ENERGY BALANCE
The first law of thermodynamics demands that energy be neither created nor
destroyed. The following is a systematic energy balance performed for each unit of
the process. The datum temperature for calculation is taken as 0 C. The different
properties like specific heat, heat of reaction, heat of vaporization, etc. are taken to
be constant over the temperature range. This does not however, introduce
significant error in the calculations.
The units are as depicted in the flow sheet (Ch-3, Fig. 3.3) Energy balance around
the refrigeration unit Inputs:
Temperature of make-up water = 30 C
Temperature of recycled water = 30 C
Sensible heat of make up water = m.CP.T = 0.40004.18(30-0)= 50 kW
Sensible heat of recycled water = m.CP.T = 7.90344.18(30-0)= 991 kW
Total heat in = 1041 kW Outputs:
Temperature of water exiting = 11 C
Sensible heat of the exit stream = m.CP.T = 8.30344.18(11-0)= 382 kW
Rate of heat removal in the refrigeration unit = 1041-382 = 659 kW
The efficiency of a heat pump, COPh, depends on several factors. Especially the temperature
difference between waste heat source and potential user is an important factor. The temperature
difference between condensation and evaporation temperature mainly determines the efficiency: the
smaller the difference, the higher the COPh.
The figure on the left shows the influence of this temperature difference on the COPh value. These
values are based on figures from a Grasso 65HP compressor with the refrigerant Ammonia.
The figure shows an increase in COPh with an increasing evaporation temperature. Futhermore it
shows a decrease in COPh with a decreasing condensation temperature. In general the COPh
decreases with an increase in temperature difference between condensation and evaporation.
The figure below gives an indication of the dependence of the COPh of an Ammonia heat pump as
a function of this temperature difference.
Another important factor that influences efficiency is the appliedrefrigerant. Ammonia, for example, is
a very efficient refrigerant with a COPh of 6 for a evaportion temperature of 30 C and condensation
temperature of 70 C. These same conditions only give a COPh of 4,5 for refrigerant R134A. Other
factors that will effect the efficiency of a heat pump are system controls, efficiency of pheripheral
equipement like fans, pumps, etc.
Carnot efficiency
The theoretical maximum efficiency of a heat pump is described by the Carnot-efficiency:
The equation shows that the Carnot-efficiency depends on the condensation and evaporation
temperature. With an ideal compression cycle without losses it is possible to achieve the Carnot
efficiency. However, in practice there are a lot of parameters that have a negative influence on the
efficiency. Therefore the real COPh is given by the product of the Carnot efficiency and the system
efficiency:
Lorentz efficiency
With a transcritical heat pump the Carnot-efficiency can not be used, because there is no
condensation temperature, but a temperature range in the gas cooler. The theoretic maximum
efficiency of a transcritical heat pump is described by the Lorentz efficiency.
Tm is the mean temperature in the gas cooler. This temperature is calculated from the temperature
at the inlet and the outlet of the gas cooler:
Similar to Carnot, the Lorentz efficiency will not be reached in practice due to all kind of losses. To
determine the real COP, a system efficiency must be taken into account:
power
is achieved for each kW of power consumed by the pumps compressor.
COP is indicated without units. Therefore the produced heat and the supplied power employ
the same units during COP calculation.
4 pts
Read :
Given:
TH
TH
560
833.15
???
Find:
TC
TC
K
COPR
???
COPHP
55
328.15
???
None.
The thermal efficiency of a Carnot Cycle depends only on the temperatures of the thermal reservoirs with
which it interacts. The equation that defines this relationship is :
Eqn 1
Part b.)
60.6%
Eqn 2
COPR
0.6498
This is an exceptionally BAD COPR because it is less than 1. This isn't terribly surprising when you consider
that the refrigerator must reject heat to a thermal reservoir at 560oC !!
Part c.)
The coefficient of performance of a Carnot Heat Pump Cycle also depends only on the temperatures of
the thermal reservoirs with which it interacts. The equation that defines this relationship is :
Eqn 3
COPHP
1.6498
This is a BAD COPHP because it is just barely greater than 1. This isn't terribly surprising when you consider
that the heat pump must put out heat to a reservoir at 560oC !!
Eqn 4
Answers :
1.65
60.6%
COPR
0.650
COPHP
Therefore CP = EER x 0.292. The range of EER's for air conditioners is typically
about 5.5 to 10.5 with those units for which EER>7.5 being classified as "high
efficiency" units. This is a range of 1.6 to 3.1 in CP.