PM

25kg bag
25kg bag

C
S

Registered
Approval

FDA
BGA

Thiurams

545

C4H9

S
N C S

C4H9

25kg bottle C
25kg bag C

409

C2H5

S
N C S

C2H5

296

CH3

TMTD
Tetramethyl
thiuram disulphide

N C S
CH3

240

CH3

S
N C

CH3

208

S
N C S2
2

385

- 12 -

Description

Powerful primary and secondary accelerator.


Will vulcanise rubber in the absence of elemental sulphur.
Effective at low and high temperatures.
Used in cables, IRP mouldings, extrusions and latex.
Used in NR, SBR, EPDM, NBR, CSM, IIR.

Liquid secondary accelerator, very soluble in hydrocarbon polymers.


Low activity as a vulcanising agent.
Used as a vital constituent in soluble e.v. systems (MRPRA Publications).
Used in NR.
*Solid/Liquid at ambient temperature - refer to specification.
Useful secondary accelerator, more soluble in rubber than TMTD.
Will act as a vulcanising agent but less active than TMTD.
Synergises with SDBC to give fast low modulus systems for CR latex.
Used in IRP.
Used in CR, NR, NBR, EPDM, SBR.

General purpose secondary accelerator.


Will vulcanise rubber in the absence of elemental sulphur.
Retarder in CR vulcanisation.
Widely used in tyre and IRP.
Used in NR, SBR, IIR, NBR, EPDM.
General purpose secondary accelerator, much safer-processing than TMTD.
Will not vulcanise rubber in the absence of elemental sulphur.
Used in tyres and IRP.
Used in NR, SBR, NBR.
Used in mercaptan-modified CR, along with DOTG and sulphur in circumstances where
ETU is not acceptable.

Primary and secondary accelerator


Heat resistant compounds and pharmaceutical closures
Used: NR, IIR, Natural Latex

- 13 -

Thiurams

Less active secondary accelerator.


Very low activity as a vulcanising agent.
Synergises in blended vulcanisation systems.
Low potential for nitrosamine generation.
May partially replace TMTD where nitrosamines are a sensitive issue.

Chemical
Molecular
Weight

CH2

H
N
C S

CH2

N
H

Trade Name
Chemical Name

M.Pt
Relative
Density
Colour

Forms
Available

Packaging
Available

22 (ETU) PM
Ethylene thiourea
2-Mercaptoimidazoline

195C
1.3
White to
off white

PM only

25kg bag

74C
1.1
White

Powder
flake
PM

25kg bag
25kg bag
25kg bag

S
C
C

LATU
Liquid Dialkyl
thiourea

Viscous
Liquid
1.0
Pale
brown to
Pale
Green

Liquid only

25kg

TRIBTU
1,1,3 Tributyl
thiourea

Liquid
0.94
Brown

Liquid only

65C
Off white

Powder

Registered
Approval

102

C4H9

H
N
C S

C4H9

N
H

DETU
Diethyl thiourea

132

Thioureas

Generalised
C2H5

H
N
C S

C4H9

N
H

160

C4H9

H
N
C S

C4H9

N
C4H9

Quadritainers

20kg drums C

244

C4H9

H
N
C S

C4H9

N
H

DBTU
Dibutyl thiourea

188

- 14 -

25kg bag

Description

The most widely used general purpose accelerator for CR.


Medium speed of vulcanisation.
Good compression set and general physical properties.
Can activate thiazoles strongly in sulphur vulcanisation.
Used in general purpose moulding and extrusion compounds.
Used in CR, ECO.

Active liquid thiourea.


Readily incorporated into adhesive formulations.
Medium speed in vulcanisation.
Used in adhesives and doughs.
Used in CR.

Useful non-staining antiozonant for unsaturated rubbers.


Will act as a slow accelerator for the vulcanisation of CR.
Used in certain tyre sidewalls, footwear etc.
Used in NR, SBR, NBR.

An active thiourea, which is a very fast accelerator for mercaptan modified


polychloroprene. .Also acts as an anticorrosive agent.

- 15 -

Thioureas

The most active thiourea for the vulcanisation of CR.


Gives rapid vulcanisation at low, medium and high temperatures.
Can be used to boost EPDM sulphur vulcanisation systems.
Particularly suited to high speed c.v processes.
Used in CR.
Also acts as corrosive inhibitor for mild and stainless steel treatments.

Xanthogens

Chemical
Molecular
Weight

CH3

Trade Name
Chemical Name

H C O C S

CH3

AS100
Di-isopropyl
xanthogen
polysulphide

M.Pt
Relative
Density
Colour

Liquid
1.3
Amber

Forms
Available

Packaging
Available

Liquid

25kg poly
bottles

PM40

25kg bag

10%
emulsion

334

CH3

ZIX
Zinc isopropyl
xanthate

H C O C S
CH3

Zn
2

Registered
Approval

25kg poly
bottles
C
200kg drum

149C
1.5
White

OTD
Powder
only

25kg bag

DIXD
Di-isopropyl
xanthogen
disulphide

54%
Yellow

Granuals

25kg bag

Delta
Activated
dithiocarbamate

N/A
2.0
Green

PM only

25kg bag

336

CH3

H C O C S
CH3

Special Products

270

N/A

20% active
dispersion

Robosol

25kg
poly bottle
200kg drum

1000kg IBC
25kg
poly bottle
50% active
dispersion

Robactivator

200kg drum C
1000kg IBC

- 16 -

FDA

BDA

Fast primary and secondary accelerator for unsaturated polymers.


Nitrogen-free in its structure. Very soluble in polymers.
May be used to formulate nil/low nitrosamine vulcanising systems.
Can be used to boost vulcanisation in synthetic rubbers.
Is a sulphur donor but is best used with low levels of elemental sulphur.
Used in moulding and extrusion compounds.
Used in NR, NBR, EPDM.
Active secondary accelerator.
Synergises strongly with AS100 in low nitrosamine systems.
Synergises strongly with dithiocarbamates and activated dithiocarbamates to give fast
vulcanisation at room temperature.
ZDBCX/ZIX may be regarded as the most active system for low temperature vulcanisation.
Boosts MBT in latex vulcanisation.
Used in adhesives and coatings. Used in NR, NBR.

Xanthogens

Description

Active boost for use in EPDM vulcanisation.


All ingredients have LD50 in excess of 2000mg/kilo.
May discolour white and light colours. Best in black and dark colours.
Used in high temperature cv systems.
Used in SBR, NBR, EPDM.
Safer nitrosamine latex accelerator system.
Applications: NR examination gloves
XNBR examination gloves
SBR and SBR/NR foamed latex applications

Primary thioamine water soluble booster for SBR, NR and XNBR latIces.
Used in conjunction with Robosol.

- 17 -

Special Products

Main use in polymerisation modifiers


Stabilisation for hypalon (CSM) polymer
Secondary accelerator
Anti oxidant for oils

Composition of Active Chemical

BiDD

Bismuth dimethyl dithiocarbamate

CBS

N-Cyclohexyl-2-benzthiazole sulphenamide

CuDD

Binder

PM Activity

Robac PM Polymer Masterbatch Range


Blowing
Agents

Trade
Name

Packs

EP

75 25kg bag

EP,NBR

75 25kg bag

Copper dimethyl dithiocarbamate

EP

75 25kg bag

Delta

Proprietary activated dithiocarbamate

EP

80 25kg bag

DETU

Diethyl thiourea

EP

75 25kg bag

DOTG

Di-o-tolyl guanidine

EP

70 25kg bag

DPG

Diphenyl guanidine

EP

75 25kg bag

DTDM

4,4-dithiodimorpholine

EP

75 25kg bag

MBT

2-Mercaptobenzthiazole

EP,NBR

75 25kg bag

MBTS

Dibenzthiazyl disulphide

EP,NBR

75 25kg bag

MBS

2-(Morpholinothio) benzthiazole

EP

75 25kg bag

NDBC

Nickel dibutyl dithiocarbamate

EP

75 25kg bag

NiDIBUD

Nickel di-isobutyl dithiocarbamate

ECO

70 25kg bag

NiDD

Nickel dimethyl dithiocarbamate

EP

75 25kg bag

ARBESTAB N

Nickel di-isononyl dithiocarbamate

EP,ECO

70 25kg bag

P25 (DPTT)

Dipentamethylene thiuram tetra/hexa sulphide

EP

70,
25kg bag
75

PVI

N-(cyclohexylthio) phthalimide

EP

75 25kg bag

Sulphur

Sulphur

EP

80 25kg bag

TBBS

N-tertiary butyl-2-benzthiazole sulphenamide

EP

75 25kg bag

TBZTD

Tetrabenzyl thiuram disulphide

EP

70 25kg bag

TETD

Tetraethyl thiuram disulphide

EP

75 25kg bag

TMTD

Tetramethyl thiuram disulphide

EP,NBR

75 25kg bag

TMTM

Tetramethyl thiuram monosulphide

EP

75 25kg bag

ZBED

Zinc dibenzyl dithiocarbamate

EP

75 25kg bag

ZDBC

Zinc dibutyl dithiocarbamate

EP

75 25kg bag

ZDEC

Zinc diethyl dithiocarbamate

EP

75 25kg bag

ARBESTAB Z

Zinc di-isononyl dithiocarbamate

EP

75 25kg bag

ZDMC

Zinc dimethyl dithiocarbamate

EP,NBR

75 25kg bag

ZMBT

Zinc salt of MBT

EP

75 25kg bag

22 (ETU)

Ethylene thiourea

EP

75 25kg bag

Robac AZ04
PM75

Azodicarbonimide

EP Slab

75 25kg box

Robac AZ 2
PM75

Azodicarbonimide

EP Slab

75 25kg box

Robac AZOR
PM75

Azodicarbonimide Formulation

EP Slab

75 25kg box

Robac OBSH
PM75

Diphenyloxide-4,4-disulphonhydrazide

EP Slab

75 25kg box

TSH PM75

p-Toluene sulphonhydrazide

EP Slab

75 25kg box

- 18 -

C6H4NCSSNHC6H11
[(CH3)2NCSS]2Cu

570

2.1

Yellow with orange seed

264

1.2

Blue

304

1.6

Dark brown

1.63

Bright Green

(C2H5NH)2CS

132

1.1

White with brown seed

(C6H4CH3NH)2CNH

239

1.1

White with violet seed

(C6H5NH)2CNH

211

1.2

Violet

[C2H4OC2H4NS]2

136

1.2

White with green/violet seed

C6H4NCSSH

167

1.4

Brown

[C6H4NCSS]2

333

1.5

Green

C6H4NCSSNC2H4OC2H4

252

1.2

Red

[(C4H9)2NCSS]2Ni

467

1.3

Dark Green

[(C4H9)2NCSS]2Ni

467

[(CH3)2NCSS]2Ni

299

[(C9H19)2NCSS]2N

748

[C5H10NCSSS]2

385

1.4

Cream with green seed

C6H4(CO)2NSC6H11

261

1.2

White with grey seed

1.8

Yellow

Dark Green
1.5

Dark Green
Dark Green

C6H4NCSSNHC(CH3)3

238

1.3

Off-white-cream

[(C6H5CH2)2NCSS]2

545

1.4

White

[(C2H5)2NCSS]2

296

1.2

White with orange seed

[(CH3)2NCSS]2

240

1.3

Orange

[(CH3)2NCS]2S

208

1.3

Yellow

[(C6H5CH2)2NCSS]2Zn

610

1.3

White

[(C4H9)2NCSS]2Zn

474

1.2

White with blue seed

[(C2H5)2NCSS]2Zn

362

1.3

White with yellow seed

[(CH3)2NCSS]2Zn

755

0.9

White

[(C4H9)2NCSS]2Zn

306

1.5

White with red seed

[C6H4NCSS]2Zn

398

1.6

Cream with brown seed

[CH2NH)2CS

102

1.2

Off-white

1.28

Yellow

1.3

Yellow

1.25

Yellow

1.2

White

1.15

White

- 19 -

Robac PM Polymer Masterbatch Range

[(CH3)2NCSS]3Bi

Colour Code

Blowing
Agents

Formula

MOL.WT
Relative
Density
of Active
of
PM Form
Chemical

Polymer chemicals for the Rubber and Plastics


industry from Robinson Brothers Ltd. UK.
Robinson Brothers are an Independent Family
Owned company established in 1869.
ISO 9001:2000 and 14001 accredited.
We offer a technical hands on Service
Web Site www.robac.co.uk

Chemicals for The Plastics Industry

Product

Form

Functions

Advantages

Arbestab Z

Powder
Free Flowing crystal

Extremely effective high temperature


processing stabiliser and thermal anti-oxidant,
combined with effective light stabilisation
properties. Will replace hindered phenols, and
synergises (improves) traditional systems

Exceptional Antioxidant even at


low levels (0.1-0.3%). Does not
cause discolouration. High
Thermal Stability, low volatility, non
toxic.

Arbestab N

Powder
70% PM ECO

Thermal stabiliser for PVC/NBR, EPDM,ECO,CR


Exceptionally effective photostabliser.
Outstanding for its ability to UV protect
polymers in presence of flame retarders and
when exposed to pesticidal chemicals.
In combination with iron dithiocarbamates
provides a fully controllable photo degradation
system for polyolefinic films.

Effective at low concentrations.

Effective at low concentrations


(0.025-0.1% )

Synergises most effectively with


hydroxybenzophenones.
Improved UV protection over
traditional chemicals in
combination with flame retarders.

FeDD

Powder

Effective photo pro-oxidant (Controllable


degradation). Degrades polyolefinic films in
sunlight

CuDD

Powder and PM

Efficient radical generator under UV conditions. Synergises well with traditional


Effective photo-pro-oxidant and photo curing
systems.
of inks.

TBUT

100% liquid,
60% dry dispersion

Soluble EV, dynamic applications in NR.

SDMC

Aqueous Solution

Chain Stopper. Used in any emulsion process

DIXD

Powder

Molecular weight Control CR, Particularly suited Cost Effective, easily emulsified
to SBR, EDPM and Chloroprene polymerisation

Metone A

Powder

Very Effective photo-pro-oxidant (degrades


Contains no metal ions, works at
plastics in presence of sunlight). Synergises with low concentrations 0.025-0.1%
iron dithiocarbamates to allow controllable
degradation

MUNDA

Powder

Exceptional Chain Transfer activity, giving


excellent control of the process AND the
molecular weight of the polymer. It is well
suited for emulsion polymerisation process

ODM

Liquid

Effective molecular weight modifier and shows Effective at low concentrations


improved chain transfer activity over traditional 0.25-1%. ODM and the polymers
made from it have excellent odour
thiols.
characteristics. Easily emulsified.
Used to protect silver from oxidation (Metal
Can lower processing temperature
Polish)

Acts as a molecular weight regulator AND


Chain Stopper

Issues being worked on at Robinson Brothers Limited


Please talk to us to add your concerns or wishes
Heat and UV stabilisation
UV Degradation
Biodegradable Polymers

Easily Emulsified.

Innovation. for innovators

- 20 -

Cost competitive, Aqueous


Solution

Efficient at low concentrations 0.11%. Low odour and easily


emulsified with both anionic and
cationic surfactants

Product
Arbestab N ECO PM
Arbestab N Powder
Arbestab Z Dispersion
Arbestab Z FF
Arbestab Z Powder
AS100
AS100 Em ulsion
AS100 PM 40
DELTA
DBTU
DETU
DETU PM
LATU
FeDD
Robac P25
Robac P25 PM
Robactivator
Robasol
SAA30 PM 50%
SAA30 Powder
TBUT 100% Liquid
TBUT 60% Powder
TRIBTU
ZDBCX
ZIX
ZPD

NR

IR

SBR

NBR /
PVC

R ubbers
EPDM
CR

ECO

CSM

11R

APPLICATIONS IN RUBBER AND PLASTIC

NBR

NR

ro b in s o n b r o th e rs ltd

CR

A dh es iv e

Polyolefins

O thers

w w w .ro b in so n b ro th e rs .ltd .u k

p h o e n ix s tre e t, w es t b ro m w ic h B 7 0 0 A H

XNBR

Latex

SBR

ZDBCX
ZIX
ZPD

TRIBTU

TBUT 100% Liquid


TBUT 60% Powder

SAA30 PM 50%
SAA30 Dispersion
SAA30 Powder

Robactivator
Robasol

Robac P25
Robac P25 PM

DBTU
DETU
DETU PM
LATU

DELTA

AS100
AS100 Em ulsion
AS100 PM 40

Arbestab Z Dispersion
Arbestab Z FF
Arbestab Z Powder

Arbestab N ECO PM
Arbestab N Powder

Product

Extru ded
Seats

H os es

O R in gs Pro files

Eng in e
M ou nts

Flo or
M ats

B ridg e C om veyor
Seat
Insu latio n
Co m po site B ea ring s System s

APPLICATIONS IN AUTOM OTIVE AND ENGINEERING


SECTORS
Tank
Lin in g

ro b in s o n b r o th e rs ltd

C orrosio n
A dh es iv e R etre ad s
Inh ib itor

w w w .ro b in s on b ro th e rs.ltd .u k

W hite
W all
Trim s

p h o e n ix s tre e t, w es t b ro m w ic h B 7 0 0 A H

Product
Arbestab N ECO PM
Arbestab N Powder
Arbestab Z Dispersion
Arbestab Z FF
Arbestab Z Powder
AS100
AS100 Em ulsion
AS100 PM 40
DELTA
DBTU
DETU
DETU PM
LATU
Robac P25
Robac P25 PM
Robactivator
Robasol
SAA30 PM 50%
SAA30 Powder
TBUT 100% Liquid
TBUT 60% Powder
TRIBTU
ZDBCX
ZIX
ZPD

Exam in ation
G lovers

Surgeo ns
G loves
C on do m s

B ab y Teats /
Soo th ers

Syrin ge
Stopp ers

Tu bing

Fo otw ear

APPLICATIONS IN PERSONAL PROTECTIVE EQUIPM ENT


AND CONSUM ER PRODUCTS
H ou sehold
G loves

ro b in s o n b r o th e rs ltd

w w w .ro b in so n b ro th e rs .ltd .u k

p h o e n ix s tre et, w es t b ro m w ic h B 7 0 0 A H

G arm en t
Elastics

RBL Companay
Activities
RBL have long-established experience in the
environmentally acceptable handling of carbon
disulphide and other reactants which others
could find problematic especially when
handled in multitonne quantities.
Thus carbon disulphide is used in a variety of
thiocarbonylation reactions to manufacture a
range of dithiocarbamates, thiuram sulphides
and alkyl thioureas plus several key
pharmaceutical intermediates.
Similarly
hydrogen sulphide is employed in thiolation
processes to provide thio and mercaptoproducts.
Catalytic reduction processes are another
established area of expertise and our range of
production scale autoclaves is being constantly
expanded in line with customer demands.
Also in place is chiral reductions using
stereospecific catalyst complexes. We are
actively seeking opportunities to develop
further this relatively new area of chemical
synthesis.
Specialised units are available designed to
carry out reactions involving challenging
gaseous reactants such as phosgene as part
of a series of unit operations. Elemental
bromine can be similarly handled in fully
authenticated plant.
Literature descriptive of RBL non-polymer
range of chemicals is available on request.
Custom synthesis is an important part of the
business and enquiries can be assured of a
confidential and thorough assessment of their
proposals.

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