CHAPTER 9
GATEWAY TO PROCESSING TECHNOLOGY
Markets and Technology
One universal theme throughout is the concept of markets and the technology to produce products for those
markets. Markets and technology have evolved to become extremely sophisticated and complex. To help
understand the complicated interactions, chapters are included that provide overviews of important markets and
technology.
In particular, gasoline and aromatics manufacturing and residuum processing are emphasized. The following
refinery schematic highlights these areas.
Refinery Schematic
Sulfur
Saturates
Gas Plant
Light Ends
Fuel Gas
LPG
Gasoline
Isomerization
Gasoline
Naphtha
Naphtha
Hydrotreating
Atmospheric
Column
Light
Distillate
Naphtha
Reforming
To Aromatics
Light Distillate
Hydrotreating
Heavy
Distillate
Kerosene &
Jet Fuels
Heavy Distillate
Hydrotreating
Atmospheric
Gas Oil
Diesel &
Heating
Oil
Olefins
Alkylation
Gas Oil
Hydrotreating
(Light) Vacuum
Gas Oil
Catalytic
Cracking
Long Residuum
Cycle Oil
Gas Oils
Vacuum
Column
(Heavy)
Vacuum
Gas Oil
Hydrocracking
Lube Fraction
Resid
Resid
Delayed Coking
Green Coke
Lube Treating
Coke Calcining
Visbreaking
Coke
Heavy
Fuel Oil
Resid
Asphalt
Lube Oils
Solvent Deasphalting
Treating Asphalt
Resid
Asphalt
Page 9-1
Asphalt
The chapter
Refinery Coke
Vacuum Residue
LPG
3
Atmospheric Resid
Hydrogenation
Crude Oil
Crude Oil
Gas Oil
Coke
1
Jet Fuel/Diesel
Cracking
0
Gasoline
0
10
20
30
40
50
LPG
Adopted from Speight, 1999. Data variability is great and does not represent specific crudes or products.
Unit
Atmospheric
Crude Distillation
Saturates Gas
Plant
Catalytic Gas
Plant
Isomerization
Naphtha
Hydrotreater
Naphtha Reformer
Gasoline from
Naphtha Reforming
Aromatics Unit
Gasoline pool
Light Distillate
Hydrotreater
Heavy Distillate
Hydrotreater
Gas Oil
Hydrotreater
Catalytic Cracking
Unit
Products
Fractions from distillation
to other processing units.
LPG, fuel gas
Olefins, sulfur, fuel gas
Gasoline
Desulfurized naphtha
Gasoline
Feed to aromatics unit
Hydrogen for use in
hydrotreating
Gasoline
Light olefins to
alkylation for gasoline
Diesel & Heating Oil
Cycle Oil to
Hydrocracker
Heavy Fuel Oil
Benzene
Toluene
Orthoxylene
Paraxlene
Unit
Hydrocracking
Unit
Products
Kerosene & Jet Fuel
Diesel & Heating Oil
Heavy Fuel Oil
Alkylation
Gasoline
LPG
Vacuum Crude
Distillation
Delayed Coking &
Coke Calcining
Visbreaking
Solvent
Deasphalting
Asphalt Treating
Naphtha to
Hydrotreating
Gas Oil to
Hydrocracking
Heavy Fuel Oil
Asphalt
Precipitate asphalt for further treatment
Recover some deasphalted oil for gas oil Gas Oil to Hydrotreating
or heavy fuel oil.
Heavy Fuel Oil
Treat asphalt to improve quality
Asphalt
Lube Treating
Fractions to other
processing units.
Naphtha to
Hydrotreating
Gas Oil to
Hydrocracking
Heavy Fuel Oil
Coke to calcining
Page 9-4
Lube stock