1.
(a)
Ammonia is manufactured by passing hot nitrogen and hydrogen at high pressure over a
catalyst containing iron.
In an experiment, 9.0 moles of nitrogen and 27 moles of hydrogen were put into an iron
vessel of volume l0 dm3. This was then heated to 250 C and allowed to reach
equilibrium. It was found that two thirds of the nitrogen and hydrogen were converted into
ammonia.
N2(g) + 3H2(g) 2NH3(g)
(i)
H = 92.4 kJ moll
(1)
(ii)
moles at start
N2
H2
NH3
9.0
27
moles at equilibrium
concentration at equilibrium
/mol dm3
(2)
(iii)
(2)
(iv)
et
(v)
State the effect, if any, of an increase in pressure on the value of the equilibrium
constant, giving a reason.
....
....
....
(2)
(b)
Some of the ammonia manufactured in this way is converted into nitric acid, HNO3. The
first step in this process is the oxidation of ammonia.
4NH3(g)+ 5O2(g) 4NO(g) + 6H2O(g)
(i)
Calculate the standard enthalpy change for this reaction given the following
standard enthalpies of formation in kJ mol1:
NH3(g) 46.2
NO(g) + 90.4
H2O(g) 242
(3)
(ii)
Enthalpy
(2)
(c)
A mixture of concentrated nitric and sulphuric acids is used in the nitration of benzene to
form nitrobenzene.
(i)
et
(ii)
The formation of the NO 2 ion occurs in two steps, the first of which is:
base .
(iii)
(iv)
Give the mechanism for the reaction of the NO 2 ion with benzene.
(3)
(v)
(1)
(Total 22 marks)
et
2.
(a)
Describe an experiment that could be used to follow this reaction. Your answer should
include a diagram of the apparatus that you would use and a statement of the
measurements that you would make.
..
..
..
..
(5)
(b)
2H O(1) + O (g)
2
(ii)
Comment on the relative values of the activation energies and the rate constants for
the decomposition reactions above.
Activation energies ...........................................
....
Rate constants ...............................................
....
(2)
et
(iii)
Explain, in terms of collision theory, the effect on reaction rates of increasing the
temperature to 60 C.
....
....
....
....
....
(3)
(iv)
(c)
acid catalyst
CH2ICOCH3 + HI
was studied with an excess of propanone and an acid catalyst. The variation of
concentration of iodine as a function of time is shown below.
[I2]
time
What is the order of this reaction with respect to iodine? Give your reasoning.
..
..
..
..
(3)
(Total 16 marks)
et
3.
Citral is a colourless natural product, which gives lemons their characteristic flavour and smell.
Its structural formula is:
CH 3
CH 3
(a)
(i)
CH CH 2
CH 3
CH 2
CH CHO
How would you show that citral has a carbonyl group, C==O?
Reagent ......
Observation ....
(2)
(ii)
(b)
Citral has geometric isomers. Draw them and explain why they are not easily
interconvertable.
Structures:
Reason
..
(3)
(c)
et
(ii)
Draw the structural formula of the product of this reaction when excess bromine
is added.
(1)
(iii)
This product is chiral. Mark all the atoms which cause chirality with a on the
structural formula that you have given in (ii) above.
(2)
(d)
State a reagent and the conditions that could be used for this reaction.
Reagent ......
Conditions ..
(2)
(ii)
How would you test the product to show that it has an OH group?
Reagent ......
Observation ....
(2)
(e)
Citral can be oxidised to an acid C9H15COOH (Mr = 168) which ionises in water
C9H15COOH + H2O H3O+ + C9H15COO
4.62 g of this acid was dissolved in water to give a solution of volume 250 cm3.
This solution had a pH of 2.91.
(i)
(1)
et
(ii)
(1)
(iii)
(3)
(Total 20 marks)
et