(MSDS)
Product
Techsol-S(Raffinate)
CAS No.
RTECS No.
UN No.
EC No.
64741-46-4
QK8000300
1268
265-046-8
List No.
Date of preparation
of the first version
AR0005
2008-07-25
Date of preparation
Department of Team
of the latest version
2013-01-09
Restrictions on use :
No data
3) Manufacture/Supplier information
Supply company : GS Caltex Corporation
Address : 679 Yoksam-dong, Kangnam-gu, Seoul, Korea
Information service or emergency call : 1544-5151
Department in charge: The customer service center
2. Hazards Identification
1) Classification of the substance or mixture
Flammable liquid category 2
Carcinogenicity category 2
2) GHS labels, including precautionary statements
Symbol
1/10
Health / Safety
Planning Team
Signal word :
Danger, Warning
Hazard statement
H225
H351
Precautionary statement
- Prevention
P201
P202
Do not handle until all safety precautions have been read and understood
P210
P233
P240
P241
P242
P243
P280
P281
- Response
P308+P313
P370+P378
P303+P361+P353
- Storage
P405
P403+P235
- Disposal
P501
Store locked up
Store in a well-ventilated place. Keep cool
- Fire
- Reactivity
Synonyms
CAS No.
Content(vol.%)
Naphtha
64741-46-4
100%
2/10
1) Eye contact
Have washed it in streaming water ideal 20 minutes.
2) Skin contact
Have washed it in streaming water ideal 20 minutes.
Wash skin thoroughly with soap and water
Wash and dry contaminated clothes and shoes perfectly before reuse.
3) Inhalation
If there is side effect, remove person to fresh air from the exposure area.
If person is not breathing, provide artificial respiration.
If there is labored respiration, certified person should manage the oxygen.
4) Ingestion
Seek medical attention immediately.
5) Most important symptoms/effects, acute and delayed
Inhalation
Short-term effect: Irritation, Headache, nausea, dizziness and other symptoms of central nervous system
(CNS) depression, severe pneumonitis (serious lung irritation), fatigue
Long-term effect: Low body temperature or febricity, blood pressure change, Vomiting, appetite,
emotional disturbance, modulation loss, disorders of menstruation , blood disorder,
cancer
Skin contact
Short-term effect: Irritation, blister
Long-term effect: Irritation, dermatitis, allergic reaction
Eyes contact
Short-term effect: Severe eye irritation
Long-term effect: Severe eye irritation
Ingestion
Short-term effect: Vomiting, stomach disturbance, chest pain, headache, drowsiness, methysis,
disorientation, eyesight disturbance, paralysis, convulsions, coma
Long-term effect: Vomiting, migraine, diarrhea,dizzines, pulmonary congestion, blood disorder, visual
impairment
6) First-aid treatment and information on medical doctors
It is gastric lavage in case of intake.
Supply oxygen in case of Inhalation.
3/10
Carbon oxides
3) Extinguishment
If it is not dangerous, remove containers from fire areas.
Even if the fire is suppressed, continuously spray water to the heated containers.
Avoid accessing to the both ends of the tank.
For fire in the storage area, spray water using unmanned hose supports or monitor nozzles to the
heated containers to cool them. If it is not possible, escape from the fire area.
Immediately escape from the fire area if there is noise from the safe exhaust system and color change of
the tank caused by fire.
Keep away at least 0.8 km (half mile) from the fire area if tanks, tank trucks, train are burning.
The efficiency of water may be low. Escape radius for tank, train, tank truck: 0.8km(0.5mile)
Do firefighting after stopping leakage.
The efficiency of water may be low.
Spray high-pressure water to spilled materials to prevent evaporation.
Spray water at safe region.
Avoid inhalation of materials or combustion products.
Stand against the wind and avoid lower region.
No data
Soil :
No data
Water :
4/10
Large leak :
No data
ACGIH :
No data
OSHA :
No data
NIOSH :
No data
No data
2) Engineering management
Ventilation equipment should be explosion-proof if explosive concentrations of dust, vapor or fume are
present.
Install local ventilation system.
Comply with limits.
3) Personal protection equipment
Respiratory protection
Use respiratory protection equipment attached the S mark of KOSHA, Korea.
Air respirator (full facepiece)
Supplied-air respirator (complex airline mask)
Air respirator (pressure-demand type, full facepiece)
Supplied-air respirator (pressure-demand type, full facepiece)
Unknown concentration or emergency :
Take a warning characteristic into consideration before use.
Eyes protection
Safety glasses or goggles are recommended for the eyes protection from dusts or mists.
A business proprietor should install eyes washing facilities near working areas to protect workers eyes for
emergency.
Hands protection
Use proper chemical resistant gloves.
Human body protection
5/10
2) Odor
3) Odor threshold
No data
4) pH
5.4
No data
36~124
7) Flash point
21
8) Evaporation rate
No data
9) Flammability(solid, gas)
No data
150mmHg @ 20
12) Solubility
No data
No data
0.6~0.7 @ 15
No data
230 ~ 260
No data
18) Viscosity
1.002mm2/s @40
No data
6/10
Harmful if inhaled
Ingestion :
Harmful if swallowed
Skin contact :
Eye contact :
2) Delayed and immediate effects and chronic effects from short or long term exposure
Acute oral toxicity
- Oral :
No data
- Dermal :
No data
- Inhalation :
No data
Skin corrosion/irritation :
No data
No data
Respiratory sensitization :
No data
Skin sensitization :
No data
Carcinogenicity :
No data
Reproductive toxicity :
No data
No data
Aspiration hazard :
No data
No data
Crustacea :
No data
Algea :
No data
No data
Degradability :
No data
3) Bioaccumulative potential
Biodegradability :
No data
Bioaccumulation :
No data
7/10
4) Mobility in soil
No data
5) Other adverse effects
No data
F-E
S-E
8/10
Not determined
EC classification
- Classification :
- Risk Phrases :
R34, R65
- Safety Phrases :
S45, S53
U.S. acts
- OSHA (29CFR1910.119) :
Not determined
Not determined
Not determined
Not determined
Not determined
Montreal
protocol :
Not determined
Not determined
Not determined
http://www.inchem.org/documents/icsc/icsc/eics0078.htm
http://www.safe.nite.go.jp/data/sougou/pkc_e_search_frm.html
http://www.inchem.org/documents/icsc/icsc/eics0667.htm
IPCS
http://www.inchem.org/documents/icsc/icsc/eics0559.htm
IPCS
http://www.inchem.org/documents/icsc/icsc/eics0279.htm
IPCS
http://www.inchem.org/documents/icsc/icsc/eics0086.htm
IPCS
http://www.inchem.org/documents/icsc/icsc/eics0657.htm
ASTDR
http://www.atsdr.cdc.gov/toxprofiles/tp67.pdf
ASTDR
http://www.atsdr.cdc.gov/toxprofiles/tp113.pdf
ASTDR
http://www.atsdr.cdc.gov/toxprofiles/tp56.html
IUCLID
http://ecb.jrc.it/esis/index.php?PGM=dat
IUCLID
http://ecb.jrc.it/IUCLID-DataSheets/142825.pdf
IUCLID
http://ecb.jrc.it/IUCLID-DataSheets/110543.pdf
IRIS
http://www.epa.gov/ncea/iris/subst/0436.htm
NOVA Chemicals
http://www.novachem.com/productservices/docs/Benzene_MSDS_EN.pdf
Sciencelab.com
http://www.sciencelab.com/xMSDS-n_heptane-9924237
Sciencelab.com
http://www.sciencelab.com/xMSDS-Toluene-9927301
KOSHA
9/10
10/10