________

MLLTIPLE CHOICE. Choose the one alternative that Iest completes the statement or answers the question.
T

value of rd-f for the reactron below is 2 kj.

mol of HBr is fonnen in this. reaction.

1-cr )c

1-fr

kJ of he.at are released when 1.0

21-11-c

B)141

Ci72

0)0.34

E36

-nswer:

2) The value of 2H for the reaction beiou.. is 90 kJ. The enthalpv change accompanying the
reaction or 0.93 g of S is
kJ.
25 s)

SOc

250501
C112

E23

Airs
3 rH for the reaction

is

IFthg

kJ. give the data below

IFg
IF(g)

FargI

LPc;g

2Fc(g)

A 35

2H=-30kJ

IFs Or

H=--l3kj

B 1135

Cr 355

Dr 35

Airs wer:
4 Given the following reactions
Fe2Osn)
31-es

3(20 (s:)

-4COcrs:

2Fe (s)

4C0c

3C02 (5)

n.H

Fer0cs

nH=th2SbT

the enthalpv of the reactjon of Fer0 with CO

sjQ

uO 0

2Fer01

28.0 kJ

F 1235

1)

Givei

tue data n the table helm

Ca CE

2EAscDc

;or the reaction

Ca i-hAC
4

21-bC

tane
Ca CE:
Ca 1-bAsCtj;
HQ
A

421d

Gner the data

in

the table below Hb\fl or the reaction

-1NH

AD2 g

4NC) g

eH2O (l

hi

Substance

1 (kj mob
XH

H7C) (I
\Cg
H\03

aq

A ca2

B -112
C i4
D -150
F The 1H o Or g

needed ror the cahulation.

C:si the aa in the :ahle heion H

: r the :eacron

4 g
Cl-i
C2H;Oh
Ci-iCC
l
2
-i

4Th4

0 -C i4

F Tn v!ue or XH

TI

o: C)

is re

:ireO :Or

tle cal:aton

value or \H ror the rollowing reaction is l.S kJ. The value or

RI mol.
CaCC)a s

CiC)

CC))

Suhstance rH tkJ mol

Cog
11C3
)L3
CC)2
CaCO 5
-\ S3.4

1
B I3,

C e35.5

ror CaO s

is

B
C
D -22
E Me data ate eeded :c an lete the ca!cdatici,.

IC Gie. the data n the table heic.

2SO(g

:r the reacticn:

2SO3g

kL
Sihtae XH.

J 4

O2 (g
SC) g
5
HSOj L
H*a I

C N
D NC
F The dH

a C),

F,

e t

: neNC

the

L:Ntoi

____br

Aenualreactonthtatxbslaat:rantlesurrounatngs.said tote
iN at :x..tartt .resurv
A e:.&ther::i: sie

_ai.dhasa

12

C e themuc i.egative
D elethemuc j.octive
E ntec: reitra

:3 Thertat

13

4A 5 : ; _A:O; s

.fl-I-=-335:k

and tlere,.re hea 1%

A eothemuc abs irted
B. er$othermic aSorbed
c. e:uotr.errx re.easea
D tn.othemuc. releasei
E thermoneutral neither released nor absorbed
-

rafln.

1-1 Vlucl if the :o:lowing is a statement 0: Hesi s law?

A It a reai.tion is carried out in a series os steps. the SN tot the reactior ill equal the
product or the enthalpy changes for the individual steps.
B. The fl-I of a reaction depend on the physical state. ot the reactants and rod;czs.
C The fl-I for a pracess in the ;orwarl directions equal in magnitude and opposite in sign
to the .11-I rot the process in the reverse direction.
D The SN for a process in the orwaid direction is eqt.al to the sN for the process in the
reverse direction.

ft a reacion is carried out in a series 0: steps. the SN for tie reaction will equal the sum
of the enthalpy changes or the individual steps.
4nswer

Fnr wlad. one of the rollowiug reactions :s SN n eqr.al tc the hear of r,nnabcn
pro
A.:
g - Oz NO g
B .c.
tH g
t.1L .1
9 31-!:
C V

X113 t

P :Xg -I:I-!L -Zag

tr -;Hg -Bfr ?H4Biiwe

the

14s

nerv atrerence
toe mr ari readniJ
dcLL

Ii

the enrgv brorie hehr; correoncb o the actiat:cn eI.erg: : r

1.iction I)1tI1
B v

35 In the nercv nmonle cm a reaction, the

A.
B
Ci
D
F

31 The

\.:

erc that

at the

a\nron on the cnrve

echanism mom :orn:atron o: the product \

cahed

31

in

slot,

The intern,e1iare rearant 1: the reaction

CC

D D

rolouin,
t,i1l lour the aLtivatior enerv :or a reaction,
A addina a catalvt :or tie reaction
B ra:s:ro the temperature 0:
ractioi
0 :: reas:nc
ca:cemratoi a: reacta:.t
D remc:rn rodu:s as the reaction proLeEds
P nreasrng the presn:re
tit

proch:ct
atomic state
activation enero:
enthalpv or reaction
activated Lomple\

AB C -D
B D 1

2. Or

E\itS

I)

(H

(N

2
7

i:

N
(N
(V

NJ
N)
I:)
jI

(V

NT)

NJ
(3

C)J

I
N)

NI

N)

(C)

NI

C)
4(V

$)

N)

C)

(H

N)

(N

N)
C)

NJ

NJ
EN

N)
NJ

(N

N)

C)

(V

IC)

N)

(I)
4-

C)
i

Cr

C
(1,

(1

CC

(C)
(V

Cr

)f)

(V

1)

If)
(I
(V

(I

(V

7:

C)

(N

N)

00000

(V

I)

(N

NJ

00

no

II

Cr

N)

(V

N
C
((

4-

(V

:1:

NJ

(H

C)

:110

(C)

NT
V

(V

11

H2

N
N

(H

$i

N)

(V
N

(N) (N

N)

N)

U (H
N)

%(I H

(I

2,

(Ti

11

(V

2
N

C)

(N

N)

(I;
N)
NN
(JC)

NJ

(H

(I

C
I

(V

i;

N)

NI
3

21

(H

(V

(V
N
N
It
N)

2(C)

4(

_________

ta sa1.

usti.n U acetvlu.e ii. Le j.nsa..e u ece O4efl wl

ic

arhon aoz It am

ater

.cQ -e4COg .2H

g
g 2
H
2
2C
01
2
t&

4
Ah

B4t4

3 K
Cnt3

432

tt

iaevtie*ss artnerta%
at.
t
Cc!nrn,ne .02 a
A c5

JK
B b3.

C5
1
_

D .3

E j39

:.

Ci

( l1cnt

C:Q\\ gel
C)

H)C) 1

-2 E3

3 g
PCI
POC1

23,13

1443

10i.

21S1

-2$,i

2t3.

311

5025

-542.2

rhiiibic

0
-3004

-3704

_3q.2

37 Tb e viI
e1:iii

:e :

325

3G

2 g.
P

25 C

2 oj
3C1

pio triC)hh0e

the

3 g
2PCI

C)

C :

r:

32:i

: :Cz::: :hmC

3.2

:r::C)

12

_.
.
________
_____

3C A

rea.don that is actai.ttu, h

A iers3
B zsen rapid
C. : i. C ttitr : ::. the rrete :re:t..t
) La- at. e.uZrn. rs:::;ta: es :ar to the :ct
E al procet1 i itha-it iuside mttrvatn

.4:3:

4 tetltra hit i.
A .nthalpv
B ::.terr.a ertenv
C o:t. energy
D leatri i
F en:rorv

eVa,_

41 tar ento e: the urtverse is

A. entmuaTh

31

deceasing

B corxrnuailv iccrtasinh
C) zew
D the same as the energt
F onstant

42. iS is positive rot the reacti*.

42

aq. a 2Fav
2
A.BaF2h. fr Ba
B2Hg.l -Og 2HgOs
C 2NO g -e N;04 g
D;C02g. C02.s
E.2H2Ig . Og. 2H20g
At.wer
33

Vh:ch one or tne ellewmg jrooesses produces a ierease it. tie entropy e: the vstem
A meitmg ice t rota: rater
B aissol Lon ot nhd ILL zn tei
C reziz water to term ice
) :auars :: ro gases :ire Xe onn:ner
F o:z.; W e tern .eam
4:. :tr

33

t:

n:D? :a:

A \ g
B HO I
C CH
D Ag

H: g
HO s
CO a

J aj

H:0

Cs

\H g
CCOa

COc

1$ ni an
C tuis :am:ai
BZ

CH(g

CH4(g

AgC

I-ha

I K nal at HS K At tn cramm meaas: tian

:ntauea::s :mder andai cai :A::cu .c.
C.3H
D H2
E

H2 g

-l$ kT aaol and S is -i2i J K mci. This caction is

A spcntaneous only at high temperature
B spontaneous at all temperatures
C r.o1:cpontaneou at all ten: erat :res
D s ntaneoi:s only at lana teiperature
is

4. A reactioi that is nor spontaneous at by: temperature can become spoitaneous at high
teaerature i: H is
and SS i
C

a reac::an to he st utaneous under

H andAg must he
and

tanda:d cci citions at ad

C-.-

1 CtL thermo namics

tenperan-re. Oc

respecC\ Ov,

r unat dete maine

he :A:
hut cc
B. hut reeci a: a
h the enpera
i:r at ii 1 area C a id Ic sionaIco
5
I) the ue:tt ia: utta e is :eacC

D-.

sim o:

::i;

Gibbs Free Fnerv

XG ar C
: Z
=

\H ac \S Ouce\

,e:Lj H

e n be rzcmes t th tnei tui e

LrC):h

A2

1eact:!Lb .rst cb

Ak

:b

_U

C Cci the ieact:oi:

Im

Cb.COH

C)

CO

kO

Ih:s r:me ustii the Tabe ofThennocheniicai Data and the :ennua

\O

\G

Fcrteieact:ot:Fe-O3COEe3CO-.
=

-I5 kJ Ca!cchue the tandaid Ciee enciev oCCeiicat:on cC the Cemc ede. FO,.
c: CC)

-15

ic

and

CO

-4 kJ inch