www.elsevier.com/locate/marpetgeo
Abstract
In the Upper Magdalena Valley, Colombia, four petroleum systems were identified. Two petroleum systems are located in the
Girardot sub-basin and the other two in the Neiva sub-basin. Limestones laterally changing to shales of the lower part of the Villeta
Gp, deposited during Albian and Turonian marine flooding events, constitutes the main source rocks of the oil families. These rocks
contain 1 4% TOC and type II kerogen. The littoral quartz arenites of the Caballos (Albian) and Monserrate (Maastrichtian) Fms.
are the main reservoir rocks. Seal rocks are Cretaceous and Paleocene shales. Overburden includes the Cretaceous rocks and the
Tertiary molasse deposited simultaneously with development of two opposite verging thrust systems during Cenozoic time. These
deformation events were responsible for trap creation. Except for the Villarrica area, where the source rock reached maturity during
the Paleocene, generation occurred during Miocene. Two oil families are identified, each in both sub-basins: One derived from a
clay-rich source and the second from a carbonate-rich source rock lithofacies of the lower part of Villeta Gp. Geochemical sourcerock to oil correlations are demonstrated for the three of the petroleum systems. Up-dip lateral migration distances are relatively short
and faults served as vertical migration pathways. A huge amount of oil was probably degraded at surface, as a result of Miocene
deformation and erosion.
q 2004 Elsevier Ltd. All rights reserved.
Keywords: Petroleum systems; Upper Magdalena Valley; Colombia; Petroleum source rock; Oil families
1. Introduction
The Upper Magdalena Valley (UMV) is a narrow
intermontane basin located along the southern upstream
portion of the Magdalena River Valley, between the Central
and Eastern Cordilleras of the Colombian Andes. Precambrian to Jurassic igneous and metamorphic rocks and locally
Paleozoic sedimentary rocks crop out on the Central and
Eastern Cordilleras on both sides of the basin. The
Natagaima structural high, where Triassic and Jurassic
economic basement rocks crop out, divides the UMV into
the northern Girardot sub-basin and the southern Neiva
subbasin (Fig. 1).
The UMV contains a number of commercial accumulations of oil and gas. Between 1962 and 1982 several
oil fields were discovered just north of Neiva in the
uppermost Cretaceous Monserrate Fm. Beginning in 1984
oil was discovered along the Dina-San Jacinto fault in
the Aptian-Albian Caballos Fm. By 1994 542.1 MMbbl
* Corresponding author. Tel.: 57-674-01-49; fax: 57-644-5444.
E-mail address: arangel@ecopetrol.com (A. Rangel).
0264-8172/$ - see front matter q 2004 Elsevier Ltd. All rights reserved.
doi:10.1016/j.marpetgeo.2003.11.019
374
Fig. 2. Generalized stratigraphic column of the UMV (modified after Geotec, 1994 and Etayo-Serna, 1994).
375
376
Fig. 3. (a). Lithofacies distribution of Tetuan Limestone and the La Luna Limestone (lower part of Villeta Gp.). (b). TOC l, HI and Tmax of the lower part of
Villeta Gp. (includes Tetuan Limestone, Bambuca Shale and Luna Limestone).
Table 1
Petroleum systems elements and oil reserves in the Upper Magdalena Valley
Main source rock
Oil family
Seal
Trap
Oil field
Reservoir rock
Villeta-Tertiary
Girardot Sub-basin
Lower Villeta
Oil Family I
HondaMonserrate
Tertiary
Claystones
Estructural
Toqui-Toqui
Pul
Doima
Monserrate
Pacande
Totare
Caballos
Honda
Chenche
Ortega-Tetuan
Monserrate
Caballos
Toy
Toldado
Quimbaya
Pauta
Ro Saldana
Purificacion
Montanuelo
Olini
Monserrate
Revancha
Venganza
Caballos
Caballos
Caballos
Caballos
Caballos
Monserrate
Monserrate
Caballos
Monserrate
Monserrate
Monserrate
Balcon-Colombia
Hatonuevo-Loma Larga
Caballos
Caballos
Tenay
San Francisco
Andaluca
Caballos
Caballos
Honda
Dina Terciario
Dina Cretacico
Honda
Monserrate
Cebu
Pijao
Tello
Palogrande
Brisas
Gigante
Los Mangos-Yaguara
La Canada
La Jagua
Santa Clara
Santa Clara Sur
Rio Ceibas
Monserrate
Monserrate
Monserrate
Monserrate
Monserrate
Monserrate
Caballos
Monserrate
Honda
Caballos
Caballos
Honda
Villeta-Caballos
Girardot Sub-basin
Villeta-Caballos
Neiva Sub-basin
Villeta-Monserrate
Neiva Sub-basin (4)
Lower Villeta
Lower Villeta
Lower Villeta
Subtotal
Oil Family II
Subtotal
Oil Family I
Subtotal
Oil Family II
Caballos
Monserrate
Villeta Fm.
Villeta Fm.
Guaduala Fm.
Estructural
Estructural
Estructural
Reserves
(MMbbl)
Oil produced
(MMbbl)
29.0
29.0
5.8
5.8
1.0
0.0
6.0
29.0
93.0
5.0
155.1
1.2
0.6
13.4
1.0
31.2
0.4
0.2
1.6
38.1
50.0
17.0
9.0
27.9
57.0
28.0
5.0
1.0
14.0
51.0
458.1
44.0
6.8
7.6
10.0
3.4
0.3
2.1
11.4
5.6
1.0
0.2
5.0
9.0
87.8
8.8
3.0
20.1
0.9
1.9
20.0
675.0
80.0
825.8
182.5
125.0
5.1
135.0
11.4
163.3
36.0
48.5
5.3
65.7
8.3
82.1
33.1
40.8
126.0
18.0
230.0
214.5
28.2
175.0
100.0
12.2
2.0
11.8
5.0
42.5
1272.7
2649.6
25.0
5.0
46.0
42.9
7.0
35.0
17.5
2.4
0.4
4.6
1.0
8.5
279.8
544.3
7.4
4.9
51.5
30.2
6.1
12.3
0.2
3.8
0.3
0.0
0.0
1.6
1.9
0.0
6.2
1.3
0.4
3.1
0.0
0.1
185.1
288.9
377
Subtotal
Total
Caballos
Oil in situ
(MMbbl)
Petroleum system
and sub-basin
378
Table 2
Average source rock data for Lower Villeta Formation (Tetuan and The La Luna Limestone)
Petroleum system
Studied well
Average TOC
(%)
Average Tmax
(8C)
Average HI
(mgHC/gC)
Average S1
(mgHC/gR)
Average S2
(mgHC/gR)
Villeta-Tertiary
Girardot Sub-basin
Lower Villeta
Villeta-Caballos
Girardot Sub-basin
Lower Villeta
Villeta-Caballos
Neiva Sub-basin
Villeta-Monserrate
Neiva Sub-basin
Lower Villeta
Rosita-1
Pacande-1
Suarez-1
Chenche-1
Toy-1
Toldado-1
Pauto-1
Olini-1
Boreal-1
Tolima-1
Coyaima-1
Balcon-1
San Francisco-1
Los Mangos-1
Nilo-1
Santa Clara Sur-1
Tarqui-1
2.2
3.1
1.8
1.6
3.1
3.0
3.2
3.7
3.2
2.9
3.5
2.5
2.1
2.1
2.0
1.9
1.2
429
424
465
426
416
421
418
419
424
420
427
428
425
425
432
430
432
374
531
100
495
652
547
538
563
441
566
581
437
419
434
436
392
200
0.73
0.99
1.10
0.62
1.42
1.56
1.54
1.27
0.67
0.60
1.72
0.85
0.77
0.51
0.49
0.28
0.15
8.4
16.6
2.0
8.1
20.4
16.5
17.4
20.6
13.9
16.0
20.2
10.9
8.7
9.0
8.6
7.4
2.5
Lower Villeta
379
Fig. 4. Pyrolysis geochemical well profiles Coyaima-1 well modified from Ecopetrol-Icp (2000).
indicating a marine-saline depositional environment (Moldowan et al., 1985). Oleanane, an Upper Cretaceous/Tertiary
indicator derived from upper plants (Peters & Moldowan,
1993; Ten Haven et al., 1988), is present in very low
concentration (oleanane/hopane ratio less than 0.02). The
C34/C35 hopane ratios are higher than 0.5 and the diasterane/
regular sterane ratios lower than 1.25. Both biomarker ratio
values indicate a depositional environment with carbonate
input/and anoxic conditions (Peters and Moldowan, 1991;
Mello et al., 1988; Peters and Moldowan, 1993).
3.2.1. Oil families
An approach to the grouping of oils was achieved by
statistical methods of hierarchical cluster analysis (HCA),
crossplots (Fig. 5), GC fingerprint, hopane and sterane
fragmentograms (Fig. 6). The HCA dendogram was
constructed using source related biomarker ratio averages
converted to indexes (Table 2). According to the cluster
analyses (Fig. 5a), two oil families were identified. The oil
Family I constituted by the oils from the Andaluca-1,
Balcon-1, Providencia-1, Hato Nuevo-1, Pacande-1, Totare7 and San Francisco 114 wells; and the oil Family II
composed by the oils from the Chenche-1, Purificacion-2,
Dina K-15, La Jagua-1, Toldado-1, Santa Clara-1, Dina T12, Los Mangos-1, La Canada-6 and Gigante-1 wells and
the oil seep La Canada. Fig. 5b shows the oil family II as
380
Table 3
Bulk geochemical parameters and some biomarker ratios and indexes for oils
Interval
Formation
GammaOleanane/
C35/C35 C23Tricyclic/ C29S/S C29aa/aa C25
8API
Sulphur Pristane/ Diasterane/ Tm/Tm C28BisnorNorhopane/
hopane/
C23Tri C30 R
bb
Olea C30 cerane/Gam C34
gravity (%)
Phytane Esterane
Ts
C30Hopane
C28Bis C30 Hopane
C30
Hopanes Hopane
Hopane
Hopane
Andaluca-34
Balcon-1
Hato Nuevo-1
Pacande-1
Providencia-1
1806-1829
9631-9716
6204-6691
5930-6490
5380-5700
33
33.7
36.4
27.9
28
0.38
0.34
0.31
0.86
0.42
2.4
1.7
2.19
1.17
1.66
1.12
1.25
1.06
1.18
0.91
0.64
0.01
0.42
0.52
0.44
0.03
0.03
0.02
0.08
0.02
0.01
0.01
0.01
0.01
0.02
0.10
0.09
0.09
0.08
0.10
0.36
0.36
0.33
0.40
0.30
0.21
0.25
0.17
0.29
0.28
0.33
0.37
0.32
0.39
0.3
0.32
0.31
0.34
0.36
0.35
0.01
0.01
0.01
0.01
0.01
San Francisco
114
Totare-7
Chenche-1
Dina K-15
Dina T-12
Gigante-1
La Canada-6
La Jagua-1
Los Mangos-1
Man Bloque
Colombia
Man Hda El
Darien
Man La Canada
Man San
Francisco
Purificacion-2
Santa Clara-1
Toldado-1
1835-1845
Doima
Caballos
Caballos
Villeta
VilletaCaballos
Tetuan
26.6
0.51
1.63
0.81
0.49
0.03
0.01
0.09
0.34
0.23
nd
nd
0.01
5262-5320
2500-3000
Oil seep
Honda
Doima
Monserrate
Honda
Monserrate
Caballos
Honda
Caballos
Caballos
21.9
32.1
21.3
20.3
23.5
21
21.2
21
nd
0.83
0.75
1.07
1.8
1.32
2.22
0.82
1.89
2.55
1.59
1.16
1.17
1.2
1.36
1.1
1.7
1.1
Biode.
1.21
0.41
0.6
0.55
nd
0.59
0.68
0.45
nd
0.49
0.55
0.58
0.62
0.59
0.66
0.58
0.65
0.57
0.07
0.15
0.05
0.07
0.09
0.13
0.03
0.09
0.15
0.02
0.03
0.02
0.03
0.04
0.02
0.01
0.02
0.06
0.07
0.14
0.11
0.12
0.12
0.11
0.11
0.11
0.06
0.38
0.43
0.43
0.44
0.46
0.45
0.41
0.46
0.49
0.32
0.29
0.31
0.42
0.46
0.46
0.30
0.40
0.48
0.39
0.32
0.32
0.32
0.36
0.3
0.31
0.26
nd
0.32
0.29
0.31
0.31
0.35
0.32
0.3
0.3
nd
0.04
0.03
0.05
0.05
nd
nd
nd
0.04
nd
Oil seep
nd
nd
2.51
Biode.
nd
0.59
0.08
0.02
0.05
0.45
0.57
nd
nd
nd
Oil seep
Oil seep
Bas-Villeta nd
Villeta Ir.
nd
1.57
0.98
Biode.
Biode.
0.72
nd
0.49
0.52
0.07
0.03
0.01
0.01
0.20
0.09
0.39
0.40
0.25
0.29
0.3
0.32
0.25
0.27
nd
nd
Guadalupe
Caballos
Caballos
0.63
1.43
2.81
1.25
1.5
1.39
0.36
0.68
0.74
0.57
0.55
0.68
0.15
0.04
0.11
0.03
0.03
0.01
0.15
0.14
0.07
0.40
0.32
0.45
0.34
0.28
0.32
0.31
0.32
0.33
0.28
0.31
0.33
nd
0.02
0.01
4557-4678
6000-6405
1890-2568
13140-13306
2714-2747
5360-5789
nd: no data
34.2
19.1
17.4
Well/seepage
381
Fig. 5. Crude oil geochemistry. (a) Cluster analysis for oil families based on biomarker indicators of depositional environment, (b) Oiloil correlation based on
indicators of depositional environment. (c) Oil-source rock correlation based on indicators of depositional environment. (d) Oil to source rock correlation based
on maturity parameters.
382
Fig. 6. Gas chromatograms (GC), m=z 191 and m=z 217 mass chromatograms from oils representatives of Family I and Family II.
383
0.15
0.32
0.42
0.12
0.35
0.14
0.41
0.44
0.23
0.42
0.15
0.12
0.30
0.24
0.40
0.28
0.34
0.22
0.17
0.14
0.18
0.29
0.33
0.13
0.36
0.24
0.33
0.21
0.27
0.15
0.48
0.41
0.32
0.53
0.37
0.46
0.38
0.44
0.33
0.47
0.50
0.54
0.42
0.52
0.29
0.12
0.10
0.04
0.09
0.08
0.09
0.06
0.07
0.09
0.08
0.12
0.07
0.08
0.11
0.07
0.01
0.01
0.02
0.01
0.01
0.01
0.01
0.01
0.03
0.02
0.01
0.05
0.01
0.01
0.03
0.67
0.57
0.33
0.89
0.51
0.66
0.43
0.53
0.53
0.64
0.84
0.69
0.58
0.71
0.64
1.25
1.27
1.40
1.04
1.72
1.08
1.51
0.97
1.69
2.49
1.51
1.30
0.81
0.82
1.31
Tetuan
Tetuan
Tetuan
Tetuan
Tetuan
Tetuan
Tetuan
Tetuan
Tet-Bamb
Tet-Bamb
Bambuca
La Luna
La Luna
La Luna
La Luna
Mangos-1
Nilo-1
Rosita-1
Tolima-1
Balcon-1
Boreal-1
Cambulos-1
Coyaima-1
Chanche-1
Tarqui-1
Miravalle-1
Balcon-1
Balcon-1
Coyaima-1
Tarqui-1
0.34
0.64
1.25
0.33
1.31
0.37
1.59
1.38
0.40
0.71
0.38
0.18
0.59
0.45
1.96
0.93
0.77
0.68
0.91
0.72
0.90
0.68
0.73
0.81
0.66
0.92
0.94
0.77
0.80
0.70
0.90
0.91
0.72
0.79
0.60
0.78
0.85
0.84
0.61
0.86
0.73
0.86
0.80
0.86
0.51
0.33
0.01
0.02
0.16
0.02
0.24
0.01
0.06
0.12
0.05
0.06
0.31
0.01
0.23
0.01
C29S/S
R
C23Tricyclic/
C23Tri C30
Hopane
C35/C35 C34
Hopanes
Gammacerane/
Gam C30
Hopane
Oleanane/
Olea C30
Hopane
C28Bisnorhopane/C28Bis
C30Hopane
Tm/Tm
Ts
C23Tricyclic/
C23Tri C24
Tetracyclic
C27Sterane/
C27 C29
Sterane
Diasterane/
Sterane
Pristane/
Phytane
Formation
Well
Table 4
Biomarker indexes for extracts
0.16
0.23
0.35
0.20
0.30
0.19
0.35
0.32
0.22
0.35
0.18
0.18
0.21
0.20
0.34
384
385
Fig. 8. Schematic structural cross-sections of the UMV Petroleum systems at their critical moment. The structural interpretation from seismic lines has been
taken from Ecopetrol et al. (1998).
386
Fig. 9. Burial history charts of the petroleum systems of the UMV. (a) Villeta-Honda(!) petroleum system associated with the Villarrica kitchen, (b) VilletaCaballos(!) and Villeta-Monserrate (!) petroleum systems associated with the Neiva syncline kitchen, (c) Villeta-Caballos (.) petroleum system associated with
the Coyaima kitchen, (d) Villeta-Caballos (!) petroleum system associated with the San Francisco kitchen and Villeta-Monserrate (!) petroleum system
associated with the Chusma kitchen.
(3) Coyaima active source rock pod (Figs. 7 and 8). This
effective source rock pod is located in the footwall block of
the Cucuana thrust fault, near Coyaima, where the analysis
of outcrop samples indicated mature source rock. A source
rock extract from the lowermost part of the Villeta Gp.
below the thrust sheets shows the same maturity level as
387
388
389
4. Conclusions
This study identified four petroleum systems. The main
source rock intervals are the lower Villeta Gp. Tetuan
Limestone and the La Luna Limestone which are,
respectively, 135 and 100 m. thick, their TOC values
range from 1 to 4%, dominantly II type marine kerogen.
The main reservoir rocks are the Caballos Fm. (Albian) and
Monserrate Fm. (Maastrichtian) quartz arenites. The main
seal rocks are the Villeta Gp. (Cretaceous) shales and the
Guaduala Fm. (Paleocene) mudstones. Overburden rock
includes all the Cretaceous and Tertiary sedimentary rocks
overlying the source rock and where burial was due to thrust
sheet stacking also includes the Yav Fm. (Aptian), Saldana
Fm. (Jurassic), or older rock units included in the thrust
sheets. Traps are structural, generally faulted, and were
390
Acknowledgements
Special thanks to the Geologist Blanca Nubia Giraldo for
her contribution to the analytical work. L.F: Sarmiento and
A Rangel would like to thank to Ecopetrol for permission to
publish this work. We are grateful to Dr L. Maggon and
reviewers for helpful suggestions and constructive review.
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