Product description
: Mixture
: Liquid.
Product type
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Petrochemical industry: Petrochemicals. Fuel additive.
1.3 Details of the supplier of the safety data sheet
Supplier/Manufacturer
Telephone no.:
Fax no.
e-mail address of person
responsible for this SDS
: Fuelcare Ltd,
Lancaster Park,
Needwood,
Staffordshire
DE13 9PD
UK
: +44 (0)1283 712263
: +44 (0)1283 262263
: info@fuelcare.com
Lebanon
London UK
Singapore
China
Beijing China
Philadelphia USA
Brazil
Brazil
: 2015-04-01
1/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Mexico
Mexico
In USA, Canada and North America, 24 hour / 7 day emergency response for our product is provided by the
CHEMTREC (R) Emergency Call Center based in the USA
Country information
USA
Signal word
Hazard statements
: Warning
: H351 - Suspected of causing cancer.
H336 - May cause drowsiness or dizziness.
H411 - Toxic to aquatic life with long lasting effects.
Supplemental label
elements
Precautionary statements
General
Prevention
Response
Storage
Disposal
Hazardous ingredients
: 2015-04-01
2/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
: Not applicable.
: Yes, applicable.
: None known.
Substance/mixture
Classification
Product/ingredient
name
Identifiers
Solvent naphtha
(petroleum), heavy
arom.
67/548/EEC
REACH #:
01-2119463583-34
EC: 265-198-5
CAS: 64742-94-5
Index: 649-424-00-3
Solvent naphtha
REACH #:
(petroleum), heavy
01-2119463588-24
arom.
EC: 265-198-5
CAS: 64742-94-5
Index: 649-424-00-3
1,2,4-trimethylbenzene REACH #: Compliant
EC: 202-436-9
CAS: 95-63-6
Index: 601-043-00-3
>=25 <35
Xn; R65
R66, R67
N; R51/53
>=10 <15
Xn; R65
R66, R67
N; R51/53
>=1 <2.5
R10
Xn; R20
Xi; R36/37/38
N; R51/53
naphthalene
REACH #: Compliant
EC: 202-049-5
CAS: 91-20-3
Index: 601-052-00-2
>=1 <2.5
2,6-di-tert-butylphenol
REACH #: Compliant
EC: 204-884-0
CAS: 128-39-2
2,4,6-tri-tertbutylphenol
REACH #: Compliant
EC: 211-989-5
CAS: 732-26-3
0.09 - 0. N; R50/53
99
3,6,
REACH #:
01-2119487290-37
EC: 203-986-2
CAS: 112-57-2
Index: 612-060-00-0
>=0.1 <0.25
9-triazaundecamethylenediamine
: 2015-04-01
Xn; R21/22
C; R34
R43
N; R51/53
Type
[1] [2]
[1] [2]
[1] [2]
[1] [2]
[1]
[1]
[1]
3/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Additional information
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
: 2015-04-01
4/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Skin contact
Ingestion
: No specific data.
: Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
: Adverse symptoms may include the following:
irritation
dryness
cracking
: No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment.
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
: 2015-04-01
5/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. Collect spillage.
Advice on general
occupational hygiene
: Put on appropriate personal protective equipment (see Section 8). Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapour or mist. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on
hygiene measures.
: Store in accordance with local regulations. Store in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10). Store locked up. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store
in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
: 2015-04-01
6/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
: Not available.
: Not available.
Recommended monitoring
procedures
DNELs/DMELs
Product/ingredient name
1,2,4-trimethylbenzene
Type
Exposure
: 2015-04-01
Value
Population
Effects
Systemic
Local
Systemic
Systemic
Local
Systemic
Local
Systemic
15 mg/kg
bw/day
Consumers
Systemic
Systemic
7/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
naphthalene
Local
3.57 mg/
kg bw/day
25 mg/m
Workers
Systemic
Workers
Systemic
25 mg/m
Workers
Local
Systemic
Systemic
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Local
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Local
PNECs
Product/ingredient name
Type
1,2,4-trimethylbenzene
Compartment Detail
Value
Method Detail
0.12 mg/l
0.12 mg/l
2.41 mg/l
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits.
Individual protection measures
: 2015-04-01
8/18
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Octamar (TM) LI-5 Plus (Public)
Eye/face protection
Skin protection
Hand protection
Body protection
Respiratory protection
Environmental exposure
controls
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with sideshields. Recommended: splash goggles
: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be different
for different glove manufacturers. In the case of mixtures, consisting of several
substances, the protection time of the gloves cannot be accurately estimated. > 8
hours (breakthrough time): Viton
1 - 4 hours (breakthrough time): nitrile rubber
: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by
a specialist before handling this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator. Recommended: organic vapour
filter (Type A)
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
: Liquid.
: Amber.
: Aromatic.
: Not available.
: Not available.
: Not available.
: Lowest known value: 168.01C (334.4F) (1,2,4-trimethylbenzene). Weighted
average: 204.29C (399.7F)
Flash point
Evaporation rate
: Not available.
: Not applicable.
: Not applicable.
Upper/lower flammability or
explosive limits
Odour
Odour threshold
pH
: 2015-04-01
9/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Vapour pressure
Vapour density
Relative density
Density
Solubility(ies)
Explosive properties
Oxidising properties
: Not available.
: Not available.
: <-40C
: No specific test data related to reactivity available for this product or its ingredients.
10.3 Possibility of
hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
: No specific data.
: No specific data.
10.6 Hazardous
decomposition products
Solvent naphtha
(petroleum), heavy arom.
naphthalene
Test
Species
Rat
Rabbit
Rat
Rat
Rabbit
Rat
Rat
Rabbit
: 2015-04-01
Result
LC50
Inhalation
Vapour
LD50
Dermal
LDLo Oral
LC50
Inhalation
Vapour
LD50
Dermal
LDLo Oral
LC50
Inhalation
Vapour
LD50
Dose
>590 mg/m
>2 mL/kg
5 mL/kg
>590 mg/m
>2 mL/kg
5 mL/kg
>340 mg/m
>2000 mg/kg
10/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Rat
2,6-di-tert-butylphenol
Rat
Rabbit
2,4,6-tri-tert-butylphenol
3,6,
Rat
Rat
Rat
Rat
Dermal
LD50
Dermal
LD50 Oral
LD50
Dermal
LD50 Oral
LD50 Oral
LD50
Dermal
LD50 Oral
9-triazaundecamethylenediamine
>2500 mg/kg
490 mg/kg
>10000 mg/kg
>5000 mg/kg
1610 mg/kg
1260 mg/kg
2100 to 3990 mg/kg
Irritation/Corrosion
Product/ingredient name
Solvent naphtha
(petroleum), heavy arom.
Test
-
Solvent naphtha
(petroleum), heavy arom.
2,6-di-tert-butylphenol
3,6,
Species
Rabbit
Result
Skin - Mild irritant
-
Mammal species
unspecified
Rabbit
Mammal species
unspecified
Rat
Rabbit
Rabbit
9-triazaundecamethylenediamine
Sensitisation
Product/ingredient name
3,6,
Test
-
Species
Guinea pig
Sensitising
Result
-
9-triazaundecamethylenediamine
Test
Species
Result
Dose
Rat
LOAEL
43 mg/kg
Rabbit
LOAEL
50 mg/kg
9-triazaundecamethylenediamine
Mutagenicity
Product/ingredient name
3,6,
Test
-
Experiment
Experiment: In vivo
Subject: Mammalian-Animal
9-triazaundecamethylenediamine
Result
Negative
Reproductive toxicity
Product/ingredient name
3,6,
Test
-
9-triazaundecamethylenediamine
Species
Mammal species
unspecified
Mammal species
unspecified
Result
Dose
: Not available.
: 2015-04-01
11/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Skin contact
Ingestion
: Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. Exposure to decomposition products may cause a health hazard. Serious
effects may be delayed following exposure.
: Defatting to the skin. May cause skin dryness and irritation.
: Can cause central nervous system (CNS) depression.
Skin contact
Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
effects
Potential delayed effects
Long term exposure
Potential immediate
effects
Potential delayed effects
: Not available.
: Not available.
: Not available.
: Not available.
Mutagenicity
: Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
: Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
: No known significant effects or critical hazards.
Teratogenicity
Developmental effects
Fertility effects
General
Carcinogenicity
Test
Algae
Daphnia
Fish
Algae
Daphnia
Species
Fish
: 2015-04-01
Exposure
72
hours
48
hours
96
hours
72
hours
48
hours
96
Result
Acute EC50 1 to 3 mg/l
Acute EC50 3 to 10 mg/l
Acute LC50 2 to 5 mg/l
Acute EC50 1 to 3 mg/l
Acute EC50 3 to 10 mg/l
Acute LC50 2 to 5 mg/l
12/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Fish - Pimephales
promelas
Daphnia - Water flea Daphnia magna
Crustaceans Daggerblade grass
shrimp Palaemonetes pugio
Fish - Oncorhynchus
mykiss
Algae
naphthalene
Daphnia
Fish
Algae
3,6,
9-triazaundecamethylenediamine
hours
96
hours
48
hours
48
hours
96
hours
72
hours
48
hours
96
hours
-
Aquatic half-life
Photolysis
Biodegradability
Inherent
Inherent
<1 day(s)
-
Inherent
Not readily
Not readily
9-triazaundecamethylenediamine
LogPow
BCF
Potential
<100
low
<100
low
4.09
3.3
4.92
6.06
-3.16
275
>100
434.9
3282
-
low
low
low
high
low
9-triazaundecamethylenediamine
: Not available.
Mobility
: Not available.
: Not applicable.
: Not applicable.
: No known significant effects or critical hazards.
: 2015-04-01
13/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Methods of disposal
Hazardous waste
Packaging
Methods of disposal
Special precautions
ADN
IMDG
IATA
14.1 UN number
UN3082
UN3082
UN3082
UN3082
14.2 UN proper
shipping name
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (Solvent
naphtha (petroleum),
heavy arom.,
naphthalene)
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (Solvent
naphtha (petroleum),
heavy arom.,
naphthalene)
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (Solvent
naphtha (petroleum),
heavy arom.,
naphthalene). Marine
pollutant (Solvent
naphtha (petroleum),
heavy arom.,
naphthalene)
Environmentally
hazardous substance,
liquid, n.o.s. (Solvent
naphtha (petroleum),
heavy arom.,
naphthalene)
III
III
III
III
14.5 Environmental
hazards
Yes.
Yes.
Yes.
Yes.
The environmentally
hazardous substance
mark is not required
when transported in
sizes of 5 L or 5 kg.
The environmentally
hazardous substance
mark is not required
when transported in
sizes of 5 L or 5 kg.
Additional information
Hazard identification
number
90
Limited quantity
Date of issue/Date of revision
: 2015-04-01
Emergency
schedules (EmS)
F-A, S-F
Special provisions
274, 335
14/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
Not available.
200
200
500
500
: Not listed
: Listed
: Not listed
Integrated pollution
prevention and control
list (IPPC) - Water
: Not listed
Product/ingredient name
Carcinogenic
effects
Carc. 2, H351
naphthalene
Chemical Weapons
Convention List Schedule I
Chemicals
: Not listed
Chemical Weapons
Convention List Schedule II
Chemicals
: Not listed
: 2015-04-01
Mutagenic effects
-
Developmental
effects
-
Fertility effects
-
15/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
International lists
Australia inventory (AICS)
Canada inventory
China inventory (IECSC)
EU Inventory (EINECS/
ELINCS/NLP)
Japan inventory (ENCS)
Korea inventory (KECI)
New Zealand Inventory of
Chemicals (NZIoC)
Philippines inventory
(PICCS)
Taiwan inventory (TCSI)
United States inventory
(TSCA 8b)
: Not listed
: This product contains substances for which Chemical Safety Assessments are still
required.
Indication of danger
Classification
Carc. 2, H351
STOT SE 3, H336 (Narcotic effects)
Aquatic Chronic 2, H411
: 2015-04-01
Justification
Calculation method
Calculation method
Calculation method
16/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
: H226
H302
H304
H312
H314
H315
H317
H318
H319
H332
(inhalation)
H335
(Respiratory
tract
irritation)
H336
(Narcotic
effects)
H351
Suspected of causing cancer.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H411
Toxic to aquatic life with long lasting effects.
: Acute Tox. 4, H302
ACUTE TOXICITY (oral) - Category 4
Acute Tox. 4, H312
ACUTE TOXICITY (dermal) - Category 4
Acute Tox. 4, H332
ACUTE TOXICITY (inhalation) - Category 4
Aquatic Acute 1, H400
ACUTE AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410 LONG-TERM AQUATIC HAZARD - Category 1
Aquatic Chronic 2, H411 LONG-TERM AQUATIC HAZARD - Category 2
Asp. Tox. 1, H304
ASPIRATION HAZARD - Category 1
Carc. 2, H351
CARCINOGENICITY - Category 2
Eye Dam. 1, H318
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 3, H226
FLAMMABLE LIQUIDS - Category 3
Skin Corr. 1B, H314
SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2, H315
SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317
SKIN SENSITIZATION - Category 1
STOT SE 3, H335
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
(Respiratory tract
EXPOSURE) (Respiratory tract irritation) - Category 3
irritation)
STOT SE 3, H336
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
(Narcotic effects)
EXPOSURE) (Narcotic effects) - Category 3
: R10- Flammable.
R40- Limited evidence of a carcinogenic effect.
R20- Harmful by inhalation.
R22- Harmful if swallowed.
R21/22- Harmful in contact with skin and if swallowed.
R65- Harmful: may cause lung damage if swallowed.
R34- Causes burns.
R38- Irritating to skin.
R36/37/38- Irritating to eyes, respiratory system and skin.
R43- May cause sensitisation by skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
: Carc. Cat. 3 - Carcinogen category 3
C - Corrosive
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
: 2015-04-01
17/18
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Octamar (TM) LI-5 Plus (Public)
: 2015-04-01
: 2015-04-01
: 2015-04-01
: 1.01
Emergency contact numbers for local language support in Asia Pacific region
Country information
Languages supported
Telephone no.:
Location
Australia
English
Australia
Bangladesh
Bengali, English
Singapore
Brazil
Portuguese, English
Brazil
China
Mandarin, English
Beijing China
India
Hindi, English
Singapore
Indonesia
Japanese, English
Japan
Korea
Korean, English
Singapore
Malaysia
Malaysia
Mexico
Spanish, English
Mexico
New Zealand
English
New Zealand
Pakistan
Urdu, English
Singapore
Philippines
Tagalog, English
Singapore
Sri Lanka
Sinhalese, English
Singapore
Thai, English
Thailand
Vietnamese, English
Singapore
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
: 2015-04-01
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