D. E. NELSON
AND
W. A. BAESLACK 111
J. C. LIPPOLLl
zone regions was ot)servecland correlated with local variations in chromium con(ent.
Introduction
1044-5803/97/$17.00
Pll S1044-.58O3(97)OOI40-X
468
MATERIALS
The plate material investigated was Ferralium Alloy 255 (UNS Number
S32550), a commercial, nitrogen-containing duplex stainless steel. The
alloy nominally contained 25 wt.% Cr, 5 wt.% Ni, 3 wt.% Mo, 2 wt.%
Cu, 0.20 wt.% N, and exhibited a solution-annealed (1038Cfollowed by
a rapid cool) microstructure containing approximately equal amounts of
the ferrite and austenite phases. Table 1 provides the actual base metal
chemistry for the alloy investigated.
Full-penetration, autogenous (no filler metal added) welds were produced on the 6.35-mm-thick plate material using the gas tungstenarc
welding process (Table 2). Subsequent to welding, specimens were sectioned transverse to the weld direction and mounted for metallographic
examination.
TABLE 1
Chemical Analysis of Ferralium Alloy 225 (Wt.%)
Manganese
Silicon
Chromium
Nickel
Molybdenum
Titanium
Magnesium
Calcium
Copper
Aluminum
Cobalt
Carbon
Sulfur
Phosphorus
Nitrogen
1.05
0.51
24.90
5.39
3.13
o. I 1
0.13
0.0027
1.72
0.99
0.22
0.27
below 0.001
0.023
0.17
469
TABLE 2
C;asTungstenArc Welding Parameters
Current
Voltage
Travel spexi
180amperes
17 volts
2,5 mmls
Electrode-t mwo]rkdistance
Electrode
Electrode diameter
Shielding gas
2.5 mm
Thoriated tungsten, 60 included angle
2.38 mm
Argon
0.29 liter/see
0.53 liter/see
METALLOGRAPHIC TECHNIQUES
The evolution of weld fusion and heat-affected zone (HAZ) microstructure is often difficult to understand due to the rapid heating and cooling
rates associated with the fusion welding process. In the case of the duplex
stainless steels, 1he process is further complicated by the transient phase
stability of the ~erriteand austenite in the temperature range between
room temperature and the melting point of the alloy. An equilibrium phase
diagram, although not rigorously applicable, is often useful as a means
for revealing the orig;inof the weld microstructure.
470
1 200 pm I
FIG.1. Opticrd micrograph of fusion boundary region. Arrows indicate approximate fusion boundary.
40pm
FIG.2. Optical micrograph of unaffected base metal. Note the directionally oriented
white austenite (y) and blue ferrite (8) phases.
...
471
I 40 pm
FIG.3. Optical micrographof far HAZ. B1ueand brown areas are ferrite(8), white areas
are austenite (y).
I 40 Mm J
FIG.4. Opticalmicrclgraph
ofmiddleHAZ.Austeniteplateausareindicatedbylarge
arrows.Notewhiteausteniteat ferritegrainboundaries
andsmallprecipitates
at ferrite
subgrainboundaries
(smallarrows).
472
1600
II
LIQUID
~/
1 2600
=y+~+L
1400
1---=2200
1200
-.
0
u
~ 100a
1<
a
L
o
u
a
z
2
\
000
# /
600
- -:
---q------\I
I
Y+u
, y+~+(J
- 1000
;
40C
a
w
a
1400 :
If
/
w
- 1800 ~
1<
:0
:
1
60 % I RON
15
20
25
30
35
40
25
20
15
10
WT ~
Cr
WT b Ni
473
474
40pm
FIG.6. Optical micrograph of near HAZ. Note appreciable ferrite grain growth. Arrows
indicate the weld fusion line.
I 40pm
I
FIG. 7. Optical micrograph of fusion zone. Arrow indicates fusion zone grain solidification direction.
475
BASE METAL
The rnicrograph in Fig. 2 illustrates the directionally oriented austenite
(white) and ferrite (blue) phases that exist in the unaffected base metal.
Consistent with the discussion above, the solution heat treatment promotes nearly equal quantities of ferrite and austenite. Electron microprobe analysis cf this structure shows that considerable alloying element
partitioning exists between the phases (Table 3), with the ferrite being
substantially enriched in chromium and depleted in nickel as compared
with the austenite.
HEAT-AFFECTED ZONE
In the far HAZ (Fig. 3), peak temperatures are sufficiently high to
promote a partial transformation of austenite to ferrite. The yellow and
brown ferrite regions surrounding the white austenite represent areas that
were originally austenite in the base metal microstructure, or possibly
ferrite adjacent to the original ferriteaustenite interface. Although these
austenite regioris are transformed to ferrite, and retained as ferrite on
cooling, there is insufficient time during the weld thermal cycle to diffuse
the chromium throughout the entire ferrite phase. Consequently, the
colors exhibited by these regions represent a transition between the blue,
chromium-rich original ferrite region cores and the white, chromium-poor
austenite. Microprobe analysis data for the ferrite and austenite in this
region differ little from those for the unaffected base metal (Table 3).
In the middle HAZ, nearly all of the austenite that exists in the roomtemperature microstructure transforms to ferrite on heating, the only exTABLE 3
Electron-hlicroprobe Analysis of Base Metal and HAZ Regions (Wt.%)
Near HAZ
F:rrite
Ferrite
(hlue)
(yellow)
Chromium
Nickel
Molybdenum
Silicon
Manganese
Copper
Far HAZ
Base metal
Ferrite
(blue)
Austenite
(white)
Ferrite
Austenite
(blue)
(white)
24.8
6,2
2.6
0.4
27.35
4,4s
3.49
0,44
23.05
7.37
2.19
0.36
I.10
1.35
I,15
2.05
26.4
~,~
3.2:
0,44
24.9
6.2
2.8
0.42
27,3
4.7
3.6
0.44
1.16
1.48
1.25
1.65
1.09
1,19
I,21
1.67
476
ception being the small plateaus of austenite shown by the large arrows
in Fig. 4. This austenite dissolution allows the formation of large, nearly
equiaxed ferrite grains. Note, however, that although high temperatures
have been reached, distinct similarities still exist between the blue areas
in the middle heat-affected zone microstructure and the ferrite morphology in the original base metal, suggesting that chromium diffusion is limited. On cooling, austenite nucleates in the form of nearly continuous
grain-boundary allotriomorphs and to a lesser extent intragranularly in
regions of low chromium where austenite originally existed. In addition,
austenite grows epitaxially from the few plateaus of austenite that did
not completely dissolve at peak temperatures.
Evidence of fine precipitation is also observable in Fig. 4, both homogeneouslywithin the ferrite grains and heterogeneouslyat ferrite grain
and subgrain boundaries. Previous work [7] suggests that the precipitates
are CrzN. Since the proportion of austenite decreases with increasing
temperature, the amount of nitrogen dissolved in the ferrite must increase.
On cooling, supersaturation occurs and the nitrogen would be precipitated
primarily in the chromium-rich blue regions of the ferrite grains as CrZN.
In the near HAZ (Fig. 6), the alloy is transformed entirely to ferrite at
peak temperatures and significant grain growth occurs. As in the middle
HAZ, austenite forms on cooling at ferrite grain boundaries and occasionally within the grains. It is of interest to note that the fine precipitation
is less in regions near austenite, even if the region is chromium enriched,
suggesting that the austenite may provide a sink for nitrogen in the matrix.
It is also important to observe that the color pattern in the base metal
still remains to a degree in the region, although it appears more diffuse.
In the preceding discussion, a correspondence of different colors in
the HAZ regions with chromium segregation has been indicated. As in
the unaffected base metal and far heat-affected zone, blue areas correspond with chromium enrichment that is residual from the original base
metal ferrite (Table 3). Brown and yellow regions correspond to lower
chromium ferrite and white areas correspond to austenite with a low chromium content.
FUSION ZONE
The fusion zone region is illustrated in Fig. 7, and generally consists
of columnar ferrite grains with substantial amounts of austenite both at
grain boundaries and within the grains. Differences in the respective quantities of austenite and ferrite between the fusion and near heat-affected
zones appear to be greater than would be expected, since these regions
experienced comparable cooling rates. The reason for this difference is
..-
477
573602.
2. F. C. Hull, Effects of composition on embrittlement of austenitic stainless steels, Welding
.JOWWUI
52:104s- 113(1973).
3. J, C, Lippold an.i W. F. Savage, Solidification of austenitic stainless steel weldments:
Part IA propo:ed mechanism, We/din#.J,~urna/58:361s-374s (1979).
4. R. A, Perkins, R. A. IPadgett,and N, K, runala. Tracer diffusion of 9Fe and 51Crin
Fe-17 wt pet. CI-12 wt pet. nickel austenitic alloy. Me[u//ur#ica/ Tran.\utrion.\4:25352540(1973).
5, R. A. Perkins. f[acerdiffusion of b3Niin Fe17 wt. pet. Cr12 wt pet. Ni, Meta/lur~ica/
Tran.suctiotrs4:1065-1669(1973).
6. E. Beraha and B. Shpigler. Co/or Me/a//ograph}. American Society for Metals, Metals
Park, Ohio (1977).pp. 321.
7. G. Herbsleb and P. Schwabb, Precipitation of intermetallic compounds, nitrides and
carbides in AF t 2 duplex steel and their influence on corrosion behavior in acids, in
Dup[e.r Sfairr/e,\s,\Stee[s (R. A. Lula, cd.), American Society for Metals, Metals Park,
Ohio (1983),pp. 15401.