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CHEMISTRY
ONE MARK TEST 1
Time: 45 min
Choose the correct answer:

Marks: 50

1. The hybridization involved in Xe F6 is

a) SP3 d2
b) Sp3 d

c) Sp3 d3

d) Sp3

2. Water exists in liquid state. This is due to

a) Freezing point is zero
b) Hydrogen bond
c) Low boiling point
d) High boiling point
3. Number of spherical nodes in 2s-orbital is
a) 1
b) 2

c) 3

d) 4

4. ________ filament is used in Davisson and Germers experiment.

a) Tungsten
b) Zinc
c) Palladium
d) Platinum
5. Paramagnetism is the property of ________
a) completely vacant electronic sub-shells
b) paired electrons
c) unpaired electrons
d) completely filled electronic sub-shells
6. The molecule which contains intermolecular hydrogen bonding ________
a) salicyclic acid
b) salicyaldehyde
c) water
d) O nitro phenol
7. The particle character of a photon can be explained by
a) diffraction
b) interference
c) photoelectric effect
d) both a and b
8. Which one of the following molecular orbital has the highest energy?
a) 1s
b) *2pz
c) 2pz
d) *2py
9. The number of possible orientation of the orbital when l=2 is
a) one
b) three
c) five

d) seven

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10. The value of plancks constant is

a) 6.626 * 10-33 g2 s
b) 6.626 * 10-33 kgm2s-1
c) 6.626 * 10-33 kgms-1
d) 6.626 * 10-34 gm2s
11. A wave is
a) localized

b) delocalized

12. The bond order of Helium is

a) 1
b) 2

c) stable

d) unstable

c) 3

d) 0

13. Energy of an electron of a hydrogen atom is ________ (in KJmol-1)

a) En = -1313/n
b) En = -1312/n2
c) En = +1312/n2 d) En = +1312/n
14. An oxygen atom is surrounded by ________ bond in the structure of water.
a) 2
b) 3
c) 4
d) 6
15. The strength of hydrogen bond is in the order.
a) H O H = H N H = H F H
b) H F H > H O H > H N H
c) H O H < H N H < H F H
d) H F H = H O H > H N H
16. Which one of the following elements has the lowest ionization energy?
a) Nitrogen
b) Carbon
c) Beryllium
d) Boron
17. The metal having maximum electron affinity is
a) Silver
b) Gold
c) Sodium

d) Calcium

18. The covalent radius of cl-cl bond distance is found to be ________ 0A.
a) 1.98
b) 1.76
c) 0.77
d) 0.99
19. The unit of electro negativity is
a) no unit
b) KJmol-1

c) nm

d) Nm2

20. In pauling scale, the electro negativity of hydrogen is arbitrarily considered

a) 0
b) 1
c) 2.1
d) 5.4
21. Among the following which has higher electron affinity value?
a) Fluorine
b) Chlorine
c) Bromine
2

d) Iodine

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22. Noble gases have ________ ionization energy.

a) zero
b) high
c) low

d) very low

23. The valence shell electron experiences ________ attraction from the nucleus.
a) no change
b) variable
c) less
d) greater
24. Which statement is false regarding ionization energy?
a) Increases with increase in nuclear charge
b) Decreases with increase in atomic size
c) Decreases with decrease in nuclear charge
d) Decreases with decrease in screening effect
25. Which of the following is correct order of the size?
a) Cu < Cu+ <Cu2+
b) Cu > Cu+ > Cu2+
c) Cu+ < Cu < Cu2+
d) Cu+ > Cu > Cu2+
26. The co-ordination number of BN is
a) 4
b) 3

c) 2

d) 5

27. Total number of atoms per unit cell in BCC.

a) 1
b) 2

c) 3

d) 4

28. In Braggs equation represents

a) angle of refraction
b) angel of reflection

c) glancing angle d) angle of incidence

29. Semiconductors are used as

a) rectifiers
b) solar cells

c) transistors

d) all the above

30. Who suggested that crystal can be used as three dimensional diffraction grating for
X rays?
a) W.L. Bragg
b) W.H. Brag
c) Both a and b
d) Laue
31. The impurity added for semi conductor is ________
a) Cu
b) Si
c) Ge

d) As

32. The charge carriers in n-type semi conductors are

a) positive holes
b) protons
c) electrons

d) neutrons

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33. Which one of the following has AB type crystal with c-ordination number 4?
a) ZnS
b) CsCl
c) TiO2
d) BN
34. The size of the anion in Frenkel defect crystal is
a) both are larger in size
b) smaller than cation
c) larger than cation
d) equal in size with cation
35. When an ion leaves its regular site and occupies a position in the space between the
lattice sites. This defect is called as
a) Schottky defect
b) Impurity defect
c) Frenkel defect d) vacancy defect
36. Oxygen atom of ether is
a) very active
b) oxidizing

c) replaceable

37. The ether used in perfumery is

a) diethylether
b) Methyl phenyl ether

c) diphenyl ether d) dimethyl ether

38. The IUPAC name of phenatole is

a) methoxy benzene
b) phenoxy benzene

c) ethoxy ethane

d) inert

d) ethoxy benzene

39. When ethyl iodide is treated with dry silver oxide, it forms
a) ethyl alcohol
b) diethyl ether
c) silver ethoxide d) ethyl methyl ether
40. Intermolecular hydrogen bonds are not present in
a) CH3COOH
b) CH3CH2OH
c) C2H5NH2

d) C2H5-O-C2H5

41. Anisole forms oxonium compounds with

a) AlCl3
b) NH3

c) HI

d) HNO3

42. The general formula of ethers is

a) CnH2n+1O
b) CnH2n+2O

c) CnH2nO

d) CnH2n-1O

43. Anisole gets phenol with

a) HI
b) dil.NaOH

c) dil.H2SO4

d) con.H2SO4

44. Lower ethers act as ________

a) lewis acids
b) anaesthetics

c) antibiotics

d) antiseptic

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45. How many ether isomers are possible for the formule C4H10O?
a. seven
b) three
c) two
46. 2C2H5OH Al2O3 . X.X is
2500C
a) CH3 O CH3
b) CH3 O C3H7
d) CH3 O C2H5

d) one

c) C2H5 O C2H5

47. According to Lewis concept of acids and bases, ethers are

a) neutral
b) amphoteric
c) acidic

d) basic

48. Metamerism is exhibited by

a) ethers
b) nitro compounds

d) mineral acids

c) hydrocarbons

49. Which of the following is ortho and para directing group?

a) COOH
b) CHO
c) NO2
50. Ethers should never be evaporated to dryness because
a) they are volatile
b) they form explosive peroxide
c) they are lighter than water
d) they are inert

d) O CH3