Reported by:
Md. Jabed Iqbal Bhuiyan
ID: PG20-02-12-005
Reported by:
Md. Jabed Iqbal Bhuiyan
ID: PG20-02-12-005
Supervisor
..
CERTIFICATION
This is certify that this thesis entitled Manufacturing of carbonated soft
drinks powder submitted by Md. Jabed Iqbal Bhuiyan,
ID: PG20-02-12-005, M.Sc Student, Department of Food Engineering &
Technology, State University of Bangladesh, has been carried out under
my supervisor. This is further to certify that this thesis work is carried
out as partial requirement for fulfillment of the M.Sc degree in Food
Engineering & Technology.
Supervisor
..
MANUFACTURING OF CARBONATED
SOFT DRINKS POWDER
Dedicated to My Parents
&
All Friends
ACKNOWLEDGEMENT
I respect to my thesis supervisor Anis Alam Siddiqui, Chairman, Department of
Food Engineering & Technology, State University of Bangladesh, for his proper and
endless guidance, advice, encouragement and support through out the progress about the
thesis.
I like to Special thanks MD. Saiful Islam (D.G.M-Production), Haque Brothers
Industries Limited, and Quality Control incharge mainly A.S.Nasir Uddin Ahamed
(Q.C.I), Haque Brothers Industries Limited, respectively for their encouragement,
valuable information and help during this thesis work.
Its a great opportunity for me to complete the thesis work a well renowned of this
semester thesis on Manufacturing of Carbonated Soft Drinks Powder. With the
help of my respected thesis supervisor, teacher and the authorities of the State University
of Bangladesh, But it has been possible with the proper guideline & cordial effort of my
teacher. I thanks to authorities of Haque Brothers Industries Limited, for give me
sufficient lab facilities. The acquisition of knowledge from this facility is a wonderful
achievement for me.
Really, I am very much glad to my teachers of department to give us a chance to
my learning system and life. I wish this department day by day development.
ABSTRACT
The study was related to preparation of powder soft drinks and there is an
exceptionality that, there is creation of CO2 (Carbon dioxide) when it is dissolved in cold
water. Especially there is used treated sodium bicarbonate. Sugar, Sweeteners, Citric acid,
Ascorbic acid (Vitamin-C), Sodium citrate, Sodium chloride, Colouring agents and
Flavouring agents etc, were also used. Carbonated Energy powder soft drinks prepared
from Energy Powder Flavour. Carbonated Clear lemon powder soft drinks prepared from
Lemon Encapsulated Flavour. Carbonated cola powder soft drinks prepared from Cola
Encapsulated Flavour. At first necessary ingredients measure accurately and then mix
properly. Dry this mixture at 60-65C until the drying properly. Should be checked
moisture content of the product, there is moisture should have below 1%. After drying the
mixture will be cooled at 22-23C and below 40% moisture controlled room then mixed
flavour. After mixing it should be packed under same condition (Moisture controlled
room) exactly as customer requirements. The prepared goods have been tested of
Physical, Instrumental, Chemical and Organoleptic test. The pH value of finished goods
should have 3.0 to 4.0; percent of Titrable acidity should be 0.150 to 0.180%. The
finished products of carbonated powder soft drinks were accepted by triangle test.
The Author
---------------------------Md. Jabed Iqbal Bhuiyan
ID: UG20-02-12-005
CONTENTS
CHAPTER
PAGE
ACKNOWLEDGEMENT
ABSTRACT
CONTENTS
LIST OF TABLES
10
ABBREVIATIONS
11
REFERENCE
40
LIST OF APPENDIX
42
LIST OF TABLES
10
ABBREVIATIONS
NMT
NMT
CSDP
BSTI
ADI
FDA
TDO
= TITANIUM DIOXIDE
BFF
BFAL
RTD
= READY TO DRINKS
LDP
BPFR
SOPQCM
MANUAL
RH
= RELATIVE HUMIDITY
RDA
11
CHAPTER 01
INTRODUCTION
1.1: Introduction
Carbonated soft drinks powder (CSDP) is very interesting part of the beverage world,
because when the powder dissolve in cold water then it create CO 2 (Carbon dioxide) in
the glasses. There are three types of carbonated soft drinks powder, such as- Carbonated
energy powder drinks, carbonated clear lemon powder drinks, carbonated cola powder
drinks. Carbonated energy soft drinks is so popular in Bangladesh, like- Royal Tiger,
Speed, Black Horse, Thunder etc., similar product is carbonated powder soft drinks, there
is one difference that this drinks will be dissolved in cold water before consume. This
drink contain 0.70% moisture, 1% sugar concentration, pH is 3.2 and percent of acidity is
0.151%. This drink is accepted by the triangle test. Carbonated clear soft drinks is the
another popular item in Bangladesh, like- Sprite and 7up etc, the similar product is
carbonated powder soft drinks. Difference only both liquid and powder, this is need to
dissolve in cold water before consume. In this drinks you will get about 0.65% moisture,
1.2% sugar concentration, pH 3.5 and percent of acidity is 0.166%. This is getting the
acceptability by an organoleptic (triangle test). Cola soft drink is the most common drinks
in Bangladesh. These are Cocacola, Pepsi, Mojo and Pran cola etc. We will make
carbonated cola powder soft drinks, which is contain about 0.6% moisture, 3.0% sugar
concentration, pH is 3.3 and percent of acidity is 0.170%. This is passed the panel and
triangle test. Carbonated soft drinks are so much popular in the world, such as- Pepsi,
Cocacola, 7up, Sprite, Marrinda etc., There is many kinds of instant powder soft drinks,
such as- Tang, Qualimax etc., These types of powder drinks found in different flavour,
such as- Orange flavour, Mango flavour, Lemon flavour, Lime flavour, Guava flavour,
Pineapple flavour. But there is no carbonated soft drinks powder.
12
13
14
CHAPTER 02
REVIEW OF LITERATURE
There are different powder soft drinks in world market. About 100 years ago
the powder soft drinks was innovated in Indonesia. Day by day it world wide
expanded, now this available in Bangladesh such as Tang, Qualimax, Rasna, shark
etc. are global products and C-vita, Vita-C, Glucose, Prome etc. are the local
products in our country. World wide found only one carbonated powder as
medicine which is ENO. This product is manufacture by gsk. This is not food
product, the gsk always marketed it as medicine.
15
16
17
CHAPTER 03
MATERIALS AND METHODS
3.1: Preparation of carbonated powder soft drinks.
3.1.1: List of Instruments:
a Balance
b Sieves
c Sugar crusher
d Powder mixture (Ribbon mixture)
e Drier (Electric / Gas)
f Air conditioner
g Dehumidifier
h Moisture controlled room
i
Moisture analyzer
Spoon
k Packaging machine
3.1.2: List of raw materials:
a. Crystal Sugar (particle size 80 mesh)
b. Permitted sweetening agents
c. Acidity regulator
d. Vitamin (Ascorbic acid / Vitamin-C)
e. Buffering agents (Sodium chloride / Sodium citrate)
f. Minerals / Anti-caking agents (Tri-calcium phosphate)
g. Carbonating agents (Sodium bicarbonate)
h. Permitted food colour
i. Permitted food flavour
19
Buffering Agents
According to the rules and regulations of BSTI vi, the buffering agents are used for
tuning pH of finished products. As buffering agents we use Sodium Citrate, sodium
chloride, potassium chloride; etc. There is used sodium citrate as buffering agent.
Carbonating Agents
For carbonated soft drinks no need any carbonating agents, there is used CO2 for
fizzing or carbonation. But to make powdered carbonated soft drinks need to add
carbonating agents for fizzing. There is used Sodium Bicarbonate as carbonating
agents, this is permitted by BSTIvii.
Anti-Caking Agents
There is used Tri-calcium phosphate as anti-caking agent, which is used 0.5% on
total batch volume. This is permitted by the BSTI viii. This is lot of sources of
minerals (calcium).
Clouding Agents
There is used food grade Clouding agents which is permitted by the BSTI ix. Some
body used food grade TDO Titanium dioxide in soft drinks as clouding agents.
Food Colouring
Colouring is the most important part for beverage items, there is have two types of
colouring agents such as- Natural and Artificial colour. There is used some
artificial colour such as- Orange red colour, Egg yellow colour, Lemon yellow
colour. This is permitted by the BSTIx.
Food Flavouring
There are used different types of flavour to increase the test of drinks. We chose
Cola, Lemon, and Energy flavour according to the sense of current market of
Bangladesh. This type of flavouring agents permitted by the FDAxi;
3.1.4: Formulations:
21
All formulations are provided by the Banga Flavour Application Lab BFAL of
Banga Flavour & Fragrance (Pvt.) Ltd BFF.
Formulation No. @ 01
Powder Energy Drinksxii
Refine Sugar
Aspartame
Citric Acid Anhydrous
Sodium Citrate
Treated Sodium Bicarbonate
6.700 gm
1.000 gm
15.000 gm
0.400 gm
13.250 gm
Vitamin Premix
2.000 gm
Anti-Caking Agents
0.3 00gm
0.050 gm
1.300 gm
TOTAL
40.000 gm
Formulation No. @ 02
22
7.850 gm
Aspartame
0.900 gm
17.000 gm
Sodium Citrate
0.400 gm
13.250 gm
Anti-Caking Agents
0.3 00gm
0.300 gm
TOTAL
40.000 gm
45.30 gm
Aspartame
0.800 gm
17.000 gm
Sodium Citrate
0.400 gm
14.00 gm
Anti-Caking Agents
0.300 gm
1.200 gm
1.000 gm
TOTAL
80.000 gm
23
Drying
Temperature 60-65C
24
Cooling
(Under moisture controlled condition)
(Temperature 22-23 C and Relative Humidity below 40 %)
Flavour mixing
(Under moisture controlled condition)
Packaging
(Under moisture controlled condition)
Cartoning
(At room temperature)
Storage
(At room temperature)
Marketing
The processing of carbonated powder soft drinks is not a difficult process, but this
is not easy to control the require environment for bring quality. The total process of
carbonated powder soft drinks is described as follows:
Raw materials:
We should collect every raw materials (Sugar, Citric acid anhydrous, Ascorbic
acid, Anti-caking agent, Carbonating agent, Buffering agents, Sodium chloride,
Clouding agents, Permitted food colour, Permitted food flavour) fresh and sound;
Weighing:
Weigh all ingredients according to the formulation. Weighing is most important
part of processing of carbonated powder soft drinks. Taste, colour, flavour and
odour etc. every thing is depends on right quantity of the batch volume. So we
should ensure the right quantity of ingredients. Another things is important that,
always calibrated balance should be used for weigh the all ingredients.
Sugar crushing:
Particle size is the most important for any types of powdered products. As a
carbonated powder products sugar particle size should be 90 meshes to 100 meshes
(as tailor standard). Because of that this is need to dissolve instantly. Crush the
sugar by a fine crusher.
Mixing:
26
Mixing is another important part of the processing of powder soft drinks. At this stage all
ingredients will be mixed by ribbon mixture accurately except flavour. All ingredients
must be mixed homogenously.
Spray water:
The water will be spray in the mixture machine on mixture for getting the appearance and
colour. The water quantity always depends on expected colour and appearance. The water
should be spraying by the spray bottle.
Drying:
After mixing the mixture put in tray and then set in the drier; Start drying at 60 to 65 C
temperature. When completed 50% drying the mixture will be subverted time to time.
When completed drying the will be screened as per requirements. Moisture level must be
reduce up to 0.5% .
Cooling:
After drying the entire mixture shift to a temperature and humidity controlled room.
Temperature and Relative Humidity should have 20-22C and below 40% respectively.
Temperature and Relative Humidity controlling is the most necessary part of any types of
powdered products, specially Carbonated powder soft drinks. Because there is have
possibility of reaction and produce CO2 (carbon dioxide) presence of moisture. So must
be controlled moisture in the cooling area.
Flavour Mixing:
After cooling mix flavour according to formulation under the same condition (Tem. 2022C and RH below 40%). Flavour is the most important ingredients for powder soft
drinks and soft drinks. This is enhancing taste and aroma of the products. There is use
special type of powder flavour, this is called Encapsulated flavour. Here use different
types of flavour; e.g. - Lemon Encapsulated Flavour, Lime Encapsulated Flavour, ColaCola Encapsulated Flavour, Orange Encapsulated Flavour, Energy Powder Flavour;
Packaging:
27
This product may packed glass jar or aluminum foil and LDP Low Density
Polyethylene film etc. The foil packs also called sachet, sachet quantity or serving
size would be 4 gm, 8gm, 12gm, and 22gm; etc. For every serving water quantity
will same (200 ml). After that this sachet will be fill in a box which is contain
about 36 sachets. And by the some boxes make carton.
Labeling:
After the completing process nutrition facts mentioned label will pasting on the jar
or bottle. Nutrition facts must be calculated by proper rules and regulation. Must be
followed BPFR1976
(Bangladesh Pure Food Rules 1976)
Storing:
Every product must be storage during product life path Step by step. Either
manufacturer hand or distributor or retailer or final consumer hand respectively, so
we need proper storage system or condition for this product storing. For the
different types of product need different temperature, humidity or different
environment. For carbonated powder soft drinks need room temperature and
normal Relative Humidity.
28
29
b Brix
Brix is concentration of the sugar in a solution. We determine the Brix or
concentration of sugar by the instrumental methods. For this test required
instrument is refractometer. At first take one serving sample (4gm or 8 gm) in a
beaker and dilute with 200 ml water properly. Wash the refractometer by distilled
water and dry it by the tissue paper. Calibrate the refractometer by distilled water,
reading will 0 Brix. Then put the sample on the refractometer plate, see the result
and put in the results table.
c pH
pH is the another instrumental test for the sample. For this test required a pH meter
and some product (one serving (4 or 8 gm) sample in 200 ml water). Sample
product put in a 250 ml beaker and switch on the machine. After 5 minutes take
reading from the pH meter and put in the results table.
Acidity or pH is the most important factor for product self life, but must be alert
abut pH because this product (Carbonated powder soft drinks) is the carbonating
food. So always should be careful about it. The pH is determined according to
method of BFF (SOPQCM-01-00-33) (2010)xvii.
Sample= 10 ml
NaOH ( 0.1 N )
= As require
= 2 pcs
Electronics balance
= 1 pcs
Conical flask
= 2 pcs
Volumetric flask
= 1 pcs
Burette
= 1 pcs
Pipette
= 2 pcs
Pipette filler
= 1 pcs
Equation:
Burette Reading x Normality of NaOH x Equivalent weight of acid x 100
% of Acidity =
Weight of sample x 1000
Titration method:
a At first take 10 ml sample product (Carrot juice) in conical flask.
b Fill the burette by 0.1(N) sodium hydroxide (NaOH)
c Take 2 (two) to 3 (three) drops phenolphthalein indicator in the
conical flask with sample product (Carrot juice)
d Take 0.1(N) sodium hydroxide (NaOH) from the burette drop by drop
into conical flask until obtained slightly pink colour.
e Take burette reading (BR) or amount of sodium hydroxide (NaOH)
and put in the table.
31
32
CHAPTER - 4
RESULTS AND DISCUSSION
33
Specification
NMT ( ) 1%
NMT ( ) 1%
NMT ( ) 1%
Results
0.70 %
0.65 %
0.60 %
Results
1.0
1.2
3.0
4.4: Results of pH
Table-03: Concentration of hydrogen of solution / pH of formulation @ 01, 02, and 03;
Attribute
Formulations @01 (Energy powder drinks)
Formulations @02 (Clear lemon powder
drinks)
Formulations @03 (Cola-cola powder drinks)
Specification
3.0 to 4.0
3.0 to 4.0
Results
3.2
3.5
3.0 to 4.0
3.3
Differenc
Average
% Acidity
34
1
2
3
e
Initial reading
Final reading
46.2
43.3
40.5
43.3
40.5
37.8
2.4
2.3
2.4
2.366
0.151
Calculation:
2.366 x 0.1 x 64 x 100
% of Acidity =
10 x 1000
= 0.151 %
1
2
3
43.3
40.5
37.8
Differenc
e
2.5
2.7
2.6
Average
% Acidity
2.6
0.166
Calculation:
2.6 x 0.1 x 64 x 100
% of Acidity =
10 x 1000
= 0.166 %
Table 06 : Burette reading for acidity test Formulation @ 03 (Cola-cola powder
drinks)
S
Differenc
Average
% Acidity
35
1
2
3
e
Initial reading
Final reading
46.2
43.3
40.5
43.3
40.5
37.8
2.7
2.6
2.7
2.65
0.170
Calculation:
2.65 x 0.1 x 64 x 100
% of Acidity =
10 x 1000
= 0.170 %
4.6: Results of Triangle test:
Table 07: Results of the triangle test of formulations @ 01 (Energy powder drinks);
Evaluation card:
Name of Product:
Two or three samples are identical. Identify and comment on the odd samples.
Serial No.
Person ~ 01
Person ~ 02
Person ~ 03
Person ~ 04
Person ~ 05
Person ~ 06
Code No. of
samples
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
Note: - 0X0= odd (testing sample) sample, X00 and 00X is same (reference sample)
sample. Four person can be identified the odd sample so product is product is satisfactory.
Table 08: Results of the triangle test of formulations @ 02 (Clear lemon powder
drinks);
36
Evaluation card:
Name of Product:
Two or three samples are identical. Identify and comment on the odd samples.
Serial No.
Person ~ 01
Person ~ 02
Person ~ 03
Person ~ 04
Person ~ 05
Person ~ 06
Code No. of
samples
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
Note: - 0X0= odd (testing sample) sample, X00 and 00X is same (reference sample)
sample. Four person can be identified the odd sample so product is product is satisfactory.
Table 09: Results of the triangle test of formulations @ 03 (Cola-cola powder drinks);
Evaluation card:
Name of Product:
Two or three samples are identical. Identify and comment on the odd samples.
Serial No.
Person ~ 01
Person ~ 02
Person ~ 03
Person ~ 04
Person ~ 05
Person ~ 06
Code No. of
samples
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
0X0, X00, 00X
Note: - 0X0= odd (testing sample) sample, X00 and 00X is same (reference sample)
sample. Four person can be identified the odd sample so product is product is satisfactory.
37
4.5: Results of Total Quality test of the products (Carbonated Powder Soft
Drinks):
Table 10: Results of total quality control test of the products (Carbonated
Powder Soft Drinks)
Attributes
Specification
s
Fine and
granular
powder
Appearance
Off white,
white, blackish,
Colour in
yellowish;
powder
Yellowish,
slightly red to
Colour in liquid blood red;
NMT 1 %
Moisture, %
3.0 to 4.0
pH
Titrable Acidity, (0.150 - 0.180)
%
%
(0.9 to 3.5) %
Brix, %
Satisfactory,
good
Triangle test
Formulation
@ 01
Formulation
@ 02
Formulation
@ 03
Fine and
granular
powder
Off-white to
slightly
yellowish
Fine and
granular
powder
Off-white to
white
Fine and
granular
powder
Off-white to
slightly
blackish
yellowish
0.70 %
3.2
colourless
0.65 %
3.5
Pale red to
blood red
0.60 %
3.3
0.151 %
1.0 %
0.166 %
1.2 %
good
good
0.170 %
3.0 %
good
CHAPTER - 5
38
CHAPTER 6
39
REFERENCES
40
About
tang
(Kraft
foods)
history
http://en.wikipedia.org/wiki/Tang_%28drink%29
i
history
on
from
web
web
management
management
BSTI (2007). Sweetener (Aspartame) for soft drinks powder (BDS 1586: 2007). first
revision, topic (3.1.1.1). p. 3
iii
About aspartame Directorate of Health Canada has been declared about aspartame on
web management http://www.hc-sc.gc.ca/fn-an/securit/addit/sweeten-edulcor/aspartameeng.php
iv
v BSTI (2007). Acidity regulator (Citric acid) for soft drinks powder (BDS 1586: 2007).
BSTI (2007). Carbonating agent (Sodium bicarbonate) for soft drinks powder (BDS
1586: 2007) first revision, topic (3.2.8); p. 3
vii
BSTI (2007). Anti-caking agent (Tri-calcium phosphate) for soft drinks drinks
powder (BDS 1586: 2007) first revision, topic (3.2.3); p. 3
viii
BSTI (2007). Clouding agent for soft drinks powder (BDS 1586: 2007) first revision,
topic (3.2.5); p. 3
ix
BSTI (2007). Colouring agent (Egg yellow colour, Orange red colour and Lemon
yellow colour for soft drinks powder (BDS 1586: 2007) first revision, topic (3.2.6); p. 3
x
xi
US code of Federal Regulations, Title 21, (Food & Drugs) part 170.30
xiv Formulation of carbonated cola soft drinks powder of Banga Flavour Application
Lab BFAL a concern of Banga Flavour & Fragrance (Pvt.) Ltd BFF
BFF (2010). (Appearance test method) Standard operating procedure and quality
control manual 01, Method no. SOPQCM-01-00-28.
xv
xvi BFF (2010). (Moisture analysis method) Standard operating procedure and quality
BFF (2010). (% of Acidity test method) Standard operating procedure and quality
control manual 01, Method no. SOPQCM-01-00-38.
xviii
CHAPTER 7
LIST OF APPENDIX
1. Defination of carbonated soft drinks powder:
Carbonated soft drinks powder (CSDP) is very interesting part of the beverage world, because
when the powder dissolve in cold water then it create CO2 (Carbon dioxide) in the glasses.
There are three types of carbonated soft drinks powder, such as- Carbonated energy powder
drinks, carbonated clear lemon powder drinks, carbonated cola powder drinks.
Mixing
Spray water
Drying
Cooling
Flavour Mixing
Packaging
Labeling
Storing
Balance
Sieves
Sugar crusher
Air conditioner
Dehumidifier
Moisture analyzer
Spoon
Packaging machine
Moisture analysis
Brix test
pH test
Acidity test
THE END