3)
Zn(s) ---> Zn2+ + 2e¯ E°= 0.76 volt
Cu(s) ---> Cu2+ + 2e¯E°= -0.34 volt
2.3 (RT/F) = 0.059 at 25 °C
A cell is set up to plate zinc onto a zinc electrode. The loss of weight of a copper electrode is
used to determine the amount of current passed.
18) In each of the following cases, a slight excess of dilute base is added to a 0.05-molar solution
of acid. The resultant heats of neutralization per mole of acid reacting are indicated for each
acid-base reaction.
Heat of Neutralization
a) HCl + NaOH 13.7 kcal.
b) HNO3 + KOH 13.7 kcal.
c) HCl + NH3 12.6 kcal.
d) CH3COOH + NaOH13.4 kcal.
e) HClO4 + KOH 13.7 kcal.
Account for the fact that the heats are the same in (a), (b), and (e) but are different in (c) and (d).
19) Give an explanation for each of the following observations:
20) The terms "activation energy" and "activated complex" (or "transition state") are commonly
employed in a theoretical discussions of rates of reaction. What is the significance of these
terms?
21) You are given a sample of ordinary sodium chloride, some glassware, a crucible, a 3-volt
battery, an ammeter, wires, distilled water, carbon tetrachloride, a bunsen burner, a balance,
equipment for supporting a crucible or beaker, and a selection of thermometers. Your problem is
to obtain experimental evidence for the assertion that sodium chloride is electrovalently bonded.
Describe a series of relevant observations and experiments. Explain how the concept of ionic
bonding gives a consistent interpretation of all of the observations and experiments.
22) Discuss a chemical and a physical method for the determination of atomic weights. State
what experimental data are needed and show how the data may be employed to achieve the
desired objective. Indicate any assumptions that are made in the use of each method.