Experimental Data of Low Temperature Heat Capacity at Constant Pressure of 1,2Dimethyl-3-ethylimidazolium bromide (C7H13BrN2) Ionic Liquid using Excel

Software
I.

Abstract
The heat capacities of pure ionic liquids (ILs) are among the
thermophysical properties that are required for certain engineering
calculations and designs. In this paper, a simple correlation is
presented to determine the appropriate model equation of 1,3Diethyl-1H-imidazol-3-ium bromide (C7H13BrN2). This correlation
is a temperature-dependent relation that use temperatures and heat
capacities. It was observed that the heat capacity of the compound
increases slowly as the temperature increases. The values of R2 are
0.383, 0.417, 0.532, 0.613, 0.686, 0.748, 0.601, 0.282, and 0.905,
respectively. The lowest value of R2 is obtained from the plot of
logarithmic while the highest is from the power function.

II.

Introduction

Specific heat capacity is the amount

of heat necessary to raise the temperature of
one kilogram (1kg) of a substance by one
kelvin (1C).Specific heat capacities provide
a means of mathematically relating the
amount of thermal energy gained (or lost) by
a sample of any substance to the sample's
mass and its resulting temperature change.
The effect of temperature on reaction
enthalpies and equilibrium constants is also
evaluated using heat capacities of the
participants.
Ionic liquids (ILs) are organic salts
that consist completely of ions but are liquid
at, or below, room temperature. Because of
their very unique properties, they have the

potential to be used in a variety of industrial

and chemical processes. However, highly
accurate data regarding the physicochemical
properties of ionic liquids are necessary for
the design and operation of such processes.
Heat capacity is among the important pure
component properties in its own right,
furthermore, the temperature-dependency of
various thermodynamic properties, such as
enthalpy, entropy, and Gibbs energy, can be
calculated from the heat capacity of a
compound. (Alireza Ahmadi Reza et
al.,2015)
Evaluation of Linear, quadratic,
cubic, polynomial of 4th degree, polynomial
of 5th degree, polynomial of 6th degree,

exponential, logarithmic, and power

relationship of 1,3-Diethyl-1H-imidazol-3ium bromide (C7H13BrN2 ) will be done using
Microsoft Excel. Different temperatures and
specific heat capacity will be plot in order to

III.

find the equation for a curve that will fit

with the given data. . The best fit equation
will be determined with the help of the
correlation coefficient that will be displayed
in the plots.

RESULTS

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

5.52
5.87
6.21
6.59
6.97
7.35
7.73
8.12
8.51
8.89
9.28
9.68
10.07
10.57
11.17
11.78
12.39
13
13.62
14.24
14.85
15.58
16.42
17.26
18.09

0.401
0.492
0.596
0.729
0.883
1.057
1.253
1.472
1.709
1.969
2.25
2.56
2.896
3.349
3.934
4.563
5.251
5.972
6.746
7.548
8.382
9.404
10.63
11.9
13.21

23.77
25.2
26.63
28.07
29.52
31.17
33.03
34.89
36.76
38.63
40.49
42.5
44.67
46.85
49.03
51.21
53.39
55.57
57.75
59.93
62.13
64.33
66.53
68.72
70.92

22.77
25.25
27.75
30.25
32.71
35.56
38.66
41.68
44.57
47.38
50.15
53
55.99
58.9
61.73
64.4
66.92
69.38
71.78
74.14
76.42
78.63
80.71
82.68
84.56

78.68
80.13
80.36
80.94
82.27
82.46
82.87
84.2
84.8
84.8
86.13
86.73
88.8
88.67
90.04
90.6
92.01
92.54
93.99
94.48
95.98
96.43
97.97
98.38
99.98

91.25
92.58
92.62
93.01
94.04
94.26
94.47
95.47
95.84
95.9
96.85
97.28
98.24
98.67
99.66
100
101.1
101.4
102.5
102.8
103.8
104.1
105.1
105.4
106.5

18.93
19.77
20.91
22.33

14.56
15.94
17.83
20.27

73.18
75.5
77.81
78.3

86.57
88.58
90.59
90.96

100.34
101.99
102.29
104.01

106.7
107.7
107.9
109

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

104.25
106.04
106.21
108.08

109.1
110.2
110.3
111.5

133.84
134.99
135.84
137.08

126
126.6
127
127.7

163.88
164.5
165.89
166.61

141.3
141.6
142.3
142.6

108.17
110.12
110.14
112.1
112.17
114.07
114.22
116.04
116.28
118.01
118.34
119.98
120.41
121.96
122.48
123.94
124.56
125.91
126.63
127.9
128.72
129.88
130.8
131.86

111.6
112.7
112.7
113.9
113.9
115
115.1
116.2
116.3
117.3
117.5
118.4
118.7
119.4
119.8
120.6
121
121.7
122.1
122.8
123.2
123.8
124.4
124.9

137.83
139.18
139.83
141.28
141.83
143.39
143.83
145.49
145.83
147.6
147.83
149.71
149.83
151.82
151.83
153.84
153.93
155.85
156.04
157.86
158.16
159.86
160.27
161.87

128
128.7
129.1
129.8
130.1
130.9
131.1
132
132.1
133
133.2
134.1
134.2
135.2
135.2
136.2
136.3
137.2
137.3
138.3
138.4
139.3
139.5
140.2

167.9
168.73
169.91
170.84
171.92
172.95
173.94
175.06
175.95
177.17
177.96
179.28
179.98
181.39
182
183.49
184.02
185.6
186.04
187.7
188.06
189.8
190.08
191.09

143.3
143.7
144.4
144.8
145.4
146.1
146.6
147.4
147.9
148.7
149.1
149.8
150.2
150.9
151.2
152
152.2
153
153.2
154.1
154.3
155.2
155.3
156.2

132.89

125.5

162.38

140.6

192.1

156.3

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

194
194.12
196.1
196.15
198.17
198.2
200.1
200.29
202.22
202.39
204.25
204.48
206.28
206.57
208.31
208.66
210.35
210.75
212.38
212.84
214.41
214.92
216.44
217
218.48
219.08
220.51
221.15
222.55

157.3
157.4
158.4
158.4
159.4
159.4
160.5
160.5
161.6
161.7
162.6
162.8
163.8
163.9
164.9
165.1
166
166.3
167.3
167.5
168.5
168.8
169.7
170.1
170.9
171.3
172.1
172.5
173.3

223.22
224.59
225.29
226.63
227.36
228.67
229.42
230.71
231.48
233.47
233.54
235.59
235.81
237.64
237.86
239.69
239.9
241.74
241.94
243.78
243.99
245.82
246.03
247.86
248.07
249.89
250.11
251.92
252.16

173.7
174.5
175
175.8
176.2
177
177.5
178.2
178.7
180
180
181.3
181.5
182.5
182.7
183.9
184.1
185.1
185.3
186.4
186.6
187.8
187.9
189.1
189.3
190.6
190.7
192
192.2

253.95
254.2
255.97
256.25
257.98
258.29
260
260.33
262
262.37
264.01
264.42
266.06
266.47
268.16
268.52
270.26
270.57
272.36
272.62
274.45
274.67
276.54
276.71
278.62
278.75
280.68
280.79
282.74

193.4
193.6
194.9
195.1
196.4
196.7
198
198.3
199.6
199.9
201.2
201.7
203.2
203.4
205.1
205.3
207.1
207.1
209.2
209.4
211.5
211.5
213.9
213.9
216.6
216.6
219.5
219.5
222.7

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

T,K

Cp, J/mol-K

282.84
284.78
284.88
286.82
288.82
290.81

222.7
226.4
226.6
230.9
236.3
242.8

292.77
294.69
296.57
298.39
300.12
301.74

251.5
262.7
278.5
300.9
334.9
387.4

303.2
304.47
305.51
306.32
306.93

470.7
613.7
844.2
1193
1697

3.1 Different degree plots heat capacity versus temperature

A. Linear

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
600
400
200
0
0

50

100 150 200 250 300

Temperature, K

350

B. Quadratic

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
600
400
200
0
0

f(x) = 0x^2 - 0.08x + 44.37

R = 0.42
50

100

150

200

Temperature, K

250

300

350

C. Cubic

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
600
400
200
0
0

f(x) = 0x^3 - 0.04x^2 + 4.62x - 63.28

R = 0.53

50

100

150

200

Temperature, K

D. Polynomial of 4th degree

250

300

350

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
600
400

f(x) = 0x^4 - 0x^3 + 0.09x^2 - 3.76x + 51.91

R = 0.61

200
0
0

50

100

150

200

250

300

350

Temperature, K

E. Polynomial of 5th degree

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
f(x) = 0x^5 - 0x^4 + 0x^3 - 0.24x^2 + 11.05x - 99.26
600
R = 0.69
400
200
0
0

50

100

150

200

Temperature, K

250

300

350

F. Polynomial of 6th degree

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K
800- 0x^5 + 0x^4 - 0.01x^3 + 0.43x^2 - 10.83x + 79.71
f(x) = 0x^6
R = 0.75600
400
200
0
0

50

100

150

200

Temperature, K

G. Exponential

250

300

350

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
600
400
200
0
0

f(x) = 16.31 exp( 0.01 x )

R = 0.6

50

100

150

200

250

300

Temperature, K

H. Logarithmic

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K
800
600
400
200
0
0

f(x) = 77.6 ln(x) - 222.31

R50
= 0.28
100 150 200 250
Temperature, K

I. Power function

300

350

350

Heat Capacity vs. Temperature

1800
1600
1400
1200
1000
Heat Capacity, J/mol-K

800
600
400
200
0
0

f(x) = 0.25 x^1.25

R = 0.91
50

100

150

200

250

300

350

Temperature, K

IV.

DISCUSSION

logarithmic while the highest is

Based on the graphs, the heat

from the power function.

capacity

of

the

compound

increases exponentially as the

V.

temperature increases, but at 300

Based on the results, it can be concluded

K, the increase is small. These

that heat capacity at constant pressure is

changes can be explained by

directly

debye

low

temperature

the

temperatures data. However, at this

theory

temperatures.

of

Moreover,

CONCLUSION

proportional
especially

with

the

at

low

model equations and the value of

condition,

R2 are also shown in the graphs.

ethylimidazolium bromide (C7H13BrN2)

The values of R2 are 0.383,

exhibits low heat capacity.

0.417, 0.532, 0.613, 0.686, 0.748,

0.601,

0.282,

and

0.905,

respectively. The lowest value of

R2 is obtained from the plot of

of1,2-Dimethyl-3-