PHOTOSYNTHESIS
is the process by which plants use their chlorophyll in
green leaves to convert solar energy into carbohydrates in
the presence of carbon dioxide from the atmosphere and
water. The carbohydrates are used by plants for their
growth. The plants absorb red and blue light but they do
not absorb green light. This is the reason why leaves of
plant or chlorophyll look green.
6CO2 + 6H2O + light energy = C6H12O6 + 6O2
In respiration process, energy is released which is used by
plant for growth and other activities.
Carbohydrate + O2 = CO2 + energy + water
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Biomass
Biomass is organic or carbon-based material that can
either react with oxygen for combustion or undergo
metabolic process to release heat.
Biomass can be used as such in its original form. More
often, it is transformed to more convenient and useful
form, thereby forming solid, liquid and gaseous fuels.
Biofules
The biofuels can be fuelwood, charcoal, fuel pellets,
bioethanol, biogas, producer gas and biodiesel.
Fuel wood
It is the most common source of biomass energy. Direct
combustion is the simplest way to obtain heat energy. It has
energy density of about 1620 MJ/kg.
Charcoal
It is obtained by carbonization of woody biomass. This
helps in providing higher energy density per unit mass of
about 30 MJ/kg. Charcoal can burn without generating
smoke.
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Biofules
Fuel pellets
Fuel pellets are formed from crop residues such as straw or
rice husk which are pressed into solid mass.
Bioethanol
It is derived from wet biomass containing sugars from
sugarcane, starches from grains and potatoes or cellulose
from woody matters. Ethanol (C2H5OH) is a colourless
liquid biofuel with boiling point of 78C and energy density
of 26.9 MJ/kg.
Biofules
Biogas
Biogas is the gaseous fuel obtained from biomass (organic
waste from plants, animals and humans) by means of
anaerobic digestion or fermentation.
The anaerobic digestion process can be profitably applied
to any wet organic matters.
Anaerobes are microorganisms or bacteria found to live
and grow in organic matter at the temperature of less than
60 in presence of moisture but in the absence of air or
oxygen.
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Biofules
The anaerobic organism consumes oxygen which it obtains
from decomposition of organic matters. Decomposition of
the organic matters by anaerobic microorganism is called
digestion or fermentation. The biogas is liberated from the
organic matters during digestion or fermentation. The biogas
produced by digestion contains (i) methane gas (CH4) 65
75%, (ii) carbon dioxide gas (CO2) 2535% and (iii) small
traces of nitrogen, ammonia, hydrogen sulphide and other
gases. The biogas has energy density of about 23 MJ/m3. It
can be used for cooking, lighting, heating and operating
small IC engines.
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Biofules
Producer gas
It is obtained by gasification of solid fuels. In this, woody
matter (crop residue, wood chips, rice husk, coconut shell
and sugarcane residue) is converted into producer gas by
thermochemical method which is infact the partial
combustion and reduction operation of biomass. The
producer gas has 19% carbon monoxide, 18% hydrogen, 1%
methane, 11% carbon dioxide and the rest remaining
nitrogen. The producer gas is used for IC engines for
running pumps, motor vehicles, heating and generation of
steam in a small-scale power plant.
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Biofules
Biodiesel
It is produced by blending of vegetable oils, with normal
diesel to obtain cheaper version of diesel engine fuel.
Besides vegetable oils, certain hydrocarbons having
molecular weight equal to that of petroleum and that are
obtainable as by-products from certain plants can also be
used for blending purpose.
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Biomass Resources
Forests
Agriculture residues
Energy crops
Urban waste
Aquatic plants
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Biomass Energy
Advantages
(i)
It is a renewable source.
(ii) It can be stored and used as per the requirement.
(iii) It helps in waste management.
(iv) It is an indigenous source of energy.
(v) It helps in economic development of rural areas.
(vi) It helps in improving sanitation in rural areas and
towns.
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Biomass Energy
Dis aadvantages
(i)
It has low energy density.
(ii) It is a labour intensive energy source.
(iii) Its production requires large land area.
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Biogas
Biogas is the gaseous fuel which is obtained from
biomass by means of an anaerobic digestion or
fermentation of wet organic matters.
flammable gas.
5060% methane gas, 3540% carbon dioxide, 5%
hydrogen and a small amount of hydrogen sulphide and
other gases.
Methane and hydrogen gases form the combustible
portion of biogas.
The biogas has energy density of about 23 MJ/m3. It can
be used for cookings, heating, lighting and running small
IC engine.
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Biomass to Biogas
Hydrolysis of organic matter
The biomass (complex compounds of carbohydrate,
protein and fats) is broken due to the action of water
(hydrolysis) into simpler soluble compounds.
Anaerobic and faculative microorganisms
These bacteria start growing to produce acetic and propionic
acids.
Digestion.
Anaerobic bacteria slowly digest the biomass slurry to
produce biogas.
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Temperature
Pressure
Water
PH value
Feeding rate
Seeding
Mixing and stirring
Toxic substances
Types od Biomass
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Advantages
Higher gas production per cubic meter of digester
volume.
No gas leakage problem.
Constant gas pressure.
No danger of gas explosion.
No separate pressure equalising device is needed
when fresh feed is added or digested slurry is
removed from the digester.
Simple installation.
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Dis advantages
It has higher cost due to movable metallic drum.
It has corrosion problem in the metallic movable
drum provided.
It requires more maintenance.
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Advantages
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Dis advantages
Gas production per cubic meter of the digester is
less.
It has variable pressure of biogas.
It has more risk of leakage due to higher pressure of
gas.
It has more risk of explosion.
It involves complex installation.
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Thermochemical
The biomass can be converted into more valuable
and convenient fuels by the use of the
thermochemical process called pyrolysis.
Pyrolysis is a thermochemical decomposition of
organic material at elevated temperatures in the
absence of oxygen (or any halogen). It involves the
simultaneous change of chemical composition and
physical phase, and is irreversible.
Pyrolysis can process all forms of biomass (organic
materials), including rubber and plastic which cannot
be converted by any other methods.
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Thermochemical
If pyrolysis is carried out at higher temperature
(above 1000C), maximum amount of gaseous
product is formed. This high temperature pyrolysis is
called gasification. This process is generally used to
produce charcoal and it is also called carbonization.
Liquid product from biomass is obtained by catalytic
liquefaction process at low temperature (250450C)
and high pressure (270 atm).
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Biochemical
The conversion of biomass is carried out using
metabolic action of microorganism or bacteria.
Anaerobic digestion or fermentation
Anaerobic digestion is a series of biological
processes in which microorganisms break down
biodegradable material in the absence of oxygen.
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Biochemical
Ethanol fermentation.
also called alcoholic fermentation, is a biological process
which converts sugars such as glucose, fructose, and
sucrose into cellular energy, producing ethanol and carbon
dioxide as a side-effect.
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