Structural Engineering
TECHNICAL NOTE
Abstract
The increasing in greenhouse gas emissions, as well as solid waste disposal from the cement manufacturing industry and the
Malaysian palm oil industries respectively contributes towards the undesirable 6C Scenario envisioned by the International Energy
Agency. The utilization of Palm Oil Fuel Ash (POFA) as partial cement replacement in the production of Oil Palm Shell (OPS)
Lightweight Aggregate Concrete (LWAC) would significantly reduce cement consumption and amount of disposed landfill waste. In
this investigation, the effect of POFA content as partial cement replacement towards the compressive strength of OPS lightweight
aggregate concrete has been conducted. A total of six OPS LWAC mixtures were prepared with varying the percentages of POFA viz.
0%, 10%, 20%, 30%, 40% and 50% to determine the best replacement of POFA as partial cement replacement. The ashes were
ground to enhance their pozzalanicity. The best replacement of POFA-20 was then used to investigate the mechanical properties of
OPS LWAC such as compressive strength, flexural strength and modulus of elasticity. The concretes containing POFA were placed in
different types of curing regimes namely water, air, sprayed and natural weather curing before subjected to compressive strength test
and flexural strength test at the age of 28, 60, 180,270 and 365 days. The compressive strength was conducted in accordance with the
BS EN12390-3 whilst the flexural strength test was carried out in accordance with the BS EN 12390-5. It was found that water curing
is the best method amongst others. OPS LWAC with POFA exhibits the highest results of compressive strength, flexural strength and
modulus of elasticity. The production of extra C-S-H gel resulting from better pozzolanic reaction for water cured OPS LWAC with
POFA has contributed to the densification of the internal structure that in turn enhances the concrete strength.
Keywords: oil palm shell, palm oil fuel ash, partial cement replacement, different curing regime compressive strength, flexural
strength
1. Introduction
Hitherto, the increase in the production of concrete is essentially
due to the higher demand from the construction industry that
continues to flourish in many parts of the globe. This material
that is produced annually over than 10 billion tonnes (Meyer,
2009) is well known for its excellent mechanical properties that
is achieved through the use of Portland cement as a sole binder.
In other words, concrete as a building material would perish
from the world of building construction upon the absence of
Portland cement in the mix. Despite its superior binding property
of Portland cement, the production of this material consumes a
large amount of natural resources and releases a colossal quantity
greenhouse gas thus posing a negative impact towards the
environment. The elimination of Portland cement use in concrete
mix is thus far impossible. However, the amount of this binder
used can be reduced by integrating supplementary cementitious
material derived from industrial wastes to produce a more
*Lecturer, Faculty of Civil Engineering and Earth Resources, Universiti Malaysia Pahang, Lebuhraya Tun Razak 26300 Gambang, Pahang, Malaysia (Corresponding Author, E-mail: khairunisa@ump.edu.my)
**MEng. Student, Faculty of Civil Engineering and Earth Resources, Universiti Malaysia Pahang, Lebuhraya Tun Razak 26300 Gambang, Pahang, Malaysia
(E-mail: nurazzimahzamri@yahoo.com)
1
2. Experimental Programme
2.1 Materials
The materials used in this study consist of ordinary Portland
cement, sand, Oil Palm Shell (OPS), Palm Oil Fuel Ash (POFA),
superplasticizer and tap water. A single batch of Ordinary
Portland Cement (OPC) that conforms with MS 522: Part 1:
(2003) for Portland cement specification was used as a binder to
produce all the concrete specimens. Tap water was used for
concrete mixing work and curing purpose. A small percentage of
Superplasticizer, categorized as Type A water reducing admixtures
in accordance with ASTM C494-05 (2005) was employed in the
mix at the amount of 1% of the cementitious material. The fine
aggregate used is local river sand with fineness modulus of 2.62.
In this study, the OPS were used as coarse aggregate in this
lightweight concrete mix. POFA was added as partial cement
replacement. OPS and POFA shown in Figs. 1 and 2 were
collected from a palm oil mill located in the state of Pahang,
West Malaysia. The OPS were washed thoroughly until the dirt
and fibers on its surface were removed at the UMP concrete
laboratory. Then, it is air dried and sieved through a 10 mm sieve
to remove smaller particles. The OPS were then crushed before
sieved again using 5 mm sieve. The physical properties of the
Mechanical Properties of Oil Palm Shell Lightweight Aggregate Concrete Containing Palm Oil Fuel Ash as Partial Cement Replacement
Ground OPS
2.3
5.80
596
22.22
13.83
Mixes
Cement
Sand
500
450
400
350
300
250
870
870
870
870
870
870
POFA-0
POFA-10
POFA-20
POFA-30
POFA-40
POFA-50
Water
225
225
225
225
225
225
ground OPS are tabulated in Table 1. POFA taken from palm oil
mill were sieved using 300 m and ground to be very fine. The
Vol. 00, No. 0 / 000 0000
Remark
Specimen was immersed inside water tank for one year
Specimen was placed in concrete laboratory for one
Air Curing
year
Natural
Specimen was placed outdoor, exposed to rain and
Weather Curing sunny day for one year
Specimen was covered using gunny sack and watered
Sprayed Curing
three times a day for one year
Chemical Constituent
Silicon dioxide (SiO2)
Aluminium oxide (AL2O3)
Ferric oxide (Fe2O3)
Calcium oxide (CaO)
Magnesium oxide(MgO)
Sodium oxide (Na2O)
Pottasium oxide (K2O)
Sulphur oxide (SO3)
Lost of ignition (LOI)
OPC
16.05
3.67
3.41
62.28
0.56
0.06
0.82
4.10
1.20
POFA
51.55
4.64
8.64
5.91
2.44
0.07
5.50
0.61
5.00
Mechanical Properties of Oil Palm Shell Lightweight Aggregate Concrete Containing Palm Oil Fuel Ash as Partial Cement Replacement
Fig. 7. Compressive Strength of OPS LWAC Specimens with Different POFA Content at 28 days
both water and sprayed curing regime throughout the curing age.
Evidently, the application of water curing successfully assists the
concrete to exhibit the highest compressive strength. The availability of moisture, assists POFA to react with calcium hydroxide
formed during the hydration process thus producing larger amount
of secondary C-S-H gel that makes the Interfacial Transition
Zone (ITZ) of the blended cement concrete denser and stronger
in comparison to plain specimen. Duan et al. (2013) opined that
occurrence of pozzolanic reaction upon the integration of pozzolanic ash as supplementary cementitious material will improve
the pore structure and ITZ to be denser. Another researcher,
Tanaka and Kurumisawa (2002) also highlighted out that the
strength of ITZ is one of the main factors that contribute towards
compressive strength. Therefore, it could be concluded that, continuous availability of moisture provides a conducive environment
for the occurrence of better pozzolanic reaction that substantially
contributes towards the refinement of pore structure that leads to
strength enhancement.
It was observed that POFA-20 in air curing regime exhibited
lower strength as compared to the fully cured concrete. Within
the initial periods which after the concrete were demoulded,
there is sufficient moisture in the concrete (until the age of 60
days) due to the high humidity environment in the laboratory for
the hydration process and pozzolanic reaction to take place. This
condition enables the specimens to exhibit higher value of compressive strength than the control specimen. The humidity level
in concrete laboratory is not uncommon in tropical regions and it
allows lower evaporation of concrete specimen compared to
drier environment (Shafigh et al., 2013a). However, at the age of
Mechanical Properties of Oil Palm Shell Lightweight Aggregate Concrete Containing Palm Oil Fuel Ash as Partial Cement Replacement
Fig. 15. SEM Image of 1 year Water Cured OPS LWAC with POFA
(POFA-20)
Fig. 16. SEM Image of 1 year Water Cured Plain Plain OPS LWAC
without POFA (POFA-0)
4. Conclusions
Based on the results obtained from this study, the following
conclusions are made:
Oil palm shell lightweight aggregate concrete exhibits the
highest compressive strength upon the inclusion of 20% POFA
as partial cement replacement. The occurrence of optimum
pozzolanic reaction has enabled the densification of the concrete
internal structure causing it to exhibit the highest strength value
amongst all mixes.
The utilisation of POFA as partial cement replacement up to
30% is able to produce oil palm shell lightweight aggregate concrete exhibiting the targeted compressive strength.
Oil palm shell lightweight aggregate concrete produced using
40 and 50% palm oil fuel ash also can be used for structural
application.
The strength performance of POFA-20 is very much dependent
on the duration of the specimen as it comes in contact with
moisture. Therefore, it can be concluded that, water curing is the
best curing method for OPS LWAC containing POFA as it
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