of (GB)
(73) Assignee: Quest International B.V., Naarden
(NL)
(*)
Notice:
US 6,172,037 B1
Jan. 9, 2001
09/424,299
PCT/GB98/01381
371 Date:
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Field of Search
(56)
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References Cited
PUBLICATIONS
(57)
ABSTRACT
13 Claims, No Drawings
US 6,172,037 B1
1
normal conditions).
The hydrophobic oil suitably has an octanol/Water parti
10
than 14 MPal/z.
For obvious reasons, the hydrophobic oil should be
5.
Hg.
The hydrophobic oil is preferably an ester and/or (poly)
Dioctyl adipate
Isopropyl myristate
30
Dibutyl phthalate
PRIOR ART
35
40
45
(a) polyvinylpyrrolidone;
?xative comprising:
Weight of PVP and HPC but this is not essential, and there
may be cases Where it is advantageous for the amount by
Weight of the HPC to exceed that of PVP.
Good results have been obtained With ?xatives
Glycerol monooleate
US 6,172,037 B1
3
ing ingredients:
levels.
Nonanal
Decanal
0.2
0.4
Benzyl Acetate
Camphor
5.0
0.4
Cineole
Citral Lemarome
Geraniol
0.4
0.7
5.0
10
Wt %
Hydroxycitronellal
2.0
Limonene Dextro
Linalol
40.0
10.0
Linalyl Acetate
16.0
Lyral (IFF)
Methyl Dihydro Jasmonate Super (Q)
15
Myrcenyl Acetate
Terpinyl Acetate
3.0
12.9
(G) Givaudan-Roure SA
(Q) Quest
20
25
improvement.
Wt %
2.0
2.0
30
Reference
Test 1
Test 2
Test 3
2.0
79.6
2.0
78.8
2.0
78.8
2.0
78.8
Distilled Water
18.4
18.2
18.2
18.2
LUVISKOL K90
KLUCEL G
0.25
0.25
0.25
0.25
0.5
0.5
MIGLYOL 840
MYVEROL 18-99
0.50
0.50
35
tional.
The colognes Were tested by a paired comparison test
Where 50 pl of each sample Was placed using a calibrated
pipette onto marked areas of a subjects forearms (one
40
Average of 5
Ethanol
Water
Subjects
Reference"
One Hour
50 Four Hours
3.0
4.1
2.0
2.7
1.00 Wt %
Fixative Blend
Trielosan
0.50 Wt %
9.25 Wt %
Subjects
55
One Hour
Four Hours
Average of 5
Subjects
One hour
Four hours
G, as discussed above.
Test 2 Comments
3.0
2.0
3.5
2.8
Reference"
Test 3
3.0
2.0
3.5
2.5
EXAMPLE 2
(Cologne)
The folloWing example illustrates the improvement in
Reference"
60
Test 1 Comments
Average of 5
80.0 Wt %
to 100.0 Wt %
Fragrance
(Aerosol)
m5
US 6,172,037 B1
6
?xativezperfume
The following solutions Were prepared:
Glycerol monooleate
Reference
Test 3
Test 4
Test 5
1.0
1.0
1.0
1.0
99.0
98.5
98.89
98.95
Perfume AP209"
Ethyl alcohol
LUVISKOL K90
0.125
0.028
KLUCEL G
0.125
0.028
MIGLYOL 840
0.25
0.056
KLUCEL E (Low
0.016
Dibutyl phthalate
Acetyl tributyl citrate.
10
0.032
0.006
Molecular Weight
HPC)
15
Reference
Test3 Comments
Initial
One Hour
Four Hours
4.8
3.6
2.3
4.9
3.8
2.9
Reference ?at in
Eight Hours
0.6
1.5
25
human skin.
9. Amethod of preparing a perfume or a perfumed product
comparison
reference
Average of 5 Subjects
Reference
4.5
3.8
4.9
4.3
Four Hours
2.5
3.3
Eight Hours
1.5
2.2
Average of 5 Subjects
Reference
30
Test 4 Comments
Initial
One Hour
35
Test 5 Comments
40
Initial
One Hour
Four Hours
5.0
3.8
1.2
4.9
3.8
2.0
Glycerol monooleate
Eight Hours
0.5
1.0
Clear difference
45
Dibutyl phthalate
Acetyl tributyl citrate.
(a) polyvinylpyrrolidone;
(c) a non-volatile hydrophobic oil having a vapour pres
folloWing: