Geology Research Group, Department of Earth and Environmental Sciences, Ludwig-Maximilians Universitt,
Luisenstrasse 37, 80333 Munich, Germany
2AngloAmerican
3Bayerische
4Section
des Sciences de la Terre, Universit de Genve, Rue des Marachers 13, 1205 Genve, Switzerland
5Institut
Abstract
The Mantoverde iron oxide copper-gold (IOCG) district, northern Chile, is known for its Cu production
from supergene ores. Recently, exploration outlined an additional hypogene ore resource of 440 Mt with 0.56
percent Cu, and 0.12 g/t Au. The hypogene sulfide mineralization occurs mainly as chalcopyrite and pyrite, typically in specularite or magnetite-cemented breccias and associated stockworks. The host rocks underwent variably intense K feldspar alteration, chloritization, sericitization, silicification, and/or carbonatization. A district
scale Na(-Ca) alteration is absent. The IOCG mineralization in the district shows a strong tectonic control by
northwest- to north-northwesttrending brittle structures. Large Cu sulfide-rich veins or Cu sulfide-cemented
breccias are absent. Therefore, head grades of 4 percent Cu are an exception. There is a positive correlation
between Cu and Au grades. Gold is probably contained mostly in chalcopyrite and pyrite. Elevated concentrations of light rare-earth elements (LREE) occur locally but are attributed to redistribution of LREE within the
deposits rather than to derivation from external sources. The Cu-Au ores in the Mantoverde district are low in
U and have relatively low contents in heavy metals that are potentially hazardous to the environment, such as
As (avg 14 ppm), Hg (<5 ppm), or Cd (<0.2 ppm). The sulfur isotope ratios of chalcopyrite from the IOCG deposits lie between 5.6 and 8.9 per mil 34SVCDT. They show systematic variations within the district, which are
interpreted to reflect relative distance to inferred fluid conduits and the level of deposition within the hydrothermal system. Most initial 87Sr/86Sr values of altered volcanic rocks and hydrothermal calcite from the
Mantoverde district are between 0.7031 and 0.7060 and are similar to those of the igneous rocks of the region.
Lead isotope ratios of chalcopyrite are consistent with Pb (and by inference Cu) derived from Early Cretaceous
magmatism. The sulfur, strontium, and lead isotope data of chalcopyrite, calcite gangue, or altered host rocks,
respectively, are compatible with a genetic model that involves cooling of metal and sulfur-bearing magmatichydrothermal fluids that mix with meteoric waters or seawater at relatively shallow crustal levels. An additional
exotic sulfur input is likely, though not required, for the copper mineralization. Apart from the IOCG deposits,
there are a number of smaller magnetite(-apatite) bodies in the district. These are geologically similar to the
Cu-Aubearing magnetite bodies, but are related to splays of the north-southtrending Atacama fault zone and
differ in alteration and texture.
Introduction
THE MANTOVERDE iron oxide Cu-Au (IOCG) district is located about 50 km southeast of the Chaaral harbor and 100
km north of the city of Copiap, northern Chile (Fig. 1). It
has become one of the most important IOCG districts worldwide. The first documented workings date back to the 18th
century. After a period of mining between 1906 and 1938 and
diverse exploration campaigns from the mid 1950s to early
the 1980s by various companies, the Empresa Minera de
Mantos Blancos, S.A. (AngloAmerican) started exploring the
site in 1989 and commenced mining in 1996. Reported initial
reserves were 85 Mt at 0.82 percent Cu of supergene Cu-Au
ores (Vila et al., 1996). Since then, district exploration has
identified additional resources that have expanded the mine
life to 2014 (Fig. 2). Currently, the annual production is 14.5
Corresponding authors: e-mail, ARieger@lmu.de; marschik@lmu.de
*Present address: AngloAmerican Chile, El Soldado Division, Santiago de
Chile, Chile.
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RIEGER ET AL.
70
26
69
a Fault Zone
Atacam
71
25
Chanaral
Copiap
CandelariaPunta del Cobre
28
Argenti
na
27
Pacific
Ocean
Mantoverde
50 km
Pliocene to Recent
Lower Cretaceous
Pre-Cretaceous
FIG. 1. Schematic geologic map of the area around Copiap and Chaaral,
northern Chile. The location of the two major IOCG districts, Mantoverde
and Candelaria-Punta del Cobre, are indicated.
= mine.
District Geology
The Mantoverde IOCG district forms part of the Coastal
Cordillera of northern Chile (Figs. 1, 3). The area represents
a Jurassic-Early Cretaceous continental magmatic arc environment related to the subduction of the Aluk plate under the
South American continent (e.g., Scheuber and Andriessen,
1990). The arc and an associated back-arc basin developed on
a late Paleozoic to Triassic basement (e.g., Mpodozis and
Ramos, 1990). The arc-derived rocks in the Mantoverde district are mainly andesitic volcaniclastic conglomerates, breccias, or flows of probable Late Jurassic age, which are correlated with the Jurassic La Negra Formation (Lara and Godoy,
1998). The volcanic rocks are intruded by Cretaceous granitoids of the Chilean Coastal batholith. Granodiorites and
monzonites of the 125 to 130 Ma Las Tazas complex (Berg
and Breitkreuz, 1983; Brown et al., 1993; Wilson et al., 2000)
are exposed in the west of the Mantoverde district, whereas
granodioritic and quartz dioritic rocks of the 120 to 127 Ma
Sierra Dieciocho, and diorites, monzodiorites, granodiorites,
and tonalites of the 90 to 110 Ma Sierra Merceditas-Remolino
plutonic complexes occur to the east (Zentilli, 1974; Berg and
Breitkreuz, 1983; Dallmeyer et al., 1996; Lara and Godoy,
1998; Fig. 3). To the south, quartz-monzodiorites, pyroxene
granodiorites, and amphibole-biotite-granodiorites of the 130
to135 Ma Cerro Morado complex crop out (Lara and Godoy,
1998). The Cerro Morado complex includes lavas of the La
Negra Formation as hornfelsed roof pendants (Gelcich et al.,
2005). Intrusive stocks and dikes are common at depth in the
mineralized areas. The latter crop out in many places of the
district.
The Mantoverde district represents a structural block that
is limited to the east and west by north-southtrending
branches of the Atacama fault zone (Figs. 2, 3), which is a
subduction-related, arc-parallel, strike-slip fault system that
stretches over 1,000 km along the Chilean coast (e.g.,
Scheuber and Andriessen, 1990). The district is divided into
a northeastern and a southwestern tectonic wedge by an approximately 12-km-long, N 15 to 20 W-trending, 40 to 50
E-dipping major brittle fault, the Mantoverde fault, which
connects the two branches of the Atacama fault zone (Figs.
24). The Mantoverde fault and several minor northwest
faults initially developed as left lateral strike-slip structures
related to a duplex evolution of the Atacama fault zone
(Brown et al., 1993; Sanhueza and Robles, unpub. internal report, 1999). Later extension caused (1) the reactivation of the
Mantoverde fault as a normal scissor fault; (2) the development of associated, curved north-northwest to north-south
normal faults (Sanhueza and Robles, unpub. internal report,
1999); and (3) tilting of the northeastern part of the district
with a northeastern-down sense (Orrego and Zamora, 1991;
Sanhueza and Robles, unpub. internal report, 1999; Fig. 4).
Ore Distribution
The Cu-Au orebodies within the district are controlled
mainly by north-northwest to northwest brittle faults. The
two largest ore zones, Mantoverde Norte and Mantoverde
Sur, occur along the central part of the Mantoverde fault
(Figs. 2, 4), and new exploration drilling has shown they may
be physically continuous with one another. The Laura and
Kuroki orebodies are located along the Mantoverde fault
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Fault
La
sA
nim
as
Celso (Fe)
Va
lley
Celso
(Cu)
Manto Ruso
Punto 62
Kuroki
N 7066
Alluvium (Recent)
rde
tove
Ma n
Legend
Rebosadero
Sur (Fe)
Laura
K feldspar-quartz rock
Argillic alteration
Calcite vein or breccia
N 7064
Mantoverde Norte
Mine in operation
Project
Mine closed
N 7062
500 m
ley
Val
de
Ver
a
L
Mantoverde Sur
Gu
ista
or
sect
ga
an
am
Altav
lle
Va
N 7060
risto
tec
Mon
or
sect
UTM
inate
Coord
)
s (km
Franko
N 7058
San Juan
E 368
E 370
E 372
FIG. 2. Geologic map of the Mantoverde district (note: the Manto Monstruo mine mentioned in the text is located outside the area covered by this map). AFZ = Atacama fault zone.
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7015W Geographic coordinate
7025W
AFZ central bra
nc
7080 DCce
2625S
Geographic coordinate
7070
Jgla
Jln
Kgsm
MVF
130.1+1.9
130.2+0.6
Legend
Jigf
Sedimentary deposit
130.3+1.3
128.7+2.8
153+1.0
Plutonic Complexes
Sierra Merceditas (Kgsm) ca. 90-110 Ma
126.8+1.3
123.7+2.7
126.8+0.5
7060
120+4
115+3
Kglt
125.7+0.6
7050
Kgsd
Kgr
Kgm
25 km
102.3+1.5
2645S
JKgm
7040
360
370
380
FIG. 3. Geologic map of the larger Mantoverde area (modified after Lara and Godoy, 1998). Locations and radiometric
ages of major plutonic complexes (see text for references) and position of the Mantoverde district, as shown in Figure 2, are
indicated. AFZ = Atacama fault zone; MVF = Mantoverde fault.
AF
ch
VF
ran
al b
tr
cen
M
Kuroki (Cu)
Mantoverde
Norte (Cu)
Mantoverde
Sur (Cu)
Franko (Cu)
Z h
AF anc
br
tal
n
ie
Manto Ruso
(Cu)
Celso
(Cu)
or
Celso
(Fe)
Rebosadero
Sur (Fe)
FerrferaSanta Clara
(Fe)
Legend
Mine in operation
Project
Mine closed
1274
1275
1000
900
(masl)
900
800
800
700
700
600
100 m
100 m
c
1100
1000
M
VF
Legend
900
Alluvium (Recent)
Dioritic dike
(masl)
800
600
Andesite, andesitic
breccia (Late Jurassic)
500
400
K feldspar-quartz rock
Argillic alteration
300
Tectonic breccia
(Mantoverde Breccia)
Specularite breccia
(Manto Atacama)
d
M
VF
Specularite stockwork
(Transition Zone)
1000
Magnetite Zone
900
(masl)
Composite sample
700
600
500
100 m
FIG. 5. Representative geologic sections through four major ore zones in the Mantoverde district (from north to south):
a) Manto Ruso; b) the Celso project; c) Mantoverde Norte; and d) Mantoverde Sur. MVF = Mantoverde fault; asl = above
sea level.
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places, have experienced brecciation, forming Cu-Aubearing specularite breccias with pervasively K feldspar-quartz
rich fragments.
In addition to the IOCG ores, the district hosts magnetite
deposits such as Rebosadero Sur and Ferrfera (Santa Clara
of Vila et al., 1996) which have been mined in the past (e.g.,
Espinoza et al., 1999; Fig. 2). These iron orebodies are hosted
in splays of the eastern branch of the Atacama fault zone and
are correlated with similar magnetite(-apatite) deposits of the
Chilean iron belt, which occur along the Atacama fault zone
between La Serena and Taltal. The hydrothermal alteration
associated with the magnetite(-apatite) bodies in the Mantoverde district is manifested mainly as variable proportions
of sericite, chlorite, carbonate, and quartz. Copper sulfides
are absent or scarce, whereas minor pyrite is present.
The Mantoverde Norte deposit
The Mantoverde Norte orebody was the first from which
supergene Cu-Au ores were extracted (total reserves of 101.6
Mt leachable copper ores). It is located in the middle part of
the Mantoverde fault and the ores show a close spatial relationship to the fault (Figs. 2, 5c; see also Vila et al., 1996).
Three main ore-bearing geologic units were distinguished at
the beginning of production: (1) a specularite-cemented, hydrothermal breccia, termed Manto Atacama, in the hanging
wall of the Mantoverde fault, that grades into; (2) a specularite stockwork zone, called the Transition zone, to the east; and
(3) a tectonic breccia (Mantoverde Breccia), which is located
in the footwall of the main fault plane of the Mantoverde fault
(Fig. 5c). The Manto Atacama, Mantoverde Breccia, and
Transition zone are parallel to the Mantoverde fault. To the
east of the Transition zone and to the west of the Mantoverde
Breccia, another hydrothermal breccia, the Breccia Verde, occurs in altered andesitic or granitoid rocks (Fig. 5c; Vila et al.,
1996). Vila et al. (1996) note that an increase in cataclastic deformation, along with an increase in Cu contents, occurs as the
Mantoverde fault is approached. Exploration drilling in 2000
and 2001 penetrated a sulfide-bearing, magnetite-rich zone in
the footwall of the Mantoverde fault, below the current bottom of the open pit. Copper-bearing magnetite near the Mantoverde fault was previously only known to occur in the Mantoverde Sur area (Montecristo and Altavista: Vila et al., 1996;
Zamora and Castillo, 2001).
The Manto Atacama: The Manto Atacama is a roughly tabular shaped hydrothermal breccia with a thickness that averages 80 m but reach up to 200 m. The breccia is composed of
subangular to subrounded fragments, mainly of andesite or
granitoid igneous rocks in a mineralized, calcite-bearing,
coarse-grained specularite matrix. The rock fragments range
from a few millimeters up to about 35 cm in diameter. They
are commonly affected by variable degrees of pervasive K
feldspar alteration with more or less intense chloritization,
sericitization, silicification, and/or carbonatization. Locally,
tourmaline, minor sphene, or scapolite may be present.
Below the oxidation zone (below mining level 750), the specularite-rich matrix contains pyrite-chalcopyrite. Digenite and
bornite have replaced chalcopyrite locally. The rock is cut
mainly by veinlets of K feldspar quartz, tourmaline, or
sericite. Postdating these, calcite veinlets and specularite
veinlets are manifestations of the latest hydrothermal activity.
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The Transition zone: The specularite stockwork of the Transition zone contains supergene copper oxide and hypogene
sulfides (Fig. 5c). The stockwork developed in both La Negra
volcanic rocks and the Breccia Verde. The wall-rock alteration
is essentially the same as in the Manto Atacama. Minor
phases include tourmaline, sphene, and apatite.
The Mantoverde Breccia: The Mantoverde Breccia is a cataclastite rock with a rock flour matrix (Vila et al., 1996; Fig. 5c).
Its thickness is commonly between 20 and 40 m, but can reach
up to 150 m in La Verde Valley, which lies between the Mantoverde Norte and Mantoverde Sur areas. In the Mantoverde
Norte pit, the rock is composed of angular andesite and/or
diorite fragments that commonly are a few mm to about 10 cm
in diameter, and show silicification, chlorite, and minor to moderate K feldspar alteration. The alteration mineralogy in the
matrix includes chlorite, quartz, calcite, K feldspar, and clay
minerals. The rock is cut by specularite, K feldspar quartz,
and calcite veins and veinlets. The calcite veins may contain
fragments of subangular magnetite or chalcopyrite.
The Breccia Verde: The Breccia Verde is composed of silicified volcanic and dioritic fragments in a chlorite-quartzrich
matrix, which also contains calcite, subordinate sericite, and,
locally, zeolite group minerals (chabasite-phillipsite) and
small amounts of tourmaline (Fig. 5c). The rock is cut by low
to moderately dense sets of K feldspar quartz, calcite
siderite, specularite quartz, sericite veinlets. Rock fragments show pervasive K feldspar alteration. Toward the surrounding country rocks, the Breccia Verde grades into a chlorite-quartzrich stockwork. The Breccia Verde has been
considered mostly barren, though it can locally contain significant grades of Cu-Au. Mineralization is normally related to
specularite veinlets.
The Magnetite zone: At Mantoverde Norte, the Magnetite
zone occurs below 680 m above sea level (a.s.l) and is open toward depth (Fig. 5c). It developed between the Breccia Verde,
an intrusion of the 120 to 127 Ma Sierra Dieciocho pluton to
the west, and the Mantoverde Breccia to the east (Fig. 5c). The
rocks of the Magnetite zone are magnetite-chlorite-sericite-K
feldsparcemented breccias, with igneous rock fragments that
are altered mainly by magnetite, K feldspar, and quartz. Magnetite and mushketovite (the pseudomorphous replacement of
an earlier specular hematite by magnetite) are observed. The
rocks are cut by K feldspar quartz, calcite, sericite, and late
specularite-calcite veinlets. Pyrite and chalcopyrite are present
as small patches, disseminations, or in discontinuous veinlets.
The Mantoverde Sur deposit
The Mantoverde Sur sector (including the former Altavista
and Montecristo mines) contains reserves of 46.8 Mt Cu of
leachable copper ores. Overall, the mineralization does not
show such a strong relationship with the Mantoverde fault,
and some rock types differ from those in Mantoverde Norte.
The Magnetite zone is characteristic of Mantoverde Sur (Fig.
5d). Two mineralization styles are distinguished: (1) magnetite stockworks and disseminations; and (2) elongate magnetite-cemented breccia or massive magnetite bodies. The
magnetite-rich rocks may be barren or may contain chalcopyrite (and/or pyrite), mainly as disseminations and discontinuous veinlets. The magnetite zone is overlain or enveloped by
pervasive argillic alteration, respectively, in the Altavista and
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which are affected by strong K feldspar alteration and silicification chloritization. Pyrite, chalcopyrite, and, locally, bornite and digenite occur interstitial to specularite. The specularite-cemented breccia grades into a specularite stockwork
zone (Transition zone), which also contains chalcopyritepyrite (the specularite breccia and stockwork envelope have
been termed Manto Ruso Breccia by Orrego and Zamora,
1991). The host rocks are characterized by strong pervasive
quartz, K feldspar, or sericite alteration. Moderate chlorite alteration may also be present. The rocks at Manto Ruso host
veinlets similar to those observed at Mantoverde.
The Manto Ruso Breccia developed over a preexisting
breccia that is correlated with the Breccia Verde (Breccia
Temprana of Orrego and Zamora, 1991; Fig. 5a, c). The fragments of the Breccia Verde-Breccia Temprana show a strong
quartz-chlorite-sericite alteration, accompanied by variably
intense K feldspar alteration. The matrix is formed of chlorite
and quartz, plus locally abundant K feldspar and/or epidote,
specularite, pyrite, and chalcopyrite.
Magnetite-rich rocks are also present at Manto Ruso. Their
dimensions vary between some decimeters to a few meters.
They may occur within the igneous host rocks, or in the Transition zone, or the Breccia Temprana (Fig. 5a). Magnetite occurs in massive form in veins and veinlets, as replacements, as
fragments, or in the matrix of breccias. Large magnetite veins
(up to several meters wide) are typically surrounded by brecciated magnetite-rich rocks or occasionally by magnetite
stockwork zones. The magnetite may show a mushketovite
texture. Magnetite-rich rocks are cut by specularite-calcite
veinlets. Pyrite chalcopyrite occur as disseminations and
veinlets in magnetite. Allanite is commonly associated with
magnetite and present as allanite-magnetite microveinlets in
the magnetite stockwork zones.
The Celso area, to the east of Manto Ruso (Fig. 5b), was previously mined for iron (Ferrfera Celso). The martitized magnetite bodies seem to be controlled by a northwest-trending
structural corridor and are located mainly at the contact of volcanic rocks and diorites (C. Astudillo, 2007, pers. commun.).
Exploration activities during 2005 and 2006 outlined an orebody with 5.2 Mt of leachable copper ores immediately to the
west of the old iron ore workings. The copper mineralization is
related to a 20 to 60 m thick, N 40 to 55 W-trending and 55
to 70 W-dipping, specularite-cemented hydrothermal breccia
body, the Celso Breccia. The breccia is enclosed by a specularite stockwork hosted predominantly in diorites. The oxidation
level reaches down to 100 to 150 m depth (820920 m a.s.l.).
Beneath these levels, hypogene sulfides occur over a vertical
distance of at least 100 m (Fig. 5b). The rock units in the Celso
area are similar to those at Manto Ruso. The Celso Breccia is
lithologically similar to the Manto Atacama at Mantoverde or
the Manto Ruso Breccia. It is best developed at depth, where
it is composed of fragments of silicified diorite and minor andesite in a specularite matrix. The breccia contains chalcopyrite-pyrite disseminated in the matrix and is cut by chalcopyrite-pyritebearing veinlets (Astudillo et al., unpub. internal
report, 2006). The surrounding Cu-sulfidebearing specularite
stockwork (Transition zone) is hosted in pervasive silicified and
chloritized rocks. Rocks similar to the Breccia Verde are also
recognized in the Celso area. They consist of silicified dioritic
and andesitic fragments in a chlorite-quartz sericiterich
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RIEGER ET AL.
Sulfide Stage
Late Stage
at shallow levels
hm I
hm II
mt I
mt II
py II
py I
at deep levels
py III
?
cp I
cp II
?
P
V
V
V
V
V
?
V+D
Loc
V+D
D
V
V+P
Time
FIG. 6. Paragenetic sequence of the iron oxide Cu-Au mineralization in the Mantoverde district. The bulk of the specularite at shallow levels is hematite I. At depth, hematite I gives way to, and was replaced by, magnetite I (mushketovitization)
as the hydrothermal system fully developed. Abbreviations: cp = chalcopyrite, D = disseminations, hm = hematite, Loc =
local, mt = magnetite, P = pervasive alteration, py = pyrite, V = veinlets.
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chl-mt II
mt II
scp
cte
ser
mushketovite
py I
100
250
100
all-mt II
cp I
Kfs
bn
Kfs-qtz
chl
Kfs-qtz
cp I
qtz
all-mt II
100
py II
250
100
cte
cp I
dg
ser
hm II
cp I
zeo
py II
100
mt
100
cte
250
FIG. 7. Photomicrographs of thin sections (ts) and polished slabs (ps) documenting paragenetic relationships in the Mantoverde district. a) Magnetite (mt I) pseudomorphously replacing bladed hematite (hm I; ps, parallel nicols). b) Scapolite
crystals cut by a chlorite-magnetite (mt II) veinlet. Calcite occurs as infill between scapolite crystals and in microveinlets cutting the scapolite (ts, cross nicols). c) Sericite and pyrite (py I) formation are followed by a second generation magnetite
(mt II; ps, parallel nicols). d) Allanite and second generation magnetite (mt II) cut by a chlorite veinlet (ts; parallel nicols).
e) Pervasive K feldspar alteration cut by quartz veinlets, which in turn are cut by K feldsparquartz veinlets. Chalcopyrite
(cp I) represents a late infill (ts, parallel nicols). f) Chalcopyrite (cp I) marginally replaced by bornite (ps, parallel nicols). g)
Chalcopyrite (cp I) marginally converted to digenite (ps, parallel nicols). h) Pyrite (py II) veinlets cut magnetite (locally
weakly martitized). Pyrite in turn is cut by thin chalcopyrite (cp I) veinlets. Late hematite (hm II) cuts the aforementioned
minerals (ps; parallel nicols). i) Pervasive zeolite (chabasite-phillipsite) alteration with interstitial calcite that is cut by a late
thin sericite veinlet (ts; cross nicols). Mineral abbreviations: all = allanite, bn = bornite, cte = calcite, chl = chlorite, cp = chalcopyrite, dg = digenite, hm = hematite, Kfs = K feldspar, mt = magnetite, py = pyrite, qtz = quartz, scp = scapolite, ser =
sericite, zeo = zeolite.
Dieciocho plutonic complex (120 4 to 126.8 1.3 Ma; Zentilli, 1974; Berg and Breitkreuz, 1983; Berg and Baumann,
1985; Dallmeyer et al., 1996). This is in permissive agreement
with a hydrothermal system that is coeval with or younger than
the constraints for the magmatic rocks. In the mined areas, intrusive rocks assigned to the Sierra Dieciocho complex are
mineralized, indicating that they were already emplaced when
mineralization occurred. A 116 to 121 Ma mineralization age
is compatible with magnetic properties of the orebodies in the
district, which show normal (Manto Ruso) or inverse polarities
(Mantoverde Norte; Tassara et al., 2000). The mineralization
in the Mantoverde district, therefore, may have occurred coeval with a change from an interval with inverse into normal
polarity at about 120 Ma (Vila et al., 1996; Tassara et al., 2000),
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RIEGER ET AL.
or alternatively with a change to a short interval of reverse polarity between 115 to 116 Ma (Chronozone M-1r; high-resolution Mesozoic timescale of Gradstein et al., 1995).
Analytical Methods
Whole-rock and mineral geochemistry
Analysis of 10-m composite samples of drill cores from different units from Mantoverde Norte-Sur (Magnetite zone,
Breccia Verde, and Manto Atacama), Manto Ruso, (Transition zone, Breccia Verde-Breccia Temprana, and Manto Ruso
Breccia) and Celso (Transition zone, Breccia Verde-Breccia
Temprana, Celso Breccia, and magnetite-rich rocks) has been
carried out. The samples represent the hypogene ores, although they locally may contain minor supergene overprint.
Concentrations of total Cu, leachable Cu (in H2SO4 and CN
solutions), residual Cu (AAS), and S (LECO) were determined on 121 samples. From these, 96 were analyzed for
their Fe content and 27 were selected for multi-element
analysis (ICP). Additionally, 25 hand specimens of altered
rocks from drill cores from the Mantoverde district were collected for whole-rock major, trace, and rare-earth element
(REE) analysis by the lithium metaborate-tetraborate fusion
ICP-MS method. Although these samples cannot be used to
determine potential REE grades, they facilitate interpretations regarding REE mobility and distribution.
Hydrothermal calcite and sulfides targeted for isotope analysis were handpicked under a binocular microscope. The trace
Sample no.
Location
Drill core or
Altitude
MV07156
MV07178
MV07209
MV07214
MV07221
MV07232
MV07277
MV07286
MV07184
MV99900
MV07421
MV07425
MV07454
MV07460
MV07483
MV07520
MV08001
MV08002
MV08004
MV08009
MV08011
MV08015
MV07323
MV07337
MV07356
MV07356
MV07368
MV07409
MV08005
MV09001
SJ09002
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Manto Ruso
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
San Juan
DDH01GT04
DDH01GT04
DDH01GT07
DDH01GT07
DDH01GT07
DDH01GT07
DDH00MR37
DDH00MR37
902 m a.s.l. (pit)
930 m a.s.l. (pit)
DDH01DS10
DDH01DS10
DDH01DS10
DDH01DS10
DDH00DS05
DDH00MV03
DDH07DS21
DDH07DS21
DDH07DS21
DDH07DS09
DDH07DS09
DDH07DS12
DDH00DS04
DDH00DS04
DDH01DS21
DDH01DS21
DDH01DS21
DDH01DS12
DDH07DS06
RCH09MC14
Stockpile
Depth
(m)
196
330
151
196
230
333
284
381
109
165
546
585
282
667
543
555
620
269
275
450
202
461
231
231
414
380
335
348
Alteration/rock type
Mineral
Specularite breccia
Specularite breccia
Specularite breccia
Specularite breccia
Magnetite-rich rocks
Qtz-chl
Specularite breccia
Qtz-chl
Specularite breccia
Specularite breccia
Specularite breccia
Specularite breccia
Magnetite-rich rocks
Magnetite-rich rocks
Specularite breccia
Magnetite-rich rocks
Magnetite-rich rocks (cte vein)
Magnetite-rich rocks
Qtz-chl
Specularite breccia
Specularite breccia
Magnetite-rich rocks (cte vein)
Calcite vein (Mantoverde Fault)
Magnetite-rich rocks
Specularite breccia
Specularite breccia
Magnetite-rich rocks
Kfs-qtz
Magnetite-rich rocks
Magnetite-rich rocks
Magnetite-rich rocks
Pyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Pyrite
Pyrite
Chalcopyrite
Chalcopyrite
Pyrite
Chalcopyrite
Pyrite
Pyrite
Pyrite
Chalcopyrite
Chalcopyrite
Pyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Pyrite
Chalcopyrite
Pyrite
Chalcopyrite
Chalcopyrite
Chalcopyrite
Abbreviations: a.s.l.= above sea level, chl = chlorite, cte = calcite, Kfs = K feldspar, qtz = quartz
0361-0128/98/000/000-00 $6.00
1280
34S ()
9.3
8.9
7.7
7.5
6.3
3.2
7.2
3.8
9.4
7.2
1.4
1.1
1.9
1.5
1.4
0.2
1.1
0.8
2.6
2.6
3.0
3.0
2.5
5.0
5.8
2.5
1.6
5.6
3.6
4.7
1281
mode using faraday cups. Results were corrected for instrumental mass fractionation to 88Sr/86Sr = 8.375209. Isobaric interference of 87Rb was controlled by monitoring 85Rb, but no
significant corrections were necessary. Total procedural
blanks were less than 100 pg, which is negligible concerning
sample Sr contents. The mean 88Sr/87Sr for NIST 987 was
0.710248 with a standard deviation of 0.000023 (2008: n = 60,
nominal value NIST 987= 0.710240). No corrections were
made. External reproducibility of 88Sr/87Sr in natural samples
usually is 0.000040 or better.
The lead isotope compositions of 12 samples of chalcopyrite and 7 samples of pyrite were analyzed in static mode
using Finnigan MAT-262 thermal ionization multicollector
mass spectrometer at the Department of Mineralogy of the
University of Geneva, Switzerland (Table 1). The sulfide samples represent different units within the Mantoverde Norte (n
= 11), Mantoverde Sur (n = 3), and Manto Ruso (n = 4) deposits. Sample preparation was carried out following the procedures described in Chiaradia and Fontbot (2003) and
Marschik et al. (2003b). The lead isotope ratios have been
corrected for mass fractionation by a 0.10 percent factor per
atomic mass unit, calculated from replicate analyses of the
SRM981 international standard. An external reproducibility
of lead isotope ratios of 0.07 percent for 206Pb/204Pb, 0.11 percent for 207Pb/204Pb, and 0.15 percent for 208Pb/204Pb has been
demonstrated at the 2 confidence level through multiple
analyses of SRM981 standard.
Error
(at 1)
207Pb/204Pb
Error
(at 1)
208Pb/204Pb
Error
(at 1)
Co
(ppm)
Ni
(ppm)
Zn
(ppm)
As
(ppm)
18.511
20.329
22.566
0.002
0.001
0.002
15.561
15.692
15.792
0.002
0.001
0.001
38.269
39.114
42.119
0.004
0.003
0.004
1.2
244.0
3200.0
2.4
49.2
151.0
5.9
5.5
9.0
1.3
23.0
54.1
19.227
18.816
0.001
0.007
15.609
15.634
0.001
0.006
39.160
38.549
0.002
0.015
70.3
223.0
137.0
68.6
8.9
4.0
18.598
19.189
19.500
18.713
18.502
0.001
0.005
0.001
0.000
0.000
15.595
15.642
15.633
15.565
15.575
0.001
0.004
0.001
0.000
0.000
38.706
40.131
38.429
38.529
38.275
0.003
0.010
0.003
0.001
0.001
2810.0
> 5000.0
2950.0
6.0
12.7
157.0
494.0
428.0
2.6
3.2
18.533
19.540
18.637
18.514
18.528
18.565
18.505
18.882
0.001
0.000
0.000
0.001
0.000
0.000
0.000
0.001
15.555
15.604
15.568
15.568
15.600
15.559
15.572
15.590
0.001
0.000
0.000
0.001
0.000
0.000
0.000
0.001
38.260
38.306
38.255
38.230
38.367
38.245
38.289
39.154
0.003
0.001
0.001
0.002
0.001
0.000
0.000
0.001
62.6
54.5
493.0
724.0
888.0
538.0
4.2
109.0
19.200
0.002
15.607
0.002
38.611
0.004
2700.0
0361-0128/98/000/000-00 $6.00
1281
Au
(ppb)
Pb
(ppm)
Th
(ppm)
U
(ppm)
26.5
< 0.5
< 0.5
1.4
2.2
2.5
< 0.1
< 0.1
4.5
< 0.1
< 0.1
0.8
6.7
23.8
5560.0
< 0.5
5.7
0.7
< 0.1
< 0.1
< 0.1
< 0.1
17.0
6.0
7.5
17.2
51.3
58.7
220.0
26.8
5.0
3.5
27.9
1.2
< 0.5
2720.0
2200.0
2.9
1.3
2.3
19.3
44.8
0.5
< 0.1
0.1
< 0.1
< 0.1
< 0.1
< 0.1
0.3
< 0.1
0.1
10.8
14.3
60.9
88.2
85.9
60.3
3.4
20.7
17.8
9.9
17.6
43.9
69.8
15.7
20.5
28.5
8.3
5.2
18.7
18.5
27.1
25.1
1.7
4.6
1040.0
208.0
675.0
33.5
3840.0
1410.0
3030.0
> 10000.0
4.2
7.7
14.2
22.1
51.0
28.6
25.2
4.4
< 0.1
< 0.1
< 0.1
< 0.1
0.1
0.1
< 0.1
< 0.1
< 0.1
< 0.1
< 0.1
< 0.1
0.1
0.1
< 0.1
< 0.1
618.0
3.7
43.7
112.0
1.1
< 0.1
< 0.1
1282
RIEGER ET AL.
Analytical Results
Composite sample geochemistry
The range of total Cu (soluble and residual) and residual
Cu values in composite samples are similar in all three deposits, with highest values in samples from Mantoverde Sur.
Total Cu and Au concentrations show a good positive correlation in the district (Fig. 8). The distribution of Cutotal and
Au in the various defined units is shown in Figure 8. Zinc
concentrations are generally low (33254 ppm) and present
at a similar range of values in the Mantoverde and Manto
Ruso deposits. Silver, Pb, and Mo are typically below detection limit, although some measureable Mo concentrations
(<32 ppm) occur locally in the Magnetite zone of Mantoverde. Cobalt concentrations in composite samples range
from 11 to 803 ppm. The Co concentrations in the samples
from Manto Ruso are near or below the crustal average of
29 ppm (crustal values of Taylor and McLennan, 1985),
whereas at Mantoverde, Co values are higher by almost one
order of magnitude. Mercury and Cd values are commonly
low (<5 ppm or <0.2 ppm, respectively). Titanium contents
are generally below detection limit (i.e., <0.01%), whereas V
0.7
0.7
Mantoverde Sur
Manto Ruso
Celso
Magnetite Zone
Breccia Verde
Manto Atacama
0.6
0.5
0.5
0.4
0.4
Au ppm
Au ppm
0.6
0.3
0.3
0.2
0.2
0.1
0.1
0.0
0.0
0.1
1.0
10.0
0.1
1.0
0.7
0.7
0.6
Celso Breccia
Transition Zone
Breccia Verde
Magnetite Zone
0.6
0.5
0.5
Au ppm
Au ppm
10.0
Cutotal wt.%
Cutotal wt.%
0.4
0.3
0.4
0.3
0.2
0.2
0.1
0.1
0.0
0.0
0.1
1.0
10.0
0.1
1.0
Cutotal wt.%
Cutotal wt.%
FIG. 8. Representative Cutotal and Au contents of composite samples from drill cores in the Mantoverde district. Overall,
there is a good positive correlation between Cu and Au.
0361-0128/98/000/000-00 $6.00
1282
10.0
1283
per mil. The single chalcopyrite sample from the magnetiterich ore of the San Juan mine has a 34S value of 4.7 per mil.
The sulfur isotope signature of pyrite shows a similar though
less pronounced spatial variation, with 34S from 3.2 to 9.4
per mil at Manto Ruso and 0.2 to 1.9 per mil at Mantoverde
Norte. Two pyrites from the Mantoverde Sur orebody have
34S values of 1.6 and 5.8 per mil.
Results of radiogenic isotope analyses
Rubidium and Sr contents in the altered host rocks range
from 17 to 204 ppm, and from 12 to 198 ppm, respectively
(Table 2). The Rb/Sr ratio in all but two samples (MV07450
and MV07658) is >1. Calcite has Rb contents of 0.2 to 0.5
ppm and Sr contents of 62 to 103 ppm (Table 2). The initial
87Sr/86Sr (87Sr/86Sr ) is based on an average alteration age of
i
119 Ma (Vila et al., 1996). The altered rocks show a relatively
wide spread in 87Sr/86Sri values from 0.703054 to 0.710053. In
contrast, the 87Sr/86Sri values of hydrothermal calcite are fairly
homogeneous, ranging from 0.703628 to 0.703708 (Table 2;
Fig. 14). Strontium contents tend to correlate negatively with
measured 87Sr/86Sr, whereas Sr contents and 87Sr/86Sri do not
show any correlation.
Lead isotope ratios of chalcopyrite have 206Pb/204Pb between 18.502 and 19.540, 207Pb/204Pb between 15.555 and
15.609, and 208Pb/204Pb between 38.230 and 39.160 (Table 1).
Those from pyrite show a wider range with 206Pb/204Pb from
18.598 to 22.566, 207Pb/204Pb from 15.595 to 15.792, and
208Pb/204Pb from 38.429 to 42.119. Most of the Pb isotope ratios of chalcopyrite plot close to the Orogene Pb isotope evolution line of Zartman and Doe (1981; Fig. 15). They show
signatures that mainly plot into the compositional field defined by arc igneous rocks in a 206Pb/204Pb versus 207Pb/204Pb
diagram (Zartman and Doe, 1981). The sample provenance,
Pb isotope analytical data, and Pb, U, and Th concentrations
in chalcopyrite and pyrite are given in Table 1.
Discussion
District alteration
The various rock, alteration, and ore types are similar among
the IOCG deposits in the Mantoverde district, as are the
mineral associations in veinlets and their relative temporal occurrence. Isocon diagrams suggest substantial mobility of elements (Fig. 10). Most notable is the widespread and variably
intense potassium metasomatism, which is expressed by
abundant K feldspar (Fig. 10). Hydrothermal biotite occurs
only in minor quantities. However, a significant early biotite
alteration may have taken place, but could have been masked
by later chloritization. Unlike other IOCG districts (e.g., Candelaria-Punta del Cobre: Marschik and Fontbot, 2001;
Ernest Henry-Cloncurry: Mark and Forster, 2000; Norbotten
region in Sweden: Edfelt et al., 2005), at Mantoverde there is
no evidence of a district- or regional-scale sodic or sodic-calcic alteration event that is commonly manifested as variable
proportions of secondary albite, marialitic scapolite, epidote, calcic-amphibole, and/or diopside. Scapolite alteration
is locally present in the Mantoverde Norte-Sur deposits,
whereas calcic-amphibole is essentially absent within the district at the present levels of exposure. In general, however,
the alteration and mineralization styles and processes appear
1283
1284
RIEGER ET AL.
10000
Ore characteristics
The Cu and Au grade distribution in the orebodies Mantoverde Norte-Sur and Manto Ruso is fairly homogeneous
1000
100
10
10
0.1
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
La
Lu
100
10
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
10000
MV96-5 (WR)
MV96-5-1 (F)
MV96-5-2 (matrix)
MV96-4 (WR)
MV07524 (F)
1000
Ce
Abundance/chondrite
Abundance/chondrite
100
0.1
1000
100
10
0.1
0.1
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
La
Lu
10000
10000
MV07464 (WR)
MV07540 (WR)
1000
Abundance/chondrite
Abundance/chondrite
MV96-5 (WR)
MV07485 (WR)
MV07427 (F)
MV07514 (F)
MV07526 (F)
1000
10000
10000
MV96-1 (WR)
MV07450 (WR)
Abundance/chondrite
Abundance/chondrite
100
10
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Mantoverde Sur
MV07335 (WR)
MV07337 (WR)
MV07356 (F)
MV07368 (F)
MV07577 (WR)
1000
100
10
0.1
0.1
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
FIG. 9. Chondrite-normalized REE patterns of altered rocks from various ore zones and units in the Mantoverde district
showing local enrichment of LREE (chondrite of Nakamura, 1974). a) Results of whole-rock (WR) analyses of samples from
the tectonic breccia (Mantoverde Breccia) at Mantoverde Norte. b) Cu-Aubearing specularite breccia (WR) and its rock
fragments (F) at Mantoverde Norte (Manto Atacama). c) Altered rocks from the Transition zone of Mantoverde Norte. d)
Sample MV96-5 of the Manto Atacama breccia of Mantoverde Norte. The patterns of the whole-rock fraction (MV96-5 WR),
the volcanic rock breccia clasts (MV96-5-1 F), the specularite matrix (MV96-5-2 matrix) are shown. e) Altered volcanic rocks
from the Mantoverde Norte sector showing near original to slightly elevated LREE. f) Samples of altered whole-rock and
breccia fragments from the Mantoverde Sur sector suggesting locally elevated LREE or relative depletion of LREE compared to HREE in other areas. Relatively flat REE patterns occur in rocks from g) Manto Ruso; h) altered plutonic rocks;
and i) volcanic rocks outside of the mineralized zones. j) REE pattern of reference basaltic andesite (Ewart, 1982), Jurassic
volcanic rocks of Cerro Blanco, Cerro Plomo, Cerro del Difunto, Sierra Minillas, Sierra Fraga, and Quebrada la Tranquita
(Lucassen et al., 2006), andesite (GERM database), and Early Cretaceous plutons from the Candelaria-Punta del Cobre district. These rock types are similar to those in the Mantoverde district (Marschik et al., 2003a).
0361-0128/98/000/000-00 $6.00
1284
Tm
Yb
Lu
1285
10000
MV07176 (WR)
MV07206 (WR)
MV07135 (F)
1000
100
10
10
0.1
0.1
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
La
Lu
Ce
Pr
MV07076 (WR)
MV07658 (WR)
MV07058 (WR)
1000
10000
Abundance/chondrite
Abundance/chondrite
MV07498 (WR)
MV07641 (WR)
MV07646 (WR)
100
10000
1000
Abundance/chondrite
Abundance/chondrite
10000
100
10
Nd
Sm
Eu
Gd
Tb
Ho
Er
Tm
Yb
Lu
Basaltic andesite
Jurassic volcanic rock
Andesite
Copiap Batholith, diorite
Copiap Batholith, hornblende-diorite
Copiap Batholith, tonalite
1000
Dy
100
10
0.1
0.1
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
FIG. 9. (Cont.)
1285
1286
RIEGER ET AL.
120
50
gain
loss
25 %
Gd
Al2O3
Fe2O3
Ta Zr Hf
SiO2
Cs Nb
TiO2 MnO
60
Tb
40
Tm
Dy
20
Er Yb Lu
0
0
10
Zn
30
40
60
70
40
K2O
50 %
80
LOI Rb
20
Sr
90
20
0
30
500
%
400
%
0%
10
15
Ni
%
75
Ta
0%
50
25
100
50
25
gain
loss
25 %
%
0
Tb
Zr Hf
Al2O3
Nb
Zn Sc
Fe2O3
MgO
20
30
40
50 %
Cr
Sm
Gd
Nd
Eu
CaO
Ni
50
60
70
75 %
V
80
90
10
15
0%
75
Ni
50
25
100
gain
s
los
K2O
80
gain
loss
80
25 %
60
Hf
CiA
Ta
Ba
CiA
CiO
Mantoverde Norte: Specularite breccia - MV07485
120
TiO2
MnO
P2O5
Ba
Cs
10
CiO
120
Ta
Dy
La
Ce
Pr
SiO
Na2O
Na2O
50
75
10
80
20
0%
Lu
60
75 %
P2O5
Sr CaO
Ho
0%
Ho
80
15
100
20
0
25 %
Sc
MgO
Eu
Tm
Yb
0%
Sm
100
LOI
20
Er
30
Ba
30
75
50
0%
40
0%
140
Nd
120
CiA
Rb
140
100
400
500
%
0
K2O
160
20
30
Pr
160
%
50
CiA
La Ce
40
0
180
50
0%
200
Zr
Zr
40
MnO
Rb
P2O5
20
LOI
Sr
Cs
Al2O3SiO2
Lu
MgO
Ho TmYb
Pr Sm Gd
Fe2O3
TiO2
Dy Er
La Ce Nd Eu Tb
Na2O CaO
50 %
Zn
Nb
Sc V
40
75 %
20
LOI Rb
Sr
0
0
10
20
30
40
50
60
70
80
25 %
K2O
60
90
Yb
Ba
Er
Tb Ho Tm Lu
Fe2O3
SiO2
Dy
Na2O
Gd
Al2O3 Pr Sm
MnO
Nb
Eu
La Ce Nd
TiO2
MgO
P2O5
CaO
Cs
10
20
30
40
50
60
Hf
Y
50 %
Cr
Zn Sc V
70
75 %
80
90
CiO
CiO
FIG. 10. Isocon analysis of selected rock samples from Mantoverde Norte and Manto Ruso (Grant, 2005). The composition of the least altered reference rock is an average of whole-rock data of Jurassic basaltic andesite and andesite (5255 wt
% SiO2) from Cerro del Difunto, Sierra Fraga, and Quebrada la Tranquita of Lucassen et al. (2006). Note that the scales of
the diagrams are different to accommodate all data. The oxides or elements used to establish the chords are: a) SiO2, Fe2O3,
and Dy; b) Tb; c) SiO2 and Al2O3; d) SiO2, and Ta. Dashed lines indicate element or element oxide percentage of enrichment
or depletion relative to the reference rocks. Abbreviations: CiA = scaled element concentration of the altered rock; CiO =
scaled element concentration of the reference rock.
The isocon diagrams (Fig. 10) suggest that REE were variably
mobilized and deposited by the hydrothermal fluids. There is
no compelling evidence for a significant LREE introduction
S vs Au per sector
100
1.0
10
Concentration in wt. %
Mantoverde Norte
Mantoverde Sur
Manto Ruso
Au ppm
chalcopyrite
0.1
0.01
0.8
0.6
0.4
pyrite
0.2
0.001
0.0001
0
10
12
14
16
18
0.0
20
Ti
S wt.%
FIG. 11. Gold content of pyrite and chalcopyrite from the Mantoverde
IOCG ores.
0361-0128/98/000/000-00 $6.00
Ti
Al
Al
Si
Si
FIG. 12. Box plots of Ti, V, Al, and Si concentrations in magnetite from
IOCG and magnetite(-apatite) bodies in the Mantoverde district.
1286
1287
: chalcopyrite
: pyrite
MVF
h
ntal branc
AFZ orie
Manto Ruso
Mantoverde
Norte
Mantoverde
Sur
San Juan
-6
-4
-2
10
34SCDT ()
FIG. 13. Location map of the Mantoverde district showing the main ore zones and distribution of sulfur isotope signatures of chalcopyrite and pyrite. A general trend in enrichment of 34S in chalcopyrite from south to north is recognized
(see arrow).
the deposit are unlikely. The identification of the LREEbearing units and the host minerals to these elements is still
in progress. Parts of the LREE are hosted by allanite and apatite. Both minerals, however, are present only in minor
quantities. In general, the Cu-Au ores in the Mantoverde district are low in U and have relatively low contents in heavy
metals that are potentially hazardous to the environment,
such as As (avg 14 ppm), Hg (<5 ppm), or Cd (<2 ppm).
The Cu and Au grades in supergene and hypogene zones
are similar, suggesting insitu supergene alteration. An enrichment blanket as, for instance, in the El Salvador porphyry
copper deposit (Gustafson and Hunt, 1975) has not developed. The relative immobility of the supergene Cu seems unfavorable for development of related exotica-type deposits in
the vicinity (e.g., Mote et al., 2001).
Iron oxide distribution
A zonation of iron oxide species exists within the individual
IOCG deposits in the Mantoverde district. Specularite is characteristic of the upper levels of the deposits, whereas magnetite is present at depth. This zonation, which is common in
IOCG deposits, is obscured at district-scale by postore tilting
Mantoverde district
0.704
0.705
0.706
0.707
0.708
0.709
0.710
initial 87Sr/86Sr
FIG. 14. Strontium isotope initial ratios of altered rocks (sample labels refer to Fig. 9) and calcite from the Mantoverde
district compared to Sr isotope signatures of relevant Sr reservoirs. Early Cretaceous seawater (Jones et al., 1994); Early Cretaceous granitoids (Chilean Coastal Batholith near Copiap, Marschik et al., 2003a; Las Tazas complex, Berg and Baumann,
1985); Early Cretaceous volcanic rocks (Morata and Aguirre, 2003); Jurassic igneous rocks (Lucassen et al., 2006). The strontium isotope signature of Early Cretaceous granitoids corresponds to the inferred composition of magmatic hydrothermal
fluids.
0361-0128/98/000/000-00 $6.00
1287
1288
0.703688
0.000028
0.703707
0.004
0.4
365
Mantoverde Sur
MV07366
DDH01DS21
194
Mantoverde Sur
MV07322
DDH00DS04
452
Mantoverde Norte
MV07490
DDH00DS05
226
114
380
461
0361-0128/98/000/000-00 $6.00
Abbreviations: a.s.l. = above sea level, chl = chlorite, cte = calcite, hm = hematite, Kfs = K feldspar, qtz = quartz, ser = sericite
119
Calcite
101.0
0.703708
0.000033
0.703735
0.005
0.5
119
Calcite
91.2
0.703681
0.000017
0.703700
0.004
0.4
119
Calcite
103.0
0.705629
0.705568
0.704323
0.705812
0.703054
0.704527
0.703886
0.704894
0.704771
0.706081
0.704260
0.704014
0.710053
0.703628
0.000016
0.000018
0.000053
0.000084
0.000059
0.000036
0.000076
0.000043
0.000032
0.000019
0.000036
0.000034
0.000390
0.000022
0.726872
0.722766
0.708080
0.723974
0.718668
0.709703
0.712725
0.714687
0.709937
0.718777
0.710165
0.705185
0.733354
0.703644
4.333
3.509
0.768
3.706
3.188
1.058
1.806
2.000
1.056
2.592
1.207
0.239
4.750
0.003
104.0
186.0
152.0
126.0
204.0
55.0
65.0
54.0
76.0
127.0
111.0
17.0
57.0
0.2
24.0
53.0
198.0
34.0
64.0
52.0
36.0
27.0
72.0
49.0
92.0
71.0
12.0
62.0
119
119
119
119
119
119
119
119
119
119
119
119
119
119
Ser-qtzchl
Kfsser-cal
Chl-serqtz
Kfs-ser-qtzcal
Kfs-qtzser
Chl-qtz-hm
Chl-qtz
Chl-qtz-cte
Kfs-qtz-chl
Kfs-qtz
Kfs-chl-hm
Chl-cte
Qtz-ser
Manto Ruso
Manto Ruso
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Norte
Mantoverde Sur
Mantoverde Sur
Mantoverde Sur
East from Laura
Northwest from Celso
Quebrada Guamanga
Mantoverde Norte
MV07176
MV07206
MV07450
MV07485
MV07514
MV07464
MV07540
MV07335
MV07337
MV07577
MV07076
MV07658
MV07058
MV07477
DDH01GT04
DDH01GT07
DDH01DS10
DDH00DS05
DDH99MV03
1001 m a.s.l. (pit)
DDH07N04
DDH00DS04
DDH00DS04
910 m a.s.l. (pit)
971 m a.s.l.
995 m a.s.l.
999 m a.s.l.
DDH00DS05
317
106
519
314
520
Specularite stockwork
Specularite breccia
Tectonic breccia
Specularite breccia
Specularite breccia
Volcanic rock
Volcanic rock
Breccia Verde
Breccia Verde
Volcanic rock (?)
Volcanic rock
Volcanic rock
Volcanic rock
Calcite vein
(Breccia Verde)
Calcite vein
(Breccia Verde)
Calcite vein
(Mantoverde fault)
Calcite vein
(Magnetite zone)
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Rock
Calcite
Rb/Sr
Rb
(ppm)
Sr
(ppm)
Age
(Ma)
Rock/
mineral
Alteration
Unit/rock type
Depth
(m)
Drill core or
Altitude
Location
Sample
no.
TABLE 2. Strontium Isotope and Geochemical Data of Altered Rocks and Calcite from the Mantoverde IOCG District
(87Sr/86Sr)
Error
(at 2)
(87Sr/86Sr)i
RIEGER ET AL.
1288
1289
40.0
39.0
39.5
208Pb/204Pb
208Pb/204Pb
B
C
39.0
B
38.5
38.5
38.0
38.0
MORB
A
37.5
17.5
18.0
18.5
19.0
19.5
20.0
20.5
18.5
15.7
204
Pb/
19.5
Pb
C
207Pb/204Pb
207Pb/204Pb
15.7
19.0
206
206Pb/204Pb
15.6
15.5
15.6
MORB
A
15.4
17.5
18.0
18.5
19.0
19.5
20.0
20.5
18.5
206Pb/204Pb
Chalcopyrite
Mantoverde Norte
Pyrite
Mantoverde Norte
Mantoverde Sur
Mantoverde Sur
Manto Ruso
Manto Ruso
19.0
19.5
206Pb/204Pb
Volcanic rocks
Coastal Batholith
Copiap (Early Cretaceous)1
FIG. 15. Lead isotope signatures of chalcopyrite and pyrite from IOCG bodies in the Mantoverde district. Pb isotope evolution curves after Zartman and Doe (1981). Letters within charts: A = mantle, B = orogene, and C = upper crust contributed
to the orogene. Reference fields of Marschik et al. (2003b)1 and Lucassen et al. (2006)2. Note that sample MV07232 has an
anomalous Pb isotope signature and is not plotted on the diagrams.
(cp II) that formed roughly coeval with calcite, calcite veins
may enclose coarse-grained, rounded to subrounded, earlier
pyrite and/or chalcopyrite (cp I) fragments, which may have
been erroneously interpreted as intergrowth textures in the
past (e.g., Benavides et al., 2007). The intense and widespread hydrothermal brecciation, the abundant open spacefilling, and the large calcite veins suggest that the mineralization occurred at relatively shallow crustal levels. This would
have potentially allowed a significant influx of basin-derived
nonmagmatic fluids that may have been relatively cool and/or
oxidized. The stable isotope data of Benavides et al. (2007)
are permissive for involvement of nonmagmatic fluids, although they are also compatible with a significant magmatic
fluid component throughout the ore-related hydrothermal
activity, based on the temperatures inferred here. A fluid in
equilibrium with magnetite at 500C has a calculated 18O
composition between 7.6 and 9.6 per mil 18O (fractionation
1289
1290
RIEGER ET AL.
TABLE 3. Major and Trace Element Concentrations in Rocks of the Mantoverde District
Sample
Location
Alteration/rock type
UTM North
UTM East
Altitude/
drill core-depth
Major elements (wt %)
SiO2
TiO2
Al2O3
Fe2O3 total
MnO
MgO
CaO
Na2O
K2O
P2O5
LOI
Total
Trace elements (ppm)
Cs
Tl
Ba
Th
U
Hf
Ta
Nb
Y
Zr
Rb
Sr
Sc
V
Cr
Co
Ni
Cu
Zn
Mo
Ag
Pb
Bi
Be
In
Ga
Ge
As
Sn
Sb
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
MV96-1 (WR)
Mantoverde
Norte
MV07450 (WR)
Mantoverde
Norte
Tectonic breccia
7062500
369000
970 m a.s.l.
Tectonic breccia
7062195
369717
DDH01DS10522 m
31.71
0.60
10.44
39.53
0.04
5.61
0.23
0.16
3.92
0.23
3.23
95.71
49.73
0.99
18.32
6.67
0.11
4.28
2.58
1.37
10.45
0.17
4.80
99.48
<1.0
740.0
7.8
<0.5
2.0
<0.5
8.0
63.0
87.0
40.0
20.1
303.0
74.0
44.0
90.0
2037.0
2.0
<2.0
<0.4
<5.0
<5.0
<2.0
8.0
2.0
434.0
692.0
171.0
21.3
3.3
<0.5
0.8
0.1
0361-0128/98/000/000-00 $6.00
<0.5
0.4
4319.0
0.9
1.4
2.1
0.3
3.0
11.0
94.0
152.0
198.0
19.0
196.0
<20.0
14.0
30.0
20.0
40.0
<2.0
<0.5
<5.0
<0.4
<1.0
<0.2
18.0
1.0
<5.0
1.0
0.9
9.4
12.4
1.4
5.2
1.2
0.3
1.6
0.3
1.8
0.4
1.4
0.3
1.7
0.3
MV96-5 (WR)
Mantoverde
Norte
Specularite
breccia
7062500
369000
MV96-5-1 (F)
Mantoverde
Norte
Specularite
breccia
7062500
369000
970 m a.s.l.
970 m a.s.l.
28.66
0.55
8.73
51.44
0.03
2.31
0.04
0.12
4.42
0.04
1.97
98.31
54.80
0.57
17.10
8.16
0.05
3.00
0.07
0.26
11.35
0.07
2.53
97.96
32.60
0.57
10.23
45.17
0.04
2.55
0.04
0.12
5.48
0.05
2.03
98.86
<1.0
<1.0
<1.0
740.0
2.4
1.5
1.0
<0.5
2100.0
4.8
3.0
2.0
<0.5
1000.0
2.7
1.7
1.0
<0.5
4.0
50.0
86.0
40.0
24.9
139.0
75.0
40.0
34.0
6615.0
2.0
<2.0
0.4
<5.0
<5.0
<2.0
8.0
133.0
194.0
110.0
20.6
57.0
63.0
67.0
46.0
7249.0
16.0
<2.0
0.8
5.0
<5.0
<2.0
4.0
57.0
91.0
51.0
24.3
118.0
66.0
31.0
38.0
6224.0
2.0
<2.0
0.4
<5.0
<5.0
<2.0
5.3
5.0
5.3
2.2
116.0
217.0
1.3
260.0
528.0
1.9
145.0
271.0
68.0
10.5
1.8
186.0
25.0
4.4
86.0
12.7
2.2
<0.5
<0.5
<0.5
1.3
0.2
2.6
0.5
1.1
0.3
1290
MV07427 (F)
Mantoverde
Norte
Specularite
breccia
7062195
369717
DDH01DS10221 m
69.51
0.28
13.19
1.66
0.07
0.44
1.30
0.20
10.27
0.03
2.54
99.49
0.8
0.2
1524.0
10.8
1.7
5.1
1.1
5.0
5.0
188.0
151.0
90.0
4.0
33.0
<20.0
44.0
<20.0
130.0
<30.0
10.0
<0.5
6.0
<0.4
<1.0
<0.2
10.0
1.0
<5.0
1.0
2.5
3.6
6.3
0.7
2.7
0.6
0.2
0.5
<0.1
0.5
0.1
0.5
0.1
0.7
0.1
1291
MV07514 (F)
Mantoverde
Norte
Specularite
breccia
7062449
369769
DDH99MV03520 m
MV07526 (F)
Mantoverde
Norte
Specularite
breccia
7062545
369133
DDH07N05155 m
MV96-4 (WR)
Mantoverde
Norte
Specularite
stockwork
7062500
369000
54.30
0.58
17.08
5.35
0.11
1.14
2.01
0.18
13.42
0.22
5.45
99.84
56.94
0.65
16.35
6.45
0.02
1.93
0.06
0.26
12.20
0.03
1.93
96.82
1.0
0.3
1931.0
1.9
3.9
4.1
0.6
6.0
7.0
159.0
204.0
64.0
4.0
34.0
< 20.0
196.0
< 20.0
< 10.0
< 30.0
< 2.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
10.0
1.0
9.0
3.0
1.8
4.3
9.3
1.1
4.4
1.0
0.3
1.1
0.2
1.1
0.2
0.9
0.2
1.3
0.3
0361-0128/98/000/000-00 $6.00
0.6
0.3
1814.0
2.5
1.8
2.9
0.6
3.0
4.0
104.0
199.0
61.0
9.0
75.0
60.0
30.0
30.0
5110.0
50.0
< 2.0
< 0.5
6.0
< 0.4
< 1.0
< 0.2
12.0
1.0
< 5.0
6.0
1.4
2.9
5.6
0.8
2.9
0.6
0.2
0.7
0.1
0.9
0.2
0.7
0.1
1.0
0.2
MV07464 (WR)
Mantoverde
Norte
MV07540 (WR)
Mantoverde
Norte
MV07335 (WR)
Mantoverde
Sur
Chl-qtz-hm
7063109
368781
970 m a.s.l.
MV07524 (F)
Mantoverde
Norte
Specularite
stockwork
7062545
369133
DDH07N0575 m
1001 m a.s.l.
Chl-qtz
7062566
369218
DDH07N04115 m
Chl-qtz-cte
7061600
369653
DDH00DS04380 m
51.06
0.76
16.16
11.18
0.10
5.05
0.05
0.24
10.13
0.03
2.80
97.55
50.56
0.81
19.70
10.37
0.11
5.38
0.06
0.09
8.11
0.12
4.34
99.65
45.73
0.83
13.29
18.76
0.11
8.34
1.71
0.14
3.64
0.14
6.22
98.90
56.73
0.68
13.90
14.93
0.04
2.40
0.37
3.90
2.60
0.15
2.73
98.41
56.26
0.58
12.44
9.22
0.08
5.21
3.71
0.15
3.21
0.12
6.61
97.58
< 1.0
1.1
0.2
767.0
1.6
1.8
2.3
0.2
3.0
17.0
87.0
197.0
33.0
45.0
219.0
110.0
22.0
50.0
7000.0
50.0
< 2.0
< 0.5
< 5.0
< 0.4
1.0
< 0.2
33.0
2.0
8.0
5.0
2.5
574.0
937.0
103.0
279.0
45.3
9.2
26.4
2.1
6.3
0.8
1.8
0.2
1.3
0.2
2100.0
1.5
< 0.5
3.0
< 0.5
9.0
79.0
155.0
108.0
30.3
150.0
96.0
43.0
46.0
1349.0
38.0
< 2.0
< 0.4
< 5.0
< 5.0
< 2.0
7.9
2.5
42.9
75.0
23.0
5.3
1.5
< 0.5
2.1
0.4
1291
< 0.5
0.3
760.0
3.3
0.7
2.2
0.2
2.0
14.0
103.0
55.0
52.0
34.0
222.0
370.0
19.0
70.0
20.0
40.0
< 2.0
< 0.5
< 5.0
< 0.4
1.0
< 0.2
26.0
2.0
6.0
2.0
1.2
57.1
114.0
14.1
45.3
8.5
2.0
5.2
0.6
2.9
0.6
1.6
0.2
1.4
0.2
1.3
< 0.1
386.0
5.4
1.2
3.4
0.8
5.0
9.0
103.0
65.0
36.0
18.0
188.0
20.0
24.0
< 20.0
290.0
< 30.0
< 2.0
< 0.5
< 5.0
< 0.4
1.0
< 0.2
14.0
1.0
5.0
2.0
4.4
9.2
21.3
2.7
9.3
2.1
0.5
2.1
0.3
1.9
0.4
1.3
0.2
1.3
0.2
< 0.5
< 0.1
363.0
10.8
1.4
5.1
1.1
9.0
18.0
182.0
54.0
27.0
13.0
90.0
50.0
28.0
40.0
800.0
< 30.0
5.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
20.0
1.0
55.0
1.0
< 0.5
83.8
139.0
14.2
40.3
6.0
1.1
4.1
0.6
3.1
0.6
1.9
0.3
1.6
0.2
1292
RIEGER ET AL.
TABLE 3. (Cont.)
Sample
Location
Alteration/rock type
UTM North
UTM East
Altitude/
drill core-depth
Major elements (wt %)
SiO2
TiO2
Al2O3
Fe2O3 total
MnO
MgO
CaO
Na2O
K2O
P2O5
LOI
Total
Trace elements (ppm)
Cs
Tl
Ba
Th
U
Hf
Ta
Nb
Y
Zr
Rb
Sr
Sc
V
Cr
Co
Ni
Cu
Zn
Mo
Ag
Pb
Bi
Be
In
Ga
Ge
As
Sn
Sb
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
MV07337 (WR)
Mantoverde Sur
Kfs-qtz-chl
7061600
369653
DDH00DS04461 m
80.25
0.28
6.99
1.49
0.02
0.61
0.74
0.20
5.28
0.04
1.25
97.14
< 0.5
0.2
1219.0
3.5
2.8
8.0
2.6
6.0
4.0
244.0
76.0
72.0
3.0
24.0
< 20.0
129.0
< 20.0
< 10.0
< 30.0
< 2.0
< 0.5
< 5.0
0.5
< 1.0
< 0.2
6.0
1.0
< 5.0
1.0
4.2
3.6
8.1
0.9
3.0
0.6
0.5
0.8
0.1
0.8
0.2
0.8
0.1
1.0
0.2
0361-0128/98/000/000-00 $6.00
MV07356 (F)
MV07368 (F)
MV07577 (WR)
Mantoverde Sur Mantoverde Sur Mantoverde Sur
Specularite
breccia
Magnetite rich rock
Kfs-qtz
7061620
7061620
7060466
369776
369776
369360
DDH01DS21DDH01DS21231 m
414 m
910 m a.s.l.
38.13
0.41
13.88
24.81
0.15
3.48
0.57
0.26
6.23
0.01
10.59
98.52
1.6
0.2
967.0
1.5
1.5
2.0
0.3
1.0
12.0
86.0
99.0
76.0
37.0
183.0
60.0
321.0
60.0
150.0
< 30.0
98.0
< 0.5
12.0
< 0.4
1.0
< 0.2
21.0
2.0
6.0
6.0
< 0.5
2.5
5.2
0.6
2.5
0.6
0.2
0.8
0.2
1.6
0.4
1.5
0.3
1.9
0.3
82.12
0.31
4.03
1.02
0.02
0.33
2.41
0.08
1.55
0.13
2.72
94.72
74.87
0.06
11.38
1.41
0.06
0.33
1.65
0.20
8.08
0.15
2.16
100.40
< 0.5
< 0.1
43.0
1.9
1.0
7.0
1.3
4.0
6.0
248.0
47.0
8.0
6.0
44.0
20.0
50.0
< 20.0
540.0
< 30.0
3.0
< 0.5
6.0
< 0.4
< 1.0
< 0.2
11.0
1.0
< 5.0
1.0
< 0.5
1.8
3.7
0.5
2.2
0.6
0.2
0.8
0.2
1.1
0.2
0.8
0.1
0.9
0.2
0.8
0.3
1037.0
1.1
1.0
1.7
2.3
4.0
6.0
30.0
127.0
49.0
3.0
7.0
< 20.0
35.0
< 20.0
120.0
< 30.0
< 2.0
30.7
< 5.0
< 0.4
< 1.0
< 0.2
6.0
1.0
< 5.0
1.0
< 0.5
2.0
3.6
0.5
2.3
0.7
0.2
1.0
0.2
1.3
0.3
0.7
0.1
0.6
0.1
1292
MV07176 (WR)
Manto Ruso
Specularite
stockwork
7065659
369567
DDH01GT04315 m
MV07206 (WR)
Manto Ruso
Specularite
breccia
7065614
369351
DDH01GT07106 m
MV07135 (F)
Manto Ruso
Specularite
stockwork
7065659
369567
DDH01GT04129 m
62.23
0.11
10.33
6.14
0.08
0.96
7.25
0.69
3.67
0.10
7.53
99.10
46.70
0.73
15.86
0.94
0.15
0.44
12.26
0.19
10.32
< 0.01
11.15
98.74
76.09
0.29
12.46
1.67
0.00
0.29
0.06
1.00
5.73
0.01
1.91
99.51
0.5
0.4
213.0
8.9
1.2
2.2
0.5
2.0
67.0
88.0
104.0
24.0
4.0
17.0
< 20.0
43.0
< 20.0
2540.0
< 30.0
< 2.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
12.0
< 1.0
< 5.0
< 1.0
< 0.5
23.0
45.7
5.4
18.2
3.8
1.0
4.8
1.0
7.8
2.0
7.3
1.2
7.0
0.9
0.7
0.3
1101.0
3.0
0.6
1.8
0.4
4.0
20.0
76.0
186.0
53.0
18.0
98.0
50.0
10.0
< 20
90.0
< 30.0
< 2.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
14.0
< 1.0
< 5.0
2.0
< 0.5
14.3
27.9
3.9
15.2
3.8
1.3
3.8
0.6
3.2
0.7
2.0
0.3
2.2
0.3
0.5
0.2
669.0
1.8
1.2
5.1
0.8
3.0
4.0
202.0
132.0
20.0
4.0
11.0
< 20.0
24.0
< 20.0
160.0
< 30.0
< 2.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
16.0
1.0
< 5.0
2.0
3.1
0.6
1.4
0.2
0.7
0.2
< 0.05
0.2
< 0.1
0.4
0.1
0.4
0.1
0.7
0.2
1293
MV07498 (WR)
MV07641 (WR)
MV07646 (WR)
MV07076 (WR)
Mantoverde Norte
Cte-chl
7062449
369769
Mantoverde Norte
Kfs-chl-cte
7061965
370085
Mantoverde Norte
ab-ep
7061713
370784
DDH99MV03-189 m
1100 m a.s.l.
51.65
0.81
17.64
8.35
0.33
5.44
7.59
4.11
1.78
0.16
2.87
100.73
50.10
1.12
14.48
8.15
0.16
5.98
5.41
0.72
6.64
0.72
6.34
99.82
0.8
0.2
597.0
3.4
1.0
2.7
0.4
4.0
16.0
107.0
38.0
466.0
28.0
243.0
40.0
37.0
20.0
110.0
280.0
< 2.0
< 0.5
< 5.0
< 0.4
1.0
< 0.2
20.0
2.0
14.0
< 1.0
2.6
13.0
28.5
4.0
16.3
3.9
1.2
3.3
0.5
3.1
0.6
1.7
0.3
1.6
0.3
Location
Alteration/rock type
UTM North
UTM East
Altitude/
drill core-depth
< 0.5
0.2
908.0
5.8
1.0
4.8
0.6
6.0
34.0
171.0
167.0
64.0
37.0
107.0
70.0
29.0
< 20.0
480.0
70.0
< 2.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
15.0
1.0
16.0
1.0
3.8
19.9
46.7
6.2
24.0
5.8
1.4
5.9
1.1
7.0
1.3
3.7
0.6
3.4
0.5
MV07658 (WR)
Northwest
from Celso
Chl-cte
7066314
369573
MV07058 (WR)
Quebrada
Guamanga
Qtz-ser
7058510
369756
1169 m a.s.l.
971 m a.s.l.
995 m a.s.l.
999 m a.s.l.
55.63
1.03
18.77
2.94
0.11
3.98
10.65
5.20
0.57
0.02
0.92
99.82
50.39
0.96
14.43
15.98
0.24
5.43
0.50
0.13
5.99
0.29
4.14
98.47
54.32
2.27
12.66
11.29
0.12
3.48
4.18
3.54
0.98
0.73
4.73
98.29
85.79
0.26
4.74
2.14
0.14
0.28
1.73
0.10
1.71
0.05
2.54
99.47
< 0.5
< 0.1
175.0
3.4
0.5
2.7
0.8
5.0
16.0
99.0
11.0
407.0
33.0
101.0
40.0
31.0
< 20.0
10.0
70.0
< 2.0
< 0.5
< 5.0
< 0.4
1.0
< 0.2
19.0
1.0
< 5.0
< 1.0
2.1
5.0
9.9
1.5
7.1
2.1
0.9
2.2
0.4
2.8
0.6
1.6
0.3
1.6
0.3
0.8
0.2
1635.0
2.9
1.0
2.4
0.3
2.0
10.0
89.0
111.0
92.0
13.0
189.0
130.0
33.0
< 20.0
< 10.0
30.0
< 2.0
< 0.5
< 5.0
< 0.4
< 1.0
< 0.2
15.0
1.0
41.0
1.0
2.4
4.0
7.1
0.9
4.1
1.1
0.3
1.5
0.2
1.5
0.3
1.2
0.2
1.3
0.2
< 0.5
0.1
142.0
4.2
1.4
7.5
1.0
12.0
39.0
275.0
17.0
71.0
18.0
256.0
< 20.0
22.0
30.0
670.0
60.0
< 2.0
0.8
< 5.0
< 0.4
2.0
< 0.2
18.0
1.0
47.0
3.0
5.6
7.2
17.2
2.7
13.4
4.2
1.3
5.6
1.2
8.1
1.7
4.9
0.7
4.5
0.7
0.6
< 0.1
85.0
3.0
0.9
10.3
1.3
4.0
4.0
380.0
57.0
12.0
3.0
23.0
< 20.0
42.0
< 20.0
< 10.0
< 30.0
< 2.0
< 0.5
< 5.0
1.5
< 1.0
< 0.2
7.0
< 1.0
< 5.0
1.0
3.4
0.6
1.6
0.2
1.1
0.3
0.1
0.6
0.1
0.7
0.2
0.6
0.1
0.8
0.2
Abbreviations: WR = whole rock, F = breccia fragments, a.s.l. = above sea level, ab = albite, chl = chlorite, cte = calcite, ep = epidote, hm = hematite, Kfs
= K feldspar, qtz = quartz, ser = sericite; blank spaces = not analyzed
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RIEGER ET AL.
coefficients of Bottinga and Javoy, 1973). A fluid in equilibrium with hematite at 350C has a calculated 18O between
8.0 and 11.6 per mil (fractionation coefficients of Zheng and
Simon, 1991). A fluid in equilibrium with chlorite at 350C
has a calculated 18O composition from 6.0 to 11.6 per mil
(fractionation coefficients of Cole and Ripley, 1998) and D
composition from 12.5 to 37.5 per mil (Graham et al.,
1984). A fluid in equilibrium with calcite at 220C has a calculated 18O composition from 7.2 to 8.4 per mil (Kim and
ONeil, 1997).
The new paragenetic scheme and relationships discussed
above differ from the recently published compilation by Benavides et al. (2007), particularly in the temporal relationships of hematite and magnetite, or the timing of carbonatization, calcite veining, and sulfide mineralization. Benavides
et al. (2007) distinguish four hydrothermal stages (stages I, II,
ore stage III, and stage IV). They state that magnetite and
hematite formed almost entirely at different paragenetic
stages, assuming that all of the hematite postdates magnetite
and disregarding the zonation of IOCG systems. Our observations suggest that magnetite at depth formed coeval with
the bulk of the hematite at shallow levels (Fig. 6). Hematite
crosscutting magnetite, as mentioned by Benavides et al.
(2007), is a late and minor event (hematite II). It also cuts the
bulk of the Cu mineralization, although it may contain minor
amounts of sulfides (e.g., Fig. 7h). The occurrence of chalcopyrite is considered to be relatively late (Ore stage III of
Benavides et al., 2007 or sulfide stage, this study). However,
Benavides et al. (2007) recognize an early chalcopyrite phase
co-genetic with early magnetite (stage I chalcopyrite of Benavides et al., 2007, cited in their Table 2, samples 2425 and
2425A). They also see evidence for the presence of another
chalcopyrite generation during their stage II mineralization
(Benavides et al., 2007, see Table 2, e.g., sample 2427), which
predates the main Cu mineralization. These chalcopyrite generations are not indicated in the paragenetic scheme of Benavides et al. (2007). Therefore, pyrite and chalcopyrite form together with the iron oxides during their stages I, II, and III.
The observations may have led Benavides et al. (2007) to conclude that the sulfides formed in equilibrium with the iron oxides (see below).
Implications of sulfur isotope data
The 34S values of chalcopyrite (5.6 to 8.9) and pyrite
(0.2 and 9.4) presented here are similar to those of Benavides et al. (2007; chalcopyrite 6.6 to 10.0; pyrite 6.8 to
11.2). A compilation of the available IOCG-related sulfur
isotope data in the Mantoverde district is given in Fig. 16.
Sulfides in association with magnetite have 34S values from
6 to 3 per mil (Fig. 16b), whereas sulfides associated with
specularite vary from 1 to 11 per mil (Fig. 16c). The data suggest that there is a variation in sulfur isotope signatures of
chalcopyrite relative to the inferred fluid conduits (e.g., the
Mantoverde fault) and the level of deposition within the hydrothermal system. Chalcopyrite with negative 34S values or
values close to 0 per mil is characteristic of magnetite-rich
ores at deeper levels or specularite-rich ores in the central
parts of the orebodies (i.e., the more internal or upflow zone),
whereas chalcopyrite enriched in 34S typically occurs outside
these fluid conduits or is developed at shallower levels. In
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12
11
10
Frequency
9
8
7
6
5
4
3
2
1
0
-8
-7
-6
-5
-4
-3
-2
-1
34SCDT
Magnetite-dominated zone
chalcopyrite
pyrite
10
11
12
chalcopyrite
pyrite
Frequency
Frequency
Specularite-dominated zone
5
4
3
5
4
3
1
0
0
-8 -7 -6 -5 -4 -3 -2 -1 0
-8 -7 -6 -5 -4 -3 -2 -1 0
9 10 11 12
9 10 11 12
chalcopyrite
pyrite
chalcopyrite
pyrite
Frequency
Frequency
8
7
5
4
3
5
4
3
0
-8 -7 -6 -5 -4 -3 -2 -1 0
9 10 11 12
-8 -7 -6 -5 -4 -3 -2 -1 0
9 10 11 12
FIG. 16. a) Compilation of sulfur isotope compositions of sulfides from IOCG ores in the Mantoverde district (Benavides
et al., 2007; this study). b) Sulfides associated with magnetite have 34S values from 6 to 3 per mil, whereas c) sulfides associated with specularite vary from 1 to 11 per mil (note that the total number of analyses of sulfides associated with hematite
is almost double the amount of analyses of sulfides associated with magnetite). d) Sulfides in calcite veins or associated with
calcite show a similar range of sulfur isotopic compositions to those associated with magnetite. e) Sulfides in altered host
rocks (with no association to magnetite, hematite, or calcite) span a similar 34S compositional range as all sulfides of the previously mentioned three groups.
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Jones, C.E., Jenkyns, H.C., Coe, A.L., and Hasselbo, S.P., 1994, Strontium
isotopic variations in Jurassic and Cretaceous seawater: Geochimica et Cosmochimica Acta, v. 58, p. 30613074.
Kendrick, M.A., Honda, M., Gillen, D., Baker, T., and Phillips D., 2008, New
constraints on regional brecciation in the Wernecke Mountains, Canada,
from He, Ne, Ar, Kr, Xe, Cl, Br and I in fluid inclusions: Chemical Geology, v. 255, p. 3346.
Kim, S.T., and ONeil, J.R., 1997, Equilibrium and nonequilibrium oxygen
isotope effects in synthetic carbonates: Geochimica et Cosmochimica Acta,
v. 61, p. 34613475.
Kolb, J., Meyer, M., Prantl, S., Sindern, S., Sakellaris, G.A., Vennemann, T.,
Bttcher, M.E., 2009, Characteristics of hydrothermal fluids forming the
Guelb Moghrein Fe Oxide-Cu-Au-Co deposit, Mauritania: Ore mineral
chemistry, fluid inclusions and isotope geochemistry, in Porter, T.M., ed.,
Hydrothermal iron-oxide copper-gold & related deposits: A global perspective: Adelaide, Australian Mineral Foundation, in press.
Lara, L., and Godoy, E., 1998, Hoja Quebrada Salitrosa, III Regin de Atacama: Santiago, Chile, Servicio Nacional de Geologa y Minera, Mapas Geolgicos 4, scale 1:100.000.
Lucassen, F., Kramer, W., Bartsch, V., Wilke, H.G., Franz, G., Romer, R.L.,
and Dulski, P., 2006, Nd, Pb, and Sr isotope composition of juvenile magmatism in the Mesozoic large magmatic province of northern Chile
(1827S): Indications for a uniform subarc mantle: Contributions to Mineralogy and Petrology, v. 152, p. 571589.
Mark, G., and Forster, D.R.W., 2000, Magmatic-hydrothermal albite-actinolite-apatite-rich rocks from the Cloncurry district, NW Queensland, Australia: Lithos, v. 51, p. 223245.
Marschik, R., and Fontbot, L., 1996, Copper(-iron) mineralization and
superposition of alteration events in the Punta del Cobre belt, northern
Chile: Society of Economic Geologists, Special Publication 5, p.
171189.
2001, The Candelaria-Punta del Cobre iron oxide Cu-Au(-Zn-Ag) deposits, Chile: ECONOMIC GEOLOGY, v. 96, p. 17991826.
Marschik, R., Leveille, R.A., and Martin, W., 2000, La Candelaria and the
Punta del Cobre district, Chile: Early Cretaceous iron oxide Cu-Au(-ZnAg) mineralization, in Porter, T.M., ed., Hydrothermal iron-oxide coppergold & related deposits: A global perspective, Adelaide, Australian Mineral
Foundation, p. 163175.
Marschik, R., Fontignie, D., Chiaradia, M., and Voldet, P., 2003a, Geochemical and Nd-Sr-Pb-O isotope characteristics of granitoids of the Early Cretaceous Copiap plutonic complex (2730'S), Chile: Journal of South
American Earth Sciences, v. 16, p. 381398.
Marschik, R., Chiaradia, M., and Fontbot, L., 2003b, Implications of Pb isotope signatures of rocks and iron oxide Cu-Au ores in the Candelaria-Punta
del Cobre district, Chile: Mineralium Deposita, v. 38, p. 900912.
Marschik, R., Spikings, R., and Kuscu, I., 2008, Geochronology and stable
isotope signature of alteration related to hydrothermal magnetite ores in
Central Anatolia, Turkey: Mineralium Deposita, v. 43, p. 111124.
Mathur, R.D., Marschik, R., Ruiz, J., Munizaga, F., Leveille, R.A., and Martin, W., 2002, Age of mineralization of the Candelaria iron oxide Cu-Au deposit and the origin of the Chilean iron belt based on Re-Os isotopes: ECONOMIC GEOLOGY, v. 97, p. 5971.
Moldovanyi, E.P., Walter, L.M., and Land, L.S., 1993, Strontium, boron, oxygen, and hydrogen isotope geochemistry of brines from basal strata of the
Gulf Coast sedimentary basin, USA: Geochimica et Cosmochimica Acta, v.
57, p. 20832099.
Monteiro, L., Xavier, R., de Carvalho, E., Hitzman, M.W., Johnson C.A., de
Souza Filho C.R., and Torresi, I., 2008, Spatial and temporal zoning of hydrothermal alteration and mineralization in the Sossego iron oxide-coppergold deposit, Carajs Mineral Province, Brazil: Paragenesis and stable isotope constraints: Mineralium Deposita, v. 43, p. 129159.
Morata, D., and Aguirre, L., 2003, Extensional Lower Cretaceous volcanism
in the Coastal Range (2920'30S), Chile: Geochemistry and petrogenesis:
Journal of American Earth Sciences, v. 16, p. 459476.
Mote, T.I., Becker, T.A., Renne, P., and Brimhall, G.H., 2001, Chronology of
exotic mineralization at El Salvador, Chile, by 40Ar/39Ar dating of copper
wad and supergene alunite: ECONOMIC GEOLOGY, v. 96, p. 351366.
Mpodozis, C., and Ramos, V., 1990, The Andes of Chile and Argentina, in Ericksen, G.E., Caas-Pinochet, M.T., and Reinemund, J.A., eds., Geology of
the Andes and its relation to hydrocarbon and mineral resources: Houston,
Texas, Circum-Pacific Council for Energy and Mineral Resources, Earth
Sciences Series, v. 11, p. 5991.
1298
0361-0128/98/000/000-00 $6.00
1299
Simard, M., Beaudoin, G., Bernard, J., and Hup A., 2006, Metallogeny of
the Mont-de-lAigle IOCG deposit, Gasp Peninsula, Qubec, Canada:
Mineralium Deposita, v. 41, p. 607636.
Tassara, A., Roperch, P., and Pavez, A., 2000, Paleomagnetsmo de los yacimientos Mantos Blancos y Manto Verde: Implicancias tectnicas y cronolgicas: Congreso Geolgico Chileno, 9th, Puerto Varas, 31 July4 August
2000, Actas, p. 166170.
Taylor, S.R., and McLennan, S.M., 1985, The Continental Crust; Its composition and evolution; An examination of the geochemical record preserved
in sedimentary rocks: Oxford, Blackwell, 312 p.
Tschernich, R., 1992, Zeolites of the world: Phoenix, Arizona, Geoscience
Press Inc., 563 p.
Ullrich, T.D., and Clark, A.H., 1999, The Candelaria copper-gold deposit,
Regin III, Chile: Paragenesis, geochronology and fluid composition, in
Stanley, C.J. et al., eds., Mineral deposits: Processes to processing: Rotterdam, Balkema, p. 201204.
Vila, T., Lindsay, N., and Zamora, R., 1996, Geology of the Manto Verde Copper Deposit, northern Chile: A specularite-rich, hydrothermal-tectonic
breccia related to the Atacama fault zone: Society of Economic Geologists,
Special Publication 5, p. 157170.
Williams, P.J., Barton, M.D., Johnson, D.A., Fontbot, L., De Haller, A.,
Mark, G., Oliver, N.H.S., and Marschik, R., 2005, Iron oxide-copper-gold
deposits: Geology, space-time distribution, and possible modes of origin:
ECONOMIC GEOLOGY 100th ANNIVERSARY VOLUME, p. 371405.
Wilson, J., Dallmeyer, R.D., and Grocott, J., 2000, New 40Ar/39Ar dates from
the Las Tazas Complex, northern Chile: Tectonic significance: Journal of
South American Earth Sciences, v. 13, p. 115122.
Zamora, R., and Castillo, B., 2001, Mineralizacin de Fe-Cu-Au en el distrito
Mantoverde, Cordillera de la Costa, III Regin de Atacama, Chile: Congreso Internacional de Prospectores y Exploradores (ProExplo 2001), 2nd,
Lima, Per, Abstracts. (CD-ROM).
Zartman, R.E., and Doe, B.R., 1981, Plumbotectonics. The model: Tectonophysics, v. 75, p. 135162.
Zentilli, M., 1974, Geological evolution and metallogenetic relationships in
the Andes of northern Chile between 26 and 29 S: Unpublished Ph.D.
thesis, Kingston, Ontario, Queens University, 394 p.
Zheng, Y.F., and Simon, K., 1991, Oxygen isotope fractionation in hematite
and magnetite: A theoretical calculation and application to geothermometry of metamorphic iron-formation: European Journal of Mineralogy, v. 3,
p. 877886.
1299
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