cenre Number "ft|*i::"

Raffles Girls' School

(sEcoNDARY)
Estrblishcd in l8?9

Name:

Class: Sec 4 | Register No:

CHEMISTRY
- PAPER 1

PRELIM INARY EXAM I NATION

Friday 26 September 2003 t hour.

INSTRUCTIONS TO GANDIDATES

Do not open this booklet until you are told to do so.

Write your name, Centre number and candidate number on the answer sheet in the
Spaces provided.

There are forty questions in this paper. Answer alt questions, For each question, there are
four possible answers, AB,G and D. Choose the one you consider correct and record your
choice in soft pencil on the separate answer sheel
' Read very caiefully the instructions on the answer sheet.

INFORMATION FOR GANDIDATES

Each correct answer will score one mark. A mark will not be deducled for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 16.

This Question Paper consists of 16 printed pages including the cover page.

flurn over
1. The best representation of a mixnue of ar_eon and heiium inside a balloon is
shown by diagram:

@@@ffi
Gas X was passed through a U-tube irnrhersed. in an ice mixture. The gas
conciensed into a colourless liquid-

Which of the following substances could be X?

Substance Meltine Point l'C BoilinePoint/ "C

A Hydrogen chloride -1 15 -85
B Arnmonia -78 --lJ
\- Sulphur dioxide -t) -10
D Octare -Jt L26

You are asked to s?axate a suspe,nsion of charcoal in a soiution of sodium

chioride and nmmonium chloride so as to obtain all three substances. The
followingprocesses caa be used: (f) Evaporation, (tr) Fileation, Gtr) Sublirnation.
In which order should you carry out these processes?

A (D, CID, @)
B (D, @), @)
c (tr), cD, @)
D @), @), CD
 se'parated' using paper cbromatography: The cbromatoglams
A
A substance X was
are shown below'
Jeveloped using water and ethanol

solvent front

(al (b)

From these experiments' it can be concluded

that X contains
A P onlY
B Q oniY
C R onlY
D either P or Q or R

5.Fivestrrdentseachdissolvedanindigesdonta.'b.letTigoT,ofwater.Theythen
each titrated zio"d-"i,rteir soiutioins
with dilule hydrochioric acid' using the
the table'
same indicator. The results are shown in

A Lrer 1 lL ) l4
Tikation value / ffn' 20.4 I 20.5 7r;120.6 122-0

-Whichstatementcouldexpiaintheresultobtainedbystudentnr:mber5?
acid-
A The burette was washed out vrith hydrochloric
B The pipette was wasbed out with tablet solution'
of the pipefce'
C The student m"^sur"d to the top of the meniscus
DThetitradonflaskwaswashedoutwiththetabietsolution.

6.Wbichoneofthefollowingcorrectlydescribestheparticlesinadilutesait
solution at room temPerature?

Salt ions
I ciose movine at ragdom
A ciose
B close toeethen viblq'u4g sli
*rd"lY seaxarcd: mor-ing at random
\- wideiv ssDarared: not : o1'ng
5 widelv separareq-me1-lgg 3!gg
 This is the srable $ructure sf salglrrrn ign.

I
I
I
I
I
I
I
l
L
It follows tbat an atoo of caicir:m contains
A 20protons, 20 electrons and20neutrons.
B 20protons, 18 elecEons aad20neutrons-
C 20protons, 18 electrons and 18 Deutrons.
D 18 protons, 18 electons and 18 neurons-

8- Z is the atomic number of a noble gas in the periodic table and (Z+L) afi(Z-1)
are the atomic numbers of the elements X and Y respectiveiy. If the elements X
au<l Y are to combine, which-willbe the most likel;r formuia of the compouod-
formed?
AXY
B X;Y
C XYz
D X2Y

9. Silicon carbide has the following $ructure.

Which statement is true forthe compound?

n It is a ver-v hard solid and the atoms are booded in a covalent network.
B It is a soft slippery solid with covalent bsnrling.
c It is a ver-y hard solid with metaiiis lsnding.
D It is a hard soiid with lattice structure.
10. Tflhich of the following occurs in the in&rstrial manufacture of sulpbr:ric acid'?

A Sulphr:r dioxide is dissoived in watcr- l

B Sulphur tioxide is dissolved in water'

C Sulphr:r dioxide is dissolved ja concentrated sulphr:ric acid'
D Su$Ur:r trioxide is dissoived in concentrated sulphuric acid-
:

t1
T I. The tabie below shows the melting and boiling points of.sulphr:r, lead@) bromide
and hydrogen chioride.

Substance M"itiog poiot /'C_ Boiling point / "C

hvdroeen chioride -111 -85
-
A A<
suiphur 1i9
lead(It) bromide 370 910

When the foilowing apparahS is set up, ttre bulb glows-

:-F-{-:
---------
beaker 1 bcaker 2
(25'C) (4O0'C)

Whicb one of the following correctly describes the substances presentin beakers
L an(l-.L!

oC beaker 2 at 400 "C

beaker 1 at 25
A dilutehydrochloricacid lead@) bromide
B lead(tr) bromide dilute h-vdro chioric aci d
C dilutehydrochloric acid sulphur
D lead@) bromide sulpbr:r
 usrng
tbrough aqueous copper(tr) sulphate
c-ulreart was passed
L?. A constant tle copper electrode
plarinum anode and copper cathode- atlSufar-rnjA*t graphs rePresetrts
of tbe foliowing
*"r r.roo.,r"{ dded Ja'*"Wd- Wbich oneagainst time (x-axis)?
ploued
the mass of copper
"i""""Jiy-axis)

a mixture of 20cm3 methane and

40cm3 of
IJ. What volume of air is required for
monoxide to burn comPletelY?
A
"urbo:r 60 cml
B 120 cm'
C 240 cfr'
D 300 crn'

are there in
of x molecuies' how manY molecules
L4- If 1i g of carbon dioxide colsist
7 g of nit'ogen gas?
Yzx
B
C
A*
D
1i Whatisthemaximrrmmassofcalcir:moxidetbatcanbeobtainedbyheating15
of li-*oo" which is 80% Prne?
A 6.72 g
B 8.40 g
C 10.92 g
"D r2g

16.Chlorideionsreactwitb'siiverionsaccordingtothefollowingequation:

Ag- (aq) + Cr(uq) -+ AgC(s)

moVdm3 soiution of the chioride

of a metal X
It was found that 10 cm3 0f a 0.05 soiution for complete reaction'
needed 10 cm, oi u o.i-"ov-o*'-.1"o "l*t"
Wn t is the formula of tbe chloride?
A I'zC.
B .)(UI
C XClz
D XCls

1'r Carbon has isotopic masses

of 12' 13 aad i4' If ethene is forrred from these
Lt.
carbonatoms,whichoftu"folio*ingi,,,ot-"possiblerelativemolecu]ar''.assof
this comPound?
r?O
fr. Jv

B3i
c32
D

18'Whichofthefollowingstate,meltsabouteiectrolysisofdilutesulphuricacidwith
platinr.tm electrodes is not correct?.
A Th" OH-;;; ; preferentiallv discbarged at tfe anode'
as electrolysis proceeds'
B The sulphr:ric acid becom", Jor"-"ooclntrated respectivelv are in the
c nt" g.t:;;;i""t"a ot'o th";;;;;d the anode

ratio 1:2 bYvolume'

rfr" ioi p""'tt i" solution include If' SOt2' and OIf ions'
D
19. A potemial difference is applied between tbe elecuodes of the apparahls sho'*n rn
the diagram

Ptatinum eiecfodes

d€ar cepp€rtll)
iellY cfiromate

Why is a blue colour observed near the negative elect'ode after some time?
A Copper@) chromate is an electrolyte
B The jeliy conducts elecricity.
C Chromare ions are biue in colour.
D Copper@) ions migrate ro the cathode.

20. The pH of the solution obtained by mixing 50cm3 of 0-5moVdm3 hydrochloric

acid and 27cm3 of lmoVdm3 sodium hydroxide solution is
A greaterthan 7
B equal to 7
C less than 7
D between 6 and 8

2'1 The following observations were made when nickel and iron were put separately
into solutions of salts of three metals P, Q and R

Solution
\of Salt of P Salr of Q SaIt of R
Metal
Nickel Yes: disolaced Nor displaced Not displaced
Iron Yes; displaced Yes; dispiaced Not displaced

The correct order of decreasing reactiviry of the five metais is

n R. Q, Fe, Ni, P
tl & Fe, Q, Ni, P
L- & Fe, Ni, Q, P
D P, Ni, Fe, Q, R
22. .I" rh"
experimen! sulphuric acid was added to aqueous barium hydroxide.

carFn Bleclrodes

=
After each additio3, fre-sol-u-tio4 was s{r-red arrd-&e-4mmelerreading noted.,
Which one of the following gaphs corectly represents the reiationship between
the voiume of acid added and the ammeter reading?

d o o

0 tcrorUqprcnl 0 t*reOr+rPd# rOne*tlpoorl 0 voU"cdr5m;c'd'

23. Crysotile, MgSizO;(OFDc, is an asbestos rnineral. From its formula we can

conclude that the oxidation stare of silicon is
A-Z
B+2
L- -.i
nLA
u .-
,,4 of
The reacrion betweeD silver nibate and sodiurr chioride is exoth ermic. Which
the following represents the energy change for this reaction?

'A l*"rg
I

I &cr(si
l-f
rl
tt
I,- | ** i=s).+ cl-'("e)

-
3 | "nerg
I
I NcNq, (i{)
lr
tlrl
I

I
| -Na+'6iq1 + Nol-
ll- (cs)

enersr

Ag* (aq) + Cl-:(is)

I -kcrtsr

DT eD.ersrj

Ni*'.(aq) {-NO; {at)

I
I *** ,""

IU
25. Which sait can be e$trinsd as the insoiuble product of a reaction beween a dilute
icid and an aqueous salt?

A barium suiphate
B copper@) sulphate
masesiuo sulphate
D silver nitrate

26. The rate of reaction between pieces of zinc foil and- 1 moVdo3 hydrochloric acid
was investigated by_recording the total volume of gas produced every minute over
a period of time. The results are sbown in the graph. The zi''c had completeiy
reacted in the reaction-

*u-"rrr
sas,itit

50.

4B

30

IB -j-- -.F - - F- -F- -*--.J

'0 lEe/fTnrn

What results would be expected. if the experiment was repeated using the same
mass of zinc (same size lumps) andthe srme volume of 2-0moVdm'hydrochloric
acid at the same te'mPeratr:re?

Maximum volurre of gas Time at which maximum volume is

produced obtained

A 40 cm3 Less than 4 minutes

B 40 cm3 Longer than 4 minutes
C 80 cm3 Longer than 4 minutes
D 80 cm3 Less than 4 minutes

i1
27. Which starement best explainq wby coal dust forms an explosive mirture with air?

A Coai dust catalyses the explosion-

B Coal dust h:s a large surface area.
C Crushing coal breaks chemical bonds-
D Cmshing coal reieases hydroge'n from compounds in coal'

28. Deuterir:m (symbol D) is an isotope of hydrogen-

'Which forrrula is incorrect for a deuterium compotmd?

at CDc
B CzD:OD
L CaOD
D DCI

29. The apparatus shown in the diagram was used to investigate the rusting of moist
iron.'Th" tube contained 100 cm3 of air at the start of tbe experimenf

'Which graph is the

The volume of gas in the tube was recorded over some days.
most likeiyresult?

B U D
volrna st gas vottna cC Atrs rclunc cd gns bLEmof !,<
uminirg/ crf rsnainhg ./ drf rstrairir€ / mt unlning/qrf
1O0 {
1 _..-.-
I
'1

.n]
--l

Jt
I
I

oL_"*------
lime

L2
30- Chlorinc is passed.into an aqueous solution of a compormd. Z. At first a brown
colorr is see,r and the,n a blackprecipitate appears- What could Z be?
A ammonir:mhYdroxide
B iron(tr) sulPhate
C Potassir:mbromide
D poussium iodide

31. Why are nirates included in fertilisers?

A To helP Piants make sugars-
B To he$ plaats make Protein.
C To help plants grow good roots-
D To neukaiise excess acid in the soil.

32. . Four reactions are given below. In which one is the rmderiined substance acting
as a reducing agent?
A hydrcgen * copoer0toxide') copper + water
B sulphuric acid + magnesium oxide ) magnesium sulphate * watgr
C zinc oxide * carbon monoride ) carbon dioxide + anc
D iron@) chloride + chlorine ) iron(m) chloride

33- The formulae of catalysts used in some important indusuial processes are given in
the table-

Frocess Formrda of catah'st used

Contact process I VzOs
Cracking ofpropane. I AizOl *CrzO:
Manufachre of ethanol I HfO+
Manufacture of poly(ethene) | TiClr + Al(CzHs):
Manufacture of ethanoic acid | (Cl{3COz)zltdn

How many different uansition eiements are included in the list?

A3
B4
c5
D6

13
^,
5+. The stnrctr:ral formulae of three organic compormds &Y,and Z arc shoqrn below.
xYZ
HHH .HHH H HH
lll lll
H-C -C -C-H
ttl
H-C-O-C-C-H
H-O-C-C-C-H
lll
HHH HOH
ttl tlr
H HH
I

Which compormds are isomers of each other?

A XandYoniy
B XandZonly
C Y'and Z only
D X.Y andZ

35. Propaae gas is cracked to produce two hydrocarbons. One of them is methane sas
and the other gas is Q- Wbat is the stnrctr:re of Q?

HH .B H H
tl
II
H-C-C-H t-t
ttl- I
H-C:'C-H
HH
DHIIH.H.
CFTHH
lrl ltrl
H-C-C-C-C-H
H_C-=C-C_H
ttt trtl
HHHH
HH.H

JO- Olive oil contains oleic acid- Oleic acid. is an unsafirrated acid *U"n has tbe
moiecular formula Cr zHl r COzH. How many carbon-carbon double bouds are
present in one molecule of oieic acid?

A1 B2 t-J D4

1 r'l
l-
37 . bottle of wine or beer is left standing in the air for some time, it becomes
.When a'Which
acidic. equation describes the reaction that takes place?

A CILCIIzOH + COz + HOCHzCIIzCQH

B CIITCTIzOII+CII3CO2H -+ CH:CQCIIzCIIT+HzO
C CHrCI{zOI{+Oz -+ CTITCOzH+HzO
D CI{aCOzH -} CIL++ COz

'What
38. The second mernber of a homologous series has the formula CzHs. is the
formula of the first member of this series?

A C6iJ6
B C6I{8
C CtHs
D CeHro

39 . Oy-* the poiynerisation of ethene to fonn polyethene there is no change in .. .

A ratio of carbon to hydrog€n atoms-

B molecular formula-
C densrtY.
D meltingPoint

'Which set contains tbe correct process for converting substance S,to the
40.
product(s)?

Process Substance S Product(s)

A Additionpollmerisation an ester Terylene

B Condensation pollmerisation starch glucose(sugar)
C Hydrolysis protein amino 3sids
D Reduction ethanol ethanoic acid

End ofpaper

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 Candidate
uenre Numoer Numoer

Raffles Girls' School

(SECONDARY)

Name:

Class: Sec 4l Register No:

Ghemistry 5068
_ PAPER 2
PRELIMINA,RY EXAMINA.TION

Friday 26 September 2003 t hour 45 minutes

INSTRUCTIONS TO CANDIDATES

Section A
Answer atl questions.
Write your ansu/ers in the spaces provided on the question paper.

Section B
Answer allthree questions, the last question is in the form of eitherlor.
Write your answers on the lined paper provided.
At the end of the examination, tie the answers of section A and B together.

INFORMATION FOR CANDIDATES

The number of rnarks is given in brackeG[ ] at the end of each question or part
question-
A copy of the Periodic Table is printed on page 15

This Question Paper consists of 15 printed pages including the cover page.

ffum over
 SectionA(50marks)
A-nswer all the questions in this section in the spaces provided.

A1 The element phosphorus is in Group V ofthe Periodic Table.

(i) What is the elecrron arrangenent in a phosphorus atom? [1m]

(ii) Write the molecularformula for aprobabie compound containing

phosphorusandhydrogen- [im]

(iii) Showing only the vaience electrons, draw a ldot and 6xsss' diagram oftle
compound namsd in (ii) above. [1m]

(iv) If lumps of phosphon:s are left in contact with aA thgy start to burn-
Explain why this is unexpected in the iight of your knowledge of
nitrogen. [2m]
A2 A snrdent prepares a soiution of ethanol as showa below-

Sug;ar and Witer cootaiuing

ycast in water Uiliversal Indicaror

(a) (i) What is given to this process ofpreparing ethanol? Iim]

''ame

(ii) The shrdent wants the process to go frster and heats tbe flask- Explain
u&y this may not be a good idea. . [1m]

(b) There is a color:r chaage to the wat€r containing Universal lndicator.

(i) State the colour change observed. Ilml

(ii) Explain the cause of the colour change. Iim]

(c) After the yeast is removed Aom the solution when the reaction has
stopped, the ethanoi is separared from the solution by disullation.

Explain why this separation process is posnble. [1m]

 B Ethane-l, 2 - dioi has the strucnrral formula shown.

HH
tl
tl
rH<-+{
' ll
oo
tl
ll
HH
Whe,n one mole of water is added to one mole of epoxyethane, one mole of
gthane-l, 2 - diol is formed as the only producl

(a) (DGivethemolecnlarformr:laof ethane-1,2-diol [in]

' (ii) Dedlcethe molecularformula of epoxyethane. Iim]

(b) Etlane-l, 2 -diol when dissolved in the water in the radlator of a car acts
as an antifreeze. Ethane-1, 2 -diol freezes at -14oC and boiis at 19fC.
When a sample of the liquid taken from a radiator that contained water
and antifreeze was cooled dowg clystais first appear at atenperature
of -21oC and not at -14oC. Give a probable eiplanation forthe
observation. [1m]
A4 An organic compound, W, contains 37.5oA carbon andT25Yohydrogen, by
maqs- The rest is oxygeo-

When W is oxidised under suitable conditions an acid, { isproduced-

Use the frcts above to answer the following guestions:

(a) Find the probable empirical formula of W- [2m]

(b) To which homologous series of compomd is W? [1m]

(c)Name compound W. [1m]

(d) W and X reacts togetherwhen wamed in the presence of a few drops of

concentrated sulphuric acid to form compound Y.

(i) Draw the structural formula of Y- [im]

(ii) Name compornd Y. [lm]

(iii) State one use ofY. [1m]

(a) One way of getting zinc from the mineral sphalerite is outiined below.

Electroiysis

(D Aprt from 'jnc, name another eiernent that is present in

r I

sphalerite- [1m]

(ii) Explain why the sulphr:r dioxide fomed should not be allowed to escape
into the air for econornic and environme,ntal reasons. [2n]
.cconouuc reasons:

Environmental reasons :

(iii) Descnbe experiments you could carry out and statetle results you
would obtain to confrm the prese,nce of zinc sulpbate. [4m]
O) Zinc blocks are anached to the steel hulls of ships, as shown in the
diagram-

(i) How does thezinc protectfte hullfromrusting? t2nl

(ii) What would be the effect of using copper blocks instead of zinc? [hn]
AO The dia-e5am below shows an indusrial ceii forthe manufacture of sodium anA
chlorine by rhe eiecrolysis of noiten sodium chloride.

Moltea Moltea
soorum sodium
--
_
- =_H__l-+-==l
= -:--^ - l--;r r=-l =. Moltcn
oirturc
conuining
----i i-=;-l;i l--.r-- sodium

-]i n i=i B li-i-:-I

-=:l
chloridc

(a) in the diagram above, labei the elecrodes A, B and C rdth + or - .ls
appropriate inthe circles below the electrodes. [lm]
(b) Write an eqrufion of the reaction that occurs at A-
[1m]

(c) Why are theproducts separaed by the hood?

Iim]

(d) Suggest why the hood does not exrend to the botom ofthe cell.
liml

(e) Why must tbe sodir:m chioride be molten and not solid?
[lm]

(D Vfhy is aqueous sodium chloride unsuitable?

[1m]

(g) why must all the air be excluded from the parts of the ceir iabelled x?[lm]

(h) Electrodes A and c are made of steel but B is made of graphite- Explain
why electrode B is not made of steel [1m]
A1
nt This question is mainly concerned wiih air pollution

(a) Freonsare compounds used as 'propellants' in aerosols- The propellant is

a liquid obtained by putting a gas rmder pressure. Many scientists beiieve
that freons desuoy a protective part ofthe Eafih's atmosphere and
manufacturen are advised to use other substinrtes.

What is the protective part of the earth made of and explain why this parr
is important? [2n]

(b) Vehicles are fined with catalytic converters which change exhaus gases
such as carbon monoxide and nitrogen monoxide into a more acceptable
form of emission

To
atnosphere

(i) Elplain why carbon monoxide is a poliutant. [1m]

One design of catalytic converter is shown beicw:

EXHAUST
G45ES -J

TO
ATilOSPHERE

CATALYTIC CONYEFTER

Each of the cataiysts, which only works at a fairly high te'mperature'

brings about one of the foilowing reactions:

2CO(g) + QG) -+ 2CQ(g)

zNO(g) -+ Nz(g) + Oz(g)

 (ii) which one of the two gases, carbon monoxide or niu'oge,n monoxide, is-.
renoved (coaverted) bY cataiYst B?
Give a reason for your answer. [2m]

(iii) Assr:ming that 10 dm3 of carbon monoxide e,tters the catalytic

conv€.fter, calanlate the minimum volume of ar, meas:red atroom
te,mperanne and pressure, needed to completely conY€rt thj cabon
monoxide to carbon dioxide.Qgnore the oxygeo produced fro,m the other
reaction in the cataiytic converter) t2nl

(c) FerUliSerS such as ammonir:m nitrats s1 rmmonirrm phosphate are needed

for plants to grow weil These ferblisers are ofte,n washed away when there
is hearyrain
E>rplain an environme,lrtal problem tbatthis would cause. [2m]

A8 Aqueous hydroge,t peroxide, HzOz, reacts with acidified agueous potassium

manganate(Vll) as shown:

5HzQ(aq) + 2\lnO4laq) + 6rf(aq) -+ 5QG) + 2lvfn2*(aq) + 8H2O0)

(a)'State the colotr cbange you wor:ld see when ]vfnO+ reacts with the
hydrogenperoxide. [1m]

(b) type of chemicai change happens to the lrdnOr- in the reaction? Give'
' ' What
ureasooforyouranswer. [2m]

10
 Section B (30 mad<s)

Answer all three questions from this section-

The tast quesrion is in the form of either/or and only one of the alternatives should be
anempted.

89 (a) iron, nicket and platinum can act as calysts. Severai indr:strial reactions
use cataiysts to iower the cost of the manufrcn:red products.

(i) Wbat tlpe of metals are abie to act as catatysts? [lm]

(ii) Name an industrial process that uses a cataiyst and name the *Ti*,

(iii)Give a balanced che,nical equation forthe reactionthat uses the catalyst

you named in (ii). [1m]

(iv) E>plam how a cataiyst is abie to lower the cost of some manufrctured
products [2m]

(b) Fineiy powdered. iron can be used as a catalyst for the laboratory
decomposition ofhydrogen peroxide.
:

ZHzAz-+ZHzO + Oz

(i) Althoug! iron does act as a catalyst forthis decomposition, it is not

suitable. E{piain why iron is not a suitable catalyst- [1n]

(ii) iron is extracted from iron(Itr) oxide in the

blasc fumace- Calculate tbe
maximum mass of iron that can be obtained from 3000 tomes of iron
ore that contains 70% iron(Itr) oxide. [2n]

(c) The relative molecularmass of iron carbonyl, Fe(COX, was formd to be

196. Whe,n. strongly heated, this compotnd decomposes to form iron and
carbon monoxide.
Determine the value of x and hence write the equation for its thermal
decomposition- t2rnl
810 (a) .4a investigation iato the reaction of Iithium with water is carried out b-v
two mrdents both using the appararus below:

Hydrogcn
Thermometer
l(D crn3 measuring
cylindcr
Wire

The voir:me ofhydrogen collected at lO-second intervals is noted-

Time in seconds u i0 20 30 40 fU 50
Totai volume ofhydrogen in Stud€nt A 0 24 39 48 )5 55 ff
cmt Student B 0 9 35 62 81 95

(i) On the same axes, piot a graph of totai volume ofhydrogen obtained
against time for snrdents A and B- L"abel the graph as student A and
snrdent B.
[2m]

(D Expiain why the volume of\,vdrogen collected by each student is

different Iim]
(iii) Give a possible reason forthe difFerence in the rate ofreaction- [im]
(iv) Student B was unable to record the volume ofhydrogen at 60 seconds-
Suggest one reasonwhlrhe was rmable to do so. [1n]

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