STS IV/MPC/P(I)/QNS
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1. This booklet is your Question Paper containing 69 questions. The booklet has 26 pages.
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Name: .
Enrollment No.:
...............................................
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IIT/STS IV/MPC/P(I) - 1
SEAL
DO NOT BREAK THE SEALS ON THIS BOOKLET, AWAIT INSTRUCTIONS FROM THE INVIGILATOR
INSTRUCTIONS:
PART A : MATHEMATICS
SECTION I
Straight Objective Type
This section contains 6 multiple choice questions numbered 1 to 6. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
2
1. If f(x) = [cos(x + 2) cos (x + 4) cos (x + 3)], where [ ] denotes the greatest integer
3
(B) 0
(D) 1
(C) 2
= x |x|
3. The value of
1
sin
x 12 cos
1
x 12
1
(B)
(C)
(D) 2
(B) an ellipse
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(B)
(C)
(D)
6. A person A draws three cards at random from a pack of 52 cards. After returning
them back and shuffling it another person B draws 3 cards at random. The
chance that their draws contain exactly two common cards is
(A)
50
52
(B)
147
52
(C)
49
52
(D)
49 50
52
SECTION II
Multiple Correct Answer Type
This section contains 4 multiple correct answer(s) type questions numbered 7 to 10.
Each question has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE is/are
correct.
7. (a, b) is a variable point on y = 3x lying between the straight lines 2x + y + 4 = 0,
x + 4y 8 = 0, then
(A) a
(C) a
(B) b
5 13
4
5
6
13
(D) b
12 24
,
5 13
12 12
,
5
13
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25 1 x
10
15
10
4 1x
15
9 1 x
8. A factor of
(A) x
(B) x + 2
is
(C) x + 1
(D) x + 3
x3
9. Let g(x) =
d
dx
log t dt , then
x2
(A) g(0) = 0
(B) g(1) + g
2
(C) g(e) = 9e 4e
10. Let x + y =
=0
(D) g (e) = 9e 8
x, y > 0
Let S (, n) =
r 2 n C x r y n r then, S(1, 5) is
r
r=0
(A) 20x + 5x
(C) 25x + 5x
SECTION III
Reasoning Type
This section contains 4 questions numbered 11 to 14. Each question contains
STATEMENT 1 (Assertion) and STATEMENT 2 (Reason). Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.
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11. Statement 1:
3i
3i
5 i 6 2i
5i
6 2i is real
6
and
Statement 2:
12. Statement 1:
and
Statement 2:
2
2
x2 y2
If x y = 1 (a > b) and
= 1 represent an ellipse and
2
2
2
2
a
b
a
b
a2 b2
a
a2 b2 respectively.
a
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13. Statement 1:
tan B =
3 x2
2x
and
In ABC, tan A + tan B + tan C = tan A tan B tan C
Statement 2:
14. Statement 1:
and
Statement 2:
The period of f(x) + g(x) is the L.C.M of the periods of f(x) and
g(x).
SECTION IV
Linked Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
Paragraph for Question Nos. 15 to 17
A straight line is such that, it is a tangent at A and normal at another point B of
2
curve x = 3t , y = 2t
(B) 2
(C) 3
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3 1
,
2
2
(B)
(C)
3 1
,
2
2
(D)
2 2
3
(B) (1, 0)
(C) (2, 0)
(D) (3, 0)
(B) (0, 1, 3)
(C) (1, 2, 1)
(D) (0, 1, 3)
(B) ( 2/3, 0)
(C) (1, 2)
(D) (2, 3)
20. The point where the line joining the origin and P meets the plane x + y + z = 1 is
1 3
,
4
4
(A) 0,
1 3
,
4 4
(B) 0 ,
(C) 0 ,
1 1
,
2 2
(D) (0, 1, 1)
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= sin cot
cos tan
sin cot 1 x
x
(B) 1
(C)
1
2
(D)
1
2
5
9
2
23. If =
(A)
(B)
17
33
(C)
3
2
(D)
2
3
1
4
(B)
1
16
(C)
15
16
(D)
7
8
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PART B : PHYSICS
SECTION I
Straight Objective Type
This section contains 6 multiple choice questions numbered 24 to 29. Each question
has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
24. The equation of motion of four bodies P, Q, R and S are as follows.
2
xP = 4t 1; xQ = 6t 5t + 3; xR = 5t + 3t 2t + 6; xS = 5 sin 30 3 cos 15
Which of these four particles move with uniform acceleration?
(A) xQ
(B) xP
(C) xR
(D) xS
25. A cube of mass 30 g wettable by water floats on the surface of water. Each face of
the cube is 4 cm long. Surface tension of water = 70 dynes/cm. The distance of the
2
(B) 1.93 cm
(C) 1.95 cm
(D) 1.98 cm
26. A solid copper sphere cools at the rate of 3.0C per minute, when its temperature
is 227C. Find the rate of cooling of another copper sphere of thrice its radius lose
its temperature at 427C, the room temperature being at 27C in both the cases.
(A) 0.48C /min
27. The electric field intensity on the surface of a solid charged sphere of radius r
and volume charge density is given by
(A)
1
4
(B)
5r
8
(C)
r
3
(D)
5 r
6
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10
28. An a.c generator consists of a coil of 150 turns and cross-sectional area 3.6 m ,
1
(B) 1.64 kW
(C) 1.5 kW
(D) 1.32 kW
(B) 5.65 cm
(C) 6.56 cm
(D) 7.67 cm
SECTION II
Multiple Correct Answer Type
This section contains 4 multiple correct answer(s) type questions numbered 30 to 33. Each
question has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
30. The potential energy u of a particle of mass m = 1 kg moving in the XY plane is
given by u = 2x + 5y xy. If the particle is at rest at 2, 1, its acceleration in m/s
at this position is given by
(A) ax = 1; ay = 3
(B) zero
(C) 10
(D) 3
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11
(B) the minimum distance between two particles in the same phase is
(C) the phase difference between two particles separated by a distance of
along the direction of propagation of wave is
5
4
(D) if its equation is 0.02 sin (5t 0.2x), then the maximum particle velocity is
1
0.1 ms
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12
and
V
Statement 2:
35. Statement 1:
and
Statement 2:
36. Statement 1:
and
Statement 2:
37. Statement 1:
and
Statement 2:
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13
SECTION IV
Linked Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
Paragraph for Question Nos. 38 to 40
A heat engine operates between two identical bodies A and B at different
temperatures TA and TB (TA > TB), with each body of mass m and specific heat
capacity s. The bodies remain at constant pressure and undergo no change of phase.
5
and
density of water = 10 kg m )
38. Obtain an expression for the final temperature T0 attained by the two bodies A
and B, if the heat engine extracts from the system the maximum amount of
mechanical work that is theoretically possible
T
(A)
(B) T T
A
(C)
T
(D) T T
A
(A) ms
T T
A
(B) ms
(C) ms
T T
B
A
B
T
(D) ms
B
A
(B) 1800 MJ
(C) 2100 MJ
(D) 2200 MJ
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14
(A) 0.329 ms , 0
(B) 0.369 ms , 0
(C) 0.392 ms , 0
(D) 0.396 ms , 0
(A) 0, 0.169 ms
(B) 0, 0.162 ms
(C) 0, 0.157 ms
(D) 0, 0.152 ms
(B) 3.97 V
(C) 4.47 V
(D) 4.97 V
(B) 3.07 eV
(C) 2.57 eV
(D) 2.07 eV
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15
PART C : CHEMISTRY
SECTION I
Straight Objective Type
This section contains 6 multiple choice questions numbered 47 to 52. Each question
has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
+
18
(C) 15.4 10
18
18
ion ?
(B) 10.35 10
(D) 4.34 10
18
18
48. In solid state each ammonia molecule has 6 other ammonia molecules as nearest
neighbours. H of sublimation of NH molecule at melting point is 30.2 kJ/mole
3
and in absence of H bonding the H sublimation is 14.4 kJ/mole. The strength
of H bond in solid state is
(A) 166.8 kJ/mol
49. Find out the number of atoms present in 100 g of the element if the element
3
occurs in bcc structure with edge length of 290 pm, density = 6.8 gcm .
(A) 6.023 10
23
(C) 24.09 10
23
atoms
(B) 12.046 10
atoms
(D) 3.073 10
23
23
atoms
atoms
50. If 2 moles of ideal gas at 27C is subjected to expand reversibly ten times of its
initial volume, the change in entropy of expansion of the gas is
(A) 19.59 JK
(C) 9.79 JK
mol
mol
(B) 38.29 JK
(D) 29.38 JK
mol
mol
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16
51. The standard enthalpy and entropy changes for the reaction in equilibrium for
forward direction are given as
CO(g) + H2O(g)
CO2(g) + H 2(g)
Calculate K at 300 K and the direction of reaction if the pressure of all gases at
p
initial state is 1 atm.
1
kJ mol
(A) 4-Aectamide-6-bromohexen-3-one
(B) 4-Bromomethyl-1-ethylamino-1-oxohept-4-en-3-one
(C) N-Ethyl-2-(2-bromoethyl)-3-keto-4-pentenamide
(D) 4-Bromoethyl-3-keto-5-ethylamidopentene
SPACE FOR ROUGH WORK
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17
SECTION II
Multiple Correct Answer Type
This section contains 4 multiple correct answer(s) type questions numbered 53 to 56.
Each question has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE is/are
correct.
53. Which of the following statements are correct ?
(A) H2O2 can act as most powerful oxidising agent in acidic medium.
(B) H2O2 can act as most powerful reducing agent in basic medium.
(C) H2O2 decomposes faster in acidic medium than in basic medium.
(D) It can be used as antiseptic and germicide.
54. Which of the following statements regarding oxides of nitrogen is/are correct ?
(A) Nitrogen dioxide is a mixed anhydride.
(B) Solid nitrogen dioxide is brown in colour.
(C) Nitrogen dioxide has two resonating structures.
(D) Nitrogen dioxide is a paramagnetic substance.
55. Which of the following statement/statements is/are not correct ?
+3
+2
(B) SO2 ion are most effective than I ion in coagulation of ferric hydroxide sol.
4
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18
56. Molal depression constant (Kf) of a solvent can be calculated from Lf = latent
heat of fusion of solid solvent, Hf = molar heat of fusion, Tf = freezing point of
solvent. The equation for Kf is
RT 2
RT 2
f
(A) K =
f
(B) K =
100 L
1000 L
100 H
RT 2 M
RT 2
(C) K =
(D) K =
f
1000 H
SECTION III
Reasoning Type
This section contains 4 questions numbered 57 to 60. Each question contains
STATEMENT 1 (Assertion) and STATEMENT 2 (Reason). Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.
(A) Statement 1 is True, statement 2 is True; statement 2 is a correct explanation
for statement 1.
(B) Statement 1 is True, statement 2 is True; statement 2 is not a correct
explanation for statement 1.
(C) Statement 1 is True, statement 2 is False.
(D) Statement 1 is False, statement 2 is True.
57. Statement 1:
and
Statement 2:
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19
58. Statement 1:
and
Statement 2:
59. Statement 1:
and
Statement 2:
60. Statement 1:
and
Statement 2:
This section contains 3 paragraphs. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
Paragraph for Question Nos. 61 to 63
All radioactive atoms in a given sample do not disintegrate simultaneously.
Radioactive disintegration is an example of 1st order reaction i.e., the rate of decay is
directly proportional to number of atoms (amount of the element present at particular
time). Some of the characteristics of radioactive decay are
SPACE FOR ROUGH WORK
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20
th
fraction t1/n
t1/n [No]
58
61. 1 g mixture of Co
Co
58
59
and Co
(A) 18.8%
(B) 0.39%
58
(C) 0.188%
211
81Ti
Bi
83
in mixture is
(D) 3.99%
207
211
0C. Half-life of
12
211
, the pressure
IIT/STS IV/MPC/P(I) - 20
21
(A) identical
(C) enantiomers
65.
IIT/STS IV/MPC/P(I) - 21
22
(A)
(B)
(C)
(D)
Paragraph for Question Nos. 67 to 69
The salient features of the theory are (1) the central metal ion has a number of
empty orbitals for accommodating electrons donated by the ligands. The number of
empty orbitals is equal to the coordination number of the metal ion for the particular
complex.
The atomic orbital (s, p or d) of the metal ion hybridize to form hybrid orbitals with
definite directional properties. These hybrid orbitals now overlap with the ligand
orbitals to form strong chemical bonds.
The d-orbitals involved in hybridisation, may be either inner (n 1)d orbitals or
outer nd-orbitals. The complexes formed in these two ways are referred to as low spin
and high spin complexes respectively.
SPACE FOR ROUGH WORK
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23
Fe Cl
3
6
unpaired electrons.
2
(A) d sp , 4
68. The
I
decreasing
Cr H O
2
(B) d sp , 3
order
3
6
; II
of
3 2
(D) sp d , 3
paramagnetism
Ni NH
3 2
(C) sp d , 5
2
3 6
of
; III
the
Cu NH
following
2
3 4
complexes
are
(C) Fe CO
3
6
(B) Ni NH
2
3 6
(D) Fe H O
2
2
6
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24
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25
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Name: .
Enrollment No.:
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
if both the statements are TRUE and STATEMENT-2 is the correct explanation of
STATEMENT-1.
Bubble (B)
if both the statements are TRUE but STATEMENT-2 is not the correct explanation of
STATEMENT-1.
Bubble (C)
IIT/STS IV/MPC/P(I) - 26