Period/Topic
Worksheets
1.
2.
3.
WS 2
4.
WS 3
5.
WS 4
6.
WS 5
7.
WS 6
8.
Electrochemical Cells.
WS 7
9.
10.
Electrolytic Cells.
11.
12.
13.
Quiz
WS 1
WS 8
WS 9
14.
WS 10
15.
Review.
Internet Review
Practice Test 1
16.
Review
Practice Test 2
17.
Test.
Worksheet #1
Define each
1.
2.
3.
4.
Oxidation
Reduction
Oxidizing agent
Reducing agent
Write half reactions for each of the following atoms or ions. Label each as oxidation or reduction.
5.
Al
6.
7.
O-2
8.
Ba2+
9.
N3-
10.
Br2
11.
12.
Ca
13
Ga3+
14.
15.
H2
16.
H+
17.
F-
18.
P3-
Balance each spontaneous redox equation. Identify the entities reduced and oxidized. State the
reducing agent and the oxidizing agent.
19.
Al
&
Zn2+
20.
F2
&
O2-
21.
O2
&
Ca
22.
Al3+
&
Li
Write the oxidation and reduction reactions for each redox reaction. The first one is done for you.
23.
24.
Fe2+
Co
Oxidation:
Co
Co2+
2e-
Reduction:
Fe2+
2e-
Fe
3 Ag+
Co2+
Fe
Ni
Ni3+
3 Ag
Pb
Pb2+
Cu
2 Sn
O2-
2 Sn2+
Oxidation:
Reduction:
25.
Cu2+
Oxidation:
Reduction:
26.
O2
Oxidation:
Reduction:
Co2+
27.
2 F-
Co
F2
Oxidation:
Reduction:
28. There are nine formulas for oxidizing agents from questions 19 to 28. List them all. Only
consider formulas that are on the left side of any equation. The first one is done for you.
Zn2+
29. There are nine formulas for reducing agents from questions 19 to 28. List them all. Only
consider formulas that are on the left side of any equation. The first one is done for you.
Al
Worksheet #2
1.
2.
_____
b) H2SO4
_____
c) ZnSO3
_____
d) Al(OH)3
_____
e) Na
_____
f) Cl2
_____
g) AgNO3
_____
h) ClO4-
_____
i) SO2
_____
j) K2Cr2O4
_____
k) Ca(ClO3)2
_____
l) K2Cr2O7
_____
m) HPO32-
_____
n) HClO
_____
o) MnO2
_____
p) KClO3
_____
q) PbO2
_____
r) PbSO4
_____
s) K2SO4
_____
t) NH4+
_____
u) Na2O2
_____
v) FeO
_____
w) Fe2O3
_____
x) SiO44-
_____
y) NaIO3
_____
z) ClO3-
_____
aa) NO3-
_____
bb) Cr(OH)4
_____
cc) CaH2
_____
ee) Fe(H2O)63+
_____
ff) CH3COOH_____
_____
b) C
_____
c) CO2
_____
d) CO32-
_____
e) C2H6
_____
f) CH3OH
_____
3.
a)
b)
For each of the following reactants, identify: the oxidizing agent, the reducing agent, the
substance oxidized and the substance reduced.
Cu2+ (aq) +
Zn (s)
Cu(s) +
Zn2+ (aq)
Substance oxidized
Oxidizing agent
_____
_____
Cl2 (g) +
2 Na (s)
Substance oxidized
Oxidizing agent
Worksheet # 3
Substance reduced
Reducing agent
2 Na+ (aq)
_____
_____
_____
_____
2 Cl- (aq)
Substance reduced
Reducing agent
____
_____
Au3+
Fe2+
Au
2.
Pb
Fe2+
Pb2+
3.
Cl2
F2
4.
S2O82- + Pb
2SO42-
+ Pb2+
5.
Cu2+ +
2Br-
Cu
Br2
6.
Sn2+
Br2
Sn4+ +
2Br-
7.
Pb2+
Fe2+
Fe3+ +
Pb
8.
Can you keep 1 M HCl in an iron container? If the answer is no, write a balanced equation for
the reaction that would occur.
9.
Can you keep 1 M HCl in an Ag container? If the answer is no, write a balanced equation for
the reaction that would occur.
10.
Can you keep 1 M HNO3 in an Ag container? If the answer is no, write a balanced equation
for the reaction that would occur. (HNO3 consists of two ions H+ and NO3-)
Fe3+
Fe3+
F-
2Cl-
11.
Can you keep 1 M HNO3 in an Au container? If the answer is no, write a balanced equation
for the reaction that would occur. (Remember, HNO3 consists of two ions H+ and NO3-)
12.
O2
Na+
Fe
13.
14.
Al3+ +
Zn
Al
Zn2+
Cr2O72-
ClO2-
Cr3+
ClO4-
__________
__________
__________
b) H2SO4
d) Al(OH)3
f) Cl2
17. Balance the redox equation using the half reaction method.
Al
&
AgNO3
Cl-
Fe
Na+
__________
__________
__________
23.
24.
25.
26.
27.
CaH2
NaIO3
C4H12
Al2(SO4)3
Al3+ +
Zn
Substance oxidized
28.
Cr2O72- +
__________
Oxidizing agent
ClO2-
Substance reduced
29.
__________
__________
__________
__________
Al
Cr3+
__________
O3 + H2O + SO2
3As2O3
__________
+ 2H+
Reducing agent
__________
ClO4-
Oxidizing agent
SO42- + O2
Substance oxidized__________
30.
Zn2+
Reducing agent
__________
+ 4NO
__________
Worksheet # 4
Balance each of the following half-cell reactions. (In each case assume that the reaction takes place
in an ACIDIC solution.) Also, state whether the reaction is oxidation or reduction.
1.
S2O32-
SO42-
2.
MnO4-
Mn2+
3.
As
AsO43-
4.
Cr3+
Cr2O72-
5.
Pb2+
PbO2
6.
SO42-
7.
NO3-
NO
8.
NO3-
NH4+
9.
BrO3-
Br2
NO3-
NO
11.
MnO4-
Mn2+
12.
As
AsO43-
13.
Cr3+
Cr2O72-
14.
Pb2+
PbO2
15.
SO42-
16.
S2O32-
17.
NO3-
NH4+
18.
BrO3-
Br2
SO42-
SO42-
________________
CaO
Ca
________________
CrO42-
Cr2O72-
________________
CrO42-
Cr3+
________________
20.
2I-
I2
________________
IO3-
I2
________________
MnO4-
Mn2+
________________
ClO2-
ClO-
________________
Cr2O72-
Fe2+
Substance oxidized
Oxidizing agent
Worksheet # 5
Cr3+
_____
_____
Fe3+
Substance reduced
Reducing agent
_____
_____
Balance each redox equation. Assume all are spontaneous. Use the half reaction method.
1.
O2-
F2
2.
Al
O2
3.
Zn+2
Cr2O72
5.
Cr3+
NO
NO3-
6.
SO42-
SO2
7.
MnO2
Mn2O3
Balance each redox reaction in acid solution using the half reaction method.
8.
H2O2 +
Cr2O72-
9.
TeO32- +
N2O4
10.
ReO4- +
IO-
11.
PbO2 +
I2
12.
As
O2
Te
IO3-
NO3-
Pb2+
IO3-
H2AsO4-
AsH3
Balance each redox reaction in basic solution using the half reaction method.
13.
O2
Cr3+
H2O2
Cr2O72-
14.
Te
NO3-
TeO32-
N2O4
15.
IO3-
Re
ReO4-
IO-
Cr3+
Re
16.
Pb2+
17.
Cr2O72- +
IO3-
Hg
PbO2
Hg2+
I2
Cr3+
State of the change represents oxidation, reduction or neither. Use oxidation #s. Remember that if the
oxidation # increases it means oxidation and when it decreases it mean reduction!
18.
MnO2
Mn2O3
19.
NH3
NO2
20.
HClO4
HCl
21.
O2
O2-
22.
P2O5
P4H10
H2O
H2S O4
22.
HS O4-
24.
P4
23.
NaH
25.
U O3
24.
Na2O 2
26.
U 2O5
25.
P b SO4
Worksheet # 6
1.
Review
2. Write half reactions for each. Describe as oxidation or reduction. Circle all oxidizing agents.
a)
b)
c)
d)
e)
f)
Na
Ca
Al3+
F1N2
O2-
3.
Write the reaction between the following: Use the half reaction method.
a)
Ca
Al(NO3)3
b)
Sn
AgNO3
c)
Sn
Au(NO3)3
Cu
Cu+
Al
Al3+
O2-
O2
4.
5.
6.
Ni+2 reacts with Mn, however, Al+3 does not react with Mn. Rank the oxidizing agents in order
of decreasing strength. Rank the reducing agents in order of decreasing strength.
7.
Ag+ reacts with Pb, however, Ca+2 does not react with Pb. Rank the reducing agents in order
of decreasing strength. Rank the oxidizing agents in order of decreasing strength.
8.
Cl2 reacts with Ag, however, Ag does not react with Mg+2. Rank the oxidizing agents in order
of decreasing strength. Rank the reducing agents in order of decreasing strength.
9.
Ni+2 reacts with Mn, however, Al+3 does not react with Mn. Rank the reducing agents in order
of decreasing strength. Rank the oxidizing agents in order of decreasing strength.
10.
Cl2 reacts with Br-, however, I2 does not react with Br-. Rank the oxidizing agents in order of
decreasing strength. Rank the reducing agents in order of decreasing strength.
SO42-
S2-
12.
MnO2
MnO4-
13.
Cr2O72-
CrO42-
14.
IO3-
I2
15.
16.
&
&
&
Ni
Fe
Fe
Spontaneous
Spontaneous
Non spontaneous.
i)
ii)
iii)
iv)
v)
H2S
MnO
17.
Br2
S2O32- +
MnO4-
18.
19.
20.
ZnCl2 &
Br2
Cu
&
BrO3-
2+
Fe
H2S
b)
d)
CuCl2 &
H2S
MnO
NaCl
&
Al3+
SO42- +
Br2
S2O32- +
BrO3-
Classify as an oxidizing agent, reducing agent or both based on its position on the table.
State the Eo or voltage of its position. Some of these are both, so state two voltages and indicate that it
can be an oxidizing and reducing agent.
e.g.
MnO422.
23.
24.
25.
26.
(in acid)
oxidizing agent
1.51 V
Br2
_________________
_________________
Fe2+
_________________
_________________
MnO4 (water)_________________
_________________
Ni
_________________
_________________
3+
Cr
_________________
_________________
27.
H2O
_________________
_________________
Write each oxidation and reduction half reaction for each question above. Determine the Eo for each.
Calculate the Eo for the overall reaction.
34.
35.
36.
Worksheet # 7
Electrochemical Cells
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Anions have a
Zn / Zn(NO3)2
ll
Cu / Cu(NO3)2
charge.
.
.
12.
Ag / AgNO3
ll
H2 / HCl
Worksheet # 8
Electrolytic Cells
1.
2.
3.
to
4.
to
5.
6.
Corrosion of a metal is
7.
Electrolysis
8.
Electrochemical cells
9.
Electrolytic cells
10.
Molten NaCl
.
electrical energy.
electrical energy.
electrical energy.
Eo =
12.
Aqueous Na2SO4
13.
Liquid K2O
14.
1.0 M LiI
15.
250.0 mL of 0.200 M MnO4- reacts with excess SO3-2. How many grams of
MnO2 are produced? This is Chemistry 11 stoichiometry.
2MnO4- + 3SO32- + H2O 2MnO2 + 3SO42- + 2OH-
16.
17.
Anode
Cathode
Spontaneous
Electron affinity
18.
What would happen if you used an aluminum spoon to stir a solution of FeSO4(aq)? Write a
reaction and calculate Eo.
19.
20.
250.0 mL of 0.500 M MnO4- are required to titrate a 100.0 ml sample of SO3-2. Calculate the
[SO3-2]
2MnO4- + 3SO32- + H2O 2MnO2 + 3SO42- + 2OHHow is the breathalyzer reaction used to determine blood alcohol content (you might need to
look this up in your textbook?
21.
22.
Worksheet # 9
Reducing agent_________
Determine the half reactions for each cell and the cell voltage or minimum theoretical voltage and
overall equation.
1.
Ag / Pb electrochemical cell.
Anode:
Anode reaction:
Overall reaction:
2.
Cathode:
Cathode reaction:
Voltage:
Cathode:
Cathode reaction:
MTV:
3.
4.
5.
Cathode:
Cathode reaction:
MTV:
Cathode:
Cathode reaction:
MTV:
Cathode:
Cathode reaction:
Possible Electrolyte:
7.
Cathode:
Cathode reaction:
Possible Electrolyte:
8.
Cathode:
Cathode reaction:
Possible Electrolyte:
Worksheet # 10 Electrolytic, Electrochemical Cells, Corrosion, & Cathodic Protection
Determine the half reactions for each cell and the cell voltage or minimum theoretical voltage.
1.
Zn / Mg electrochemical cell
Anode:
Anode reaction:
Overall reaction:
Cathode:
Cathode reaction:
Voltage:
2.
3.
Electrolyte:
Anode:
Anode reaction:
Overall reaction:
The electrolysis KI(aq)
Anode:
Anode reaction:
Overall reaction:
Cathode:
Cathode reaction:
MTV
4.
The electrorefining of Pb
Anode:
Anode reaction:
5.
Cathode:
Cathode reaction:
6.
7.
8.
9.
10.
Draw a Cd/Pb electrochemical cell. Cd is not on the reduction chart, however, the Cd
electrode gains mass and the total cell potential is 0.5 v. Determine the half-cell potential for
Cd.
11.
Write the overall reaction and describe the anode and cathode for a Zn/C, fuel, alkaline and
lead/acid cell.
12.
2HIO3 +
5H2SO3
oxidizing agent
substance reduced
I2 +
5H2SO4
H2O
substance oxidized
reducing agent
13.
14.
15.
Describe the differences and similarities between an electrolytic and electrochemical cell.
16.
17.
18.
19.
20.
21.
State two metals that can be used to cathodically protect Fe. Describe how they protect iron
from corrosion.
22.
23.
Write the half reaction that describes the reduction reaction that occurs when iron corrodes in
air and water.
24.
25.
Write the anode and cathode reaction in an electrolytic cell with a CaCl2(l) electrolyte.
26.
27.
28.
29.
Write the anode and cathode reactions for each of the above processes.
30.
Al and AgNO3(aq) are mixed and the surface of the Al darkens. List the two oxidizing agents in
decreasing strength. List the two reducing agents in decreasing strength.
31.
Analyze This
1.0 M KNO3
Ag
Mg
1 M Mg(NO3)2
Pt
1 M AgNO3
Pt
1 M CuSO4
is oxidized
is called the cathode
C.
D.
2.
3.
Fe3+ to Fe2+
Fe2+ to MnO4MnO4- to Fe2+
MnO4- to Mn2+
8.
Fe2+
Fe3+
Mn2+
MnO4-
7.
6.
Ag, Pt, Au
Pt, Au, Ag
Au, Ag, Pt
Au, Pt, Ag
5.
Cu2+
Pb2+
Ni2+
Sn2+
Metallic platinum reacts spontaneously with Au3+(aq) but does not react with Ag+(aq). The metals,
in order of increasing strength as reducing agents, are
A.
B.
C.
D.
4.
Cu
Fe
Sn
Zn
A spontaneous redox reaction occurs when a piece of iron is placed in 1.0 M CuSO4. The
reducing agent is
A.
B.
C.
D.
9.
10.
Hg2+
13.
12.
loses protons
gains protons
loses electrons
gains electrons
A strip of titanium, Ti, is placed in 1.0 M Sn(NO3)2. The shiny surface of the titanium darkens,
indication that a reaction has occurred. From this observation it may be concluded that
A.
B.
C.
D.
11.
is a
Fe
Cu2+
H2O
SO42-
loses mass
is oxidized
is the oxidizing agent
increases in oxidization number
Samples of Uranium, Vanadium and Yttrium (U, V, Y) were placed in solutions containing the
metallic ions U3+, V2+, and Y3+. The following observations were recorded.
Trial
1
2
3
4
Ion
U3+
V2+
V2+
Y3+
Metal
Y
U
Y
V
Observation
reaction
reaction
reaction
no reaction
B.
C.
D.
2.
3.
increases by 2
increases by 4
increases by 8
does not change
4.
5.
NO3- NO
N2O4 NI3
NH3 NH4+
NO2 N2O5
6.
I2
H+
Fe2+
IO3-
Consider the following half reaction: Sb2O3 + 6H+ + 6e- 2Sb + 3H2O
The oxidation number of antimony in Sb2O3
A.
B.
C.
D.
7.
8.
+2
0
+4
+1/2
10.
HClO2 HClO
9.
increases by 3
increases by 6
decreases by 3
decreases by 6
11.
12.
H2O
MnO4CH3CHO
CH3COOH
H2
NaH
H2O
KOH
(basic)
14.
15.
reduction
oxidation
neutralization
decomposition
Al
MnO4Al(OH)4MnO2
16.
17.
N2
NO2
NH3
HNO3
18.
II2
H+
ClO3-
reduction
oxidation
electrolysis
neutralization
+2
+3
+4
+6
20.
Cl2
Cr3+
H2O
Cr2O72-
2.
E0 = 0.73 V
-0.86 V
-0.60 V
+0.60 V
+0.86 V
Which of the following systems would be correct if the zinc half-cell would have been chosen
as the standard instead of the hydrogen half-cell?
A.
The reduction potentials of all the half-cells would remain unchanged
B.
The reduction potentials of all the half-cells would increase by 0.76 V
C.
The reduction potentials of all the half-cells would have positive values
The reduction potentials of the hydrogen half-cell decrease by 0.76 V
3.
Three beakers contain 1.0 M CuCl2. A piece of metal is placed in each of the beakers
BEAKER
1
2
3
SOLUTION
CuCl2
CuCl2
CuCl2
METAL
Zn
Ag
Ni
Reactions occur in
A.
B.
C.
D.
4.
beaker 2 only
beakers 1, 2, and 3
beakers 1 and 2 only
beakers 1 and 3 only
D.
What two substances are produced when Cr and 1.0 M MnO4- react in a basic solution?
A.
B.
C.
D.
6.
II2
ClCl2
The substances H2O2, H3PO4 and H2SO3 in order of increasing strengths as oxidizing agents
are.
A
B.
C.
D.
8.
7.
+0.06 V
+0.39 V
+1.21 V
+1.54 V
9.
10.
11.
Zn
ClSn2+
Fe3+
15.
Referring to the data booklet, which of the following can act as an oxidizing agent but not as a
reducing agent?
A.
B.
C.
D.
14.
IO3- and I2
SO42- and S
BrO3- and Br AuCl4- and Au
13.
12.
tin
zinc
aluminum
magnesium
In a redox reaction, ClO- was converted to Cl- in a basic solution. The balanced half-reaction
for this process is
A.
B.
C.
D.
1.0 M KNO3
Pb
Zn
1M Zn(NO3)2
1.
2.
3.
1M Pb(NO3)2
-0.89 V
-0.63 V
+0.63 V
+0.89 V
4.
5.
Zn2+ + 2e- Zn
Pb2+ + 2e- Pb
Zn Zn2+ + 2ePb Pb2+ + 2e-
6.
Zn2+ + 2e- Zn
Pb2+ + 2e- Pb
Zn Zn2+ + 2ePb Pb2+ + 2e-
7.
Which of the following is formed at the anode during the electrolysis of 1.0 M NaI?
A.
B.
C.
D.
8.
I2
O2
H2
Na
Power Source
Pt
9.
+
Pt
Molten
towards
theMgCl
anode
2 through the wire
towards the cathode through the wire
C.
D.
voltmeter
1.0 M KNO3
Cu
Mg
1 M Mg(NO3)2
10.
11.
14.
13.
12.
1 M CuSO4
2.03 V
2.52 V
2.71 V
2.89 V
Which of the following aqueous solutions produces H2(g) and O2(g) during electrolysis
A.
1.0 M KI
B.
1.0 M CuI2
C.
1.0 M K2SO4
D.
1.0 M CuSO4
In the electrolysis of molten zinc chloride, the half-reaction at the anode is
A.
B.
C.
D.
voltmeter
1.0 M KNO3
Ag
Ni
1 M AgNO3
1 M Ni(NO3)2
15.
16.
17.
-1.06 V
-0.54 V
+0.54 V
+1.06 V
voltmeter
1.0 M KNO3
Pb
Au
1 M Au(NO3)3
1 M Pb(NO3)2
18.
19.
20.
-1.37 V
0.00 V
1.37 V
1.63 V
22.
21.
Cr3+ Cr
Cr3+ Cr2+
Cr3+ Cr2O72CrO42- Cr2O72-
The corrosion of iron can be prevented by attaching a piece of zinc to the iron because
A.
B.
C.
D.
2.
An iron spoon is electroplated with copper. The equation representing the reduction
reaction is
A.
B.
C.
D.
A.
B.
C.
D.
ANODE
carbon
pure lead
pure lead
impure lead
D.
4.
3.
In an operating zinc-copper electrochemical
cell, the oxidizing agent
A.
B.
C.
gains electrons from the anions
oxidation of anions
reduction of cations
reduction at the anode
oxidation at the cathode
7.
CATHODE
impure lead
carbon
impure lead
pure lead
6.
5.
dry cell
fuel cell
alkaline cell
lead-acid storage cell
8.
A.
B.
C.
D.
Power Source
Iron Key
Pt
1.0 M CuSO4
9.
In the electrolysis of molten PbBr2, the products at the anode and cathode are
A.
B.
C.
D.
10.
CATHODE
(INERT)
ANODE
(INERT)
Br2
O2
Pb
Br2
H2
Pb
Br2
Pb
Cathode
Anode
Cu
Mg
Mg
Ag
Pb
11.
12.
Ba2+
Al3+
Sn2+
Na+
produce fuel
electrolyze fuel
produce hydrogen
produce electricity
17.
16.
15.
2e- Pb
Pb2+ + 2ee- Ag
Ag+ + e-
14.
Pb2+ +
Pb
Ag+ +
Ag
13.
Cu
Pb
Ag
19.
Quiz #6
Which of the following metals could be used to cathodically protect a sample of lead?
iron
gold
silver
copper
3.
2I- I2 + 2eNa+ + e- Na
H2O + O2 + 2H+ + 2e2H2O +2e- H2 + 2OH-
A.
B.
C.
D.
2.
is reduced
loses mass
is the reducing agent
is the site of reduction
When 1.0 M NaI is electrolyzed, bubbles of gas form on one electrode and a reddish-brown
substance forms on the other. The half-reaction at the cathode is
A.
B.
C.
D.
1.
making it a cathode
placing it in an acidic solution
attaching a small piece of lead to it
attaching a small piece of gold to it
To determine the [Fe2+] in a solution of FeSO4 by a redox titration, a suitable reagent would
be an acidified solution of
A.
B.
Cr3+
Mn2+
C.
D.
4.
As a metal corrodes,
A.
B.
C.
D.
5.
9.
Mn
Cu
Pb
Sn
8.
7.
it gains electrons
it becomes reduced
it acts as a reducing agent
its oxidation number decreases
6.
SO42Cr2O72-
Br2
SO2
H2O
Na2SO4
The reaction that occurs when pieces of lead, zinc, copper and silver are placed in a solution
of Ni(NO3)2 is
A.
B.
C.
Pb + Ni2+ Pb2+ + Ni
Zn + Ni2+ Zn2+ + Ni
Cu + Ni2+ Cu2+ + Ni
D.
voltmeter
1.0 M KNO3
Cu
Pb
1M Pb(NO3)2
10.
11.
1M Cu(NO3)2
0.03 V
0.21 V
0.29 V
0.47 V
12.
A.
B.
C.
D.
13.
0.0131 L
0.0262 L
0.200 L
0.400 L
Cu2+
Cu
2)
Fe2+2
Zn2+
Au3+
Hg(l)
Cu2+
Sn4+
Ba
Al
4.
5.
Will AgNO3 react with Zn? Write a balanced redox reaction and calculate Eo
6.
7.
What would happen if you used an iron spoon to stir a solution of Al2(SO4)3(aq) ? Write a
balanced redox reaction and calculate Eo.
What are the differences between an electrochemical cell and an electrolytic cell?
Electrochemical cell
8.
Electrolytic cell
What are the similarities between an electrochemical cell and an electrolytic cell?
9.
State how you would determine each of the following in an electrochemical or electrolytic
cell.
Electrochemical Cell
The site of reduction
The site of oxidation
The +ve electrode
The -ve electrode
Electrolytic Cell
Draw an operating electrochemical cell using an Al half-cell and a Mg half-cell. Label the
parts of the electrochemical cell including the anode or cathode, and all reagents and materials
used. Write the reactions and determine the E0.
11.
Write the half reaction that occurs at each electrode during the electrolysis of aqueous
1.0 M NaI.
Anode :
Cathode :
What is the minimum required voltage for this process?
12.
Write the half reaction that occurs at each electrode during the electrolysis of molten NaI.
Anode :
Cathode :
What is the minimum required voltage for this process?
13.
(iii) Describing how the problem of the high melting point ofAl2O3 is overcome.
14.
Eo = +0.64 V
3V2+ + 2Al
Eo = +0.46 V
3V + 2Al3+
Based on these observations, a student concludes that Ga+3 and Al will react spontaneously.
List the oxidizing agents in order of decreasing strength. Write reduction reactions for each.
Determine the strongest reducing agent. Determine if Ga+3 and Al will react spontaneously.
15.
Balance the equation for the following half reaction occurring in acid solution:
V(s)
16.
HV2O73-
17.
C2O42-
MnO2
CO2
250.0 ml 0.200M MnO4- reacts with excess SO32-. How many grams of MnO2 are produced?
2MnO4- + 3SO32- +H2O 2MnO2 +3SO42- + 2OH-
18.
MnO2
IO3-
Cr2O72-
C2O42-
HOOH
NO3-
H3PO4
Na2C2O4
19.
Al(NO3)3 NH4Cl
I2
N2O3
NaH
Pt(H2O)42+
250.0 mL of 0.500M MnO4- are required to titrate a 100.0 ml sample of SO3-2. Calculate the
[SO3-2]
2MnO4- + 3SO32- +H2O 2MnO2 + 3SO42-+ 2OH-
20.
How is the breathalyzer reaction used to determine BAC? Write the reaction and describe how
it works.
21.
2H+
Mg
Mg2+ +
H2
23.
a) Fuel cell
b) Charging a car battery
c) Discharging a car battery
d) Ni plating
e) Industrial Al production
f) Cl2 production
g) Electrowinning
24)
Which of the reactants is gaining electrons? Which of the reactants is the oxidizing agent?
Br2 + SO2 + Na2SO4 + H2O 2H2SO4 + 2NaBr
25)
26)
Cu
27.
List the anode, cathode, anode reaction , cathode reaction, and electrolyte for each
commercial electrochemical cell.
Cell
electrolyte
Leclanche or
Common Dry
Cell
Alkaline Cell
Lead Storage or
Car Battery
Fuel Cell
28.
Which of the above cells requires continuous input of O2 and H2 and is produced by Ballard
Industries.
29.
List the anode, cathode, anode reaction, cathode reaction, and electrolyte for each commercial
electrolytic cell.
Cell
Electrolysis of
Molten Al2O3
Electrolysis of
Aqueous NaCl
Silver-plating a
Cu plating
Electrorefining
pure Pb from
impure Pb
30.
salt bridge
electrolyte
electrolyte
anode
cathode
spontaneous
electron affinity
cation
anion
electrochemical
cell
electrolytic cell
oxidation number
electrolysis
oxidation
reduction
oxidizing agent
reducing agent
electrode
corrosion
electrowinning
electrorefining
over potential
effect
fuel cell
31.
Define corrosion of a metal, and illustrate your definition with reference to an example, using
appropriate equations. Give TWO methods by which corrosion can be prevented and describe
how each method works. The two methods must involve different chemical principles.
32.
33.
A2+ does not react with B, while C2+ reacts with B. Rank the oxidizing agents in decreasing
order of strength. Rank the reducing agents in decreasing order of strength. Will A2+ react with
C?
34.
Write half reactions for each using the reduction table and list the half-cell potential.
Half Reaction
oxidation of water
oxidation of water in acid
reduction of water
reduction of water in alkaline
oxidation of H2 in water
oxidation of H2 in acid
oxidation of H2 in base
reduction of Cr2O72- in acid
Eo
reduction of HBr
35.
voltmeter
1.0 M KNO3
Cu
Zn
1 M Zn(NO3)2
1 M Cu(NO3)2
36.
voltmeter
1.0 M KNO3
H2(g)
Cu
1 M HCl
1 M Cu(NO3)2
Power Source
Molten Al2O3
Anode Reaction
Cathode Reaction
Chemicals produced at the anode
Chemicals produced at the cathode
The electrons flow from __to __
The chemical used to lower the mp is:
Which electrode is the anode ?
38.
Completely analyze the following electrolytic cell. Note that the electrodes are not inert and
because of that, the anode might oxidize.
Power Source
Cu
Cu
1 M NaF
Anode Reaction
Cathode Reaction
Chemicals produced at the anode
Chemicals produced at the cathode
The electrons flow from
The MTV
Which electrode is the anode ?
Electrochemistry Practice Test # 1
1.
The following represents the process used to produce iron from iron III oxide:
Fe2O3 + 3CO 2Fe + 3CO2 What is the reducing agent in this process?
A.
B.
C.
D.
Fe
CO
CO2
Fe2O3
2.
3.
4.
SO42- 2PbSO4 + 2e2H+ + SO42- PbSO4 + 2H2O + 2e+ 4H+ + SO42- + 2e- PbSO4 + 2H2O
+ 2SO42 + 2H2O + 2e- PbSO4 + 2OH-
-1.12 V
-0.40 V
+0.40 V
+1.12 V
7.
Pb +
Pb +
PbO2
PbO2
6.
2I- + Ag Ag+ + I2
Co2+ + Cu Co + Cu2+
Cu2+ + Pb Pb2+ + Cu
Ni2+ + 2Ag 2Ag+ + Ni
5.
increases by 1
increases by 2
decreases by 1
decreases by 2
fuel cell
electroplating
redox titration
carbon dry cell
0.024 moles
0.060 moles
C.
D.
8.
9.
Cathode
O2
Na
Cl2
Cl2
H2
Cl2
H2
Na
1.0 M H+
1.0 M Ag+
1.0 M Sr2+
1.0 M Mn2+
13.
Anode
A solution containing an unknown cation reacts spontaneously with both zinc and copper. The
unknown cation is
A.
B.
C.
D.
12.
0.26 V
0.28 V
0.54 V
0.80 V
What substances are formed at the anode and cathode during electrolysis of molten sodium
chloride?
A.
B.
C.
D.
11.
Cu + Br2 CuBr2
CO + H2O CO2 + H2
CH4 + H2O CO2 + 2H2O
NaOH + HCl NaCl + H2O
What is the minimum voltage required to form nickel from an aqueous solution of NiI2 using
inert electrodes?
A.
B.
C.
D.
10.
1.5 moles
0.30 moles
ClO- + H2O + e- Cl2 + 2OH2ClO- + H2O + 2e- Cl2 + 3OH2ClO- + 2H2O + 2e- Cl2 + 4OH2ClO- + 2H2O Cl2 + 4OH- + 2e-
Ag+ + I- AgI
B.
C.
D.
14.
Salting the roads during the winter increases the amount of corrosion of cars. The is because
the salt
A.
B.
C.
D.
Consider the following electrochemical cell for the next five questions.
voltmeter
1.0 M KCl
Cu
u
Ni
1M Cu(NO3)2
15.
16.
0.41 V
0.78 V
0.34 V
0.60 V
19.
18.
17.
1M Ni(NO3)2
K+
Cu2+
ClCl-
Cu2+
Ni2+
NO3NO3-
Ni2+
2e-
C.
D.
20.
Which of the following will not react spontaneously with 1.0 M HCl?
A.
B.
C.
D.
21.
25.
a voltmeter.
a salt bridge.
a power supply.
an aqueous solution.
In the electrolysis of molten ZnCl2 using carbon electrodes, the reaction that occurs at the
anode is
A.
B.
C.
D.
24.
nickel
sodium
aluminum
magnesium
23.
tin
lithium
mercury
magnesium
Which of the following can be produced by electrolysis from a 1.0 M aqueous solution
containing its ion?
A.
B.
C.
D.
22.
Mn
Cu
Pb
Sn
26.
27.
+2
+3
+4
+6
Consider the following electrochemical cell for the next five questions.
voltmeter
1.0 M KNO3
Cu
Zn
uu
1M Cu(NO3)2
28.
29.
A.
I and II only
B.
I and III only
C.
II and III only
D.
I, II, and III
The balanced equation for the overall reaction is
A.
B.
C.
D.
30.
1M Zn(NO3)2
Zn + Cu2+ Cu + Zn2+
Cu + Zn2+ Zn + Cu2+
Zn2+ + Cu Cu2+ + Zn
Cu + Zn Zn + Cu
-1.10 V
0.00 V
+0.42 V
D.
31.
32.
KCl
NaOH
H2SO4
KOH
37.
36.
35.
-1.10 V
+1.10 V
+0.91 V
+0.86 V
34.
33.
+1.10 V
KCl
NaOH
H2SO4
KOH
A.
B.
C.
D.
38.
C
Pt
Al
Al2O3
The anode and cathode used in the electrorefining of impure lead to pure lead are
A.
B.
C.
D.
39.
Anode
Cathode
Pure Pb
Impure Pb
Pb2+
Pb
Impure Pb
Pure Pb
Pb
Pb2+
C
Zn
Mg
KOH
40.
Electro winning
Electroplating
Charging a car battery
Fuel cell
A.
B.
C.
D.
I and II only
I, II, and III only
II and II only
I, II, III, and IV
Subjective
1.
2.
C2O42-
MnO2
(basic)
b)
c)
Write the overall reaction and determine the minimum theoretical voltage required.
Power Source
3.
CO2
Impure Pb
a)
b)
c)
4.
Describe two chemically different methods that can be used to prevent corrosion of iron and
explain why each method works.
Method 1:
Explanation:
Method 2:
Explanation:
5.
The data below were obtained in a redox titration of a 25.00 mL sample containing Sn2+ ions
using 0.125 M KMnO4 according to the following reaction:
2MnO4- + 16H+ + 5Sn2+ 2Mn2+ + 8H2O + 5Sn4+
Calculate the [Sn2+]
Volume of KMnO4 used (mL)
Trial 1
Trial 2
Trial 3
6.
2.00
13.80
13.80
24.55
24.55
35.32
b)
c)
7.
Consider the electrolysis of molten magnesium chloride with Cu electrodes (Cu
are not inert and can oxidize: Cl-, or Cu will oxidize)
8.
a)
b)
c)
Mn
Sn
nn
n
1M Sn(NO3)2
1M MnNO3)2
electrodes
Chemistry 12
1.0 M KCl
Pd
Ni
1M Pd(NO3)2
1M Ni(NO3)2
1.
As the cell operates, the electrons flow from the nickel electrode to the palladium electrode.
The reaction occurring at the anode is
A
B
C
D
2.
+ 2e+ 2e Pb
Ni
3.
Pd Pd2+
Ni Ni2+
Pd2+ + 2eNi2+ + 2e-
both the K+ and the NO3- migrate into the nickel half-cell
both the K+ and the NO3- migrate into the palladium half-cell
the K+ migrates into the nickel half-cell and the NO3- migrates into the palladium halfcell
the K+ migrates into the palladium half-cell and the NO3- migrates into the nickel halfcell
-1.21 V
-.95 V
+0.95
+1.21 V
4.
What substances are formed at the anode and cathode during electrolysis of molten
sodium chloride, NaCl(l)?
A
B
C
D
5.
Anode
Cathode
O2
Na
Cl2
Cl2
H2
Cl2
H2
Na
Inert
Electrode
Inert
Electrode
Molten NaI(l)
Which of the following are necessary for electroplating to occur using an electrolytic
cell?
I
Two electrodes
II
A metal being reduced
III
A direct current power supply
A
B
C
D
I and II only
I and III only
II and III only
I, II, and III
7.
A fuel cell consumes H2 and O2 gas, uses a KOH electrolyte, and produces electricity.
reaction at the anode is
A
B
2H+ + 2e- H2
1/2O2 + 2H+ + 2e- H2O
The
C
D
8.
V2+
U4+
U3+
V2+
Te
Te
Te2Te2-
U4+
V2+
V2+
U3+
9.
What is the minimum voltage required to form nickel from an aqueous solution of
using inert electrodes?
A
B
C
D
0.26 V
0.28 V
0.54 V
0.80 V
strongest to
NiI2
10.
voltmeter
1.0 M KNO3
Zn
Ni
1M Zn(NO3)2
1M Ni(NO3)2
12.
Ag+ + I2
Pb2+ + Zn
Mg2+ + Ca
Zn2+ + Mn
13.
KBr
SnCl2
KMnO4 (basic)
KBrO3 (acidic)
I2(s)
Ni(s)
Zn(s)
Br2(l)
14.
15.
+3
+4
+5
+6
16.
17.
H+
H2O
NO3AsO3
Water
Oxygen gas
Nitrogen
19.
I only
III only
I and II only
II and III only
A
B
C
D
20.
21.
23.
22.
0.40 V
0.75 V
1.08 V
2.50 V
corrosion
ionization
hydrolysis
electrolysis
change
24.
no reaction
Cu + Br2 CuBr2
CO + H2O CO2 + H2
CH4 + O2 CO2 + 2H2O
NaOH + HCl NaCl + H2O
29.
I2
Cu
H2S
Ag2S
28.
U4+
V2+
V2+
U3+
Consider the redox reaction: 2BrO3- + 10Cl- + 12H+ Br2 + 5Cl2 + 6H2O
the oxidation half-reaction ivolved in this reaction is
A
B
C
D
27.
Te
Te
Te2Te2-
26.
V2+
U4+
U3+
V2+
Na+ + 1e- Na
2SO42- S2O82- + 2e2H2O O2 + H+ + 4e2H2O + 2e- H2 + 2OH-
PtO2 PtO
PtO3 PtO2
strongest to
C
D
30.
Pt(OH)2 Pt
Pt(OH)22+ PtO3
31.
Which of the following can be produced by the electrolysis from a 1.0 M aqueous solution
containing its ions?
A
B
C
D
32.
In the electrolysis of molten ZnCl2 using carbon electrodes, the reaction that occurs at the
anode is
A
B
C
D
33.
nickel
sodium
aluminum
magnesium
a voltmeter
a salt bridge
a power supply
an aqueous solution
Subjective
1.
a)
Indicate in the blank spaces on the following chart whether or not a reaction will
occur when the metals are added to the aqueous ions.
Pd
Rh
Pt
Pd2+
Rh2+
no reaction
Pt2+
reaction
b)
2.
no reaction
reaction
Describe and explain two methods, using different chemical principles, to prevent
formation of rust.
a)
b)
3.
4.
Cl-
O2
AuCl4-
OH-
the
5.
Draw and label a simple electrolytic cell capable of electroplating and inert electrode with
silver.
6.
a)
During the production of magnesium metal from seawater, magnesium ions are first
precipitated from seawater as magnesium hydroxide. The magnesium hydroxide is
neutralized by hydrochloric acid, producing magnesium chloride. Write the
neutralization reaction.
b)
The salt produced, magnesium chloride, is dried melted and undergoes electrolysis.
Write the reaction at each electrode.
Anode
Cathode
c)
d)
7.
Impure Pb
a)
b)
c)
d)
Quiz
WS 1
WS 2
1
WS 3
WS 4
WS 5
WS 6
8. Electrochemical Cells.
WS 7
WS 8
WS 9
WS 10
Internet Review
Quizmebc
15. Review
Practice Test # 1
16. Review
Practice Test # 2
17. Test.
Text book
Hebden
Read Unit V
If you want an A in this class you need to do this!!
- loss of electrons
- gain of electrons
- causes oxidation by undergoing reduction
- causes reduction by undergoing oxidation
Write half reactions for each of the following atoms or ions. Label each as oxidation or reduction.
Al3+
3e-
5.
Al
----------->
6.
7.
2O2- ---------->
8.
Ba2+
9.
2N3- ---------->
10.
Br2
11.
P +
12.
Ca
----------->
13
Ga3+
3e- -----------> Ga
reduction
14.
2e- --------->
reduction
15.
H2
--------->
16.
2H+
17.
2F-
---------->
F2
18.
P3-
---------->
P +
2e- --------->
O2
S2-
reduction
4e-
oxidation
+ 2e- -----------> Ba
N2
3e-
reduction
6e-
oxidation
2Br-
reduction
2e- --------->
P3-
---------->
Ca2+
reduction
2e-
2H+
S2+
2e-
2e- ---------> H2
+
oxidation
oxidation
oxidation
reduction
2e3e-
oxidation
oxidation
Balance each spontaneous redox equation. Identify the entities reduced and oxidized. State the
reducing agent and the oxidizing agent.
19. Al
&
Zn2+
20. F2
21. O2
2Al +
oxidized
reducing agent
3Zn2+
reduced
oxidizing agent
2Al3+ +
3Zn
&
O22F2
+
reduced
oxidizing agent
2O2
oxidized
reducing agent
4F-
O2
&
Ca
2Ca +
oxidized
reducing agent
22. Al3+
&
O2
reduced
oxidizing agent
2Ca2+ +
2O2-
3Li+
Li
Al3+ +
reduced
oxidizing agent
3Li
oxidized
reducing agent
Al
Label the species that is reduced, that is oxidized, the reducing agent and the oxidizing agent.
Fe2+
23.
Co
Fe
Co
Co2+
+ 2e- oxidation
Ni
Ni2+
+ 2e-
oxidation
Pb
Co2+
Fe2+
Fe
2e-
3 Ag
1e-
Cu
reduction
3 Ag+
24.
Ni
Ag
25.
Ni3+
Ag+
reduction
Cu2+
Pb2+
Pb
Cu
26.
+ 2e-
oxidation
2 Sn
Sn2+
+ 2e-
oxidation
2 F-
F2
+ 2e-
oxidation
Cu2+
2e-
2 Sn2+
O2
F2
Co2+
Sn
2O2-
O2-
Co
Coreduction
28. List the species (formulas from above) that lose electrons:
Ni
Pb
Sn
F-
29. List the species (formulas from above) that gain electrons:
Fe2+
Ag+
Cu2+
O2
Co2+
I-
Cl2
---------->
Substance oxidized
Oxidizing agent
31.
Co
4e-
reduction
Co2+
2F-
Co
reduction
O2
27.
Pb2+
Fe3+
Cl-
I2
ICl2
Reducing agent
Substance reduced
----------->
Co2+
Fe2+
ICl2
2e-
Substance oxidized
Oxidizing agent
32.
Cr6+
Fe2+
Co
Fe3+
Reducing agent
Substance reduced
Co
Fe3+
Cr3+
Fe3+
----------->
Substance oxidized
Oxidizing agent
Fe2+
Cr6+
Reducing agent
Substance reduced
Fe2+
Cr6+
Zn
Cu
2+
Substance reduced
Reducing agent
Cu2+
b) Cl2 (g)
2 Na (s) -------->
Substance oxidized
Oxidizing agent
2 Cl- (aq)
2 Na+ (aq)
Na
Substance reduced
Reducing agent
Cl2
Cl2
Na
WS # 3
Fe+3
----->
Fe+3
------>
Fe+2
------>
F2
4. S2O8-2 + Pb
------>
2SO4-2
5.Cu+2
2Br-
------>
Cu
Br2
2. Pb
3. Cl2
F-
Fe+2
Au
Pb+2
2Cl-
Pb+2
6. Sn+2
Br2
------>
Sn+4
+ 2Br-
spontaneous
7. Pb+2
Fe+2
------>
Fe+3
+ Pb
nonspontaneous
8. Can you keep 1 M HCl in an iron container. If the answer is no, write a balanced equation for the
reaction that would occur. No
Fe
2H+
-------->
Fe2+
H2
9. Can you keep 1 M HCl in an Ag container. If the answer is no, write a balanced equation for the
reaction that would occur.
Yes. There is no reaction.
10. Can you keep 1 M HNO3 in an Ag container. If the answer is no, write a balanced equation for the
reaction that would occur. (remember HNO3 consists of two ions H+ and NO3-)
No
3Ag
NO3-
4H+
--------> 3Ag+
NO
2H2O
11. Can you keep 1 M HNO3 in an Au container. If the answer is no, write a balanced equation for the
reaction that would occur. (Remember, HNO3 consists of two ions H+ and NO3-)
Yes. There is no reaction.
12. Circle each formula that is able to lose an elecron
Cl-
O2
Na+
Fe
Al3+ +
Zn --------->
Substance oxidized
15.
Cr2O72- + ClO2-
Al
Zn
------------>
Substance reduced
Zn2+
Oxidizing agent
Cr3+
Cr2O72-
Al3+
ClO4-
Oxidizing agent
Cr2O72-
16. State the Oxidation Number of each of the elements that is underlined.
a) NH3
c) ZnCO3
e) Na
-3
4
0
b) H2SO4
d) Al(OH)3
f) Cl2
6
3
0
17. Balance the redox equation using the half reaction method.
Al
3Ag+ ---------->
Al3+
Cl-
Fe
Na+
3Ag
22.
23.
24.
25.
26.
Na202
CaH2
NaIO3
C4H12
Al2(SO4)3
27.
Al3+
-1
-1
5
-3
6
Zn
---------->
Substance oxidized
Cr2O72- +
28.
Al
Zn2+
Zn
ClO2- ---------------->
Cr3+
Cr2O72-
Substance reduced
Al3+
Oxidizing agent
+
ClO4-
Oxidizing agent
2-
Cr2O7
29.
30. 3As2O3
SO42- +
O2
+ 2H+
SO2
Reducing agent
Substance reduced
NO3-
WS # 4
SO2
+ 4NO
Reducing agent
As2O3
Balance each of the following half-cell reactions. (In each case assume that the reaction takes place
in an ACIDIC solution.) Also, state whether the reaction is oxidation or reduction.
1.
5H2O +
10H+ +
8e-
oxidation
2.
8H+
5e-
4H2O
reduction
3.
4H2O +
As
-------------->
AsO43-
8H+
5e-
Cr2O72-
14H+ +
6e-
oxidation
4.
7H2O +
2Cr3+ ----------->
oxidation
5.
Pb2+
2H2O +
--------------> PbO2 +
4H+
2e-
oxidation
8H+
6.
SO42- +
6e-
--------------> S
NO3-
3e-
------------->
8e-
NO3- -------------->
10e-
2BrO3- -------------->
4H2O
reduction
4H+
7.
NO
2H2O
NH4+ +
3H2O
reduction
10H+ +
8.
reduction
12H+ +
9.
Br2
reduction
Balancing Half Cell Reactions
Balance in basic solution.
10.
3e-
11.
4H2O +
12.
8OH-
13.
14OH-
14.
4OH-
15.
4H2O +
16.
10 OH-
17.
7H2O +
2H2O
5e+
As
+
+
NO3-
--------------> NO
MnO4-
-------------->
AsO43- +
Pb2+ -------------->
6e-
4H2O +
8e-
5e-
7H2O +
6e-
PbO2 +
2H2O +
2e-
SO42- --------------> S
NO3-
8OH-
4OH-
--------------> Mn2+ +
+
5H2O +
--------------> NH4+ +
8OH8e-
10 OH-
6H2O
18.
10e-
6H2O +
12 OH-
20.
SO32-
-------->
SO42-
oxidation
CaO
-------->
Ca
reduction
CrO42-
-------->
Cr2O72-
neither
CrO42-
-------->
Cr3+
reduction
2I-
-------->
I2
oxidation
IO3-
-------->
I2
reduction
MnO4-
-------->
Mn2+
reduction
ClO2-
-------->
ClO-
reduction
Cr2O72-
Fe2+
Substance oxidized
Cr2O72Oxidizing agent
Fe2+
WS #5
-------->
Cr3+
Fe3+
Fe2+
Substance reduced
Cr2O72-
Reducing agent
Balance each redox equation. Assume all are spontaneous. Use the half reaction method.
1.
2O2-
2F2
----------->
O2
4F-
2.
4Al
3O2
----------->
6O2-
4Al3+
3.
2K
Zn+2
----------->
Zn
2K+
6e-
--------------> 14OH-
Cr2O72-
7H2O +
2Cr3+
5.
NO
6.
2H2O
7.
2MnO2
4OH-
------------------>
2H2O
-------------->
SO2
-------------->
Mn2O3
2e-
SO42-
H2O
2e-
NO3- + 3e4OH-
2OHBalance each redox reaction in acid solution using the half reaction method.
8.
8H+ +
7H2O
Cr2O72-
9.
TeO32 - + 2N2O4
10.
4H+
4ReO4- +
7IO-
11.
8H+
5PbO2 +
I2
12.
12H2O + 8As
3H2O2 +
H2O
------->
------->
3O2
2Cr3+ +
4NO3- +
2H+
-------> 7IO3- +
4Re
2H2O
-------> 5Pb2+ +
2IO3- +
4H2O
3H2AsO4-
5AsH3
------->
Te
3H+
Balance each redox reaction in basic solution using the half reaction method.
8OH-
+ 2Cr3+
13.
3O2
14.
H2O
15.
7IO3- +
4OH- + 4Re
16.
8OH- +
5Pb2+ +
17.
7H2O
+ Te +
-------> H2O
2OH7IO-
3H2O2
2N2O4
2H2O
Cr2O72-
I2 + 4H2O
14OH- + 2Cr3+
State of the change represents oxidation, reduction or neither (use oxidation #s).
18.
19.
20.
21.
MnO2
NH3
HClO4
O2
-------->
-------->
------->
-------->
Mn2O3
NO2
HCl +
O2-
H2O
reduction
oxidation
reduction
reduction
22.
-------->
P2O5
P4H10
reduction
22.
23.
24.
HS O4NaH
Na2O 2
6
-1
-1
26.
25.
P b SO4
U 2O5
5
WS #6
Review
- loss of electrons
- gain of electrons
- causes oxidation by undergoing reduction
- causes reduction by undergoing oxidation
2. Write half reactions for each. Describe as oxidation or reduction. Circle all oxidizing agents.
a)
b)
c)
d)
e)
f)
Na
Ca
Al3+
2F1N2
2O2-
-----------> Na+
+
e2+
-----------> Ca
+
2e+ 3e- -----------> Al
----------> F2 +
2e+
6e- ----------> 2N3----------> O2 +
4e-
oxidation
oxidation
reduction
oxidation
reduction
oxidation
3. Write the reaction between the following: Use the half reaction method.
a) Ca +
Al(NO3)3
3Ca
b) Sn +
-------------> 2Al
3Ca2+
AgNO3
2Ag+
Sn +
c) Sn +
3Sn
2Al3+
-------------> 2Ag
Sn2+
3Sn2+
Au(NO3)3
+
2Au3+
-------------> 2Au
Cu
Cu+
Al
Al3+
F-
O2-
O2
6. Ni+2 reacts with Mn, however, Al+3 does not react with Mn. Rank the oxidizing agents in order of
decreasing strength. Rank the reducing agents in order of decreasing strength.
strongest oxidizing agent
Ni2+ +
Mn2+ +
Al3+ +
2e2e3e-
----------->
----------->
----------->
Ni
Mn
Al
7. Ag+ reacts with Pb, however, Ca+2 does not react with Pb. Rank the reducing agents in order of
decreasing strength. Rank the oxidizing agents in order of decreasing strength.
strongest oxidizing agent
Ag+
Pb2+
Ca2+
+
+
+
1e2e2e-
----------->
----------->
----------->
Ag
Pb
Ca
8. Cl2 reacts with Ag, however, Ag does not react with Mg+2. Rank the oxidizing agents in order of
decreasing strength. Rank the reducing agents in order of decreasing strength.
strongest oxidizing agent
Cl2
+
Ag+ +
Mg2+ +
2e1e2e-
-------->
----------->
----------->
2ClAg
Mg
9. Ni+2 reacts with Mn, however, Al+3 does not react with Mn. Rank the reducing agents in order of
decreasing strength. Rank the oxidizing agents in order of decreasing strength.
strongest oxidizing agent
Ni2+ +
Mn2+ +
Al3+ +
2e2e3e-
----------->
----------->
----------->
Ni
Mn
Al
10. Cl2 reacts with Br-, however, I2 does not react with Br-. Rank the oxidizing agents in order of
decreasing strength. Rank the reducing agents in order of decreasing strength.
strongest oxidizing agent
Cl2
Br2
I2
+
+
+
2e2e2e-
-------->
-------->
-------->
-------->
S2-------->
MnO4-------->
CrO42-------->
I2
reduction
oxidation
neither
reduction
&
&
&
Ni
Fe
Fe
Spontaneous
Spontaneous
Non spontaneous.
2Cl2Br2I-
Ni2+
Fe2+
Fe2+
+
+
+
Sn
Ni
Cr
Sn2+
Ni2+
Fe2+
Cr3+
+
+
+
+
2e2e2e3e-
----------->
----------->
----------->
----------->
Sn
Ni
Fe
Cr
iii) Rank the reducing agents in decreasing order of strength. See above.
iv) Will SnCl2 react with Cr? Explain? Yes, because Sn2+ is a stronger oxidizing agent than Cr3+ .
v) Will Fe2+ react with Sn?
2H+
16.
5H2S -------->
oxidizing agent
reducing agent
5S
+ 6H2O +
2MnO
17.
2H+ + 10SO42+
4Br2
oxidizing agent
18.
5H2S --------> 5S +
20.
ZnCl2
CuCl2
Br2
H2S
&
&
&
&
Cu
NaCl
Fe2+
Al3+
nonspontaneous
nonspontaneous
spontaneous
nonspontaneous
H2O
10SO42- + 4Br2
Classify as an oxidizing agent, reducing agent or both based on its position on the table.
State the Eoor voltage of its position. Some of these are both, so state two voltages and indicate that it
can be an oxidizing and reducing agent.
e.g.
MnO422.
23.
24.
25.
26.
27.
(in acid)
Br2
Fe2+
MnO4- (water)
Ni
Cr3+
H2O
oxidizing agent
oxidizing agent
oxidizing agent / reducing agent
oxidizing agent
reducing agent
oxidizing agent
oxidizing agent / reducing agent
non-spontaneous
non-spontaneous
spontaneous
spontaneous
non-spontaneous
spontaneous
1.51 v
1.09 v
-0.45 v / 0.77 v
0.60 v
-0.26 v
-0.74 v
-0.40 v / +0.80 v
Write each oxidation and reduction half reaction for each question above. Determine the Eo for each.
Calculate the Eo for the overall reaction.
MnO4-
34.
MnO4-
4OH-
4OH-
+0.60 v
-0.77 v
-0.17 v
35.
36.
NO3-
NO3-
Mg
2H+
Mg
+
2H2O
2H2O + 3Ag+
+0.96 v
-0.80 v
+0.16 v
37.
38.
39.
+
2e------> H2
---------->
Mg2+ +
2e2H+ ---------->
Mg2+ +
H2
0.00 v
2.37 v
2.37 v
WS # 7
Electrochemical Cells
Cu / Cu(NO3)2
2 e-
voltmeter
2 e-
1.0 M KNO3
NO3- K+
Zn
Cu
Zn Zn2+ + 2eoxidation
anode
0.76 v
loses mass
Zn2+
Cu2+
NO3
NO3
1 M Zn(NO3)2
1 M Cu(NO3)2
Cu2+ + Zn Zn2+ + Cu
12. Ag / AgNO3
H2 / HCl
1.10 v
2 e-
voltmeter
2 e-
1.0 M KNO3
NO3- K+
H2
H2 2H+ + 2eoxidation
anode
0.00 v
Cu
H+
Ag+
Cl-
NO3
-
1 M HCl
1 M Ag(NO3)2
0.80 v
WS # 8
1. In an electrolytic cell, reduction occurs at the negative electrode and oxidation occurs at the
positive electrode.
2. If there are two possible reduction reactions, the highest one on the chart occurs.
3. For reduction, the chart is read from left to right.
4. For oxidation, the chart is read from right to left and the sign of the voltage is changed.
5. If there are two possible oxidation reactions, the lowest one on the chart occurs.
6. Corrosion of a metal is oxidation.
7. Electrolysis uses electrical energy.
8. Electrochemical cells produce electrical energy.
9. Electrolytic cells use electrical energy.
10. What is the standard reference cell? hydrogen Eo = O v
Draw and completely analyze each electrolytic cell.
11. Molten NaCl
Power Source
Pt
Pt
Na+
Cl-
Na(s)
-2.71 v
MTV = +4.07 v
C
Na+
SO42H2O
Anode: H2O
MTV = +1.23 v
-1.23 v
2H+
Power Source
Pt
Pt
K+
O2-
Cathode: K+ + 1e-
4e?v
K(s)
Anode: 2O2- O2 +
-2.93 v
-? v
MTV = +? v
Pt
Pt
Li+
I-
H2 + 2OH-
-0.41 v
-0.95 v
MTV = +0.95 v
15. 250ml of 0.200M MnO4- reacts with excess SO3-2. How many grams of MnO2 are produced? This
is Chemistry 11 stoichiometry.
2MnO4- + 3SO3-2 + H2O -----> 2MnO2 + 3SO4-2 + 2OH0.250L MnO4- x 0.200 mol x 2 mol MnO2
L
2 mol MnO4-
x 86.9g = 4.34g
mol
Al(NO3)3
3Fe
E0 = 1.21 v
Spontaneous. There
Cu ------>
Anode (-)
Cu
Cu -------> Cu2 + 2e
0.80v
2Ag
Cu2+
E0 = 0.46 v
spontaneous
-0.34v
20. 250ml of .500M MnO4- are required to titrate a 100ml sample of SO3-2. Calculate the [SO3-2]
2MnO4- + 3SO3-2 + H2O -----> 2MnO2 + 3SO4-2 + 2OH.250L MnO4- x 0.500 mol x 3 mol SO3-2
L
2MnO40.100L
1.88M
21. How is the breathalyzer reaction used to determine blood alcohol content (you might need to look
this up in your textbook)?
The breathalyzer reaction uses a spontaneous redox reaction between acidic Cr2O72- and
ethanol C2H5OH. If alcohol is present in your breath sample, it will react with a solution of
Cr2O72- reducing the orange color as it reacts to form Cr3+, which is green. The drunker you are,
the greater the reduction in orange color, which is measured with a spectrophotometer.
22. 2H+ + Mg-----> Mg+2 +H2
Oxidizing agent
H+
WS #9
Reducing agent
Mg
Determine the half reactions for each cell and the cell voltage or minimum theoretical voltage and
overall equation.
1. Ag / Pb electrochemical cell.
Anode:
Anode reaction:
1e- -------> Ag
Overall reaction:
Pb
Pb
--------> Pb
2+
Pb + 2Ag+
Cathode:
Cathode reaction:
+ 2e
-----> Pb2+
2Ag
Ag
Ag+ +
Voltage: 0.93v
C
2Cl- --------> Cl2 + 2e2Cl-
+ Zn2+
Cathode:
Cathode reaction:
-----> Cl2
Zn
Zn
2+
C
+ 2e-
MTV: +2.12 v
Cathode:
C
Cathode reaction:
+ 1/2O2 + Cu
MTV: +0.48 v
C
2I- --------> I2 + 2e2H2O + 2I-
Cathode:
C
Cathode reaction: 2H2O + 2e-----> H2 + 2OH- +
I2
MTV: +0.95 v
5. The reaction needed to make Al. The electrolyte is Al2O3 and its phase is molten (molten or
aqueous).
To lower the mp. from 2000 oC to 800 oC cryolite is used.
Anode:
Anode reaction:
-------> Al
Overall reaction:
6.
+ 4Al3+
Ag
Cathode:
+
Ag-----> Ag + e-
penny
Cathode reaction:
Ag+ + e- ----->
penny
Cathode reaction:
Ni2+ + 2e-
Anode:
Anode reaction:
-----> Ni
Possible Electrolyte
8.
6O2-
Cathode:
C
Cathode reaction: Al3+ + 3e-
+ 4e-
Anode:
Anode reaction:
Ag
7.
C
2O2- -------> O2
Ni
Cathode:
+2
Ni-----> Ni + 2eNi(NO3)2
Anode:
Anode reaction:
Impure Lead
Pb-----> Pb+2 + 2e-
Cathode:
Cathode reaction:
Pure Lead
Pb2+ + 2e- -----> Pb
Zn / Mg electrochemical cell
Anode:
Anode reaction:
2e- -------> Zn
Mg
Mg
--------> Mg
2+
+ 2e
Cathode:
Cathode reaction:
Zn
Zn+2 +
Overall reaction:
2.
Zn
Voltage: 1.61v
Electrolyte:
Anode:
Anode reaction:
-------> Al
Overall reaction:
3.
Al2O3
Phase (aqueous or molten)
C
2O2- -------> O2 + 4e6O2-
+ 4Al3+
Molten
Cathode:
C
Cathode reaction: Al3+ + 3e-
Anode:
C
Anode reaction:
2I- --------> I2 + 2e2e -------> H2 + 2OH
Overall reaction:
2H2O + 2I-----> H2 + 2OH- +
4.
I2
MTV: +0.95 v
The electrorefining of Pb
Anode:
Anode reaction:
5.
Cathode:
C
Cathode reaction: 2H2O +
Impure Lead
Pb-----> Pb+2 + 2e-
Cathode:
Cathode reaction:
Pure Lead
Pb2+ + 2e- -----> Pb
Anode:
Anode reaction:
-----> Ni
Possible Electrolyte
Ni
Cathode:
+2
Ni-----> Ni + 2eNi(NO3)2
nail
Cathode reaction:
Ni2+ + 2e-
Zn
Zn
--------> Zn
Zn + 2Ag+
2+
Cathode:
Cathode reaction:
+ 2e
-----> Zn2+
2Ag
Ag
Ag+ +
Voltage: 1.56v
C
2F- --------> F2 + 2e2F- + 2K+-----> Cl2
Cathode:
C
Cathode reaction: K+ + e- -------> K
+ K
MTV: +5.80v
Cathode:
Anode reaction:
H2O --------> 2H+ + 1/2O2 + 2e2H2O + 2e -------> H2 + 2OHOverall reaction:
H2O
-----> H2 + 1/2O2
Cathode reaction:
MTV: +1.23 v
C
2I- --------> I2 + 2eFe2+
+ 2I-
Cathode:
C
2+
Cathode reaction: Fe +
-----> Fe
I2
MTV: +0.99 v
10. Draw a Cd/Pb electrochemical cell. Cd is not on the reduction chart, however, the Cd electrode
gains mass and the total cell potential is .5v. Determine the half-cell potential for Cd.
Anode:
Pb
Anode reaction:
Pb --------> Pb2+ + 2e+2
Cd + 2e -------> Zn
x volts
2+
Overall reaction:
Pb + Cd -----> Pb2+ +
0.13 + x = 0.50
0.13v
Cd
Cathode:
Cathode reaction:
Cd
Voltage: 0.50v
x = 0.37v
11. Write the overall reaction and describe the anode and cathode for a dry (Leclanche), fuel, alkaline
and lead/acid cell.
Cell
anode
Leclanche or
Common Dry
Cell
Zn
Zn-->Zn+2 + 2e- C
Alkaline Cell
Zn
Zn-->Zn+2 + 2e- C
Lead Storage or
Pb
Car Battery
PbO2
H2SO4
Fuel Cell
H2 + 2OH- --->
2H2O + 2e-
electrolyte
substance oxidized
reducing agent
H2SO3
H2SO3
H2 and O2
15. Describe the differences and similarities between an electrolytic and electrochemical cell.
Electrolytic
Electrochemical
Uses electricity
Nonspontaneous
Makes chemicals
Inert carbon electrodes
The negative electrode is reduction
Produces electricity
Spontaneous
Uses chemicals
Usually has a salt bridge
The higher metal is reduction
Na
Pb
Au
Ag
Zn
Li
Ca
Mg
20. What is the electrolyte in a fuel cell, alkaline battery, Dry Cell (Leclanche) and lead acid battery?
KOH
PbSO4
21. State two metals that can be used to cathodically protect Fe. Describe how they protect iron from
corrosion.
Zn and Mg. When attached to Fe they form an electrochemical cell. Zn or Mg is a stronger
reducing agent (lower on the chart) and is the anode and Fe is the cathode. Since the cathode is
the site of reduction, Fe cannot oxidize or corrode.
22. Write the half reaction that describes the corrosion of iron. Fe --------> Fe2+
+2e-
23. Write the half reaction that describes the reduction reaction that occurs when iron corrodes in air
and water. 2e- + H2O + 1/2O2 ----------> 2OH-
25. Write the anode and cathode reaction in an electrolytic cell with a CaCl2 (l) electrolyte.
Cathode: Ca2+ + 2e- ---------> Ca
Anode:
2e-
26. Explain why you would choose Zn or Cu to cathodically protect iron? Zn. It is a stronger
reducing agent than Fe and it will allow Fe to be the cathode, which cannot corrode.
27. Choose a suitable redox reactant to oxidize Cl- to ClO4- in a redox titration.
MnO4- in acid gives a spontaneous reaction as well as a color change from purple to clear.
28. Describe as an electrochemical or electrolytic cell:
a) Fuel cell
electrolytic
c) Discharging a car battery
electrolytic
e) Industrial Al production
electrolytic
electrochemical
electrochemical
d) Ni plating
electrolytic
f) Cl2 production
anode
cathode reaction
electrolyte
Cl2 production C
Na+ + e- -----> Na
NaCl(l)
Leclanche or
Zn
Common Dry Cell
Nickel Plating
Ni
Ni-->Ni+2 + 2e-
Metal to be
Ni2+ +2e- -----> Ni
plated
Lead Storage or
Car Battery
Pb
PbO2
H2SO4
Fuel Cell
H2 + 2OH- --->
2H2O + 2e-
KOH
Ni(NO3)2
30) Al and AgNO3(aq) are mixed and the surface of the Al darkens. List the two oxidizing agents in
decreasing strength. List the two reducing agents in decreasing strength.
Oxidizing Agents
Ag+
Al3+
Reducing Agents
Al
Ag