I j Malaysia
PAHANG
Engineering . Technology Creativity
: ANALYTICAL CHEMISTRY
COURSE CODE
: BKF1243
LECTURER
: EMAN N. ALl
FARHAN BT MOHD SAID
DATE
: 18 JUNE 2014
DURATION
: 3 HOURS
SESSION/SEMESTER
INSTRUCTIONS TO CANDIDATE:
1.
2.
3.
4.
This question paper consists of FOUR (4) questions. Answer ALL questions.
All answers to a new question should start on new page.
All the calculations and assumptions must be clearly stated.
Candidates are not allowed to bring any material other than those allowed by
the invigilator into the examination room.
EXAMINATION REQUIREMENTS:
1.
APPENDICES - List of Formulas and Statistic Tables
CONFIDENTIAL
BKB/BKC/BKG/1314111BK1F1243
QUESTION 1
Ca level (ppm)
no.
i)
Laboratory A
Ca level (ppm)
Laboratory B
10.1
10.6
10.0
10.5
10.4
11.1
ii) Conduct a statistical test to determine whether the laboratories differ at the
95% confidence level?
(12 Marks)
iii) Do they differ at 99% confidence level (F 11 = 18)?
(2 Marks)
CONFIDENTIAL
BKB/BKCIBKG/1314111BKF1243
(NHPtC16 + 2H
The precipitate was then decomposed on ignition, yielding metallic platinum and
gaseous products (02, NH3, HCI).
i)
Perform the complete reaction of the precipitation when the ignition process
complete.
(2 Marks)
ii) Determine the weight and percentage of ammonia in a sample, if 0.2115 g gave
rise to 0.4693 g of platinum.
(7 Marks)
QUESTION 2
a) A solution of Ba(OH) 2 was standardized against 0.1175 g of primary standard grade
benzoic acid, C61-15 COOH (122.12 g!mol). The end point was observed after
additional of 45 ml of base.
i) Determine the molarity of the base.
(7 Marks)
ii) If the standard deviation of weighing was 0.2 mg and for the volume was
0.03 ml, determine the standard deviation/absolute uncertainty of the molarity
of the base.
(5 Marks)
CONFIDENTIAL
BKB/BKC/BKG/131411JBKF1243
QUESTION 3
(3 Marks)
CONFIDENTIAL
BKBIBKCIBKG/1314111BKF1243
iv) The path length through a 3.40 X 10 M solution of the complex that is needed
for an absorbance that is the same as the solution in (a).
(3 Marks)
b)
Identify factors that cause the Beer's law relationship to depart from linearity.
(5 Marks)
c)
d)
QUESTION 4
Chromatography analytical method is the most general and common separation
technique, where separation, identification and determination of compound can be done.
a) The following data were obtained by gas-liquid chromatography on a 40 cm packed
column.
Compound
tR (mm)
W(min)
Air
1.9
Methylcyclohexane
10.0
0.76
Methylcyclohexane
10.9
0.82
Toluene
13.4
1.06
Calculate:
i) An average number of plates from the data.
(5 Marks)
CONFIDENTIAL
BKB/BKC/BKG/1314111BKF1243
CONFIDENTIAL
BKBIBKC/BKG/1314IIJBKFI 243
APPENDICES
Appendix A
Table 2: F-table for one-tailed test at 95% confidence level
FTabIe forOne-Tajied lest at c 005
(95% Confidence Level)
.1
1
161 4
18.51
-3
10.13
2
199.5
19.00
3
215.7
19.16
4. ,
224.6
19.25
5 -
230.2 1930
2.34.0
1933
236.8
19.35
10
15
20
238.9
240.5
2439
2459
248.0
1937
19.38
19.40
19.43
19.45
2543
19.50
9.552
9.277
9.117
9013
7.709
6.941
8941
8.587
8.945
8.812
8.786
8-703
6591
6383
6.256
6.608
5.786
6.153
6.041
5.999
5364
5-409
S 192
5050
4.950
60-4
4.876
5.987
5143
4.613
4.772
4.733
5.858
4.619
4.757
4.534
37
4394
5391
4.207
4337
4.147
4, 0-59
4.060
3933
4.347
4.120
1972
3.866
3.787
1637
4.459
4,066
3.838
3.687
3.581
3.500
3.3SS
3.347
3.511
1210
3.445
5,318
3.677
3.726
3438
3.150
2.928
9
10
5.117
4.965
4.256
4.103
1863
3.708
3.633
3.479
3482
3326
3,374
3.217
1293
3.135
3.230
3.072
3.179
3.020
3,137
2.978
3.005
2,845
2.938
2.774
11
4.844
3.982
3.587
3.337
3.095
3012
2.948
2.896
2854
2.719
2 646
12
4.747
3.885
3.490
3.259
3.204
3106
2.707
2S38
2.404
2.996
2.913
2.849
2.753
2.617
2.544
2.296
13
4.667
3.806
3.411
3.179
3.025
2,915
2.832
2,767
2.796
2.714
2671
4.600
3.739
3.344
3.112
2.958
2.848
2.699
2.646
2.602
15
4.534
3.682
3.287
2.901
2.790
2.641
2.583
2.544
2.403
2.328
2.131
2.066
16
4.494
3.634
3.239
3.056
3.007
2.764
2.707
2.459
2,388
2.206
14
2.533
2.463
2.852
2.741
2.657
2.276
2.010
3.592
3.197
2.965
2810
2.699
3614
2.538
2.494
2.352
4451
2.591
2.548
2.494
17
2.450
2.308
2.230
1.960
18
4.414
3.555
3.150
2.928
4.381
3.552
3.127
2.895
2661
2.628
2.577
2,544
2.510
2477
2,456
2.423
2412
19
2.773
2.740
2.378
2.269
2.234
2.191
2.155
1.878
20
4.351
3,493
3.098
2865
2.711
2.599
2.514
2.447
2.393
2.348
2.203
2.124
1.843
3.842
2.996
2.605
2.372
2.214
2.099
2.010
1.938
1,880
1.831
1,656
1.570
1.000
9.660
5303
4.558
3.874
8526
5.628
4365
3.669
3.230
1,917
10
15
20
993.1 1018
9. 68.6
984.9
948.2
956.7
9613
937.1
899.6
921.8
864.2
647.8
799.5
39.498
3943
3945
39.39
39.36
39.37
39.40
39.33
39.30
39.25
39.17
38.51
39,00
14.17
1.3.902
14.25
14.54
14.47
14.42
14.62
14.73
14.88
15.10
15.44
16.04
17.44
8.560
8.257
8.844
8.657
8380
8.905
9.074
9.197
9,605
9.364
9.979
10.65
12.22
6.015
6.619
6:428
6329
6.681
6.757
6.853
6.978
7.146
7.388
7.764
8,434
10.01
4.849
5.461
5.269
5.168
5.523
5.695
5.600
5.820
5.988
6.227
6.599
7.260
8.813
0.142
4.467
4.761
4.568
4.823
4.899
5.119
4.995
5.285
5.523
5.890
6.542
8.073
4.101
3.999
3.670
4,433
4.357
4.295
4.652 4.529
4.817
5.053
5.416
6.059
7.571
3.667
3,769
3333
4.102
4.026
3.964
4.320 4.197
4.484
4.718
56078
5.715
7.209
1080
3.522
3.717
1419
1855
3.779
3.950
4.072
4.236
4.468
4.826
5.456
6:937
2.883
3.526
3.330
3.226
3,664
3.588
3.759
4.044
3.881
4.275
4630
5156
6.724
2.725
3.436
3.374
3.073
3.177
3.607
3.512
3.728
3.891
4.121
4474
5.096
6.544
2.948
2.596
3.250
3.312
3.053
3.388
1483
3.604
3.767
3.996
4.347
4.965
6.414
2.844
2.487
3.285
1209
3,147
2149
3380
3.501
3663
3.892
4.242
4.857
6.298
2.39.5
2.862
2.756
3,123
1060
3.293
3.199
3.415
3.576
3.804
4.153
4.765
6,200
VA
CONFIDENTIAL
BKB/BKCIBKG/1314111BKF1243
IA
LuBe
19
13
L 2431
20
21
23
22
24
VIJIB
14
Si
i1
17
Cl
is
Ar
38.95
III
HR
20.98
30.08
34.97
32.07
25.45
20
77
28
29
343
31
32
33
34
35
345
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
72.61
14.92
18.90
78.90
8300
Ca
Sc
Ti
Cr
Mn
Fe
39.10
40.00
44.56
47.61
60.94
52,05
54.44
05.55
55.93
68.69
'82.00
50.39
68.72
41
47
43
44
06
.16
17
49
49
Ag
Cd
Sn
1001
Sb
121.43
Te
30
39
40
Sr
Zr
Nb Mo
(4
58.91
9122
92.91
95.54
(50)
109,1
102,9
'(00.4
107.0
112.4
57
72
73
74
75
75
77
75
79
85
51
92
84
85
55
83
55
Ba
137.3
La
130.4
Hf
178.5
Ta
150.9
Re
Au
197.0
Hg
TI
Bi
2006
.
204.4
Po
(200)
At
(210)
153.5
Pt
195.1
Pb
Cs
59
104
106
(06
Ac
Rf
1Db
55
59
1325
87.62
FrlIRa
RPd
Tc
Ir
160.2
Os
850.2
192.2
107
150
108
Sg
Bh
Hs
Mt
(.0
-51
04
227.2
005.0
877,8
026.5
112
UunUuu Uub
110
Iii
...
--
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
5409 54
91
('0
(231)
04
Pu'
Pa
Th
20
04
(145)
(244)
9
]
67
mBkf
(043)
(Li
(24 fl
(251)
(252)
s21.0
(257)
258
54
in
114.3
E8547
20.98
05
15
26
VB VIB VflB
IIIB 1V13
Al
1i
99,00
10.81
ri
I Mg
Na
2295
MT
0F
4.003
VA VIA VIIA
WA
lilA
hA
-
(259) [i!
138.3
88
Rn
222)
BKBIBKC/BKG/1314111BKF1243
CONFIDENTIAL
Appendix B
Po
2AZ
R =
WA + WB
hcE=hv==hcv
PT
2[(tR)B(tR)A]
WA+WB
Z
- tR
kA
= -X -
tM
tM
XThLI0
(tR)3-tM
(tR)A tM
(tR)l - ( R)
- (R,
(R)
(t
N=16(t/w)2
-;-
xp_
(R) 1 -
(R)2j
IN
N= L/H
s=1J
j1
Ni
SR -SA+SB
- z
ii= X
/('4)
Fexp
+1
R1,ftA) B)
SA