PUNJAB COLLEGE

BAHAWALPUR
Examination: FSC-Part-1(Evening)
Maximum Marks: 50
Paper: Chemistry
Time Allowed: 1 hr.30 min
Q.No.1
Choose the Correct Option
1 x 22 = 22
1. A limiting reactant is one which
(a) Present in least amount
(b) gives minimum amount of the product
(c) Gives maximum amount of the product (d) does not affect the amount of product
2. In combustion analyses H2O vapor are absorbed by
(a) 50% KOH
(b) Mg (ClO4)2
(c) NaOH
(d)
MgCl2
3. Molecular mass of CaCO3 is
(a) 100
(b)
120
(c)
90
(d)
106
4. Which one element is monoisotopic?
(a)
Carbon
(b)
Nitrogen
(c)
Arsenic (d) both b and c
5. How many moles are present in 80 gm NaOH?
(a) 1 mole
(b) 40 moles
(c) 2 moles (d) None of them
6. Molecular ions are produced by passing
(a) High energy beam of electrons (b) - particles through gas (c) X-rays through gas
(d) all of these
7. Which one is not a molecular ion?
(a)
CH4+
(b)
N2 +
(c)
CO+
(d) n NH4+
8. Swedish Chemist J.Berzlies determined the
(a) Atomic number
(b) atomic volume
(c)
atomic mass
(d)
atomic
density
9. The number of molecules present in 10 g of water is
(a) 3.37 X 1023
(b)33.7 X 1023
(c) 3.37 X 1024
(d) 3.037 X 1024
10.Mass Spectrometer Separates the different positive isotopes ions on the basis of their
(a) Mass value
(b)
m/e value
(c) e/m value
(d)
All of these
11.The volume occupied by 1.4 g of N2 at STP is
(a)
22.4 dm3
(b)2224 dm3
(c) 1.12 dm3
(d) 28 dm3
12.Dumpsters mass spectrometer was designed for the identification of isotopes of the element
which were available in
a)
Gaseous state
b)
liquid state c)
solid state d)
plasma state
13.The mass of one mole of electrons is
a)
1.0088
b)
0.55 mg
c)
0.184 mg
d)
1.673 mg
14.How many times a hemoglobin molecules is heavier than hydrogen atom?
a)
38000 times b)
58000 times
c)
68000 times d)
88000 times
15.Empirical formula of glucose is
a)
CHO
b)
C2H4O2
c)
CH2O
d)
C6H12O6
16.Electrometer is also called
a)
Voltmeter
b)
Avometer
c)
ion collector d)
galvanometer
17.Formula mass of CaCO3 is
a)
100
b)
90
c)
120
d)
106
18.The number of moles of CO2 which contain 8.0 g of oxygen.
(a)

0.25

(b)

0.50

(c)

1.0

(d)

1.50

19.The largest number of molecules are present in

(a)

3.6g of H2 O

(b)

4.8g of C2H5 OH

(c)

2.8 g of CO

(d)

5.4g of N2O5

20.One mole of SO2 contains

(a) 6.02x1023 atoms of oxygen

(b) 18.1x1023 Molecules of SO2

( c) 6.02x1023 atoms of Sulphur

(d) 4 gram atoms of SO2

PUNJAB COLLEGE
BAHAWALPUR
21.The amount of product that would form, if at least one of the reactants is completely consumed
first is called:
(a) Actual yield
(b) Theoretical yield
(c) Percent yield
(d) Product
recovery
22.In the periodic table, isotopes are
(a) Arranged in order of increasing mass.(b) Given no place. C) Kept at the same position.
d)
None of these

Q.No.2
10 = 20

Attempt any ten of the following

2x

1. Differentiate between mole and Avogadros number.

2. What are ions? How positive and negative ions are formed. Give examples.
3. What is the theoretical and actual yield? Why actual yield is lesser than theoretical
yield.
4. Calculate the
(a) gram atom in 10g of sodium (b) number of atoms in 15g
Sulphur
5. Define with examples:
(a) molar volume
(b) atomicity
6.
Can you explain the places of negative charges in PO 4-3, MnO4-3, Cr2O7.-2
7. How many hydrogen atoms are present in 2.43 g of Aspartame C 14H18N2O5 , (H=1, C=12,
N=14, O= 16)
8. Which one is the larger quantity, 0.4 moles of oxygen atoms or 0.4 moles of ozone
molecules?
9. Justify that 23 grams of sodium and 238 gram of uranium have equal number of atoms
in them.
10.
Define molar volume. Give two examples.
11.
How limiting reactant controls the amount of products formed?
12.
What is the function of electrometer in separation of isotopes in mass
spectrometer?

Q.No.3

Extensive Question

4x2=

8
A) The combustion analysis of an organic compound shows it to contain 65.44%
carbon.5.50% hydrogen and 29.06% Oxygen. What is the empirical formula of the
compound? If the molecular mass of this compound is 110.15 g/mol 1.
Calculate the molecular formula of the compound.
B) Mg metal react with HC l
The density of HC l
+H2(g)

solution (27% by weight) required to produce 12. 1g of H 2.

solution

1.14g/cm3.

Mg(s) + 2HC l

(aq)

Mg C2 l

(aq)