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PERATURAN PEMARKAHAN
PROGRAM PENINGKATAN PRESTASI AKADEMIK
PEPERIKSAAN PERCUBAAN

SPM 2014
KIMIA KERTAS 2 (SET 1)
SECTION A
Question
1

(a
)

(b
)

Description

(i)

The total number of proton and number of neutron in the nucleus of an atom

(ii)

(iii)

Lithium : 2.1
Sodium : 28.1

1
1

(iv
)
(i)

The lithium atom is smaller than the sodium atom

(ii)

Hydrogen gas

(iii)

Colourless solution turns pink

The reaction produces alkaline solution
a: presence of OH- ion
Total

1
1

.5

Question
2

(a
)

Marks

(i)
(ii)

.......4
9

Description

Marks

Magnesium
r: Mg

Has 3 shell occupied with electrons

1
......2

(b
)

Chlorine atom is more electronegative than sodium

Proton number of chlorine is higher than sodium //
the number of proton of chlorine atom higher than sodium
atom

1
1

// total positive charged in nucleus higher than sodium

The attractive force between the nucleus and the electrons

in chlorine atom stronger than sodium atom // nuclei

attraction towards electrons stronger

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......3
(c
)

(i)
(ii)

(d
)

1
Argon
1

Light bulb // in welding process

(i)

3 Cl2
(ii)

......2

2Fe

--------

2 FeCl3
1

Mass of iron (III ) chloride = 0.05 x 161 // 8.05 g

......2
(iii)
1

Total
Question
3

(a) (i)
(ii)
(iii
)
(b
)

Description

10
Marks

R /
Sunburn/ wounds

Apply gel from the leaf to the skin.

1
......3

(i)

X: Analgesics
Y: Psychotherapeutic medicines
Z: Antibiotics

1
1
1

(ii)

Paracetamol/ aspirin

(iii Becomes calmer.

)
(iv) Finish the course of antibiotics.
To kill all the bacteria.

1
1
1 .
7
Total

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10

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Question
4

4541/2

(a)

Description
Zinc oxide

Marks
1
.....1

(b)

(c)

(i)

Zinc carbonate

(ii)

By filtration

(iii)

Yellow when hot,

white when cold

1
1

(i)
(ii)

2Zn(NO3)2

2ZnO + 4NO2 + O2
1. Correct formula of reactants and product
2. Balanced equation
Number of mol of zinc nitrate = 37.8g / 189
= 0.2 mol
0.2 mol zinc nitrate produces 0.4 mol of nitrogen dioxide
So, volume of nitrogen dioxide = 0.4 mol x 24 dm3 = 9.6 dm3

4.

1
1
1
1
1
......5

Total
Question
5

(a)

10

Description
Alkene

Marks
1

........
1

(b)

(c)

CH3 CH CH3

OH
(i)

(ii)

(d)

//

H-CH-CH2-CH3

OH

1
........
1

2C3H6 + 9O2 6 CO2 + 6H2O

-Correct formulae of reactants and products
-Balancing

1
1

Gas is bubbled through lime water.

Lime water turns cloudy

1
1

correct set up apparatus

Label

1
1

........
4

........
2

(e)

Acidified potassium dichromate(VI) solution

1
.......1

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(f)

(i)

C2H5COOC3H7

(ii)

Float on the water

1
..2
Total

Question
6

(a)

(i)
(ii)
(iii
)

(b)

(i)
(ii)

11

Description
Heat change/heat energy released when 1 mole of propanol burn
completely in excess oxygen
C3H7OH + 9/2O2
2C3H7OH + 9O2

3CO2 + 4H2O /
6CO2 + 8H2O

The heat energy given out during combustion by propanol , Q

= mc
= 500 (4.2)(30)
= 63000 J
No. of mole of propanol = 1.8 /60
= 0.03
Heat of combustion of propanol
= m c
n

Marks
1
1
1
......3
1

Jmol-1

= - 6300 kJoule/mol
0.03

= - 2100 kJ/mol
(iii
)

Energy
C3H7OH + 9/2O2
H = - 2100 kJ mol-1
3CO2 + 4H2O

1. Label of energy with two different energy levels

2. Energy level for exothermic reaction with correct position of
reactants and products
(e)

1
1
......4

The number of carbon atom per molecule butanol is bigger/higher than

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(f)

propanol
Butanol produce more carbon dioxide and water molecules than
propanol// more heat energy is released during formation of bonds

Use wind shield / stir water continuously / weigh the spirit lamp
immediately

1
2
1

10
SECTION B
Question
7

(a)

(i)

(ii)

(iii)

Description

Marks

Z is reactive metal towards oxygen gas

Z, Y, X

1
1

4Al + 3O2
2Al2O3
3. Correct formula of reactants and product
4. Balanced equation

1
1

Qualitative aspect :
Aluminium and oxygen gas are the reactants and aluminium oxide is the
product //
Solid aluminium reacts with oxygen gas to form solid aluminium oxide.
Quantitative aspect :
4 mole of aluminium reacts with 3 mole oxygen gas to produce 2 mole of
aluminium oxide.

(iv)

1. No. of mole Al = 2.7 / 27 = 0.10 mol

2. 4 mol of Al produces 2 mol of Al2O3
Therefore No. of mole for Al2O3 = 0.05 mol
3. Mass of Al2O3 = 0.05 mol X 102 g mol = 5.10 g
-1

1
1
1
1
.....9

(b)
Element
Mass(g)
Number of moles
of atoms
Ratio of moles
Simplest ratio of
moles

C
40.90
40.90
12
= 3.41
3.41
3.41
=1
3

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H
4.55
4.55
1
= 4.55
4.55
3.14
= 1.33
4

O
54.55
54.55
16
= 3.41
3.41
3.41
=1
3

1
1
1

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Empirical formula = C3H4O3

1
(C3H4O3)n = 176
n[(3x12) + (4x1) + ( 3x 16)] = 176
88n = 176
n = 176 = 2
88
Molecular Formula : C6H8O6

(c)

(a)

1
.......
7

(i)

Copper (II) oxide

(ii)

Gas is bubbled through lime water

Lime water turns cloudy/chalky
Carbon dioxide is present

1
1
1

Question
8

.......
4

Total

20

Description

Marks

(i)

Temperature

(ii)

s-1

1
.....2

(b)

(i)

Rate of reaction is the amount of product produced per unit time

// amount of reactant used up per unit time

(ii)

Set A:
1/210=0.0048 s-1

Set B:
1/45=0.022 s-1

1
.......
3

(c)

(d)

Presence of catalyst
Concentration of reactant
// size of reactant particles

1
1
........
.2

Factor : catalyst
Example decomposition of hydrogen peroxide with catalyst
mangan(IV) oxide.
In the presence of mangan(IV) oxide, activation energy is lower

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More hydrogen peroxide molecules collide with energy equal to or

more than activation energy
Frequency of collision between particles increases
Frequency of effective collision between hydrogen peroxide
molecules increases
Rate of reaction increases
**Note: hydrogen peroxide molecules mentioned in either one
sentence underlined above

1
1
1
1

Factor : concentration
Example : reaction between sodium thiosulphate solution and
dilute sulphuric acid

(e)

When concentration of sodium thiosulphate solution increases,

number of thiosulphate ions per unit volume increases
Frequency of collision between particles increases
Frequency of effective collision between thiosulphate ions
increases
Rate of reaction increases
**Note: hydrogen peroxide molecules mentioned in either one
sentence underlined above

Temperature:
Pressure:
Catalyst:
N2 + H2 2 NH3

1
1
1

1
1
1
......9

........
4
20

SECTION C
Questio

Description

Marks

n
9 a

1.Electron arrangement of element Z- 2.8.8.1

2.Atom Z has 1 valence electron

3.Element Z is group 1

4.Atom Z has 4 shells occupied by electron

5.Element Z is in period 4

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1. Electron arrangement of atom P is 2.8.1 and not stable

2.To achieve stable octet electron arrangement

3.atom P releases 1 electron to form ion P +

4.Electron arrangement of atom Q is 2.8.7 and not stable

5.To achieve stable octet electron arrangement

6.atom Q gain 1 electron to form ion Q-

1
+

7.Electrostatic force of attraction between ion P and Q

form the ionic bond and compound PQ is formed

8.Electron arrangement of atom R is 2.4 and not stable

9. To achieve stable octet electron arrangement

10.Atom R contribute 4 electrons for sharing

11Atom Q contribute 1 electron for sharing

12Atom R share 1 pair of electrons with atom Q to form

single covalent bond

13Atom R share electrons with 4 atom Q to form molecule

RQ4
Note: pt 12 and 13 can be replaced with diagram

1
1
10
mar
ks
max

Sublimation

Covalent compound

Low melting and boiling point

Force of attraction between molecules is weak
Less energy is needed to overcome the weak force of
attraction

.1
0

1
1
..5

Total

Question
10 (a)

20

Description

Anode: Fe Fe + 2e
Cathode: 2H2O + O2 + 4e 4 OHFe: From 0 to +2
2+

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Marks

1
1
1
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O: From 0 to -2

1
........4

(b)

Iron, magnesium:
Iron nail does not rust/ No Fe2+ ions present
Magnesium is more electropositive than iron.
Magenesium corrodes/ releases electrons.

1
1
1

Iron, copper:
Iron nail rusts/ Fe2+ ions present.
Copper is less electropositive than iron.
Iron corrodes/ releases electrons

1
1
1
........6

(c)

Suitable chemical:
Iron(II) sulphate solution/ Potassium iodide/ Potassium bromide

Functional diagram
Label

1
1

Carbon
electrode
Elektrod L
Chlorine water
Air klorin

Carbon electrode
Elektrod M
Iron(II) sulphate
solution
Larutan ferum(II)
sulfat

Dilute sulphuric acid

Asid sulfurik cair

1. Pour dilute sulphuric acid into a U-tube until half full.

2. Using a dropper, add chlorine water into one arm and iron(II)
sulphate into the other arm.
3. Immerse a carbon electrode into each solution.
4. Using connecting wires, connect the carbon electrodes to a
galvanometer.
Observation:
Galvanometer needle deflects.
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1
1
1

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10

Iron(II) solution changes from pale green to brown.

Inference:
Iron(II) ion is oxidized to iron(III) ion.
Chlorine receives electrons from iron(II) ion and acts as the
oxidizing agent/ chlorine is reduced to chloride ion.

1
1
1
1

Total

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20

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