a,*
, R
udiger Schellschmidt
Applied Geophysics, Aachen University (RWTH), Lochnerstr. 4-20, D-52056 Aachen, Germany
b
Leibniz Institute for Applied Geosciences (GGA), Stilleweg 2, 30655 Hannover, Germany
Received 10 August 2002; received in revised form 20 November 2002; accepted 4 April 2003
Abstract
Thermal modeling down to great depth, e.g. down to the Mohorovicic discontinuity, requires representative values of thermal
conductivity and thermal capacity at an appropriate depth. Often there is a lack of data, especially concerning temperature and
pressure dependence of thermal conductivity and thermal capacity, due to missing or questionable data from boreholes. Studies of
the temperature and pressure dependence of thermal conductivity and thermal capacity showed that temperature is dominating.
Thus measurements on a set of magmatic, metamorphic and sedimentary rocks sampled from dierent depth levels of the Eastern
Alpine crust were used to obtain an estimate of the temperature dependence of both propertiesat least for the area of investigationand to give a review of the temperature dependence of thermal conductivity (k), thermal capacity (q cp ) and thermal
diusivity (j) for dierent types of rock.
The temperature dependence of thermal conductivity for crystalline (magmatitic and metamorphic) rocks is dierent to that of
sedimentary rocks. Using the approach that the thermal resistivity (1=k) is a linear function of temperature whose slope increases
with k0, the conductivity at a temperature of 0 C, two general equations were determined. The equation for crystalline rocks was
veried in the temperature range of 0500 C and the equation for sedimentary rocks was tested in the temperature range from 0 to
300 C. A general equation for the temperature dependence of k for Eastern Alpine rocks can thus be formulated:
kT
k0
0:99 T a b=k0
with empirical constants and corresponding uncertainties a 0:0030 0:0015 and b 0:0042 0:0006 for crystalline rocks. The
constants for corresponding sedimentary rocks are a 0:0034 0:0006 and b 0:0039 0:0014. k is given in W m1 K1 , T in C.
At ambient conditions thermal diusivity (j) and thermal conductivity (k) for Eastern Alpine crystalline rocks show the relationship:
j 0:45 k:
2003 Elsevier Science Ltd. All rights reserved.
Keywords: Geothermics; Rock physics; Thermal conductivity; Temperature dependence; Thermal capacity; Thermal diusivity
1. Introduction
As a part of the European multidisciplinary TRANSALP campaign to investigate the Eastern Alpine orogenic processes (TRANSALP Working Group, 2002), a
project was set up to (1) obtain a complete data set of
the thermophysical properties of the main rock units of
*
the Eastern Alpine crust and (2) model the steady state
conductive heat transport. Due to the lack of rock
samples from deep boreholes, we took advantage of the
complex tectonics, which yield representative outcrops
of rocks from nearly all depth levels of the Eastern
Alpine crust. According to the resolution of the nite
element grid the main sampling criterion for each rock
unit was an estimated minimum thickness of 1 km in the
cross section along our prole. We performed laboratory measurements of thermal conductivity, specic heat
capacity, density, and porosity on this collection of
newly gained rock samples from 26 dierent substantial
1474-7065/03/$ - see front matter 2003 Elsevier Science Ltd. All rights reserved.
doi:10.1016/S1474-7065(03)00069-X
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2. Measured properties
We collected a total of 118 rock samples for thermal
property measurements in a campaign at 26 locations
along the TRANSALP-prole (Fig. 1) during the summer of 1999. On these specimens bulk density qb , rock
density qr , heat production rate, specic heat capacity cp
and thermal conductivity k of dry and of water saturated rock were determined in the laboratory. Additional information concerning measurement techniques
is summarized in the Appendix A. For further details on
the sampling strategy and on measurements of the heat
production rate refer to the companion paper by Vosteen et al. this issue.
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501
Table 1
Rock types and associated geological units
Location no.
Petrography of sample
Geological unit
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
q qb
/ r
qr
M M
Vr Vb
M Vb Vr
Vr
Vb
Table 2
Bulk density (q) and porosity (/) (sd means standard deviation)
Location no.
q (kg m3 )
sd q (kg m3 )
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
2590
2620
2810
2700
2670
2790
2710
2660
2910
2870
2610
2720
2700
2610
2680
2680
2950
2710
2620
2740
2790
2560
2830
2540
2770
2740
20
70
100
40
30
20
40
10
20
80
40
20
20
40
50
30
50
60
30
60
50
70
40
40
30
20
/ (%)
5.7
3.6
1.4
0.9
2.6
1.0
0.9
2.0
1.1
2.2
2.5
3.8
1.2
4.6
2.1
2.5
1.4
2.0
1.1
1.1
1.9
4.7
1.6
3.1
1.7
1.9
sd / (%)
0.6
2.3
1.0
0.9
1.1
1.0
0.8
0.7
0.6
1.2
1.3
0.3
1.3
1.4
1.4
0.8
1.2
1.3
0.7
0.7
1.7
2.4
0.5
1.5
1.2
0.2
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af mineral
kparlineation
;
knormlination
af shape
kparfoliation
knormfoliation
1.2
1.0
0.8
6
anisotropy factor
(W m-1 K-1)
5
4
3
2
1
parallel lineation
normal lineation
anisotropy factor
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26
location number
(a)
1.6
1.4
1.2
1.0
0.8
anisotropy factor
(W m-1 K-1)
502
6
5
4
3
2
1
parallel foliation
normal foliation
anisotropy factor
(b)
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26
location number
Fig. 2. Scattering of laboratory measurements of the thermal conductivity (vertical bars), mean values (symbols) and anisotropy factors
(squares) of 26 suits of water saturated rocks at ambient conditions (25
C): plane of measurement (a) parallel and normal to lineation; (b)
parallel and normal to bedding, foliation or schistosity of the rock.
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magmatic rocks
metamorphic rocks
1000
-1
cP (J kg K )
2.5
-1
-1
-1
(W m K )
3.5
503
900
800
1.5
magmatic rocks
metamorphic rocks
sedimentary rocks
0.5
700
100
200
(a)
300
400
500
100
(a)
T (C)
200
300
T (C)
4.5
sedimentary rocks
* cP (10 J m K )
2.8
-1
-3
6
-1
-1
(W m K )
3.5
2.5
2.4
magmatic rocks
metamorphic rocks
1.5
sedimentary rocks
2.0
(b)
100
200
300
T (C)
morphic rocks (L6, L10, L11, L12, L14, L16, L17) and
sedimentary rocks (L1, L2, L4, L5, L21). For rocks with
a large thermal conductivity at ambient conditions (krt )
the decrease in thermal conductivity with temperature is
more pronounced than for rocks with a low krt . As
anisotropy of the rock matrix usually decreases with
increasing temperature (Seipold, 2001), it becomes negligible at high temperatures. Therefore it was not considered in our study.
2.4. Temperature dependence of thermal capacity
The thermal capacity is the product of density q and
specic heat capacity cp . Specic heat capacity cp at
constant pressure was determined as a function of
temperature for at least one rock sample from each rock
unit using a dynamic dierential heat ow calorimeter
from ambient temperatures to 300 C, the maximum
temperature range of the device. Fig. 4a shows the mean
values of these measurements for magmatic, metamorphic, and sedimentary rocks (same rock samples as Fig.
3a and b; Table 1). Specic heat capacity measured at
ambient conditions ranges from 740 to 850 J kg 1 K1
(b)
100
200
300
T (C)
Fig. 4. Mean values and ranges of variation of (a) specic heat capacity cp at constant pressure and (b) thermal capacity (q cp ) as a
function of temperature of for magmatic, metamorphic, and sedimentary rocks. The sampling rate of the device is DT 0:05 K. For
better visualization mean values of data points (symbols) as well as
minimum and maximum value (bars) are displayed in an interval of
30 K.
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k
q cp
k0
0:99 T a b=k0
magmatic rocks
1.6
1.7
metamorphic rocks
1.6
1.5
1.2
L14
L11
L10
L9
L6
L16
L17
L22
L19
L23
1.4
(0) / (T)
-6
-1
(10 m s )
sedimentary rocks
0.8
1.3
1.2
1.1
0.4
1
100
(a)
200
300
0.9
T (C)
0.8
0
2.0
50
100
150
(a)
200
250
300
350
0.4
0.5
0.6
0.7
T (C)
3.E-03
1.5
metamorphic rocks
2.E-03
= 0.45 *
sedimentary rocks
= ( 1 / 2.2 ) *
1.0
slope
-6
-1
(10 m s )
magmatic rocks
(1 / * c P ) *
= 0.53 * - 0.2
= ( 1 / 1.9 ) * - 0.2
0.5
1.0
(b)
2.E-03
1.E-03
5.E-04
y = -4.15E-03x + 2.98E-03
R2 = 0.51
0.E+00
1.5
2.0
2.5
3.0
-1
3.5
4.0
4.5
-1
(W m K )
(b)
0.1
0.2
0.3
1/ (0) (W -1 m K)
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The TRANSALP data set (L1, L2, L4, L5, L21) and
supplementary data from measurements of 23 limestones, dolomites and sandstones from the Molasse
Basin (Clauser et al., 2002) were used to determine coecients for a general equation for kT for sedimentary
rocks as well. A rst metamorphosis of sedimentary
rocks occurs at temperatures of around 300350 C
(matching a depth level of 1012 km). Thus we veried
the equation for temperatures from 0 to 300 C. The
equation for kT of sedimentary rocks was determined
in the same way (as described above) and can be formulated as:
q
1
k0 0:54k25 2 1:16k252 0:39k25
6
kT
k0
0:99 T a b=k0
(%)
30
30
20
20
10
10
-10
-10
-20
-20
-30
-30
-40
-40
coefficients Sass
this study
coefficients
et al. (1992)
coefficients this
Sass
et al. (1992)
coefficients
study
-60
-60
-70
0
(%)
(a)
50
100
150
200
250
300
T (C)
350
400
450
500
-70
550
30
30
20
20
10
10
-10
-10
-20
-20
-30
-30
-40
-40
-50
-50
coefficients this study
coefficients Sass et al. (1992)
-60
-70
(b)
-50
-50
20
40
60
-60
-70
80 100 120 140 160 180 200 220 240 260 280 300 320
T (C)
Fig. 7. Deviation of k (measured) and k (calculated) versus temperature for dierent crystalline and sedimentary rocks (ordinate: k (measured) ) k (calculated) in percent). Open diamonds: calculated with the
coecients of Sass et al. (1992); black crosses calculated with coecients of this study (shading): (a) crystalline rocks; (b) sedimentary
rocks.
505
kT
A
B
350 T
705
0:75
350 T
807
0:64
350 T
10
474
1:18
350 T
11
1293
0:73
350 T
12
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(W m K )
14
metamorphic rocks
3.0
2.5
1.5
0
400
500
limestones
5.5
salt rocks
5.0
-1
4.5
-1
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0
100
200
(b)
300
400
500
T (C)
4.5
basic rocks
4.0
acid rocks
ultrabasic rocks
3.5
metamorphic rocks
3.0
2.5
(c)
100
200
300
400
500
T (C)
Fig. 8. Comparison of the equations of this study with dierent general equations for kT . Lines correspond to Eq. (5) and (7) and
symbols to: (a) Zoth and H
anel (1988) dierent crystalline rocks; (b)
Zoth and H
anel (1988) sedimentary rocks, (c) Sass et al. (1992) different crystalline rocks.
16
300
T (C)
6.0
1.5
kT
200
6.5
100
(a)
2.0
kT
ultrabasic rocks
3.5
15
kT
acid rocks
2.0
(W m K )
basic rocks
4.0
for limestone.
Excluding salt and ultrabasic rocks, they summarized
the average temperature dependence of thermal conductivity for dierent rocks as:
770
0:7
kT
B350 T
4.5
13
-1
1073
0:13
350 T
-1
kT
H.-D. Vosteen, R. Schellschmidt / Physics and Chemistry of the Earth 28 (2003) 499509
(W m K )
506
17
shows that above 100 C the curves for rocks with either
very large or very low thermal conductivity at ambient
conditions dier signicantly. The t of Seipold for these
rocks leads to a smaller decrease in thermal conductivity
with temperature than ours. As Seipold (2001) species
the standard deviation of the t of all curves to the
measured data to be 0.3 W m1 K1 , the deviation to
our curve would most certainly be lower if the measured
data were grouped according to the procedure in this
study.
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507
4.5
basic rocks
acid rocks
4.0
ultrabasic rocks
-1 -1
(W m K )
3.5
metamorphic rocks
3.0
2.5
2.0
1.5
0
100
200
(a)
300
500
T (C)
4.5
amphibolites
felsic granulites
granites
mafic granulites
gneisses
peridotites
4.0
-1 -1
(W m K )
400
3.5
3.0
2.5
2.0
1.5
0
(b)
100
200
300
400
Acknowledgements
We are grateful to N. Klitzsch for many helpful
suggestions and comments and to L. Rybach and an
anonymous reviewer for thoughtful reviews. C. Clauser
and H. Trautmann helped us a lot to improve the
manuscript. Special thanks to H.-W. Fesche (Leibniz
Institute for Applied Geosciences, Hannover) who
helped us to cope with fatigue of material of high
temperature components of the divided bar. We also
want to thank K.P. Burgath and M. Mohr (Federal
Institute of Geosciences and Natural Resources (BGR),
Hannover) for carrying out extensive thin section microscopy and X-ray uorescence in order to provide a
proper rock naming. D. Behain helped us by carrying
out density measurements, using facilities advised by
H.-G. Dietrich (Federal Institute of Geosciences and
Natural Resources (BGR), Hannover). The German
Science Foundation supported this project under grant
number CL 141/10-(1, 2) to C. Clauser and B. Lammerer.
500
T (C)
Fig. 9. Comparison of Eq. (5) for crystalline rocks of this study with
kT according to Seipold (1998). Lines are results from Eq. (5),
symbols are results from Seipold (1998) and Seipold (2001): (a) Eq.
(15); (b) Eq. (17).
5. Conclusions
We nd that the thermal conductivity at 0 C characterizes the temperature dependence of thermal conductivity for dierent types of rock. There is no
substantially dierent behavior for dierent rock types.
This is also observed for dierent sedimentary rocks.
Because genesis and mineralogical composition of these
two rock-categories are fundamentally dierent, two
separate sets of coecients are necessary. We veried
the equation of Sass et al. (1992) using the TRANSALP
dataand show that the original coecients of Sass et
al. (1992) can be used to estimate the temperature dependence of thermal conductivity for crystalline rocks
up to 300 C. Above 300 C the coecients of Sass et al.
(1992) yield an error that increases with temperature.
Using the coecients of Sass et al. to determine kT for
sedimentary rocks also yields errors. For temperatures
above 300 C, the coecients of this study for kT of
crystalline rocks yield an improved t to the data set
from the Eastern Alps. The corresponding equation for
kT for dierent types of sedimentary rock also ts the
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