(Edu - Joshuatly.com) Terengganu SPM Trial 2011 Chemistry (W Ans) PDF

SULIT
4541/1(PP)
JABATAN PELAJARAN NEGERI TERENGGANU
PEPERIKSAAN PERCUBAAN
SIJIL PELAJARAN MALAYSIA 2011
4541/1(PP)
CHEMISTRY
Kertas 1
Sept. 2011
PERATURAN PEMARKAHAN
UNTUK KEGUNAAN PEMERIKSA SAHAJA
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4541/1(PP) 2011 Hak Cipta JPNT
http://edu.joshuatly.com/
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SULIT
SULIT
4541/1(PP)
CHEMISTRY
PAPER 1
ANSWER
Question
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Answer
C
B
A
D
A
C
C
A
A
A
B
C
A
D
A
D
C
A
B
D
A
C
D
C
A
Question
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Answer
B
D
C
C
B
D
B
B
B
D
A
B
B
C
D
A
B
D
A
C
D
B
A
B
C
END OF MARKING SCHEME

PERATURAN PEMARKAHAN TAMAT
SULIT
SULIT
4541/2(PP)
4541/2(PP)
CHEMISTRY
Kertas 2
Sept. 2011


SULIT
SULIT
4541/2(PP)
SECTION A [60 MARKS]

Question
1 (a) (i)
(ii)
(b)
(a)
(b)
(c)
(d)
(a)
(b)
Marking Criteria
Melting point: 53 C
Boiling point: 259 C
Marks
1
[values and unit]
Physical state
Region
AB
Solid
DE
Liquid and gas
(iii) The heat energy absorbed by the particles
Is used to overcome the forces of attraction between particles
(i) 7
(ii) 33
16Q
(iii) P and S
(iv) Q and R
Have same number of protons but different number of neutrons //
Have same proton number but different nucleon number
TOTAL
(i) Ammonia
(ii) (NH4)2SO4
Corrodes buildings
Corrodes metal structures
pH of the soil decreases
Lakes and rivers become acidic
(i) Urea, (NH4)4CO
2 14
100% or 43.8%
2(14 + 4) + 12 + 16
Compound Y / Ammonium Sulphate, (NH4)2SO4

2 14
100% or 21.2%
2(14 + 4) + 32 + 4(16)
(ii) Urea
Urea has a higher percentage or nitrogen by mass
(i) Produce poisonous / toxic gases
(ii) Recycle // Reuse // Pirolysis // Use biodegradable polymers
TOTAL
(i) Proton number
(ii) 18
(iii) Electric bulb // (Any suitable uses)
(i) Group 17, Period 3
(ii) Size of sodium atom is bigger than chlorine atom
Number of protons in sodium atom is more than chlorine atom
Attraction force between nucleus and electron sodium atom is
stronger
(iii) Ionic
1
1
1
1
1
1
1
1
1
9
1
1
1
1
1
1
1
1
1
1
1
1
9
1
1
1
1
1
1
1
1
SULIT
SULIT
(a)
(i)
(ii)
(b)
(c)
(i)
(ii)
(d)
(i)
(ii)
(a)
(i)
(ii)
(b)
(c)
(i)
(ii)
(d)
4541/2(PP)
Number of electron occupied with electron and symbol

Charge of Na+ and Cl-
1
1
TOTAL
0.1 mol of HCl in 1 dm3 of solution
Mole of HCl = 0.1
Concentration = 0.2 mol dm-3
Concentration of hydrogen ion in Experiment I is higher than
Experiment II
The higher the concentration of hydrogen ion, the lower the pH
value
pH value of Experiment II is higher than Experiment III
Concentration of hydrogen ion / H+ in sulphuric acid is higher than
hydrochloric acid
Volumetric flask
Mol = 1 250 1000 // 0.25 mol
Mass = 0.25 x 40 // 10 g
TOTAL
Lead (II) nitrate
White
To ensure all acid to be reacted completely
Formula of reactants and products correct
Balance
PbO + 2HNO3 Pb(NO3)2 + H2O
Mole of HNO3 = 1 50 1000 // 0.05
10
1
1
1
1
1
1
1
1
1
1
10
1
1
1
1
1
2 mol HNO3 1 mol Pb(NO3)2 //

0.05 mol HNO3 0.025 mol Pb(NO3)2
Mass of Pb(NO3)2 = 0.025 x 331 // 8.275 g

Add dilute sulphuric acid to solution followed by Iron(II)
sulphate solution
Drop concentrated sulphuric acid slowly
A brown ring is formed
TOTAL
1
1
1
1
11

SULIT
SULIT
6
(a)
(b)
4
(i)
(ii)
(i)
(ii)
A reaction where oxidation and reduction occur at the same time

Set
1
2
Changes oxidation
+2 to +3
+2 to 0
number of iron
Half equation
Fe2+ Fe3+ + e
Fe2+ + 2e Fe
Type of reaction
Oxidation
Reduction
X: Copper // Silver // (Other metals situated lower than iron in
the electrochemical series)
Y: Magnesium // Zinc // (Other metals situated higher than iron
in the electrochemical series)
Iron atoms lost electrons to form Iron(II) ion / Fe2+ // Iron
undergoes oxidation
The Iron (II) ion // Fe2+ is present
TOTAL
4541/2(PP)
1
1+1
1+1
1+1
1
1
1
1
11
SECTION B [20 MARKS]
Question
(a)
(b)
(c)
(i)
Marking Criteria
Electrode Copper X: Type of electrode
Electrode carbon Y: The position of ions in the electrochemical
series
Electrode
Carbon electrode Y Copper electrode X
(cathode)
(anode)
2+
+
2List of all ions
Cu , H , SO4 , OHpresent in
electrolyte
List of ions
Cu2+, H+
SO42-, OHattracted to each
electrodes
Name of the ion
Copper(II) ion
Copper(II) ion
selectively
discharge and ion
formed at the
electrode
The reason why the
Cu2+ ion lower in
ion selectively
the electrochemical
discharge at
series
cathode
Half equation for
Cu2+ + 2e Cu
Cu Cu2+ + 2e
the reaction at each
electrodes
Oxidation
Release / donate electron
Marks
1
1
1+1
1+1
2+2
1
1
SULIT
SULIT
5
(ii)
(d)
(i)
(ii)
(a)
(i)
(ii)
(b)
4541/2(PP)
Formula of reactant and products correct

Balanced
1
1
4OH- O2 + 2H2O + 4e
Zinc
More electropositive than copper
To allow the movement of ions
Sulphuric acid // (Any suitable answers)
TOTAL
Heat is released when 1 mole of metal copper is displaced from
copper sulpahte solution by zinc metal
Formula of reactants
Formula of products
Zn + Cu2+ Zn2+ + Cu
(iii) Reactant: Zn & CuSO4
Products: Cu & ZnSO4
Total energy of Zn and CuSO4 is higher / more than total
energy of Cu & ZnSO4
The reaction is exothermic / release energy
P kJ heat is released when 1 mole of copper is displaced
(iv) Heat released, Q
Q = 2.5 4.2 10 // 1050 J mol-1 / 1.05 kJ mol-1
Mole of Cu ion = 0.2 25 1000 // 0.005 mol
H = 1.05 0.005 kJ mol1 // -210 kJ mol-1
(Correct sign and unit)
(v) Heat is lost to the surrounding
Thermometer and beaker absorb some heat
(i) HCl is strong acid // CH3COOH is a weak acid
HCl ionises completely // CH3COOH ionises partially
Some of heat released are absorbed by the CH3COOH
molecules to break down the O-H bonds
(ii) HCl is a monoprotic acid // H2SO4 is a diprotic acid // Number
of H+ ion in H2SO4 is twice
In Experiment I, 1 mol of H+ ion reacts with 1 mol of OHproduced 1 mol of water; heat released is 57 kJ
In Experiment II, 2 mol of H+ ion reacts with 2 mol of OHproduced 2 mol of water; heat released is 2 57 kJ
TOTAL
1
1
1
1
20
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
20

SULIT
SULIT
4541/2(PP)
SECTION C [20 MARKS]

Question
9 (a) (i)
(b)
Marking Criteria
P: (Name of any metal situated above Cu in the
electrochemical series)
Sample answer: Magnesium // Zinc // Aluminium
[reject: Sodium // Potassium]
Q: (Name of any acid)
Sample answer: Hydrochloric acid // Sulphuric acid // Nitric
acid
[Accept weak acid]
(Chemical equation)
Correct formula of reactants and products
Balanced
Mg + 2HCl MgCl2 + H2
(ii) Experiment I = 30 10 3.0 cm3 s 1
Experiment II = 30 20 1.5 cm3 s1
[With correct unit]
(iii) Rate of reaction in Experiment I is higher than Experiment II
The concentration of acid in Experiment I is higher than
Experiment II // The number of hydrogen ions per unit volume
in Experiment I higher than Experiment II
Frequency of collision between hydrogen ions and atoms of P
in Experiment I is higher than in Experiment II
Frequency of effective collision between the particles in
Experiment I is higher than in Experiment II
Factor: Size of Reactant
[Name of catalyst used]
Example: calcium carbonate / marble chips and hydrochloric acid //
Zinc and sulphuric acid
[Procedure]
A burette is filled with water and inverted over a basin of water
and the burette is clamped vertically using retort stand.
Initial burette reading is recorded
(1.0 2.0 g) of large pieces / granules / pieces of metal /
metal carbonate is weighed and put into a conical flask
(20 50 cm3) of (0.5 2.0) mol dm-3 of acid is poured and into
the conical flask. The conical flask is closed immediately with
stopper and delivery tube
Stopwatch is started and the conical flask is swirled throughout
the experiment
The burette reading is recorded at 30 seconds interval
Marks
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
SULIT
SULIT
4541/2(PP)
The experiment is repeated by using small pieces / powder of

metal / metal carbonate
[Results]
Experiment I: Using a large pieces of metal / metal carbonate
Time / s
0
30
60
90
Burette reading / cm3

Volume of gas / cm3
Experiment II: Using a small pieces / powder of metal / metal

carbonate
Time / s
0
30
60
90
3
Burette reading / cm
Volume of gas / cm3
Sketch the graph of volume of gas against time for both experiment
at same axis
Volume of gas / cm3

II
I
Time / s
[Gradient of the graph using small pieces is stepper / higher than
large pieces]
1
[Max 10]
Rate of reaction using powder is higher than granules
Factor: Temperature
Name of reactant used: sodium thiosulphate and hydrochloric /
sulphuric acid
[Procedure]
(20 100) cm3 of (0.1 1.0) mol dm3 sodium thiopsulphate is
poured into a conical flask
The initial temperature of sodium thiosulphate is recorded
The conical flask is placed on the top of a piece of white paper
marked with X
5 cm3 of (0.1 1.0) mol dm3 hydrochloric acid is measured
and quickly poured into the conical flask. The conical flask is
1
1
1
1

SULIT
SULIT
4541/2(PP)
swirled throughout the experiment

A stopwatch is started immediately
The time taken for the mark X to disappear from sight is
recorded
The experiment is repeated using sodium thiosulphate solution
at 35C, 40C, 45C and 50C
[Results]
Temperature / C
Time / s
1
/ s 1
30
35
40
45
50
55
1
1
1
Plot the graph of temperature against time or temperature against

1/time
Temperature / C
Time / s
10
(a)
(b)
(c)
Conclusion: The higher the temperature, the higher the rate of

reaction
TOTAL
Carbon dioxide / CO2 and water / H2O
[Any correct chemical equation]
Chemical formula of reactant
Balanced
Example:
2C4H10 + 13O2 8O2 + 10H2O
Compound B and Compound D
Same molecular formula, C4H8
Different structural formula
Pour compound A / B into a test tube
Add bromine water to the test tube
Test tube contain compound A unchanged
Test tube contain compound B brown colour turns colourless
OR
Pour compound A/B into a test tube
Add acidified potassium manganate(VII) solution into the test tube
Test tube contain compound A unchanged
Test tube contain compound B purple turn colourless
1
[Max 10]
20
1
1
1
1
1
1
1
1
1
1
SULIT
SULIT
(d)
9
(i)
(ii)
4541/2(PP)
Any members of carboxylic acid and correct ester

Example:
Methanoic acid
Prophylmetanoate
1
1
H
||
H C OH
O
H H H
||
|
| |
HCOCCCH
|
| |
H H H
Pour 2 cm3 of (methanoic acid) into a boiling tube

Add 2 cm3 of propanol / Compound E into the boiling tube
Slowly / carefully drop 1 cm3 of concentrated sulphuric acid
Heated the mixture (with a smaller flame)
Pour the mixture in a beaker that contains water
Observation: formed liquid that fruity smell / floats on water
surface
TOTAL
1
1
1
1
1
1
20


SULIT
SULIT
4541/3(PP)
4541/3(PP)
CHEMISTRY
Kertas 3
Sept. 2011


SULIT
SULIT
4541/3(PP)
Question 1 (a)
Rubric
Able to construct a table to record the data that contains:
Score
3
Correct titles
Correct readings with 2 decimal places
Correct unit
Sample Answer:
Alcohol
Initial reading / g
Final reading / g
Methanol
374.95
373.40
Ethanol
332.00
330.80
Propanol
344.40
343.29
Butanol
372.90
371.29
Able to construct a less accurate table that contains:
Mass / g
1.55
1.20
1.11
1.61
Title
Readings
Without unit
Able to construct a table with at least 3 correct reading
No response or wrong response
1
0
Question 1 (b)
Rubric
Able to state all the variables correctly
Sample answer:
Manipulated variable: Alcohols // methanol // ethanol // propanol / butanol
Responding variable: Heat of combustion // Change in temperature
Constant variable: Water // Copper can / container // change in temperature
Able to state any 2 variables correctly
Able to state any 1 variable correctly
Score
3
2
1
0
SULIT
SULIT
4541/3(PP)
Question 1 (c)
Rubric
Score
3
Able to give the hypothesis accurately

Sample answer
The higher the number of carbon atom per molecule alcohol, the higher the heat of
combustion
Able to give the hypothesis almost accurately
Sample answer
Different type of alcohol produce different heat of combustion
Able to state an idea of hypothesis
Sample answer
Type of alcohol affects heat of combustion
Question 1 (d)
Rubric
Able to calculate the heat of combustion accurately
Score
3
Sample answer
Change in temperature, = 58 28 // 30C
Heat released, =
= 200 4.2 30 // 25 200 J
1.55
Number of moles of methanol =
// 0.048 mol
32
25200
Heat of combustion =
0.048
= -525 000 J mol-1 // -525 kJ mol-1
(the value must be in negative and correct unit)
Able to calculate the heat of combustion correctly
Change in temperature
Heat released
Number of moles of methanol
Able to calculate at least temperature change correctly
1
0

SULIT
SULIT
4541/3(PP)
Question 1 (e)
Rubric
Score
3
Able to draw the graph correctly
-axis is Heat of combustion / kJ mol-1 and -axis is number of carbon atom per
molecule
Consistent scale and the graph is half of the paper
All the points are transferred correctly
Straight line
Heat of combustion / kJ mol-1
Number of carbon atoms per molecule

Able to draw the graph incorrectly
-axis is Heat of combustion / kJ mol-1 and -axis is number of carbon atom per
molecule
Consistent scale
About 3 points are transferred correctly
Straight line
Able to state an idea to draw the graph
Draw the x-axis and y-axis

Straight line
Question 2 (a)
Rubric
Score
3
Able to state 3 observations correctly

Sample answer
Test tube
I
II
Intensity of
None
blue colour
Intensity of
High
pink colour
Able to record any 2 observations correctly
Able to record any 1 observation correctly
III
-
IV
Low
2
1
0
SULIT
SULIT
4541/3(PP)
Question 2 (b)
Rubric
Able to state the inference correctly based on the observation
Score
3
Sample answer:
Iron(II) ions / Fe2+ is formed
Sample answer:
The iron nail rust
Sample answer:
Iron changed // Oxidation // Redox reaction
Question 2 (c)
Rubric
Able to state the operational definition of rusting correctly
Score
3
Sample answer:
Blue colour is formed when iron is contact with less electropositive metals
Able to state the operational definition of rusting less accurately
Sample answer:
Blue colour is formed when iron is contact with metals
Able to state any idea of operational definition
Sample answer:
Blue colour is formed

SULIT
SULIT
4541/3(PP)
Question 2 (d)
Rubric
Able to predict the observation correctly
Score
3
Sample answer:
Blue colour is formed // The intensity of blue colour higher
Able to predict the observation less accurately
Sample answer:
Iron rust // rusting occurs
Able to state an idea of observation
Sample answer:
Colour changed
Question 2 (e)
Rubric
Able to state the relationship correctly
Score
3
Sample answer:
The higher the intensity of blue colour, the higher the rate of rusting // vice versa
Able to state the relationship less correctly
Sample answer:
Different of the intensity of blue colour, different of the rate of rusting
Able to give an idea of relationship
Sample answer:
The intensity of blue colour affect the rate of rusting
SULIT
SULIT
4541/3(PP)
Question 2 (f)
Rubric
Score
3
Able to classify all the metals correctly

Sample answer:
Metal that inhibit rusting of iron
Aluminium / Al
Metal that speed up the rusting of iron

Lead / Pb
Tin / Sn
Silver / Ag
Able to classify any 3 metals correctly

Able to classify any 2 metals correctly or give opposite heading
2
1
Sample answer:
Metal that speed up the rusting of iron
Lead / Pb
Tin / Sn
Silver / Ag
Metal that inhibit rusting of iron

Aluminium / Al
Question 3 (a)
Rubric
Able to the aim of the experiment correctly
Score
2
Sample answer
To construct the Electrochemical series based on the potential difference between two
metals
Able to state the aim of the experiment incorrectly
Sample answer
To construct the Electrochemical series based on the potential difference // Can an
Electrochemical series of metals be constructed based on the potential difference
between two metals?

SULIT
SULIT
4541/3(PP)
Question 3 (b)
Rubric
Able to state the 3 variables correctly
Sample answer
Manipulated variable: Pair of metal
Responding variable: Potential difference // Voltmeter reading // Voltage
Constant variable: Copper(II) sulphate // CuSO4 // Electrolyte // Positive terminal
[reject volume and solution]
Able to state any 2 variables correctly
Able to state any 1 variable correctly
Score
3
2
1
0
Question 3 (c)
Rubric
Able to state the relationship between manipulated variable and responding variable
correctly
Sample answer
The further the distance between two metals in the electrochemical series, the higher
the potential difference / voltage / voltmeter reading
Able to state the relationship between manipulated variable and responding variable
but in the opposite direction
Score
3
Sample answer
The higher the potential difference / voltage / voltmeter reading, the further the
distance between two metals in the electrochemical series // The further the distance
between two metals, the higher the potential difference / voltage / voltmeter reading
Able to state an idea of hypothesis
Sample answer
The distance between two metals affect the potential difference / voltage / voltmeter
reading
SULIT
SULIT
4541/3(PP)
Question 3 (d)
Rubric
Able to give complete list of materials and apparatus
Score
3
Sample answer
Materials: Copper(II) sulphate solution, magnesium metal, zinc metal, iron metal,
copper metal, sandpaper
Apparatus: Beaker, connecting wire, voltmeter
Able to give at least two materials and at least two apparatus
Able to give at least one material and at least one apparatus
2
1
0
Question 3 (e)
Rubric
Score
3
Able to list all the procedure correctly

Sample answer
Clean the metals with sandpaper
Pour / fill a beaker with Copper(II) sulphate solution
Dip / immerse the magnesium strip and copper strip into Copper(II) sulphate
solution
Complete the circuit // Connect the electrolyte to the voltmeter
Record the potential difference / voltage / voltmeter reading
Repeat the experiment using zinc, iron and lead to replace the magnesium
Able to list down Steps 2, 3, 4 and 6
Able to list down Steps 2, 3 and 4
2
1
0

SULIT
SULIT
10
4541/3(PP)
Question 3 (f)
Rubric
Able to tabulate the data with the following aspects
Correct titles
Correct unit
Correct list of pair of metals
Sample answer
Pair of metal
Potential difference / V
Mg and Cu
Zn and Cu
Fe and Cu
Pb and Cu
Able to tabulate the data with the following aspects
Score
3
Negative terminal
Correct titles
Correct unit
Sample answer
Pair of metal
Mg and Cu
Zn and Cu
Fe and Cu
Pb and Cu
Able to exhibit the tabulation of data less accurately
Sample answer
Pair of metal
Mg and Cu

SULIT
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SULIT

JABATAN PELAJARAN NEGERI TERENGGANU

Peraturan pemarkahan ini mengandungi 2 halaman bercetak

[Lihat halaman sebelah]

END OF MARKING SCHEME

4541/1(PP) 2011 Hak Cipta JPNT

JABATAN PELAJARAN NEGERI TERENGGANU

Peraturan pemarkahan ini mengandungi 9 halaman bercetak

[Lihat halaman sebelah]

SECTION A [60 MARKS]

Compound Y / Ammonium Sulphate, (NH4)2SO4

4541/2(PP) 2011 Hak Cipta JPNT

Number of electron occupied with electron and symbol

2 mol HNO3 1 mol Pb(NO3)2 //

Mass of Pb(NO3)2 = 0.025 x 331 // 8.275 g

4541/2(PP) 2011 Hak Cipta JPNT

[Lihat halaman sebelah]

A reaction where oxidation and reduction occur at the same time

SECTION B [20 MARKS]

4541/2(PP) 2011 Hak Cipta JPNT

Formula of reactant and products correct

4541/2(PP) 2011 Hak Cipta JPNT

[Lihat halaman sebelah]

SECTION C [20 MARKS]

4541/2(PP) 2011 Hak Cipta JPNT

The experiment is repeated by using small pieces / powder of

Burette reading / cm3

Experiment II: Using a small pieces / powder of metal / metal

Volume of gas / cm3

Rate of reaction using powder is higher than granules

4541/2(PP) 2011 Hak Cipta JPNT

[Lihat halaman sebelah]

swirled throughout the experiment

Plot the graph of temperature against time or temperature against

Conclusion: The higher the temperature, the higher the rate of

4541/2(PP) 2011 Hak Cipta JPNT

Any members of carboxylic acid and correct ester

Pour 2 cm3 of (methanoic acid) into a boiling tube

END OF MARKING SCHEME

4541/2(PP) 2011 Hak Cipta JPNT

[Lihat halaman sebelah]

JABATAN PELAJARAN NEGERI TERENGGANU

Peraturan pemarkahan ini mengandungi 10 halaman bercetak

[Lihat halaman sebelah]

4541/3(PP) 2011 Hak Cipta JPNT

Able to give the hypothesis accurately

4541/3(PP) 2011 Hak Cipta JPNT

[Lihat halaman sebelah]

Able to draw the graph correctly

Heat of combustion / kJ mol-1

Number of carbon atoms per molecule

Draw the x-axis and y-axis

Able to state 3 observations correctly

4541/3(PP) 2011 Hak Cipta JPNT

4541/3(PP) 2011 Hak Cipta JPNT

[Lihat halaman sebelah]

4541/3(PP) 2011 Hak Cipta JPNT

Able to classify all the metals correctly

Metal that speed up the rusting of iron

Able to classify any 3 metals correctly

Metal that inhibit rusting of iron

4541/3(PP) 2011 Hak Cipta JPNT