OPTICAL PROPERTIES
ISSUES TO ADDRESS...
What happens when light shines on a material?
Why do materials have characteristic colors?
Why are some materials transparent and other not?
Optical applications:
--luminescence
--photoconductivity
--solar cell
--optical communications fibers
Absorbed : IA
Transmitted
: IT
Incident: I o
transmitted
light
electron
cloud
distorts
Material
Lead glass
Silica glass
Soda-lime glass
Quartz
Plexiglas
Polypropylene
n
2.1
1.46
1.51
1.55
1.49
1.49
OPTICAL PROPERTIES OF
METALS: ABSORPTION
Absorption of photons by electron transition:
Energy of electron
unfilled states
Io
on
t
o
h
p
t
en
h
d
i
Inc
gy
r
e
n
of e
Planck constant
(6.63 x 10 -34 J/s)
freq.
of
incident
light
E = h required!
filled states
Adapted from Fig. 21.4(a), Callister 6e.
OPTICAL PROPERTIES OF
METALS: REFLECTION
Electron transition emits a photon.
Energy of electron
IR
re-emitted
photon from
material surface
unfilled states
onducting?electron
E
filled states
Adapted from Fig. 21.4(b), Callister 6e.
Photo Device
Compact Disk
APPLICATION: LUMINESCENCE
Process:
Energy of electron
Energy of electron
unfilled states
unfilled states
incident
radiation
E gap
E gap
emitted
light
filled states
electron
transition occurs
Adapted from Fig. 21.5(a), Callister 6e.
filled states
re-emission
occurs
Adapted from Fig. 21.5(a), Callister 6e.
hite?light
UV
radiation
unfilled states
Io
E gap
filled states
Adapted from Fig. 21.5(a), Callister 6e.
COLOR OF NONMETALS
Color determined by sum of frequencies of
--transmitted light,
--re-emitted light from electron transitions.
-- adding Cr2O3 :
Transmittance (%)
-- Sapphire is colorless
80
sapphire
70
Ruby
60
50
40
0.3
wavelength,
0.5
0.7
(= c/ )(m)
0.9
SUMMARY
When light (radiation) shines on a material, it may be:
--reflected, absorbed and/or transmitted.
Optical classification:
--transparent, translucent, opaque
Metals:
--fine succession of energy states causes absorption
and reflection.
Non-Metals:
--may have full (Egap < 1.8eV) , no (Egap > 3.1eV), or
partial absorption (1.8eV < Egap = 3.1eV).
--color is determined by light wavelengths that are
transmitted or re-emitted from electron transitions.
--color may be changed by adding impurities which
change the band gap magnitude (e.g., Ruby)
Refraction:
--speed of transmitted light varies among materials.
12
Display
CRT
Display
PDP
Display
FED
Display
VFD
Photo Device
Laser Diode
Display
LED
Display
OLED
Photo Device
Optical Fiber
time
shorter path
longer paths
cladding : glass
w/lower n
n enhances
internal reflection
input pulse
intensity
time
broadened!
Adapted from Fig. 21.19, Callister 6e. (Fig. 21.19 adapted from S.R. Nagel, IEEE
Communications Magazine, Vol. 25, No. 4, p. 34, 1987.)
time
Adapted from Fig. 21.20, Callister 6e. (Fig. 21.19 adapted from S.R. Nagel, IEEE
Communications Magazine, Vol. 25, No. 4, p. 34, 1987.)
input pulse
intensity
time
less
broadening!
11
APPLICATION: PHOTOCONDUCTIVITY
Description:
Energy of electron
Energy of electron
unfilled states
unfilled states
semi
conductor:
E gap
Incident
radiation
filled states
filled states
A. No incident radiation:
little current flow
conducting
electron
E gap
B. Incident radiation:
increased current flow
Photo Device
Photo Detector
Operation:
P -doped Si
Si
Si
Si
Si
creation of
hole-electron
pair
- -
+
+ + +
Si
Si
light
n-type Si
p-n junction
p -type Si
n-type Si
p-n junction
p -type Si
hole
Si
Si
B-doped Si
polycrystalline Si
Los Alamos High School weather
station (photo courtesy
P.M. Anderson)
10
S/D
Passn
ITO
(c) MOSFET
Inter-insulator
Glass
Gate Oxide
N+ poly-Si
Poly-Si
a-Si
S/D
Passn
ITO
Glass
Gate nitride
Gate
POSTECH
Pohang University of Science and Technology