X i t
r. 1
\,f<>!c,p!!:>,"
,~+'gi., ,,.>d <,,!.?St!
.
:,,sra;tllar
., .
i.rvr,iix~r:i
-. --
'?&, %
i C , a:.
- ~ -- - .
--
;319
H:rc>7T;L:ei.6
- ,.
;
.
,320
s:e;rnzno
...
455,16
D ; s ? ~ ~ a s a :?~ieI?l5CU?,
~ce
b:
il\..<.>fr,;stiii:r:.s~ diameter..
- --
- -
~-t;~:,,
- - - - - ~
0.3'.
-
----
.I,
--
- -----.-~
0 52
56.0
;a :
5:: 0
455.16
~-
- - --
---.
i
an&
T', ylnr
%'.'.:!~,os sel-,:::rJ
--
...
'56.31
,h>,.~&.?
925
'1, g,n.!c.c.
<*(
"G:,S!m,ts
of Blsssocne-9S
-- --- --
we:;hi
- - . .--
-.- ..
3 v cil,:ra:r
...
rn"z$:ig?ilon.
i.'lr
:hi? inv?st!yatio-,,
beco w J .
P,
a,
- 5G.uJ
->
0 52
"9
u rnin.
~c.c.
:,
E b p o pi-c.,rurs
~
:
~ i v;.pour
z
pressure d a t a of phosgene has beer. axperimenlaiiy deter%lnr,i by h i k ~ n s o n et oi.', Patelno a n d h.lazzuccheih'~ G e r m a m and Taylor4
anii Glituqus aiid Jones5. Vapoor pressure data i s also presented In ifle
:n:erxai?onoL Critical ~ a b l e s ' . Table 3 gives :ha ;:wiiahle thta o!oiig wl:itb
ihc rncgz of availability.
'fbe mothood adopteo by Germmi: a n d Tayior4 for tile puriiication of the
,.Ii,is!r:
. -.
used is m e n t i m e d earlier.
? h e i n p o u r pressure dati; a r e s:ated iu Le
;ixrti!e to 0.1 a t m . T h e snmpie used by Giauque and J o n e s is stared t o he
99 493 noid 7; pure.
However, t h e accuracy of t h e vapour pressure data are
Pa!erno a n d MrzzucchelEil' have not reported t h e accuracy of
: A ! xported.
tiie &<a. tjermann a n d Taylor4 dctermiiied vrrpouir pressure of phcsgeilr
. ; Y z ~wvo :an;prrarure re_eio:~s,i u n i e l y 273 i G -- 301.06 'I< and 42C.26 - 455 16 'h:.
T b e ~ ss u t h c r s fitted their data t o the s q u a t l c n :
1323
+ ( 1 3 2 % 7' T ' )
Pr:erno a n d M ~ z z u c chelli
..... 243.74-29429
0 2.5-1.75
ill
It
--lor:
,
vapolrr presbure data was caleulilted using Equation [I] and was
f o m d t o 'or: i n very good agreement w i t h t h a t presenrcd in Iuterna:ional
Criricnl Tabics.
For t h i s investigation, the vapour pressure data shove 1 aim. h a s been
from t b e Intzrnetiunal Critical Tables. Beiow d atrn., the data of
Giarrque end Ionea5 has been used.
Zskt::
Equation [2] predicts the vapour pressure data with a maximum diviation
of 0.1%.
rn the present work, t h e vapour pressure d a t a above I atm. was filled :,
the equation,
IO~P=A+(B~T)+CIO~T+DT
[JI
This equation predicts vapour pressure data9 with average absolute and
maximum deviations of 0.1% a n d 0.23% respectively.
mar
155
Heat capacity of phosgene ia the ideal gaseous state have been evaluated
by ~ h o n p o n ' ~Gordon
,
a n d ~ o l a n d ' a n d by Giauque and Ottf
Giauque
and Ott used the constant recommended by Rossini et sl." and Dumond and
cohen3. The data o f Gordon a n d Goland7 deviates by about 5yL with the
data of Giauque and 0 t t 6 .
For this inveszigation, t h e data o f Giauque and OEt has been used. The
hest capacity data of Giauque and Ott was fitted by the method of least
squares to the equation :
Equation [41 predicts heat capacity data with maximum and average
absolute deviations of 0.03% a n d 0.02% respectively. For the calculation of
thermodynamic properties, Equarion [4] has been used.
6.
Heat o f Vaporizotiort :
A K - ( ~ P / ~ T )(VsT . VI)
[-"I
3Y
C.&LCULATIONOF ~ N X M ~ ~ U Y N A M I PROPERTIES
C
Nc u (biH,
--
I B.O5OY(37
&.- i.2038681
u. 10."
Es]
function
of
volunx
TABLE3
Comparlsoo of Calculated Pressures
-
T, "K
P, atms
PCOM, alms.
--
---
96 Deviation
[ill
[I:]
and
Uring Equations 141 and 1101 in the above tquetions and carrying out the
inragrac~on,\re obtain expressions for entrory a n d enthalpy a s :
The reference stale chosen depends upon the available data. The
reference state chosen should f iciliraie easy camparison and utilization of
the t a b ~ L z e c ! & l a . The rrfe,ence state H - 0 and S - R In P - 0 for
*kmkn~6' is appiicable for pure substances and also for pure substances
that undergo a chemical reaction.
1. the presen: work the rererencc s t a t e a s given above itas been used.
AH,.=?-AS,.
[!53
using
rile equations
S, =. Ss
in
- A S:.
to
heck the m t e l n d
10 00
50.00
100.00
-.
5500.8
5501
41C4
0.02
0.04
4706.0
3584.0
2750.2
3533
2760
6.03
0.01
14C5
0.08
240 GOO
300 -- 630
380 - 600
460 600
540 - 600
0.10
0.00
--
--
1466.7
.-
-- -.-- - - -
--
Critical point
Gas or vapoix
Liq aid
Pressure
Temperature
Volume
--
OWr-45h
?*9<
C W W C 1
N N N N
295.1
103.1
754.7
440.0
460.0
H
5
80.07
377.2
-46710
78.69
360.8
- 47026
77.99
721.8
-49025
79.37
420.0
H
S
- 46709
114.6
-47341
75.08
172.1
- 47340
75.88
344.4
-47338
77.26
V
689.0
1% -47338
S
78.64
400.0
77.31
188.5
- 46'911
180.3
- 47027
76.61
109.1
- 47649
74.32
163.8
-47648
75.13
328.0
- 47646
76.51
656.2
- 47646
77.89
76.51
125.6
75.49
75.27
71.97
-47031
74.78
'68.68
- 47344
74.06
65.38
- 43652
73.31
62.08
-47955
72.53
58.79
-45252
71.72
0.90
--
36.63
0.80
74.55
46.96
4489
- 47035
93.85
42.83
47348
93.12
40.76
-49656
72.37
71.59
38.70
- 47958
70.78
- 48256
(contd.)
74.10
37.52
--
73.29
24.94
17.82
-47052
72.00
23.83
87045
72.58
35.87
- 47038
73.40
16.98
- 47364
71.28
22.73
- 47359
71.86
34.21
- 43350
72.67
~,--
18.65
-46735
72.71
16.15
-4762
70.3
21.62
- 47665
71.11
3 2 56
47658
7192
69.75
.- 47974
15.31
14.48
-48271
65.95
--
70.33
20.51
- 47968
69.53
- 48264
19.40
--
2.00
D 0 5 to 3.50
71.64
30.90
- 47961
70.34
29.25
- 482%
.-
1.SO
Pre?=ure Ranse:
-- . --
1.00
120.1
- 47029
75.50
73.55
74'35
380 0
75.73
- 47952
!55.6
- 47951
311.5
- 47950
92.74
98.18
73.35
147.4
- 48249 - 48250
0.30
74.93
- 48248
0.20
77.11
623.3
598.5
-48247
76.30
0.10
0.05
TABLE5-
- 47949
PAtms.
-.
El
360.0
TCK
s'
12.36
-46749
71.88
11.80
- 47065
71.15
V1
'S
u$
11.24c
- 47378 2
70.45 2
$
69.70
?
,
3
?
-- 44bS5
I0.6i
68.9!
-- 47987
1O.ii
68.13
- 48283
9.551
3.00
aim.
...
-. . . . ..
~
.-
0 atrns.
C. T. a n d . .
..
..
---,and
Dtt, J . 5.
..
..
..
..
9.
..
..
Rosrini. F.
.Gucker, F. T.Jr.,
..
Johnston,
l'auling. L. and
Vinal, G . W.
Thompson, W. M.
..
..
10. Martin, J.
J. and Hou, Y. C.
12.
D.,
H . L.,
E3.