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Hydrometallurgy
Hydrometallurgy is concerned with the selective leaching of metallic
compounds to form a solution from which the metals can be precipitated
and recovered. Leaching processes are used when it is the simplest
method or when the ore is of too low a grade for more expensive
extractive procedures.
Conversion
Because not all ores and concentrates are found naturally in a form that
is satisfactory for leaching, they must often be subjected to preliminary
operations. For example, sulfide ores, which are relatively insoluble in
sulfuric acid, can be converted to quite soluble forms by oxidizing or
sulfatizing roasts. On the other hand, oxide ores and concentrates can
be given a controlled reducing roast in order to produce a calcine
containing a reduced metal that will dissolve easily in the leaching
solution. These treatments are described in more detail above (see
Pyrometallurgy: Roasting).
A second popular treatment for converting sulfides is pressure oxidation,
in which the sulfides are oxidized to a porous structure that provides
good access for the leaching solution. This treatment was developed for
the recovery of gold from sulfide ores, which are not suitable for cyanide
leaching without first being oxidized. A finely ground concentrate slurry
is preheated to 175 C (350 F) and pumped into a four- or fivecompartment autoclave, each compartment containing an agitator.
Gaseous oxygen is added to each compartment, and retention time in
the autoclave is two hours in order to achieve the desired oxidation.
Leaching
Oxides are leached with a sulfuric acid or sodium carbonate solvent,
while sulfates can be leached with water or sulfuric acid. Ammonium
hydroxide is used for native ores, carbonates, and sulfides, and sodium
hydroxide is used for oxides. Cyanide solutions are a solvent for the
precious metals, while a sodium chloride solution dissolves some
chlorides. In all cases the leach solvent should be cheap and available,
strong, and preferably selective for the values present.
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Recovery
Pregnant solution from leaching operations is treated in a variety of ways
to precipitate the dissolved metal values and recover them in solid form.
These include electrolytic deposition, transfer of metal ions, chemical
precipitation, solvent extraction in combination with electrolytic and
chemical methods, and carbon adsorption combined with electrolytic
treatment.
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Bibliography
"Metallurgy". Encyclopdia Britannica. Encyclopdia Britannica Online.
Encyclopdia Britannica Inc., 2016. Web. 03 Mar. 2016.